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JP2016003365A - Plated composite article and production method therefor - Google Patents

Plated composite article and production method therefor Download PDF

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JP2016003365A
JP2016003365A JP2014124398A JP2014124398A JP2016003365A JP 2016003365 A JP2016003365 A JP 2016003365A JP 2014124398 A JP2014124398 A JP 2014124398A JP 2014124398 A JP2014124398 A JP 2014124398A JP 2016003365 A JP2016003365 A JP 2016003365A
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plating
layer
parts
composite product
plated composite
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JP6389069B2 (en
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潔 木田
Kiyoshi Kida
潔 木田
貴文 木田
Takafumi Kida
貴文 木田
裕文 木田
Hirofumi Kida
裕文 木田
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Kidaseiko KK
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Abstract

PROBLEM TO BE SOLVED: To achieve high corrosion resistance and improve the appearance while keeping floating of bonded parts in a smooth state.SOLUTION: A composite article comprises at least two parts 2 and 3 bonded inseparably in a freely floating state through an engagement structure between them. In the individual parts 2 and 3, there is formed a surface-treated layer 10 with a Zn plating as the outermost layer, in an engagement part where the parts 2 and 3 come in slide contact with each other during floating. In parts other than the engagement part, there is formed a surface-treated layer 11 formed by laminating a metal plating layer on the Zn plating as the ground layer.

Description

本発明は、座付きナットのような複合品にめっきを施して成るめっき済み複合品と、このめっき済み複合品を製造する方法とに関する。   The present invention relates to a plated composite product obtained by plating a composite product such as a nut with a seat, and a method of manufacturing the plated composite product.

図3に例示した座付きナットのように、スプリングワッシャーや皿バネ等の付属パーツ101を、ナット等の本体パーツ102に遊動自在(図例では回転自在)で且つ分離不能に結合して成る複合品100は公知である(例えば、特許文献1等参照)。このような複合品100としては、前記した座付きナット等の他にもコイルスプリングや弛み止めパーツ等を内蔵したナット、或いはボルトの首部へスプリングワッシャーや平座金を回転自在で且つ分離不能に嵌め込んだ座金組み込みボルトなども知られている。   Like the seated nut illustrated in FIG. 3, a composite product in which an accessory part 101 such as a spring washer or a disc spring is freely movable (in the illustrated example, rotatable) and inseparably coupled to a main body part 102 such as a nut. 100 is well-known (for example, refer patent document 1 etc.). As such a composite product 100, in addition to the above-mentioned nuts with seats, etc., nuts incorporating coil springs and locking parts, etc., or spring washers and plain washers are fitted into the necks of bolts in a freely rotatable manner. A bolt with a built-in washer is also known.

このような複合品100でも、多くの場合は、耐食性を向上させたり金属光沢を持たせたりするために、例えばニッケルと亜鉛の合金に三価クロメートによるめっき(特許文献2等参照)などを施すようにしている。   Even in such a composite article 100, in order to improve corrosion resistance or give a metallic luster in many cases, for example, plating with an alloy of nickel and zinc with trivalent chromate (see Patent Document 2, etc.) is performed. I am doing so.

特開平9−4630号公報Japanese Patent Laid-Open No. 9-4630 特開2005−126796号公報JP 2005-126696 A

