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JP2018177311A - Cold insulated container - Google Patents

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JP2018177311A
JP2018177311A JP2017080555A JP2017080555A JP2018177311A JP 2018177311 A JP2018177311 A JP 2018177311A JP 2017080555 A JP2017080555 A JP 2017080555A JP 2017080555 A JP2017080555 A JP 2017080555A JP 2018177311 A JP2018177311 A JP 2018177311A
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container
cold
vacuum
heat insulating
inner container
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JP7170297B2 (en
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雅享 後藤
Masayuki Goto
雅享 後藤
一男 橋本
Kazuo Hashimoto
一男 橋本
橋本 義之
Yoshiyuki Hashimoto
義之 橋本
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Japan Aerospace Exploration Agency JAXA
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Abstract

【課題】外部電源を用いない場合や、外部電源が使用できない環境下においても、内部温度の変化を長期間抑制することができる保冷保温容器を提供すること。【解決手段】本発明の保冷保温容器は、被保冷保温物が収容される収容部を有し、断熱素材を備えた開口可能な内側容器と、前記内側容器を収容し、断熱素材を備えた開口可能な外側容器と、を備え、前記内側容器の収容時に、前記内側容器の外面と前記外側容器の内面とが隙間なく対向して配置され、前記被保冷保温物の収容時に、前記内側容器の内面と前記被保冷保温物との間に保冷保温剤が配置された、保冷保温容器である。【選択図】図1PROBLEM TO BE SOLVED: To provide a cold and heat insulating container capable of suppressing a change in internal temperature for a long period of time even when an external power source is not used or in an environment where an external power source cannot be used. SOLUTION: The cold and heat insulating container of the present invention has a storage portion for accommodating a cold and heat insulating material, and has an openable inner container having a heat insulating material and the inner container having the heat insulating material. The inner container is provided with an openable outer container, and the outer surface of the inner container and the inner surface of the outer container are arranged so as to face each other without a gap when the inner container is housed. A cold and heat insulating container in which a cold and heat insulating agent is arranged between the inner surface of the container and the cold and heat insulating material. [Selection diagram] Fig. 1

Description

本発明は、被保冷保温物を収容して保冷保温する保冷保温容器に関する。   BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to a cold storage / heat storage container for storing a cold storage / retaining material and for cold storage / warming.

従来より、被保冷保温物を収容して保冷保温する保冷保温容器が知られている。例えば保冷の場合には、保冷剤を用いて食品その他の低温を維持することが望ましい被保冷物を保冷することが行われており、被保冷物が収容される収容部を有する保冷保温容器に、保冷剤を被保冷物とともに収容し、保冷剤が相変化する時の吸熱現象を利用して被保冷物を保冷することが行われている。   DESCRIPTION OF RELATED ART Conventionally, the cold preservation heat retention container which accommodates a cold preservation heat retention thing, and carries out cold preservation heat retention is known. For example, in the case of cold preservation, cold preservation is performed using a cold insulator to keep food or other cold matter to be kept cold, and a cold keeping warm container having a storage portion in which the cold matter is stored. In some cases, a cold storage agent is stored together with a cold storage material, and the cold storage material is cold stored using an endothermic phenomenon when the cold storage material undergoes a phase change.

このような保冷保温容器においては、保冷剤の冷気が被保冷保温物に効率的に伝達されるように、保冷容器の内面に伝熱板を配置することが考えられる。例えば、特許文献1の発明においては、保冷容器の内面の全てに保冷剤を配置するとともに、この保冷剤の表面に伝熱板を配置することが考えられている。   In such a cold storage and heat retention container, it is conceivable to dispose a heat transfer plate on the inner surface of the cold storage container so that the cold air of the cold storage agent can be efficiently transmitted to the cold storage and retention material. For example, in invention of patent document 1, while arrange | positioning a cold-storage agent on all the inner surfaces of a cold-storage container, arrange | positioning a heat exchanger plate on the surface of this cold-storage agent is considered.

また、その改良技術が特許文献2に開示され、そこにおいて伝熱板は、前記収容部の内側面及び前記蓋部による天面のうち少なくとも内側面に設けられ、該内側面においては上端側のみに設けられている。   Further, the improvement technique is disclosed in Patent Document 2, in which the heat transfer plate is provided on at least the inner side surface of the inner side surface of the housing portion and the top surface by the lid portion, and on the inner side surface, only the upper end side Provided in

