JP2013012490A - Battery using chaff regenerated by both light and heat, and power generation method thereof - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a battery with high output that is regenerated at a low cost as renewable silicon-based photovoltaic power generation is expensive and difficult to be implemented in ordinary households although it is expected in place of nuclear power generation.SOLUTION: Semiconductors of titanium oxide or zinc oxide and chaff easily available at a low cost are used and power for generating current and voltage of iodine is utilized, so that the semiconductor can easily be used for power generation of P-type and N-type semiconductors with the use of plants and various kinds of additives. A restorable battery which generates power by both heat and light can discharge electricity with high output during the nighttime.

Description

  TECHNICAL FIELD The present invention relates to a rechargeable battery and a power generation method thereof capable of simultaneously performing a function of accumulating and discharging semiconductor thermoelectric power generation and dye-sensitized power generation using a biomass material rice husk in a single cell like a capacitor. Thus, the battery can be used for a solar battery as an example of a method of regenerating with light and heat, and at the same time, a temperature difference can be given to the cell and semiconductor thermoelectric generation can be regenerated.

As of July 2014, solar cells use light and heat, and various types of solar cells such as silicon-based, organic-based, dye-sensitized solar power generation, and concentrating solar cells can achieve high-efficiency conversion rates. A lot of research results are announced every day. However, the conventional silicon system is still the mainstream, and it is awaiting the practical use of these high-efficiency products that are expensive and even cheap. .
Secondary batteries and solar cells using carbonized or ash husks have been announced and patented, but they have not been put into practical use at the research stage.

  Patent No. 3997305

JP 2009-81046 A
JP 2011-170991 A
JP 2006-128133 A
WO96 / 027911

  Solar cells can be used for solar heat, light, condensing type, and semiconductor thermoelectric generation by stacking cells. In 2010, there was a report that the semiconductor thermal power generation of the human body and solar cells were realized with cells, but it is not possible to generate both at the same time. From a different point of view, research on the use of rice ash and charcoal as materials for secondary batteries and solar cells has also been announced. Biomass power generation using rice husk gas has already been implemented in India, but solar cells using rice husk have not been put into practical use at the research stage.

  As of 2012, the mainstream of solar cells that are actually used in the world is silicon-based expensive conventional solar cells with a conversion rate of around 30%. Therefore, it is expensive to implement renewable energy using light in real life. Some products produce semiconductor thermoelectric power, but this is also expensive. High-purity silicon is not required so that cheap solar cells can be produced, raw materials are changed to familiar and inexpensive ones, simple manufacturing processes are improved, and the module is not limited to black or amber, but can be selected in multiple colors A practical solar cell that can maintain the aesthetic of the town with a battery of the appearance of is waiting for recently.

    The present inventor has made it possible to use several power generation methods that can be regenerated with heat and light at the same time, and to make them widely available. I felt the need for renewable and solar batteries that could be manufactured and implemented without spending money. Conventional products and the above-described innovative technologies are expensive when they are commercialized because they require a large amount of research and development and expensive raw materials such as rare metals.

  What should be done to put these innovative technologies into practical use and dissemination at present when nuclear power generation is a problem around the world for safety? Therefore, cheap materials that can be obtained immediately, improving the conversion rate, simplifying the structure of the battery, and using materials that are close at hand so that they can be implemented immediately anywhere in the world, even in developing countries, The challenge was to switch to renewable energy-free batteries, power sources, and power generation methods at low cost. Silicon-based solar cells have a uniform exterior appearance in colors such as blue and black, and the traditional beauty and scenery of the towns are damaged.

  The battery structure has three layers of two types of metal and a layer containing titanium oxide or titanium or titanium alloy, a layer of salt, a layer containing zinc oxide or zinc or zinc alloy, and the three layers are mixed with rice husk. Simple structure. As a battery, two kinds of metals are used as upper and lower substrates, a layer containing titanium oxide or titanium or a titanium alloy is formed on one of the upper and lower substrates, and a layer containing zinc oxide or zinc or a zinc alloy is formed on the other. The top and bottom of the cell are the basic structure of two types of metals. The layer containing titanium oxide or titanium or titanium alloy and the layer containing zinc oxide or zinc or zinc alloy can be interchanged.

  The metal is described. The metal according to claim 1, 2, 3, 18, 19, 20 is not only a single metal, but also a mixture of one or more of the above elements in addition to a typical metal element, a transition metal element, and a typical nonmetal element , Also refers to alloys that are combined or that contain other additives such as synthetic resins.

  Iodine, aluminum, chromium, nickel, cobalt, manganese, molybdenum, copper, titanium, calcium, iron, tin, zinc, zirconium, lithium, panadium, cadmium, lead, gold, silver, platinum, magnesium, barium, strontium, radium, Various elements such as indium, ruthenium, barium, oxygen, hydrogen, silicon, and alloys of various combinations can be used. Alloys containing lithium iodide, calcium iodide, potassium iodide, sodium iodide, and various iodide metals such as nickel iodide and copper iodide, stainless steel, steel, nickel alloy, aluminum alloy, titanium alloy, zinc alloy Stainless steel, copper alloy, cobalt alloy, iron alloy, stainless steel, stainless steel, tinplate, tin, various metal plywood, zinc and titanium alloy, etc. They may be plated but not limited. Furthermore, it may be an alloy with other additives such as synthetic resin added or painted, so it is defined as a metal including various alloys in a broad sense.