複合品100にめっきを施すに際して、付属パーツ101と本体パーツ102とを結合後にめっき槽へ漬けると、付属パーツ101と本体パーツ102との嵌合部位では両者間に生じる隙間S(座付きナットの例では、皿バネを嵌めるためにナットに設けた段付き凸部分の外周面と皿バネの内周部との周隙間や皿バネの上下両面にできる隙間等)が微小となっているので、この隙間Sに対してめっき液が殆ど浸入しなということがあった。そのため、この嵌合部位(隙間S)ではめっきが未着となったりめっき厚が極度に薄くなったりして、黒ずんだ外観となるので、見栄えが悪いという問題があった。また、めっきが未着か又はめっき厚が薄い部分では、当然に耐食性を高めにくいという問題もあった。   When the composite part 100 is plated, when the accessory part 101 and the main body part 102 are joined and immersed in the plating tank, a gap S (an example of a seated nut) is generated between the attachment part 101 and the main body part 102 at the fitting portion. Then, the circumferential gap between the outer peripheral surface of the stepped convex portion provided on the nut for fitting the disc spring and the inner peripheral portion of the disc spring, the gap that can be formed on the upper and lower sides of the disc spring, etc.) are very small. In some cases, the plating solution hardly penetrated into the gap S. For this reason, there is a problem in that the fitting portion (gap S) has a poor appearance because the plating has not been deposited or the plating thickness has become extremely thin, resulting in a dark appearance. In addition, there is a problem that it is difficult to improve the corrosion resistance in a portion where the plating is not deposited or the plating thickness is thin.

一方、この問題を解消する目的で、仮に、付属パーツ101と本体パーツ102とを結合前に、それぞれ別個にめっきを施しておき、その後、結合するように複合品100の製作手順を変更したとする。このようにすることで付属パーツ101及び本体パーツ102の両者ともに、それらの全面に均一めっきを施すことができる。ところが、多くの場合、めっき表面はその表面粗さが粗く円滑性が低下することから、全面めっき後の付属パーツ101と本体パーツ102とを結合したときに、それらの間の遊動性が低下するという問題もあった。   On the other hand, for the purpose of solving this problem, it is assumed that the accessory part 101 and the main body part 102 are separately plated before joining, and then the manufacturing procedure of the composite product 100 is changed so that they are joined. To do. By doing in this way, both the attachment part 101 and the main-body part 102 can perform uniform plating on the whole surface. However, in many cases, since the surface of the plating is rough and the smoothness is lowered, when the attachment part 101 and the main body part 102 after the entire plating are joined, the mobility between them is lowered. There was also a problem.

のみならず、付属パーツ101と本体パーツ102との結合の際に、いずれか一方にカシメ等を必要とする場合では、カシメによってパーツ表面に傷が付き、この傷を発端として腐食が発生乃至拡大するといった問題もあった。
本発明は、上記事情に鑑みてなされたものであって、結合したパーツ同士の遊動を円滑な状態に保持しつつ高い耐食性が得られ且つ外観性を向上させることができるめっき済み複合品及びその製造方法を提供することを目的とする。
In addition, when the attachment part 101 and the main body part 102 are joined together, when caulking or the like is required on one of the parts, the surface of the part is damaged by caulking, and corrosion starts or expands due to this scratch. There was also the problem of doing.
The present invention has been made in view of the above circumstances, and is a plated composite product capable of obtaining high corrosion resistance and improving appearance while maintaining smooth play between joined parts, and its An object is to provide a manufacturing method.

前記目的を達成するために、本発明は次の手段を講じた。
即ち、本発明に係るめっき済み複合品は、少なくとも2つのパーツが相互間の嵌合構造によって遊動自在で且つ分離不能に結合されて成る複合品であって、それぞれのパーツには、互いの遊動時に摺接し合う嵌合部位にZnめっきを最外層とする表面処理層が形成されていると共に、前記嵌合部位を除く他の部位にはZnめっきを下地層として当該下地層上に他の金属めっき層を積層させて成る表面処理層が形成されていることを特徴とする。
In order to achieve the above object, the present invention has taken the following measures.
That is, the plated composite product according to the present invention is a composite product in which at least two parts are freely movable and separable by a fitting structure between each other. A surface treatment layer having Zn plating as the outermost layer is formed at the fitting part that is in sliding contact with the other part, and other metal other than the fitting part is made of Zn plating as a base layer on the base layer. A surface treatment layer formed by laminating plating layers is formed.