さらに、特許文献3には、底面部及び側面部を有する金属製の内筒容器と、天面部及び側面部を有する金属製の外筒蓋体とを少なくとも有する保冷容器であって、該内筒容器の底面部内及び側面部内と、該外筒蓋体の天面部内及び側面部内は、真空二重壁構造により形成された真空断熱部がそれぞれ設けられ、該内筒容器に外筒蓋体を被せて一体化した際、保冷容器の側面部おいて、該内筒容器と該外筒蓋体が有する真空断熱部が重なり合うようにした保冷容器が開示されている。
また、特許文献4には、外容器と内容器の二重殻構造となっており、外容器内側底部と上部には内容器が移動しないように柔軟性のある底部支持板と上部支持板を収めており、内容器本体内は温度管理対象物を中心として側面には蓄冷材を収めた温度管理対象物と密着するような形状を呈した蓄冷材側面設置用容器を配し、底面には蓄冷材を収めた上下面を硬く且つ変形しない強度を持つ材料で挟んだ耐振動性や耐衝撃性のある柔軟な緩衝材の蓄冷材底面設置用容器を配し、上面には温度管理対象物上面をすべて覆う板状の蓄冷材を配している構造となっており、外容器及び内容器の蓋を開けた状態で温度管理対象物及び蓄冷材を内容器上方から直接出し入れ出来るように配置された保冷容器が開示されている。
加えて、発泡スチロール、発泡ウレタン等の発泡合成樹脂の断熱材を用いた容器本体と蓋体とから構成される保冷容器において、少なくとも前記容器本体の周壁内面全周に蓄冷剤を取り付けたことを特徴とする保冷容器が特許文献5に開示されている。
Furthermore, Patent Document 3 is a cold storage container having at least a metal inner cylinder container having a bottom surface and a side surface, and a metal outer cylinder lid having a top surface and a side surface, wherein the inner cylinder is A vacuum heat insulating portion formed of a vacuum double wall structure is provided in the bottom and side portions of the container, and in the top and side surfaces of the outer cylinder lid, respectively, and the outer cylinder lid is attached to the inner cylinder container. There is disclosed a cold storage container in which the inner cylindrical container and the vacuum heat insulating portion of the outer cylindrical lid overlap each other at the side surface portion of the cold storage container when covered and integrated.
Further, Patent Document 4 has a double shell structure of an outer container and an inner container, and a bottom support plate and an upper support plate having flexibility so as to prevent the inner container from moving in the inner container bottom and upper portions. In the inner container main body, a container for installing a side of a cold storage material, which has a shape that closely adheres to a temperature control target containing a cold storage material, is disposed on the side surface centering on the temperature control target. A container for installing a cold storage material of a shock absorbing and flexible shock absorbing material sandwiched between upper and lower surfaces containing a cold storage material between hard and non-deformable materials is disposed, and the upper surface is a temperature controlled object It has a structure in which a plate-shaped regenerator material covering all the upper surface is disposed, and arranged so that the temperature control object and the regenerator material can be taken in and out directly from above the inner container with the lids of the outer and inner containers opened. A cold insulated container is disclosed.
In addition, a cold storage container composed of a container body and a lid using a heat insulating material of foam synthetic resin such as polystyrene foam, urethane foam, etc. is characterized in that a cold storage material is attached to at least the entire inner peripheral surface of the peripheral wall of the container body. Patent Document 5 discloses a cold insulating container as described above.

特開2004−43020号公報JP 2004-43020 A 特開2013−203461号公報JP, 2013-203461, A 実用新案登録第3206726号公報Utility model registration 3206726 gazette 特開2014−84176号公報JP 2014-84176 A 実開昭61−151177号公報Japanese Utility Model Application Publication No. 61-151177

上述した保冷容器においては、断熱性能が十分ではないなどの理由により、長期間内部温度を維持することが難しい場合がある。これに対して、例えば冷凍機と外部電源などを用いて保冷容器の内部温度を長期間維持する保冷手段が考えられる。しかしながら、電源がない場所や電源が使用できない空間などにおいては、外部電源を用いた保冷容器は保温機能を十分に発揮することができないという問題があった。   In the cold storage container mentioned above, it may be difficult to maintain the internal temperature for a long time because the insulation performance is not sufficient. On the other hand, the cold storage means which maintains the internal temperature of a cold storage container for a long period of time, for example using a refrigerator and an external power supply etc. can be considered. However, in a place without a power source or in a space where a power source can not be used, there is a problem that a cold storage container using an external power source can not sufficiently exhibit the heat retention function.

本発明は、上述した問題点に鑑みてなされたものであって、外部電源を用いない場合や、外部電源が使用できない環境下においても、内部温度の変化を長期間抑制することができる保冷保温容器を提供することを目的とする。   The present invention has been made in view of the above problems, and it is possible to suppress the change in the internal temperature for a long time even when the external power supply is not used or in an environment where the external power supply can not be used. Intended to provide a container.

上記目的を達成するために本発明の保冷保温容器は、被保冷保温物が収容される収容部を有し、真空断熱材を備えた開口可能な内側容器と、内側容器を収容し、真空断熱材を備えた開口可能な外側容器と、を備え、内側容器の収容状態で、内側容器の外面と外側容器の内面とが実質的に隙間なく対向して配置され、被保冷保温物の収容状態で、内側容器の内面と被保冷保温物との間に保冷保温剤が配置された、保冷保温容器であることを特徴とするものである。   In order to achieve the above object, the cold and heat insulating container of the present invention has a housing portion in which a cold and heat insulating material is housed, and an openable inner container provided with a vacuum heat insulating material and an inner container are accommodated. And an openable outer container provided with a material, the outer container and the inner container of the inner container being disposed substantially facing each other with substantially no gap in the storage condition of the inner container, and the storage condition of the cold keeping material The container is characterized in that the container is a cold-held thermal container, wherein a cold-insulating thermal agent is disposed between the inner surface of the inner container and the cold-held thermal material.

本発明の保冷保温容器においては、内側容器の収容状態で、内側容器の一端に形成された開口部の少なくとも一部が、外側容器の端部近傍に配置され、かつ、外側容器の一端に形成された開口部の少なくとも一部が、内側容器の端部近傍に配置されていてもよい。   In the cold storage container according to the present invention, at least a part of the opening formed at one end of the inner container is disposed in the vicinity of the end of the outer container and is formed at the one end of the outer container. At least a portion of the opening may be located near the end of the inner container.

本発明の保冷保温容器においては、内側容器の内面と被保冷保温物との間に隙間なく前記保冷保温剤が敷設されていてもよい。   In the cold preservation heat retention container of the present invention, the above-mentioned cold retention heat insulation agent may be laid without a crevice between the inner surface of an inner side container, and the cold preservation heat retention thing.

本発明の保冷保温容器においては、内側容器の真空断熱材及び/又は外側容器の真空断熱材が、グラスウール、シリカ粉末、及びウレタンフォームの、少なくとも一つ又は複数を芯材とした真空断熱材であってもよい。   In the cold preservation heat retention container of the present invention, the vacuum heat insulation material of the inner container and / or the vacuum heat insulation material of the outer container is a vacuum heat insulation material having at least one or more of glass wool, silica powder and urethane foam as a core material. It may be.