  When a temperature difference is given to one metal or both metals of the upper and lower substrates, power can be generated and regenerated. The metal of the cell may be brought into contact with the heat source of the electrical appliance that generates heat, but when it is regenerated by solar heat or sunlight, it contains titanium oxide or titanium or a titanium alloy under the various transparent materials at the top of the upper and lower substrates. There is a layer with a perforated metal beneath it, a layer of salt underneath it, and a layer containing zinc oxide or zinc or a zinc alloy under it, another type of metal underneath The structure is equipped with. The layer containing titanium oxide or titanium or a titanium alloy and the layer containing zinc oxide or zinc or a zinc alloy can be switched in the vertical position. In this way, the top layer of titanium oxide or a layer containing titanium or a titanium alloy, or a layer containing zinc oxide or zinc or a zinc alloy, in either case, semiconductor thermal power generation is performed with solar heat, and dye-sensitized power generation with solar light. Is realized at the same time.

  Describe the layer. Titanium oxide or titanium alloy of the layer containing titanium or titanium alloy is, for example, iodine, aluminum, chromium, nickel, cobalt, manganese, molybdenum, copper, titanium, calcium, iron, tin, zinc, zirconium, lithium, panadium, An alloy in which various elements such as cadmium, lead, gold, silver, platinum, magnesium, barium, strontium, indium, ruthenium, sodium, barium, oxygen, hydrogen, radium, and silicon are mixed and combined with titanium. is there. Various other additives may also be included in the layer comprising titanium oxide or titanium or a titanium alloy.

  Zinc oxide or zinc alloy in a layer containing zinc or zinc alloy is also the same, for example iodine, aluminum, chromium, nickel, cobalt, manganese, molybdenum, copper, titanium, calcium, iron, tin, zinc, zirconium, lithium, Various other elemental elements such as panadium, cadmium, lead, gold, silver, platinum, magnesium, barium, strontium, indium, ruthenium, sodium, barium, oxygen, hydrogen, radium, silicon, etc. are mixed and combined with zinc. It is an alloy. Various other additives may also be included in the layer comprising zinc oxide or zinc or zinc alloy. Titanium layers in which one or more of titanium oxide and titanium and titanium alloys are mixed are also possible. A zinc layer in which one or more of zinc oxide, zinc and zinc alloys are mixed is also possible.

  According to the present invention, as a battery to be regenerated is increased in output and durability, the metal disposed above and below, the titanium alloy as the layer, and the raw material of the zinc alloy as the layer are changed. In the present invention, it is not limited whether titanium is an anatase type, a rutile type or another type. It is not limited whether the raw material titanium or zinc is for ceramics, dye sensitization or other uses. In the present invention, semiconductor thermal power generation and dye-sensitized power generation can be realized simultaneously.

  In the present invention, in order to reduce the cost of the semiconductor material, the husks that are also waste, usually formed after threshing, are not carbonized and ashed, but the husks that have broken the shell are made of a layer containing titanium oxide or titanium or a titanium alloy, salt A battery that can be regenerated by being mixed with a layer containing zinc oxide or zinc or a zinc alloy, for example, a solar battery. Titanium oxide or titanium or titanium alloy as well as zinc oxide or zinc or zinc alloy is in powder form (can be other than powder form) and mixed with rice husk that has broken the shell, for example, crushed, crushed, ground, or ground rice husk It can be a layer (various layers such as solid, semi-solid and liquid). Instead of carbonizing and ashing the rice husk, it is a battery that can be regenerated using just the broken rice husk, for example, a solar cell material. The rice husk is carbonized, incinerated, and the rice husk is in a different state.

  This is because one of the reasons why the inventor wants to improve silicon-based solar cells is to construct a battery that regenerates while maintaining the design of the traditional cityscape and the buildings that have been preserved there. The solar cell will be installed while keeping the traditional plaster wall. When the present inventor constructs a solar cell as a solar cell, the solar cell that expresses the cherry blossom in full bloom is desired to be constructed even at a slightly higher price. The same goes for the storehouses, storehouses, castles, and xylem. It is the battery which this invention reproduce | regenerates which can maintain the design property in the whole roof, wall, pillar, and building. For this purpose, the conductive film required for the dye-sensitized solar cell is not required for glass or plastic (used in the meaning of synthetic resin), and the desired design is applied to the glass or plastic by printing technology.

  An idea of printing an organic dye with a printing technique and attaching it to a cell as a dye is used in the present invention. Currently, there is research to apply printing technology to dye-sensitized solar cells. In that case, since the light transmittance deteriorates, it was considered to use solar heat. The solar cell that maintains this design is very important for the inventor. If the rice husk is mixed with titanium or zinc and the color is added, the crushed rice husk looks like “straw” in the earth wall, It is a solution to the problem to use raw rice husks that are not carbonized, not ashed, or just broken shells.

  Using rice husks with broken shells has advantages in that it contains moisture, other nutrients, and other elements, and is novel and inventive. Most of the known methods that have already been announced and published are carbonized and ashed to be used as battery materials. Even in the present invention, not only the rice husk is broken (crushed, crushed, ground, kneaded, etc.), but also carbonized, ashed (may be husk or steamed), and is carried out in various different states. Rice husk, rice husk carbonization, rice husk ash mixed in various types and ratios, etc. with semiconductor titanium oxide or titanium or titanium alloy, salt, zinc oxide or zinc or zinc alloy or powdered materials thereof It is carried out with mixing. The characteristics of rice husk, which is effective as a material for solar cells, will be explained by mixing rice husk with those of semiconductor titanium oxide and zinc oxide.