前記他の金属めっき層は、Ni−Zn合金めっき層とするのが好適である。
前記他の金属めっき層の上に、更に三価クロメートによる表面処理層を施すことも可能である。
一方、本発明に係るめっき済み複合品の製造方法は、少なくとも2つのパーツが相互間の嵌合構造によって遊動自在で且つ分離不能に結合されて成るめっき済み複合品を製造する方法であって、個々のパーツをZnめっきによって個別に表面処理し、各パーツを互いに遊動自在な状態に嵌合させたうえで更に分離不能に結合させ、各パーツを結合した状態のまま前記Znめっきとは異なる金属めっきで表面処理することを特徴とする。
The other metal plating layer is preferably a Ni—Zn alloy plating layer.
It is also possible to further apply a surface treatment layer with trivalent chromate on the other metal plating layer.
On the other hand, the method of manufacturing a plated composite product according to the present invention is a method of manufacturing a plated composite product in which at least two parts are freely and separably joined by a fitting structure between them. Each part is individually surface-treated by Zn plating, and each part is fitted to each other in a freely movable state, and then further separably coupled, and each metal is different from the Zn plating in a state in which each part is coupled. The surface treatment is performed by plating.

Znめっきとは異なる前記金属めっきは、Ni−Zn合金めっきとするのがよい。   The metal plating different from Zn plating is preferably Ni—Zn alloy plating.

本発明に係るめっき済み複合品では、結合したパーツ同士の遊動を円滑な状態に保持しつつ高い耐食性が得られ、しかも外観性を向上させることができる。   In the plated composite product according to the present invention, high corrosion resistance can be obtained while maintaining the smooth movement between the joined parts, and the appearance can be improved.

本発明に係るめっき済み複合品の第1実施形態を模式的に示した側断面図である。It is the sectional side view which showed typically 1st Embodiment of the plated composite goods which concern on this invention. 本発明に係るめっき済み複合品についてその製造方法の一例(途中の段階)を模式的に示した側断面図である。It is the sectional side view which showed typically an example (middle stage) of the manufacturing method about the plated composite goods which concern on this invention. 従来の複合品を示した側断面図である。It is the sectional side view which showed the conventional composite goods.

以下、本発明の実施の形態を、図面に基づき説明する。
図1は、本発明に係るめっき済み複合品1の第1実施形態を模式的に示した側断面図であり、また図2は、このめっき済み複合品1を製造する途中の段階を模式的に示した側断面図である。本第1実施形態は複合品が座付きナットである場合を例示してある。従ってこの複合品は、スプリングワッシャーや皿バネ等の付属パーツ2と、ナット等の本体パーツ3との二つのパーツを有して構成されている。
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
FIG. 1 is a side sectional view schematically showing a first embodiment of a plated composite product 1 according to the present invention, and FIG. 2 schematically shows a stage in the middle of manufacturing the plated composite product 1. FIG. This 1st Embodiment has illustrated the case where a composite article is a nut with a seat. Therefore, this composite product has two parts, an accessory part 2 such as a spring washer and a disc spring, and a main body part 3 such as a nut.

本体パーツ3には、中央を貫通して設けられた雌ねじ孔4の一方の開口端側を延長させるようにして、円形ボス状に突出する段付き凸部分5(図2参照)が設けられている。これに対し、付属パーツ2には、本体パーツ3の段付き凸部分5に嵌め入れる中央開口7が形成されている。従って、本体パーツ3の段付き凸部分5に、付属パーツ2の中央開口7を嵌め入れ、その後、段付き凸部分5の端縁が径方向外方へ広がるようにカシメを行う。これにより、付属パーツ2が本体パーツ3の段付き凸部分5のまわりで遊動自在(回転自在)で且つ分離不能となるように保持される。   The main body part 3 is provided with a stepped convex portion 5 (see FIG. 2) protruding in a circular boss shape so as to extend one opening end side of the female screw hole 4 provided through the center. Yes. On the other hand, the accessory part 2 is formed with a central opening 7 that fits into the stepped convex portion 5 of the main body part 3. Therefore, the central opening 7 of the accessory part 2 is fitted into the stepped convex portion 5 of the main body part 3, and thereafter, crimping is performed so that the edge of the stepped convex portion 5 spreads radially outward. Accordingly, the accessory part 2 is held so as to be freely movable (rotatable) and not separable around the stepped convex portion 5 of the body part 3.