本発明の保冷保温容器においては、内側容器の真空断熱材及び/又は外側容器の真空断熱材が、それぞれ実質的に均一な厚さの複数枚の真空断熱材からなり、内側容器及び外側容器の底部において複数枚の真空断熱材が積層され、内側容器及び外側容器の側壁において、底部に積層された真空断熱材の枚数の二分の一の真空断熱材が積層されていてもよい。   In the cold insulation container according to the present invention, the vacuum insulation of the inner container and / or the vacuum insulation of the outer container comprises a plurality of vacuum insulators of substantially uniform thickness respectively, and the inner container and the outer container A plurality of vacuum heat insulating materials may be stacked at the bottom, and a half of the number of vacuum heat insulating materials stacked at the bottom may be stacked on the side walls of the inner and outer containers.

本発明の保冷保温容器においては、内側容器の真空断熱材及び/又は外側容器の真空断熱材が、複数枚の真空断熱材からなり、複数枚の真空断熱材のそれぞれの端部が実質的に重ならないように積層されていてもよい。   In the cold preservation heat retention container of the present invention, the vacuum heat insulation material of the inner container and / or the vacuum heat insulation material of the outer container is composed of a plurality of vacuum heat insulation materials, and each end of the plurality of vacuum heat insulation materials is substantially It may be laminated so as not to overlap.

本発明の保冷保温容器においては、内側容器の真空断熱材及び/又は外側容器の真空断熱材が、内側容器及び/又は外側容器の角部において折り曲げられていてもよい。本発明の保冷保温容器においては、内側容器の端部近傍が、内側容器の底部であり、及び/又は外側容器の端部近傍が、外側容器の底部であってもよい。本発明の保冷保温容器においては、内側容器の真空断熱材及び/又は外側容器の真空断熱材が、実質的にL字状、U字状又はコの字状に折り曲げた状態で配置されていてもよい。本発明の保冷保温容器においては、内側容器の真空断熱材の端部と、内側容器の真空断熱材に隣接する前記外側容器の真空断熱材の端部とが全体として重ならないように積層されていてもよい。本発明の保冷保温容器においては、内側容器の真空断熱材及び/又は外側容器の真空断熱材が、複数枚の真空断熱材からなり、隣接する真空断熱材がそれぞれの端部が全体として重ならないように積層されていてもよい。本発明の保冷保温容器においては、真空断熱材のそれぞれの端部が、真空断熱材のそれぞれの周縁部であり、周縁部がそれぞれ真空断熱材の厚さ方向からみて全体として一致しないように積層されていてもよい。   In the cold storage container according to the present invention, the vacuum insulation of the inner container and / or the vacuum insulation of the outer container may be bent at the corners of the inner container and / or the outer container. In the cold storage container according to the present invention, the vicinity of the end of the inner container may be the bottom of the inner container and / or the vicinity of the end of the outer container may be the bottom of the outer container. In the cold preservation heat retention container of the present invention, the vacuum heat insulation material of the inner container and / or the vacuum heat insulation material of the outer container is disposed in a substantially L-shaped, U-shaped or U-shaped bent state It is also good. In the cold preservation heat retention container of the present invention, the end of the vacuum heat insulation material of the inner container and the end of the vacuum heat insulation material of the outer container adjacent to the vacuum heat insulation of the inner container are laminated so as not to overlap as a whole. May be In the cold preservation heat retention container of the present invention, the vacuum heat insulating material of the inner container and / or the vacuum heat insulating material of the outer container is composed of a plurality of vacuum heat insulating materials, and adjacent vacuum heat insulating materials do not overlap as a whole. May be laminated. In the cold preservation heat retention container of the present invention, the respective end parts of the vacuum heat insulating material are the respective peripheral parts of the vacuum heat insulation material, and the peripheral parts are laminated so that they do not match as a whole in the thickness direction of the vacuum heat insulation material. It may be done.

本発明によれば、外部電源を用いない場合や、外部電源が使用できない環境下においても、内部温度の変化を長期間抑制することができる保冷保温容器を提供することができる。   According to the present invention, it is possible to provide a cold insulation container capable of suppressing a change in internal temperature for a long time even when an external power supply is not used or in an environment where the external power supply can not be used.

本発明の保冷保温容器の実施の一形態である保冷容器を示すものであり、内側容器と外側容器、被収容物の収納容器を取り囲む保冷剤の関係を示す斜視図である。It is a perspective view which shows the cold-storage container which is one form of embodiment of the cold-storage thermal container of this invention, and is a perspective view which shows the relationship of the cold-storage agent surrounding the storage container of an inner side container and an outer side container, and an accommodation thing. 図1の保冷容器において、内側容器と外側容器、被収容物の収納容器の収容関係を示す斜視図である。The cold storage container of FIG. 1 WHEREIN: It is a perspective view which shows the accommodation relationship of an inner side container, an outer side container, and the storage container of a thing to be accommodated. 図1の保冷容器の収容状態を示す斜視図である。It is a perspective view which shows the accommodation state of the cold-storage container of FIG. 図3の正面図である。It is a front view of FIG. 図3のA−A断面図である。It is AA sectional drawing of FIG. 図3のB−B断面図である。It is a BB sectional view of FIG. 複数の断熱材の配置の一例を示す概略図である。It is the schematic which shows an example of arrangement | positioning of several heat insulating materials. 実施例の実験結果を示すグラフである。It is a graph which shows the experimental result of an Example.

以下に、本発明の保冷保温容器の実施の形態について、保冷容器を例として、図面を参照して説明するが、保温容器としても同様の構成を備えることができる。なお、本発明は以下の実施形態によって限定的に解釈されるものではない。   Hereinafter, the embodiment of the cold storage / heat storage container of the present invention will be described by taking the cold storage container as an example with reference to the drawings, but the same configuration can be provided as a heat storage container. The present invention is not to be interpreted limitedly by the following embodiments.