  The components of rice husk are about 8% moisture, about 70% hemicellulose, lignin, cellulose (these are fibers, like wood), about 20% silicic acid, Nature, water retention, and moisture control. By using rice husk in the cell, the moisture necessary for dye-sensitized solar power generation can be retained. It is not necessary to worry about the moisture retention for the dyes that are regarded as important in dye-sensitized solar power generation. The rice husk can be used as an absorbent, so it absorbs iodine that makes the cell high in output and prevents loss due to vaporization of iodine.

  The reason why both rice husk and iodine are used as raw materials is considered effective because of the redox action of silicon tetraiodide, which is a combination of silicon and iodine. Dye-sensitized solar cells have a redox action to keep the exchange of dye electrons and iodine electrons. By using rice husks as the raw material, we will be able to use the redox action of silicon tetraiodide, and we believe that it will be able to generate a variety of power generation that could not be realized before. It can be made into a multifunctional renewable battery that generates electricity simultaneously with light and heat.

The reason is that the battery of the present invention is in such a way that it is recharged without being aware of it. The effect of gas from rice husk or the combination of rice husk and iodine has some new possibilities. That is to utilize the existence of silicon tetraiodide. Silicic acid is a compound of silicon (silicon Si), oxygen, and hydrogen. Silicic acid (silicon dioxide SiO ₂ ) is silica and a raw material for glass. The outer surface of the rice husk has a nano-scale porous and complexed cellular part of silica and silica, and the outer surface of the rice husk has a large surface area. Therefore, when mixed with titanium or zinc, the titanium layer and zinc layer mixed with rice husk can be made porous without baking titanium. Since it is porous and has a large surface area, it can absorb the dye sufficiently.

  Rice husks contain plant growth promoters. In the case of natural dyes, a commercially available product obtained by drying and pulverizing plants such as hibiscus, oolong tea, and henna is dissolved in water, and only the dye dissolved in water is not used for dye-sensitized power generation. Dry powdered plants such as hibiscus, oolong tea, henna and green onions are mixed in titanium, zinc and salt and used directly for dye-sensitized power generation. By using the plant itself, it reacts sensitively to slight heat and solar heat and can be used for semiconductor thermoelectric generation.

  Henna is a commercial product for hair dyeing. Various processed plants can also be implemented. Petals processed for tea, such as oolong tea, tea leaves, crushed plants, dried and powdered, freshly picked plants, liquefied plants like juice, various states, various processing, It can also be used on plants that have been modified in various ways. In the present patent application, a plant whose main raw material is a plant, whether mixed with other substances or additives or in various different states other than flour, is defined as a plant.

  Even if there is no original dried pigment such as hibiscus, oolong tea, or henna, the aqueous solution that produces pigment in water does not differ depending on the plant such as hibiscus, oolong tea, henna, etc. Even if it is, electrons are emitted and a weak current flows. However, with only a dye dissolved in water, the current cannot be confirmed after a few days. If the original plant (dried flowers, grass, etc.) that has been dried and pigmented, such as hibiscus, oolong tea, and henna, is present together with water, it will continue to emit electrons even after the date and time. Although it is very slight, it keeps flowing. The presence of the dyes in the dye-sensitized solar cell together with the dried ones can keep the plant dye alive and continue to emit electrons for a long time. In this experiment, it is confirmed that electrons are emitted from herbs, shiso and various plants, so various plants are possible.

  In the present invention, power is generated not only by plants but also by reagents such as sodium copper chlorophyllin, eosin, and coumarin. If you use various organic dyes that have been researched and developed by various companies, the power generation efficiency will be further improved and the output will be higher. Currently, organic dyes can generate electricity for many years so that they can be commercialized. In the present invention, even effective organic dyes generate electricity efficiently. Although it was confirmed that a commercially available organic dye was implemented in the present invention and a battery that could be regenerated for a long time had been realized, it was known that the structure of the battery of the present invention was not wrong. Considering the relationship with other patent applications, it is better to explain the present invention and to implement the present invention. We began to improve plant pigments that were readily available.

  The inventor knew that in dye-sensitized solar power generation, natural plant pigments generate an electric current when used in cells, but quickly dipped the petals of the herbs that were just picked into water. When the current was measured with a tester, a numerical value that could be measured in micro units was obtained. When the dried petals of hibiscus were immersed in water and measured for current, they showed values that could be measured in micro units.

  If you measure the current of only commercially available iodine tinctures quickly, you can confirm that a very small amount of current is being emitted. We have long known that trace amounts of current can be clearly measured from the solid iodine of Wako Pure Chemicals. Commercially available iodine tinctures are often used in this implementation, but they are not specific to iodine tinctures but are intended to explain the present invention quickly.

  Commercially available iodine tincture is a mixture of iodine, potassium iodide and ethanol. Claim 5 states that one or more of iodine or iodide compounds are used in the cell, including nickel iodide, lithium iodide, sodium iodide, calcium iodide, potassium iodide, etc. Iodide compounds can be made. Which other element, which other substance and iodine are combined to form an iodide compound is not limited.