すなわち、本体パーツ3の段付き凸部分5は、カシメにより、付属パーツ2の中央開口7と摺接し合うための周溝を形成すべく変形されることになり、この周溝の溝内面が、付属パーツ2に向けた嵌合部位ということになる。
これに対して付属パーツ2では、本体パーツ3の嵌合部位(周溝の溝内面)に対して中央開口7の内周面及びこの開口周部の上下両面が摺接し合うものとなり、これらの部位が、本体パーツ3に向けた嵌合部位ということになる。
That is, the stepped convex portion 5 of the main body part 3 is deformed by caulking to form a circumferential groove for sliding contact with the central opening 7 of the accessory part 2, and the groove inner surface of the circumferential groove is That is, the fitting part is directed to the attached part 2.
On the other hand, in the accessory part 2, the inner peripheral surface of the central opening 7 and the upper and lower surfaces of the peripheral part of the opening are in sliding contact with the fitting part of the main body part 3 (the groove inner surface of the peripheral groove). The part is a fitting part directed to the main body part 3.

そして、本発明に係るめっき済み複合品1では、これらの嵌合部位(本体パーツ3に形成した周溝の溝内面及び付属パーツ2において周溝に嵌る領域)に対して、Znめっきを最外層とする表面処理層(以下、説明の便宜上「第1処理層」と言う)10が形成されていると共に、これらの嵌合部位を除く他の部位に対して、Znめっきを下地層としてこの下地層上に他の金属めっき層を積層させた表面処理層(以下、説明の便宜上「第2処理層」と言う)11が形成されているものである。   In the plated composite product 1 according to the present invention, Zn plating is applied to the outermost layer of these fitting portions (the groove inner surface of the circumferential groove formed in the main body part 3 and the region fitted in the circumferential groove in the accessory part 2). A surface treatment layer 10 (hereinafter referred to as “first treatment layer” for convenience of description) 10 is formed, and Zn plating is used as an underlayer for other portions except these fitting portions. A surface treatment layer 11 (hereinafter referred to as “second treatment layer” for convenience of explanation) is formed by laminating another metal plating layer on the base layer.

換言すれば、このめっき済み複合品1は、付属パーツ2及び本体パーツ3が互いに嵌合し合う部分(外観したときに小さな隙間となる領域)に限っては第1処理層10のみが形成されており、その他の領域(主に外部に曝される面)は第2処理層11により包み込まれるように被覆されている、というものである。
なお、第1処理層10は最外層がZnめっきであればよいので、Znめっきの下に別のめっき層などを設けることは任意である。また、第2処理層11についても、Znめっきを下地層としてその上に積層したものであることを条件とするならば、Znめっきの上(
他の金属めっき層の下)に他のめっき層を設けることは任意に行える。
In other words, in the plated composite product 1, only the first treatment layer 10 is formed only in a portion where the accessory part 2 and the main body part 3 are fitted to each other (an area that becomes a small gap when viewed from the outside). The other region (mainly the surface exposed to the outside) is covered with the second treatment layer 11.
In addition, since the outermost layer of the 1st process layer 10 should just be Zn plating, it is arbitrary to provide another plating layer etc. under Zn plating. In addition, if the second treatment layer 11 is also formed by depositing Zn plating as a base layer on the Zn treatment,
It is possible to arbitrarily provide another plating layer under the other metal plating layer.

第2処理層11において、第1処理層10に積層する金属めっき層は、具体的にはNi−Zn合金めっき層とするのがよい。金属光沢を一層強調させ、また耐食性を高めさせるために、この第2処理層11の上に、更に三価クロメート等による化学系の表面処理層(図示略)を積層してもよい。
次に、このような構成のめっき済み複合品1を製造する方法を説明する。
In the second treatment layer 11, the metal plating layer laminated on the first treatment layer 10 is preferably a Ni—Zn alloy plating layer. In order to further enhance the metallic luster and enhance the corrosion resistance, a chemical surface treatment layer (not shown) of trivalent chromate or the like may be further laminated on the second treatment layer 11.
Next, a method for manufacturing the plated composite article 1 having such a configuration will be described.