本実施形態の保冷容器11は、図1及び図2に示すように、被保冷物を収納する収納容器(試料収納ボックス)21が収容される収容部12aを有する一端を開口した、真空断熱材からなる内側容器12と、該内側容器12を開口部側から収容する収容部13aを有する一端を開口した真空断熱材からなる外側容器13とを備えている。図において内側容器12及び外側容器13は、いずれも底部12b、13bが形成されている。
また、前記内側容器12の底部12bの内面側及び側壁の内面側(内壁)に沿って保冷剤を収納した複数の保冷剤収容用板状容器22を連続させて敷設した状態において、被保冷物収納容器21を内側容器12内に収容し、その上で内側容器12を外側容器13内に収容・保持されている。
The cold storage container 11 of the present embodiment, as shown in FIGS. 1 and 2, is a vacuum heat insulating material having an opening at one end having a storage portion 12a in which a storage container (sample storage box) 21 for storing a material to be stored is stored. And an outer container 13 made of a vacuum heat insulating material having an opening at one end having a housing portion 13a for housing the inner container 12 from the opening side. In the drawing, the inner container 12 and the outer container 13 both have bottoms 12b and 13b.
Further, in a state in which a plurality of plate containers 22 for storing a cold storage agent containing a cold storage agent are continuously laid along the inner surface side of the bottom portion 12 b of the inner container 12 and the inner surface side (inner wall) of the side wall The storage container 21 is accommodated in the inner container 12, and the inner container 12 is accommodated and held in the outer container 13 thereon.

本実施形態の保冷容器11において、内側容器12の外側容器13への収容時には、内側容器12の外面12cと外側容器13の内面13cとが実質的に隙間なく対向して配置されている。内側容器12の外面12cの少なくとも一部と、外側容器13の内面13cの少なくとも一部とは、実質的に対流が生じない限り接していなくてもよい。内側容器12の外面12cと、外側容器13の内面13cとがクリアランスがほとんどない密接した状態(好ましくは隙間が0mm)で、内側容器12が外側容器13へ収容されていてもよい。これにより、内側容器12の外面12cと、外側容器13の内面13cとの間への空気の侵入を防止することができ、空気の対流による保冷容器11内の温度変化を抑制することができる。   In the cold storage container 11 of the present embodiment, when the inner container 12 is stored in the outer container 13, the outer surface 12 c of the inner container 12 and the inner surface 13 c of the outer container 13 are disposed substantially facing each other without a gap. At least a portion of the outer surface 12 c of the inner container 12 and at least a portion of the inner surface 13 c of the outer container 13 may not be in contact with each other as long as no convection occurs. The inner container 12 may be accommodated in the outer container 13 with the outer surface 12 c of the inner container 12 and the inner surface 13 c of the outer container 13 in close contact (preferably with a gap of 0 mm) with almost no clearance. In this way, air can be prevented from entering between the outer surface 12 c of the inner container 12 and the inner surface 13 c of the outer container 13, and temperature change in the cold storage container 11 due to air convection can be suppressed.

また、本実施形態の保冷容器11においては、内側容器12の収容時に、内側容器12の一端に形成された開口部12aの少なくとも一部が、外側容器13の端部近傍(例えば底部13bの内面側の近傍)に配置され、かつ、外側容器13の一端に形成された開口部13aの少なくとも一部が、内側容器12の端部近傍(例えば底部12bの外面側の近傍)に配置されていることが好ましい。これにより、内側容器12と外側容器13との間への空気の侵入を防止することができ、空気の対流による保冷容器11内の温度変化を抑制することができる。また、内側容器12の断熱素材と、外側容器13の断熱素材との重畳する領域が増加し、保冷容器11の断熱性が向上する傾向にある。   Further, in the cold storage container 11 of the present embodiment, at least a part of the opening 12a formed at one end of the inner container 12 when the inner container 12 is accommodated is in the vicinity of the end of the outer container 13 (for example, the inner surface of the bottom 13b) ) And at least a part of the opening 13a formed at one end of the outer container 13 is arranged near the end of the inner container 12 (for example, near the outer surface of the bottom 12b) Is preferred. Thereby, the penetration | invasion of air between the inner side container 12 and the outer side container 13 can be prevented, and the temperature change in the cold storage container 11 by the convection of air can be suppressed. Moreover, the area | region which the heat insulation raw material of the inner side container 12 and the heat insulation raw material of the outer side container 13 overlap overlaps, and it exists in the tendency for the heat insulation of the cold storage container 11 to improve.

本実施形態の保冷容器11においては、真空断熱材を用いる。内側容器12及び/又は外側容器13を構成する真空断熱材としては、特に限定されるものではなく公知の真空断熱材を用いることができる。特に、グラスウールを芯材とした真空断熱材、例えばビップエース(VIP−A、商品名:旭ファイバーグラス株式会社製)が好適に使用される。なお、真空断熱材の芯材としては、グラスウールに限定されず、公知の任意の芯材、例えば、グラスウール、シリカ粉末、及びウレタンフォームの、少なくとも一つ又は複数を用いることもできる。   A vacuum heat insulating material is used in the cold storage container 11 of the present embodiment. It does not specifically limit as a vacuum heat insulating material which comprises the inner container 12 and / or the outer container 13, A well-known vacuum heat insulating material can be used. In particular, a vacuum heat insulating material having glass wool as a core material, for example, Vip-Ace (VIP-A, trade name: manufactured by Asahi Fiber Glass Co., Ltd.) is suitably used. In addition, as a core material of a vacuum heat insulating material, it is not limited to glass wool, For example, at least one or more of well-known arbitrary core materials, for example, glass wool, a silica powder, and a urethane foam, can also be used.