  Many solvents other than ethanol and ethanol can be implemented. Mixing one or more of acetonitrile, methoxynitrile, ethylene carbonate, propionitrile, methoxypropionitrile, propylene carbonate, etc., and also changing the ratio of the capacity, it is possible to The performance of the battery used will also change significantly. An infinite number of these combinations can be implemented. The present invention uses commercially available iodo tincture to demonstrate the effectiveness of the present invention. Therefore, since it is first desired to explain that the present invention is effective under a certain condition using a solvent and an iodide compound as a constant material, the intention was to implement and explain these actions using the same iodine tincture. Of course, iodine tincture is not optimal. A unique mixture other than iodine tincture is also implemented, and the use of iodine tincture is not the object of the present invention.

  In order to improve performance, high output, and durability, non-iodine tinctures will also be implemented, but from the following, in order to demonstrate the novelty, inventive step, and uniqueness of the present invention, the above-described similar action is used. Let's take an example of iodine tincture that can be experimented quickly. This implementation is not limited to iodine tincture. In reality, it is implemented in many combinations. Therefore, the following experiment was tried.

  As a plant mixture << 1 >>, the following mixture was produced in an approximate weight ratio. However, it is a weight ratio when there is an example and is an example. (In one example of adding iodine to the plant, mix the plant with the iodine-containing solution)

Plant mixture << 1 >>
“Hibiscus powder: 7 (reference weight 0.9 g) vs. iodine tincture: 42 (reference weight 5.5 g) vs. henna powder: 2 (reference weight 0.3 g) vs. zircon powder (metal 1 is an example) 1 (reference weight 0.1 g) "

  The above was mixed and current measurement was continued for several days. This is an about number, not the best number, but a quick experiment. It does not specify this raw material, numerical value, or ratio. (It is only one example because it is replaced with another plant and different numerical values. Zircon in one example of metal may be alumina, copper, iron, cobalt. Commercially available iodine tincture is iodine and potassium iodide. Because it is made up of ethanol and ethanol and can be used quickly, it is just used, and another solution of iodine and another solvent is also used, so iodine tincture is just one example.

  Then, although the mixture of plants << 1 >> had a clear current for a few days, the positive and negative poles were often swapped. If free electrons continue to exit the tester's black test lead, then free electrons continue to exit the red test lead. This is because free electrons flow backward in the mixed solution. Looking at this phenomenon with an analog tester, the tester's needle moves normally to the right, but when it flows backward, it moves to the left, and the magnitude of the movement of these two tester needles to the left and right is surprising. If the current flow changes, the magnetic field should change greatly accordingly. I discovered that a large change and movement of the magnetic field accompanies it. In the experiment, many familiar plants are used in the experiment, and there are various plants such as oolong tea, green onion, perilla, herb, etc., but even if you change hibiscus and henna to other plants, there is a big or small movement Such a backflow phenomenon has been confirmed.

  Also, changing the contents of the plant mixture variously, measuring the current of the mixture with the lead rod of the tester, and dropping the liquid or thing attached to the tip of the lead rod with water, if the lead rod is put on the water of another container, At the moment I put the water, I saw a large current flowing from the water in another container. The water in the separate container contained a small amount of the mixture and the mixture was smudged, but when this was the case, the tester measured the current flow greatly, though instantaneously. This represents a change in the magnetic field that is moving greatly. Looking at it, the present inventor thought that it would be possible to create P-type and N-type semiconductors with a mixture of plants using the change of the magnetic field.

  According to Fleming's law, when a magnetic field is generated, current and moving force are generated simultaneously. Therefore, this diluted material is used as the counter electrode of the mixture. If the mixture is considered to be N-type and the mixture contains iodine tincture, the counter electrode uses water instead of iodine tincture to make the mixture (b), and the counter-current mixture is counter electrode (b). Plants with weak current generation are used for the mixture of the counter electrode (c), and the thinned mixture is put in the counter electrode to make them P-type (d). The change in the magnetic field is larger than the number of free electrons in the plant pigment, and the current flow accompanying the change in the magnetic field is generated.

  np dantem type dye-sensitized solar cells are known. But the inventor's idea was different. If we use the fact that the magnetic field moves greatly in this way, we can generate a current flow without doping the semiconductor with boron or phosphorus, and increase that flow. The present inventor thought that a large current could be obtained by using a magnetic field. In many dye-sensitized solar cells and Gretzels, the source of free electrons is an organic dye or a natural dye, but in the present invention, not only the dye but also the plant as it is is mixed with rice husks as a raw material in the cell, This is the principle of generating free electrons from the dye and generating electricity.

  This idea was eventually implemented in the present invention by adding minerals that the layers could be made P-type and N-type by doping the mineral pigment added to the cell coloring in the present invention. Minerals contain various elements, and of course, each element has an electron and a tendency to ionize. By devising the arrangement of minerals rather than the number of free electrons coming from minerals, a large magnetic field can be generated and changes in the magnetic field can be created in the cell even if the minerals are intentionally used. For this reason, the present invention is carried out using minerals in addition to pigments containing other materials and additives. Ores containing minerals, red and green can be colored, and some ores contain metals, sometimes using ores.