まず、本体パーツ3の段付き凸部分5に付属パーツ2を嵌合するより前に、付属パーツ2及び本体パーツ3の個々を、それぞれZnめっきによって全面的に表面処理し、第1処理層10を形成させる(図2参照)。
次に、本体パーツ3の段付き凸部分5に付属パーツ2の中央開口7を嵌め合わせ、段付き凸部分5の端縁が径方向外方へ広がるようにカシメを行う。このカシメにより、付属パーツ2と本体パーツ3との間は、互いに遊動自在で且つ分離不能な状態に結合される。
First, before fitting the accessory part 2 to the stepped convex portion 5 of the main body part 3, each of the accessory part 2 and the main body part 3 is entirely surface-treated by Zn plating, and the first treatment layer 10 (See FIG. 2).
Next, the central opening 7 of the accessory part 2 is fitted to the stepped convex portion 5 of the main body part 3 and caulking is performed so that the edge of the stepped convex portion 5 extends radially outward. By this caulking, the attachment part 2 and the main body part 3 are coupled to each other so as to be freely movable and inseparable.

次に、付属パーツ2及び本体パーツ3を結合した状態のまま、Ni−Zn合金めっきによって全面に表面処理する。このとき、付属パーツ2の嵌合部位及び本体パーツ3の嵌合部位では、それら両者間に生じる隙間が微小となっていることから、めっき液は殆ど浸入せず、従ってNi−Zn合金めっき層は形成されないか、又は形成されたとしてもめっき厚が極めて薄くなり、Ni−Zn合金めっき層としての特有の作用は殆ど生じない状態になる。   Next, the entire surface is subjected to surface treatment by Ni—Zn alloy plating while the attached part 2 and the main body part 3 are joined. At this time, the fitting part of the accessory part 2 and the fitting part of the main body part 3 have a very small gap between them, so that the plating solution hardly penetrates, and thus the Ni—Zn alloy plating layer. Is not formed, or even if it is formed, the plating thickness becomes extremely thin, and the characteristic action as the Ni—Zn alloy plating layer hardly occurs.

すなわち、本発明では、付属パーツ2と本体パーツ3との嵌合部位が互いの隙間を微小とさせていることに着眼し、この隙間にはめっき液が浸入しないことを利用して、この嵌合部位でNi−Zn合金めっき層を意図的に形成させないようにしていると言うことができる。
要するに、Ni−Zn合金めっきによる表面処理を施したとしても、これら付属パーツ2の嵌合部位及び本体パーツ3の嵌合部位を除いた全体が第2処理層11によって被覆形成されるだけで、この嵌合部位では、第1処理層10(Znめっきによる層)が実質的な最外層として残存するものとなる。
That is, in the present invention, the fitting part between the accessory part 2 and the main body part 3 is focused on making the gap between each other minute, and this fitting is utilized by utilizing that the plating solution does not enter the gap. It can be said that the Ni—Zn alloy plating layer is not intentionally formed at the joint portion.
In short, even if the surface treatment by Ni-Zn alloy plating is performed, the entire portion excluding the fitting part of the accessory part 2 and the fitting part of the main body part 3 is only covered and formed by the second treatment layer 11, In this fitting part, the 1st processing layer 10 (layer by Zn plating) remains as a substantial outermost layer.