保冷容器11においては、内側容器12の内底部及び内壁に沿って連続させて敷設した保冷剤を収納した複数の保冷剤収納用板状容器22中、内底部の保冷剤収納用板状容器22aはその周囲に段差22bを形成されている。したがって、当該段差22b部分に側壁部分の保冷剤収納用板状容器22の端部を組み付けることにより、前記内側容器12の内底部及び内壁に沿って隙間なく敷設することができる。なお、保冷剤は、内側容器12の内底部及び内壁に沿って連続させて敷設したものとしたが、完全に連続させて敷設する必要はない。例えば、内側容器12の内底部及び内壁の合計表面積に対して、好ましくは90%以上、より好ましくは95%以上を保冷剤で覆えばよい。   In the cold storage container 11, a plate-shaped container 22a for storing a cold storage agent at an inner bottom portion among a plurality of cold storage containers 22 for storing a cold storage agent, which stores a cooling agent laid continuously along the inner bottom portion and the inner wall of the inner container 12. A step 22b is formed on the periphery thereof. Therefore, by assembling the end portion of the plate for cold storage container 22 of the side wall portion to the step 22b, it can be laid along the inner bottom portion and the inner wall of the inner container 12 without a gap. In addition, although a cold-preserving agent shall be continuously made and installed along the inner bottom part and inner wall of the inner side container 12, it is not necessary to make it completely continuous and to lay. For example, preferably, 90% or more, more preferably 95% or more of the total surface area of the inner bottom portion and the inner wall of the inner container 12 may be covered with a coolant.

本実施形態に係る保冷剤について説明する。保冷剤としては、特に制限されることなく公知のものを用いることができ、目的とする保冷温度に応じて選択することが好ましい。
例えば、15℃〜0℃程度の低温域で被保冷物の温度を保つことが可能な含水ゲル状の保冷剤組成物が知られている(特開平8−325563号公報)。
また、例えば、−50℃〜−20℃程度の低温域で被保冷物の温度を保つことが可能な保冷剤として、固体状態の二酸化炭素であるドライアイスが知られている。
さらに、−80℃以下のような極低温域で用いる保冷剤としては、水と、塩化リチウム及び塩化ナトリウムを含有する溶質とを含み、溶質の各成分の中で塩化リチウムの重量換算における含有割合が最も高いもの、水と、塩化リチウム及び塩化カリウムを含有する溶質とを含み、溶質の各成分の中で塩化リチウムの重量換算における含有割合が最も高いもの、又は水と、塩化リチウム及び塩化ナトリウム、並びに、塩化カリウム、塩化アンモニウム及び硝酸カリウムからなる群より選ばれた1種を含有する溶質とを含み、溶質の各成分の中で塩化リチウムの重量換算における含有割合が最も高いものである(特願2016−007002号参照)。
The cold storage agent according to the present embodiment will be described. As a cold-preserving agent, a well-known thing can be used, without being restrict | limited in particular, It is preferable to select according to the target cold-retention temperature.
For example, a water-containing gel-like cold-preserving agent composition capable of maintaining the temperature of a material to be stored in a low temperature range of about 15 ° C. to 0 ° C. is known (Japanese Patent Application Laid-Open No. 8-325563).
Moreover, for example, dry ice which is solid carbon dioxide is known as a cold storage agent capable of maintaining the temperature of a material to be stored in a low temperature range of about -50 ° C to -20 ° C.
Furthermore, as a cold storage agent used in a very low temperature range such as −80 ° C. or less, it contains water and a solute containing lithium chloride and sodium chloride, and the content ratio of lithium chloride in weight conversion among the components of the solute That is the highest, which contains water and a solute containing lithium chloride and potassium chloride, and among the components of the solute, the content ratio of lithium chloride in terms of weight conversion is the highest, or with water, lithium chloride and sodium chloride And a solute containing one selected from the group consisting of potassium chloride, ammonium chloride and potassium nitrate, and among the components of the solute, the content ratio by weight conversion of lithium chloride is the highest (especially Application 2016-007002).

次に、本実施形態に係る保冷剤収納用板状容器について説明する。本実施形態に係る保冷剤収納用板状容器は、上述した実施形態に係る保冷剤を密封などして収納するものである。
ここで、保冷剤を密封するものとしては、一般的に使用されているナイロン、ポリエチレンなどのラミネートフィルムでもよいが、−80℃程度の極低温域では、耐低温性がないので、繰り返しの使用に耐えることができない場合がある。
繰り返し使用する場合には、−80℃での使用に耐える高密度ポリエチレンフィルムやポリイミドフィルム、高密度ポリエチレン樹脂、ポリイミド樹脂などで形成された−80℃での耐低温性を有する容器が、保冷剤を密封するものとして好適である。
Next, the plate-shaped container for cold storage agent storage which concerns on this embodiment is demonstrated. The plate-shaped container for storing a cold-preserving agent according to the present embodiment seals and holds the cold-insulating agent according to the above-described embodiment.
Here, as what seals a cold-storage agent, laminated films, such as generally used nylon and polyethylene, may be sufficient, but since there is no low-temperature resistance in a very low temperature range of about -80 ° C, repeated use There are times when you can not bear.
In the case of repeated use, a container having low temperature resistance at -80.degree. C. formed of high density polyethylene film, polyimide film, high density polyethylene resin, polyimide resin, etc. which withstands use at -80.degree. Is suitable for sealing the

また、保温剤としては、特に制限されることなく公知のものを用いることができ、目的とする保温温度に応じて選択することが好ましい。保温剤収納用容器についても目的とする保温温度に応じて選択することが好ましい。   Moreover, as a heat retaining agent, it is possible to use a known one without particular limitation, and it is preferable to select according to the target temperature of heat retention. It is preferable to select the heat retaining agent storage container also in accordance with the desired heat retention temperature.