  Also, depending on the plant used, there is a magnitude of current generation. In the above, zircon is used. However, doping with other metals such as alumina, copper, iron, cobalt etc. makes it easier to reverse flow depending on the plant. It has been found that the P type and N type can be intentionally created in the semiconductors of titanium and zinc by changing the plants and metals that produce the pigment.

  Assuming that the normal current movement is N-type and the backflow state is P-type, in the case of a titanium layer directly receiving light or heat, for example, titanium-sized nano-sized titanium oxide or titanium or titanium alloy In a layer containing, mix something like the plant mixture << 1 >>. (B) A layer that makes free electrons easily formed. If the zinc layer is at the bottom, (b) it is easy to backflow into the layer containing zinc oxide or zinc or zinc alloy (zinc can also be nano-sized), or This is because the mixture of plants with a weaker current generation << 1 >> (the mixture of plants << 1 >> changes the positive and negative poles in various ways) into the zinc layer. The free electrons that return to the counter electrode are (e) lost somewhere, causing free electrons to be made up to some extent with a layer containing zinc oxide or zinc or a zinc alloy. However, the amount of free electrons is less than the titanium layer, and the zinc layer could be P-type relative to the titanium layer.

  If there is a force that makes a reverse flow, a weak current can be generated with the force of moving the magnetic field. The present inventor thought so. When implemented in the present invention, it has been found that cells that intentionally create such differences will regenerate longer than cells that are simply mixed with pigments of natural plant pigments. Of course, because it is a plant, it will not regenerate forever.

  As an example, the plant mixture << 1 >> was now changed to water instead of iodine tincture. This does not contain iodine. Mixing metal with plants. As a plant mixture << 2 >>, the following mixture was made at an approximate weight ratio. However, this is a weight ratio at one time, and is only one example.

Plant mixture << 2 >>
“Hibiscus powder: 7 (reference weight 0.9 g) vs. water: 42 (reference weight 5.5 g) vs. henna powder: 2 (reference weight 0.3 g) vs. zircon powder (metal An example): 1 (reference weight 0.1 g) "

  It does not specify this raw material, numerical value, or ratio. (Since another plant is replaced with another numerical value, it is only one example. Zircon in one example of metal may be alumina, copper, iron, cobalt, and so on.) In early experiments, the mixture of iodine tincture is more likely to generate current than the mixture of iodine tincture and water, depending on whether the solvent is iodine tincture or water. N type P type can be made.

  In addition, a plant and rice husk mixture << 3 >> was made and tested, and various improved versions of the plant and rice husk mixture << 3 >> were also prototyped. As a mixture of plant and rice husk << 3 >>, the following mixture was produced in an approximate weight ratio. However, it is the weight ratio at a certain time of Example, and is Example 1. This mixture contains rice husk.

Mixture of plant and rice husk << 3 >>
"Chaff: 3 (reference weight 0.9 g) vs. iodine tincture: 17 (reference weight 5.6 g) vs. hibiscus powder (may be henna powder or other plants): 1 (reference weight 0. 3g) vs
Zircon powder (an example of metal): 1 (reference weight 0.3 g) "

  The above was mixed and current measurement was continued for several days. This is an about number, not the best number, but a quick experiment. It does not specify this raw material, numerical value, or ratio.

  Various metals are also being implemented, and lead, alumina, copper, iron, manganese, etc. are being implemented, so zircon is not specified. In the future, there will be more effective metals than zircon, but only a quick experiment is described.

  Mixture of plants << 1 >> Mixture of plants << 2 >> Of the mixture of plants and rice husks << 3 >>, various types of plant and metal powders (zircon is an example) are changed into P-type and N-type. In the present invention, this is implemented. Therefore, the contents of this mixture combination are innumerable and can be used in mid-winter, mid-summer, spring seasons and climatic conditions, in hot or cold places of implementation, or in the cell of the present invention indoors or outdoors. Even if it is implemented in, the identification of plants and metals must be changed greatly, the contents will change. Iodine tincture is also used for quick experimentation, and one of the three examples of <1>, <2>, and <3> in this description happens to be a quick experiment. It does not represent the best in terms of the type or number of things.

  In a dye-sensitized solar cell, not only the dye but also the electrolyte used is any solvent, and on the condition that the ratio of the solvent, iodine or iodide compound greatly affects the reproducibility, iodo tinc Can only be used for limited experiments. It cannot be specified by performance evaluation, commercialization, or claims. Not only ethanol, but also various solvents such as acetonitrile and various solutions and their ratios, there are significant differences in cell performance.

  However, by adding such a difference to the layer containing titanium oxide or titanium or titanium alloy, the layer containing salt, the layer containing zinc oxide or zinc or zinc alloy in the mixture of the above plants, boron, boric acid, phosphorus It has been demonstrated in the present invention that the semiconductor can be changed to a P-type or N-type in addition to additives such as these. By implementing such use of the plant unique to the inventor for the battery to be regenerated according to the present invention, all the necessary components of the battery to be regenerated have a novel idea and an inventive step.

  By using dried plants such as hibiscus, oolong tea, henna, and coffee powder, grass, rice husks and water together, rice husks contain plant growth-promoting substances. They will not rot and remain a useful powder for a long time. It is better to dry the plant because it will rot in a few days if the plant is left untreated and allowed to produce pigments in its raw state.