このように製造されためっき済み複合品1では、付属パーツ2の嵌合部位及び本体パーツ3の嵌合部位が、それぞれ軟質のZnめっきによる第1処理層10により被覆されているので、パーツ間の遊動が円滑性に優れた状態として確保される。言うまでもなく、これら付属パーツ2の嵌合部位及び本体パーツ3の嵌合部位は、第1処理層10(Znめっき)によって耐食性を備えたものとなっている。   In the plated composite product 1 manufactured in this way, the fitting part of the accessory part 2 and the fitting part of the main body part 3 are respectively covered with the first treatment layer 10 made of soft Zn plating. Is ensured as a state of excellent smoothness. Needless to say, the fitting part of the accessory part 2 and the fitting part of the main body part 3 are provided with corrosion resistance by the first treatment layer 10 (Zn plating).

また、付属パーツ2及び本体パーツ3において、嵌合部位以外は硬質のNi−Zn合金めっきを積層して成る第2処理層11により被覆されているので、耐食性、耐摩耗性などに優れ、また金属光沢を強調した外観を呈するものとなる。なお、付属パーツ2と本体パーツ3との結合時に、カシメによって万が一、小さな傷がつくようなことがあったとしても、このカシメの後に、Ni−Zn合金めっきを施して第2処理層11に形成させているので、傷を発端として腐食が発生するといったこともない。   In addition, since the attached part 2 and the main body part 3 are covered with the second treatment layer 11 formed by laminating a hard Ni—Zn alloy plating except for the fitting part, the corrosion resistance and the wear resistance are excellent. Appearance that emphasizes metallic luster. Even if the attachment part 2 and the main body part 3 are joined to each other, even if a small scratch may be caused by caulking, Ni-Zn alloy plating is applied to the second treatment layer 11 after the caulking. Since it is formed, corrosion does not occur due to scratches.

ところで、本発明は、前記実施形態に限定されるものではなく、実施の形態に応じて適宜変更可能である。
例えば、付属パーツ2と本体パーツ3とを遊動自在とすることに関しては、回転自在とする場合に限らず、軸移動自在とする場合や、面対偶で摺動自在とする場合などでもよいものとする。
By the way, this invention is not limited to the said embodiment, It can change suitably according to embodiment.
For example, with regard to making the accessory part 2 and the main body part 3 freely movable, it is not limited to being rotatable, but may be a case where the axis is movable or a case where the face part is slidable. To do.

なお、第1実施形態では付属パーツ2と本体パーツ3である場合を例示して説明したが、必ずしも、パーツ間に「付属」と「本体」という主従の関係が生じることが限定されるものではない。また、パーツ数についても、3つ以上のパーツが互いに遊動自在に結合されている場合でも、本発明を適用可能であるものとする。
第2処理層11において、第1処理層10に積層する金属めっき層は、Ni−Zn合金めっき層以外としてもよい。またそもそも、合金めっき層とすることが限定されるものではない。第2処理層11の上に設ける化学系の表面処理層についても、三価クロメート以外としてもよい。
In the first embodiment, the case of the accessory part 2 and the main body part 3 has been described as an example. However, it is not necessarily limited that the master-slave relationship of “attachment” and “main body” occurs between the parts. Absent. Further, regarding the number of parts, the present invention can be applied even when three or more parts are slidably coupled to each other.
In the second treatment layer 11, the metal plating layer laminated on the first treatment layer 10 may be other than the Ni—Zn alloy plating layer. In the first place, the alloy plating layer is not limited. The chemical surface treatment layer provided on the second treatment layer 11 may also be other than trivalent chromate.

1 めっき済み複合品
2 付属パーツ
3 本体パーツ
4 雌ねじ孔
5 段付き凸部分
7 中央開口
10 表面処理層(第1処理層)
11 表面処理層(第2処理層)
DESCRIPTION OF SYMBOLS 1 Plated composite product 2 Attached parts 3 Body parts 4 Female screw hole 5 Convex part 7 Step opening 10 Surface treatment layer (1st treatment layer)
11 Surface treatment layer (second treatment layer)

Claims (5)