図3〜図6は、内側容器12と外側容器13とを組み付けた状態を示すものである。
保冷容器11においては、内側容器12及び外側容器13をそれぞれ実質的に均一な厚さの複数枚の真空断熱材15(図7参照)で構成し、内側容器12及び外側容器13の底部においては必要な枚数の真空断熱材15を積層して形成され、また内側容器12及び外側容器13の側壁においては底部の枚数の二分の一の真空断熱材15を積層して形成することにより、最終的に底部の真空断熱材15の積層枚数と、側壁の真空断熱材15の積層枚数とがほぼ等しくなるように形成されている。これにより、底部側と側壁側の厚さ方向の断熱性がほぼ等しくなり、保冷容器11の内部温度をほぼ均一にし、内部温度の変化を長期間抑制することができる。なお、本発明において、実質的に「均一な厚さ」とは、完全に均一な厚さである必要はなく、例えば、設計上の厚さに対して、約±5.0%の範囲にある厚さを公差として含んでもよく、約±3.0%の範囲にある厚さを公差として含んでもよい。
3 to 6 show a state in which the inner container 12 and the outer container 13 are assembled.
In cold storage container 11, inner container 12 and outer container 13 are each formed of a plurality of vacuum heat insulating materials 15 (see FIG. 7) of substantially uniform thickness, and at the bottom of inner container 12 and outer container 13. It is formed by laminating the required number of vacuum heat insulating materials 15, and by forming a half of the vacuum heat insulating material 15 of the number of the bottom on the side walls of the inner container 12 and the outer container 13, the final The number of laminated layers of the vacuum heat insulating material 15 at the bottom is substantially equal to the number of laminated layers of the vacuum heat insulating material 15 of the side walls. As a result, the heat insulating properties in the thickness direction on the bottom side and the side wall side become almost equal, and the internal temperature of the cold storage container 11 can be made substantially uniform, and the change in the internal temperature can be suppressed for a long time. In the present invention, the substantially "uniform thickness" does not have to be a completely uniform thickness, and for example, in the range of about ± 5.0% with respect to the designed thickness. A thickness may be included as a tolerance, and a thickness in the range of about ± 3.0% may be included as a tolerance.

内側容器12を外側容器13に収容して強固に保持する部材又は器具としては、外側容器13に接着剤や融着加工、その他の部材又は器具で取り付けた結束及び取り外し可能なベルト31が採用されている。
ベルト31の一端には横長の開口を備えた一対の保持金具32,33が取り付けられ、ベルト31の他端を挿通して一対の保持金具32,33間を掛け回すことにより、ワンタッチで強固にロックすることができる。
また、一対の保持金具32,33の側端部には対向する位置においてテーパがそれぞれ形成されているため、ベルト31の端部を左右に振るだけでロックを簡単に解除して、ベルト31を取り外すことができる。
As a member or a device for housing the inner container 12 in the outer container 13 and firmly holding it, a binding and removable belt 31 attached to the outer container 13 with an adhesive, fusion processing, other members or devices is adopted ing.
A pair of holding fixtures 32 and 33 having a laterally long opening is attached to one end of the belt 31, and the other end of the belt 31 is inserted and the pair of holding fixtures 32 and 33 are wound around to make a strong one-touch operation. It can be locked.
Further, since the tapers are respectively formed at the opposite positions of the side end portions of the pair of holding metal fittings 32 and 33, the lock is easily released simply by swinging the end portion of the belt 31 to the left and right. It can be removed.

図7は、本実施形態の保冷容器における複数の断熱材の配置の一例を示す概略図である。点線の楕円で示す部分は、前方側断熱材15aにおける断熱性の劣る端部(周縁部)である。ここで、前方側断熱材15aの後ろ側に後方側断熱材15bを配置し、前方側断熱材15aにおける断熱性の劣る端部(周縁部)に、後方側断熱材15bの中心部分を重ね合わせて積層させている。これにより、保冷容器11の高い断熱性能を発揮することができる点で好ましい態様である。図7に示されるように、前方側断熱材15aの周縁部(輪郭線)と後方側断熱材15bの周縁部(輪郭線)とが、好ましくは、断熱材の厚さ方向から見て全体として重ならない又は一致しないように積層されてもよい。前方側断熱材15aの周縁部と後方側断熱材15bの周縁部とは、限定するものではないが例えば、交差するか又は実質的に直交するように積層されてもよい。さらに、限定するものではないが例えば、交差する位置は、矩形状の後方側断熱材15bのほぼ中心部分とすることができる。
また、内側容器12及び/又は外側容器13の角部や角状の端部において、真空断熱材を実質的にL字状、U字状又はコの字状に折り曲げて配置してもよい。これにより、断熱性の劣りやすい部分における断熱性能の低下を抑制できる点で好ましい態様である。
FIG. 7: is schematic which shows an example of arrangement | positioning of the several heat insulating material in the cold storage container of this embodiment. The part shown by the dotted-line ellipse is the edge part (periphery part) which is inferior to the heat insulation in the front side heat insulating material 15a. Here, the rear side heat insulating material 15b is disposed behind the front side heat insulating material 15a, and the central portion of the rear side heat insulating material 15b is superimposed on the end (peripheral part) of the front side heat insulating material 15a. Is stacked. This is a preferable embodiment in that the high heat insulation performance of the cold storage container 11 can be exhibited. As shown in FIG. 7, the peripheral edge (outline) of the front side heat insulating material 15 a and the peripheral edge (outline) of the rear side heat insulating material 15 b are preferably as a whole viewed from the thickness direction of the heat insulating material It may be laminated so as not to overlap or coincide. The peripheral portion of the front side heat insulating material 15a and the peripheral portion of the rear side heat insulating material 15b may be, for example, but not limited to, be laminated so as to intersect or be substantially orthogonal to each other. Furthermore, although not limited thereto, for example, the intersecting position may be substantially at the center of the rectangular rear side heat insulating material 15b.
In addition, the vacuum heat insulating material may be substantially bent in an L shape, a U shape, or a U shape at a corner or a corner of the inner container 12 and / or the outer container 13. This is a preferred embodiment in that it is possible to suppress the decrease in the heat insulation performance in the portion where the heat insulation is likely to be inferior.