  It is known that silica becomes a semiconductor, solar cell, and ceramic material. The technology for extracting high-purity silicon from rice husks has been researched and developed, but in this patent, batteries are crushed as they are in the raw state of rice husks (meaning that they are not carbonized or ashed), and the batteries are used as is Can be used for solar cells, dye-sensitized solar power generation, semiconductor thermoelectric power generation, dried pulverized grains, powdery plant usage and other additives, metal powder, boric acid, boron, phosphorus We have invented and demonstrated that sufficient power can be generated by doping various additives such as charcoal, paste, black ink, black ink, carbon black, graphite, and those containing chemical compounds. This power generation using rice husks in this way is the world's first battery that regenerates new semiconductor thermal power generation and dye-sensitized power generation using rice husks of biomass materials.

  Of course, not only the rice husks are pulverized but also carbonized and ash are used in the present invention and are also effective in the present invention. Biomass power generation has already been implemented in some parts of India and Japan, etc., in order to generate electricity using the gas generated when the rice husks are baked. In Japan, where rice is a staple food, rice husks can be produced after threshing and discarded. Since it is baked by processing as a product, it is easy to obtain carbonized and ashed rice husks, which can be used and implemented in the present invention.

  In the present invention, the use of iodine or an iodide compound is specified in claim 5 in order to increase the output of a battery to be regenerated, for example, a solar battery. There are various ways to use iodine. Of course, iodine compounds are used in addition to the use of iodine alone, or in combination with iodine and iodide compounds and other elements, and then mixed with various solutions such as ethanol in the above three layers, or one or more of the above For example, iodine is left in a solid state without being directly mixed in the three layers, and is arranged in a cell. The above-mentioned iodine or the like is used for one or more layers, and iodine is solid or coated and placed in the cell.

  Individual iodine remains solid, or is coated in solid cells with water-based, oil-based paint, ink, or various other materials and placed in the cell. There are various coating methods. When iodine is doped into other materials, nickel iodide, copper iodide, etc. may be used in combination with iodine and other materials, and various methods of using iodine or iodide compounds are possible. . It does not specify usage. By using rice husk and iodine in the cell, there is an advantage that the redox action of silicon tetraiodide can be used. The combination of iodine and rice husk containing silicic acid is effective for regenerating batteries.

I → 3I and four iodide silicon I ₄ ^- use Table 1 of the two oxidation-reduction action of

  Silicon tetraiodide is an inorganic compound of silicon and iodide. Reacts with water and decomposes into silicic anhydride (silicon dioxide is silica) and hydrogen iodide. In dye-sensitized power generation, an oxidation-reduction action is required by exchange of free electrons between iodine and the dye, but this oxidation-reduction of silicon tetraiodide works effectively for these two oxidation-reduction actions. Hydrogen iodide has a reducing action, is easy to return to iodine in response to oxygen in the air, helps to produce redox in dye-sensitized power generation, and is beneficial.

I → 3I and silicon tetraiodide I ₄ ^- two redox actions take place in the cell, complementing each other (1) water, (2) iodine dissolved in tincture, (3) rice husk silicon, Then, (4) silicon tetraiodide in which iodine and silicon are combined and (5) silicon tetraiodide reacts with water to decompose into silica of silicon dioxide and (6) hydrogen iodide. At this time, it contributes to dye-sensitized power generation. (2) Return to iodine and (1) hydrogen again. Recycle.

  In the present invention, iodine is important in a battery for semiconductor power generation, but iodine essential for semiconductor power generation is also recycled. Conventionally, electrolytes connect electrodes and use a solution that has a redox effect, but in the present invention, the salt layer is not regarded as an electrolyte, but as an empty portion located in the middle of the P-type N-type. The action is carried out by a combination of iodine and rice husk.

  Using rice husks of biomass material, two different power generation methods, new dye-sensitized power generation by light and semiconductor thermoelectric power generation by heat, the function of storage and discharge like a capacitor occurs simultaneously in one cell. This is the invention that is the main subject of the present inventor, and can be used for waste disposal of rice husks, and can be used to produce batteries that are useful for agriculture and cheaply. In order to perform dye sensitization, it is necessary for light to emit free electrons from the dye. Titanium and zinc may be nano-sized. Semiconductor thermoelectric generation requires two different metals and P-type and N-type semiconductors.

  For biomass materials, rice husk is used. Rice husk can be used as a raw material for secondary batteries. In the present invention, not only regeneration by light and heat but also a function capable of storing, charging and discharging like a capacitor is required even when there is no light and heat. The three power generations are imaged in the image diagram of FIG. In FIG. 4, semiconductor thermoelectric power generation is performed in the lower part of the cell or device, light and dye sensitized power generation is performed in the upper part, and the action of a condenser is described using biomass material in the intermediate part. Although FIG. 4 implements the battery structure of claim 2, it may be a total of four layers of two different upper and lower metals, one layer, and three layers of claim 3.

  A battery structure that simultaneously meets the requirements for each power generation shown in the table below, and internal adjustment and unification are necessary so that the above two power generation methods and the above secondary battery such as a capacitor can be realized in one cell. It is.

Table 2

  A transparent plastic (which means a synthetic resin) that covers the cell. Utilizing its various characteristics, for example, polyethylene is impervious to water, but oxygen is permeable, polycarbonate is heat resistant. Taking advantage of the characteristics of various plastics such as the above, there is a possibility that the cell does not need to be completely sealed more than necessary. On the other hand, if properly sealed with various types of glass, plastic, silicon, rubber, and vinyl, it may continue to be regenerated in the cell forever. When the rice husk is a raw material, it seems that it depends on the material of the uppermost part whether complete sealing is necessary, or conversely, complete sealing is unnecessary. This is because rice husk generates gas, and this gas has the effect of acting on oxygen and hydrogen in water and air.