少なくとも2つのパーツが相互間の嵌合構造によって遊動自在で且つ分離不能に結合されて成る複合品であって、
それぞれのパーツには、互いの遊動時に摺接し合う嵌合部位にZnめっきを最外層とする表面処理層が形成されていると共に、
前記嵌合部位を除く他の部位にはZnめっきを下地層として当該下地層上に他の金属めっき層を積層させて成る表面処理層が形成されていることを特徴とするめっき済み複合品。
A composite product in which at least two parts are freely and separably connected by a fitting structure between them,
In each part, a surface treatment layer having Zn plating as the outermost layer is formed at a fitting portion that is in sliding contact with each other during sliding,
A plated composite product characterized in that a surface treatment layer is formed by laminating another metal plating layer on the base layer using Zn plating as a base layer in other portions except the fitting portion.
前記他の金属めっき層は、Ni−Zn合金めっき層とすることを特徴とする請求項1記載のめっき済み複合品。   The plated composite article according to claim 1, wherein the other metal plating layer is a Ni-Zn alloy plating layer. 前記他の金属めっき層の上に、更に三価クロメートによる表面処理層が形成されていることを特徴とする請求項1又は請求項2記載のめっき済み複合品。   3. The plated composite product according to claim 1, wherein a surface treatment layer made of trivalent chromate is further formed on the other metal plating layer. 少なくとも2つのパーツが相互間の嵌合構造によって遊動自在で且つ分離不能に結合されて成るめっき済み複合品を製造する方法であって、
個々のパーツをZnめっきによって個別に表面処理し、
各パーツを互いに遊動自在な状態に嵌合させたうえで更に分離不能に結合させ、
各パーツを結合した状態のまま前記Znめっきとは異なる金属めっきで表面処理することを特徴とするめっき済み複合品の製造方法。
A method of manufacturing a plated composite article in which at least two parts are loosely and non-separably joined by a mating structure between them,
Individual parts are individually surface treated by Zn plating,
After each part is fitted in a freely movable state, it is further connected inseparablely,
A method for producing a plated composite product, characterized in that surface treatment is performed with metal plating different from the Zn plating while the parts are joined.
Znめっきとは異なる前記金属めっきは、Ni−Zn合金めっきであることを特徴とする請求項4記載のめっき済み複合品の製造方法。   The method for producing a plated composite product according to claim 4, wherein the metal plating different from Zn plating is Ni-Zn alloy plating.
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Citations (5)

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Publication number Priority date Publication date Assignee Title
US4520077A (en) * 1983-03-03 1985-05-28 Zincroksid S.P.A. Process for the protection of galvanized steel rolled sections with a two layer chromium-chromate coating
JPS60139909A (en) * 1983-12-27 1985-07-24 本田技研工業株式会社 Washer incorporated bolt and manufacture thereof
JPS6310085A (en) * 1986-06-27 1988-01-16 Daiwa Can Co Ltd electrode roll
JP2004279382A (en) * 2003-03-19 2004-10-07 Citizen Watch Co Ltd Decorative light pointer and its manufacturing method
JP2005126796A (en) * 2003-10-27 2005-05-19 Dipsol Chem Co Ltd Method of forming hexavalent chromium-free corrosion resistant film on zinc-nickel alloy plating, and activation liquid for zinc-nickel alloy plating used for the method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4520077A (en) * 1983-03-03 1985-05-28 Zincroksid S.P.A. Process for the protection of galvanized steel rolled sections with a two layer chromium-chromate coating
JPS60139909A (en) * 1983-12-27 1985-07-24 本田技研工業株式会社 Washer incorporated bolt and manufacture thereof
JPS6310085A (en) * 1986-06-27 1988-01-16 Daiwa Can Co Ltd electrode roll
JP2004279382A (en) * 2003-03-19 2004-10-07 Citizen Watch Co Ltd Decorative light pointer and its manufacturing method
JP2005126796A (en) * 2003-10-27 2005-05-19 Dipsol Chem Co Ltd Method of forming hexavalent chromium-free corrosion resistant film on zinc-nickel alloy plating, and activation liquid for zinc-nickel alloy plating used for the method

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