本実施例では、図1で示す構成の保冷容器を用いた。
内側容器及び外側容器の底部及び側壁には真空断熱材を適用した。具体的には、ビップエース(VIP−A、商品名:旭ファイバーグラス株式会社製)を用い、側壁側に2枚ずつの真空断熱材を配置した。また、底部側には4枚の真空断熱材と、1枚の予備の真空断熱材を合わせて、5枚の真空断熱材を配置した。
保冷容器の内側容器の内寸法は、31.3×27.2×9.3(cm)であった。
In the present embodiment, a cold storage container having a configuration shown in FIG. 1 was used.
Vacuum insulation was applied to the bottom and sidewalls of the inner and outer containers. Specifically, two vacuum heat insulating materials were disposed on the side wall using VIP ACE (trade name: manufactured by Asahi Fiber Glass Co., Ltd.). Further, on the bottom side, four vacuum heat insulating materials and one spare vacuum heat insulating material were combined to arrange five vacuum heat insulating materials.
The inner dimension of the inner container of the cold container was 31.3 × 27.2 × 9.3 (cm).

保冷剤としては、株式会社STS研究所製の保冷剤(STS2)を用いた。保冷剤の成分は純水であり、保冷剤を入れる保冷剤収納用板状容器としてビニール容器(ソフトパック)を用いた。保冷剤収納用板状容器は図1に示すとおり、試料収納ボックスの周囲に10枚が取り囲むように、内側容器の内面に配置した。   As a cold storage agent, a cold storage agent (STS2) manufactured by STS Laboratory Co., Ltd. was used. The component of the heat insulating agent is pure water, and a vinyl container (soft pack) was used as a plate-shaped container for containing the cold insulating agent. As shown in FIG. 1, the cold-preserving agent-storing plate-like container was disposed on the inner surface of the inner container so that ten sheets surrounded the sample storage box.

内側容器内には試料収納ボックスを被保冷物収納容器21として収容し、試料収納ボックスの外側の6面の保冷温度を測定して平均保冷温度を算出した。
なお、実験環境における外部環境の温度は、約12〜23℃であった。
A sample storage box was stored as a cold storage container 21 in the inner container, and the cold storage temperatures of the six surfaces outside the sample storage box were measured to calculate the average cold storage temperature.
The temperature of the external environment in the experimental environment was about 12 to 23 ° C.

図8は、本実施例の実験結果を示すグラフである。
図8に示すとおり、本実施例の保冷容器においては、試料収納ボックスを収容してから開封を行うまでの10日間という長期間、外部電源なしに、内部温度を3℃から4℃の間で維持することができ、非常に高い保冷効果を実現し、内部温度の変化を長期間抑制することができた。
FIG. 8 is a graph showing the experimental results of this example.
As shown in FIG. 8, in the cold storage container of the present embodiment, the internal temperature is between 3 ° C. and 4 ° C. without an external power supply for a long period of 10 days from storing the sample storage box to opening it. It was possible to maintain, to realize a very high cooling effect, and to suppress the change of the internal temperature for a long time.

11 保冷容器
12 内側容器
12a 収容部
12b 内側容器の底部
12c 内側容器の外面
13 外側容器
13a 収容部
13b 外側容器の底部
13c 外側容器の内面
15a 前方側断熱材
15b 後方側断熱材
21 被保冷物収納容器
22 保冷剤収納用板状容器
22a 底部の保冷剤収納用板状容器
22b 段差
31 ベルト
32,33 保持金具
11 Cold Storage Container 12 Inner Container 12a Housing 12b Bottom 12c of Inner Container Outer Surface 13 of Outer Container 13 Outer Container 13a Housing 13b Bottom of Outer Container 13c Bottom 13c of Outer Container Inner Surface 15a of Outer Container Front Side Heat Insulating Material 15b Rear Side Heat Insulating Material 21 Cold Storage Material Storage Container 22: Coolant storage plate container 22a: Cold storage container container 22b at the bottom portion: Step difference 31 Belt 32, 33 Holding bracket

Claims (12)