  One of two different power generation methods is dye-sensitized power generation and one is semiconductor thermoelectric power generation in a single cell using biomass material rice husks simultaneously with light intensity and temperature rise. This is shown in FIG. 2, FIG. 3, FIG. 4, FIG. 5, FIG. However, there are sustainability issues at this time.

  Among various additives, any one of boric acid, boron, phosphorus and sulfur according to claim 6 is doped into a layer containing titanium oxide or titanium or a titanium alloy or a layer containing zinc oxide or zinc or a zinc alloy. The two layers are simply made into a P-type semiconductor and an N-type semiconductor (in some cases, even in a salt layer). The P-type semiconductor is a layer that easily generates holes, and the N-type semiconductor is a layer that easily generates free electrons. Silicon contained in rice husk is 14-valent, titanium is 4-valent, and zinc is 12-valent. Boron is 13-valent. Phosphorus is 15 valent. It is well known that silicon semiconductors can be made P- and N-type by doping the semiconductor with boron or phosphorus.

  In the present invention, commercially available boric acid can also be used. Utilizing this difference, the plant is further added to the one or more layers of the present battery structure, and they are combined in various ways to form a P-type semiconductor layer that is easy to generate holes and a layer that is easy to generate free electrons. The N-type semiconductor layer is intentionally created easily. In order to further increase the output of the dried plant grains and powders used as a source of the pigment, metal grains and powders may be added to the one or more layers.

  Ruthenium dyes used in dye-sensitized solar power generation are known to be highly efficient using rare metals called rare metals, but in the present invention, they are dried and pulverized instead of dyes. Or the plant (not a pigment) processed in various ways and the use of various metals in the form of grains or powders are different from the conventional ones. The invention unique to the present inventors. In this way, the flow and movement of electrons can be activated in the cell easily and inexpensively without using a rare metal such as a ruthenium dye.

  The conductivity of the salt layer can be increased by putting black ink into the salt between the P and N type layers. Charcoal, black ink, pigment, and glue may be added to the above four layers or one or more layers. Addition of glue increases the adhesion of the four layers in the cell. In some cases, one or more of pigments, minerals, charcoal, black ink, black liquor, carbon black, graphite, glue, and those containing a chemical compound are used in the cell. Due to the effect of various metal elements such as copper, iron and cobalt contained in pigments and minerals, the layer can be easily made into a P-type or N-type layer, and is also implemented for that purpose.

  To the layer that receives light and heat-Add the above-mentioned various substances containing plants, metals, pigments and minerals-As an N-type semiconductor layer, free electrons are excited by light and heat, making it easy to exit to the external circuit, Free electrons that have returned from the external circuit to the cell through the electric wire enter the P-type semiconductor layer where holes are easily formed as counter electrodes (plants, metals, pigments and minerals are added to this P-type semiconductor layer, Free electrons are used to compensate for the loss of free electrons), and through the salt layer, free electrons are generated again in the N-type semiconductor layer, and free electrons excited by light and heat are emitted to the external circuit again. is there. This is repeated.

  In solar power generation, power cannot be generated without receiving light, but in the present invention, not only light but also heat can be generated at the same time. Even when there is no power generation. Many electrical appliances generate heat. For example, when the cell of the present invention is placed in contact with various adapters that generate heat, power is generated by the heat of the adapter.

  Depending on how the present invention is implemented, one or more materials of building material, wall material, heat storage material, heat insulating material, glass, plastic, silicon, rubber, vinyl, wood, metal on the outside or one side of the cell May be applied to the exterior. Another material that is not conductive is attached to or installed on the bottom metal surface of the cell to prevent leakage and electric shock. Epoxy resin can also be used for the exterior. You may laminate with a film. In some cases, this may be done by further stacking one layer of the present invention on the outside or both sides or one side of the cell. The present invention may be practiced in contact with and coupled to various other parts, devices, equipment, equipment, and products. The present invention is applied to other parts, devices, facilities, equipment, and products in plus alpha, and is also implemented as new parts, devices, equipment, devices, and products. Implementation as a solar cell is an example.

  Although it is a big assumption, this power generation can be carried out using the heat of a garbage incineration plant or a thermal power plant. If there is heat in the appliance, adapter, or multifunctional mobile device, you can use a battery that generates electricity. Alternatively, the engine, the motor, and the personal computer generate heat, and the battery is used to generate electric power by using the heat generation action, and the electric power regenerated by the battery is further used as electric power for the motor and personal computer. Completion of recycling energy.

  A heating wire with a snow removal function is placed on the roof in a snowy country, and the heat generated by the heating wire is placed at the bottom of the heating wire, which is used as a heat source for the battery, and the power generated by the battery is used as the heating wire. To do. It can generate heat from various sources such as factories, bathhouses, hot springs, water heaters, home appliances, personal computers and cars.

  Since there are various ways of using and implementing the above, the raw materials in the battery, specific optimal ratios and numerical values, and the structure of the battery (within the scope of the claims and specification) are greatly increased. Because we know that it will change, this implementation is about and we can't identify the numbers. This is because many examples are implemented depending on the purpose of use.