被保冷保温物が収容される収容部を有し、真空断熱材を備えた開口可能な内側容器と、
前記内側容器を収容し、真空断熱材を備えた開口可能な外側容器と、を備え、
前記内側容器の収容状態で、前記内側容器の外面と前記外側容器の内面とが実質的に隙間なく対向して配置され、
前記被保冷保温物の収容状態で、前記内側容器の内面と前記被保冷保温物との間に保冷保温剤が配置された、保冷保温容器。
An openable inner container having a vacuum heat insulating material and a storage portion for storing a cold storage material.
An openable outer vessel containing the inner vessel and provided with vacuum insulation;
In the accommodated state of the inner container, the outer surface of the inner container and the inner surface of the outer container are disposed substantially facing each other without gaps.
A cold / warm thermal container, wherein a cold / warm thermal agent is disposed between an inner surface of the inner container and the cold / warm thermal material in a storage state of the cold / warm thermal material.
前記内側容器の収容状態で、前記内側容器の一端に形成された開口部の少なくとも一部が、前記外側容器の端部近傍に配置され、かつ、前記外側容器の一端に形成された開口部の少なくとも一部が、前記内側容器の端部近傍に配置された、請求項1記載の保冷保温容器。   In the storage state of the inner container, at least a part of the opening formed at one end of the inner container is disposed in the vicinity of the end of the outer container and of the opening formed at one end of the outer container The cold insulation container according to claim 1, wherein at least a part of the container is disposed near an end of the inner container. 前記内側容器の内面と前記被保冷保温物との間に隙間なく前記保冷保温剤が敷設された、請求項1又は2記載の保冷保温容器。   The cold storage / warming container according to claim 1, wherein the cold storage / warming agent is laid without a gap between an inner surface of the inner container and the cold storage / retaining material. 前記内側容器の真空断熱材及び/又は前記外側容器の真空断熱材が、グラスウール、シリカ粉末、及びウレタンフォームの、少なくとも一つ又は複数を芯材とした真空断熱材である、請求項1〜3のいずれか一項に記載の保冷保温容器。   The vacuum heat insulating material having at least one or more of glass wool, silica powder, and urethane foam as a core material, the vacuum heat insulating material of the inner container and / or the vacuum heat insulating material of the outer container is preferably used. The cold preservation heat retention container as described in any one of. 前記内側容器の真空断熱材及び/又は前記外側容器の真空断熱材が、それぞれ実質的に均一な厚さの複数枚の真空断熱材からなり、
前記内側容器及び前記外側容器の底部において前記複数枚の真空断熱材が積層され、
前記内側容器及び前記外側容器の側壁において、前記底部に積層された真空断熱材の枚数の二分の一の真空断熱材が積層された、請求項1〜4のいずれか一項に記載の保冷保温容器。
The vacuum insulation of the inner container and / or the vacuum insulation of the outer container each comprising a plurality of vacuum insulation of substantially uniform thickness,
The plurality of vacuum heat insulating materials are stacked at the bottom of the inner container and the outer container,
5. The cold and heat insulation according to claim 1, wherein on the side walls of the inner container and the outer container, a half of the number of vacuum heat insulating materials stacked on the bottom is laminated. container.
前記内側容器の真空断熱材及び/又は前記外側容器の真空断熱材が、複数枚の真空断熱材からなり、前記複数枚の真空断熱材のそれぞれの端部が実質的に重ならないように積層された、請求項1〜5のいずれか一項に記載の保冷保温容器。   The vacuum insulator of the inner container and / or the vacuum insulator of the outer container comprises a plurality of vacuum insulators, and the respective ends of the plurality of vacuum insulators are laminated so that they do not substantially overlap. The cold preservation heat retention container as described in any one of Claims 1-5. 前記内側容器の真空断熱材及び/又は前記外側容器の真空断熱材が、前記内側容器及び/又は前記外側容器の角部において折り曲げられている、請求項1〜6のいずれか一項に記載の保冷保温容器。   The vacuum insulation of the inner vessel and / or the vacuum insulation of the outer vessel are folded at the corners of the inner vessel and / or the outer vessel. Cold insulated container. 前記内側容器の前記端部近傍が、前記内側容器の底部であり、及び/又は、前記外側容器の前記端部近傍が、前記外側容器の底部である、請求項2〜7のいずれか一項に記載の保冷保温容器。   8. The method according to any one of claims 2 to 7, wherein the vicinity of the end of the inner container is the bottom of the inner container and / or the vicinity of the end of the outer container is the bottom of the outer container. Insulated and insulated container as described in. 前記内側容器の真空断熱材及び/又は前記外側容器の真空断熱材が、実質的にL字状、U字状又はコの字状に折り曲げた状態で配置されている、請求項1〜8のいずれか一項に記載の保冷保温容器。 9. The vacuum insulation of the inner container and / or the vacuum insulation of the outer container are arranged in a substantially L-shaped, U-shaped or U-shaped manner. The cold preservation heat retention container of any one statement. 前記内側容器の真空断熱材の端部と、前記内側容器の真空断熱材に隣接する前記外側容器の真空断熱材の端部とが全体として重ならないように積層されている、請求項1〜9のいずれか一項に記載の保冷保温容器。   The end of the vacuum insulator of the inner container and the end of the vacuum insulator of the outer container adjacent to the vacuum insulator of the inner container are laminated so as not to overlap as a whole. The cold preservation heat retention container as described in any one of. 前記内側容器の真空断熱材及び/又は前記外側容器の真空断熱材が、複数枚の真空断熱材からなり、隣接する真空断熱材がそれぞれの端部が全体として重ならないように積層されている、請求項1〜10のいずれか一項に記載の保冷保温容器。   The vacuum insulator of the inner container and / or the vacuum insulator of the outer container comprises a plurality of vacuum insulators, and adjacent vacuum insulators are laminated such that their respective ends do not overlap as a whole. The cold preservation heat retention container as described in any one of Claims 1-10. 前記真空断熱材のそれぞれの前記端部が、前記真空断熱材のそれぞれの周縁部であり、前記周縁部がそれぞれ真空断熱材の厚さ方向からみて全体として一致しないように積層されている、請求項6、10、11のいずれか一項に記載の保冷保温容器。   The respective end portions of the vacuum heat insulating material are the respective peripheral portions of the vacuum heat insulating material, and the respective peripheral portions are laminated so that they do not match as a whole when viewed from the thickness direction of the vacuum heat insulating material. Item 12. A cold and heat-retaining container according to any one of Items 6, 10, and 11.
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06298283A (en) * 1993-04-16 1994-10-25 Kubota Corp Vacuum insulation box
JPH11109561A (en) * 1997-10-06 1999-04-23 Konica Corp Photosensitive plate package for photomask
JP2008030790A (en) * 2006-07-28 2008-02-14 Hitachi Appliances Inc Insulated container
US20090078708A1 (en) * 2007-09-20 2009-03-26 Preston Noel Williams Temperature Maintaining Package Having Corner Discontinuities
JP2013039102A (en) * 2011-08-19 2013-02-28 Hitachi Ltd Cell-transporting container
WO2015063820A1 (en) * 2013-11-01 2015-05-07 安人 日下 Heat-insulated box
JP2017047942A (en) * 2015-09-02 2017-03-09 大日本印刷株式会社 Cold and warm box

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06298283A (en) * 1993-04-16 1994-10-25 Kubota Corp Vacuum insulation box
JPH11109561A (en) * 1997-10-06 1999-04-23 Konica Corp Photosensitive plate package for photomask
JP2008030790A (en) * 2006-07-28 2008-02-14 Hitachi Appliances Inc Insulated container
US20090078708A1 (en) * 2007-09-20 2009-03-26 Preston Noel Williams Temperature Maintaining Package Having Corner Discontinuities
JP2013039102A (en) * 2011-08-19 2013-02-28 Hitachi Ltd Cell-transporting container
WO2015063820A1 (en) * 2013-11-01 2015-05-07 安人 日下 Heat-insulated box
JP2017047942A (en) * 2015-09-02 2017-03-09 大日本印刷株式会社 Cold and warm box

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