  Moreover, the present invention has a function of storing and discharging electricity like a capacitor. These actions can be realized with the minimum of two kinds of metals and the above three layers. There are two types of metal on the upper and lower substrates, and the structure shown in Fig. 1 in which the above three layers exist between the two types of metal, and is covered with a transparent material such as glass or plastic. There is one layer at the top, and there is one kind of metal directly below it (the metal has several holes in direct contact with the bottom and can communicate with the bottom). There is the structure of FIG. 2 in which there are the remaining two layers of layers with another kind of metal directly underneath. As described above, iodine is used in various ways in the cells having the two different structures.

  In addition, there is a cell of FIG. 3 in which a fourth layer is provided on the upper substrate according to claim 3. In this case, there are three layers between the upper and lower substrates, and one layer on the metal of the upper substrate (the metal has several holes drilled so that it is in direct contact with the lower part and can communicate with the lower part). Since it is provided, the total number of layers is four. There is also a cell in which the fourth layer provided at the top is formed by stacking layers of different layers within the layer. In any case of FIGS. 1, 2 and 3, iodine is used and implemented in various ways. The cell of rice husk without iodine can output current, but the output is weak.

  In the case of claim 1 (FIG. 1), claim 2 (FIG. 2), and claim 3 (FIG. 3), various shapes of wire mesh can be arbitrarily provided in the cell. The use of a wire mesh in the cell has the disadvantage that not all free electrons are sufficiently captured as current even though there are actually many free electrons in the cell. In addition, there is an advantage that a lot of free electrons are easily taken out as a current by a wire mesh inserted in the cell. By using various types of wire mesh in the cell, the current may be several times higher than the current extraction method without the wire mesh.

  When using a wire mesh in a cell, there is a variation, and if the wire mesh is not arranged well, contact failure will occur and the current to be taken out will be zero. The arrangement of the wire mesh enables high output because the output can be changed depending on the type of metal of the wire mesh, the shape of the wire mesh, and the arrangement location. In particular, when placed in contact with solid iodine, the output is high. This battery is another type of battery (the inventor's invention), and it has been confirmed and verified frequently that the current of 40 mA is increased to 120 mA when the wire mesh is placed in the cell without the wire mesh. . The output is as small as a 10-yen stamp (thickness is about 4 mm).

  To achieve high output, one layer can be multi-layered or multi-staged so that electricity can be generated by light of a wide range of wavelengths. Infrared rays are 780 nm or more, ultraviolet rays are 380 nm or less, and dyes are roughly classified into flavonoids, carotenoids, betalains, and chlorophylls, and dyes corresponding to wavelengths are used for each layer. Multi-layer and multi-stage are not limited to the upper layer. It is envisaged that one layer is multi-layered and multi-staged in order to achieve high output in any layer inside the cell, or to make it P-type or N-type.

  For example, when minerals and plants are used in the form of thin plates, such as P-type and N-type, the titanium and zinc layers that become P-type and N-type are one layer, but the breakdown of one layer is multilayer and multi-stage. The inside of two different metals and three layers (Claims 1 and 2) or four layers (Claim 3) can be formed in multiple layers in this way. Iodine is also used inside 3 and 4 layers as a containment layer. In this case, even one layer is multi-layered and multi-staged. Additives may be added as a layer. Moreover, the separator may be implemented before and after the salt layer.

  The solution to the above-mentioned problem is that a battery that regenerates power more easily and simply by performing power generation such as silicon-based solar power generation using a P-type semiconductor and an N-type semiconductor as described above. It was to create in the battery. It uses only cheap materials such as those used in dry batteries, rather than expensive silicon, avoiding expensive raw materials even at high output, and keeping the manufacturing process in a vacuum state. Using a manufacturing method that is not necessary and not difficult, it is commercialized as a low-cost raw material, a low-cost manufacturing process, a battery that can be regenerated at a low price, such as a solar cell, and is widely available on the market.

  Mainly by using rice husks that are made of titanium oxide or titanium, which is an inexpensive semiconductor, and zinc oxide or zinc, alloy layers and salt layers, and ground or carbonized rice husks. Making raw materials cheap, using iodine to make high output, additives such as boric acid, boron, phosphorus, sulfur, etc. to make semiconductors P, N type, in addition to making it easier to make free electrons in plants, now It can be changed from a primary battery such as a dry battery to a secondary battery and a solar battery, and various functions such as a condancer can be implemented in the present invention.

  In the solution of the problem, not only the battery to be regenerated but also this battery is implemented as an apparatus. Examples include solar cell modules, arrays, panels, etc. It will be implemented in other parts, devices, equipment, equipment and products with plus alpha, and will be implemented in various forms for various purposes as a device with different functions regenerated by light and heat. We will also apply for a patent on the method of manufacturing the battery to be recycled.

  In conventional dye-sensitized solar power generation, it is necessary to form a conductive film on the transparent material glass or plastic at the top of the cell in order to flow the free electrons of the dye excited by light to the external circuit. Or plastic is useless. In the present invention, the conductive film is unnecessary. Current can be taken from the top and bottom two types of metals, and even if a normal commercial product transparent glass or plastic without conductive film is placed on the top of the cell, it functions well as a battery to be regenerated or a solar cell for dye sensitization I can do it. Depending on the purpose, wiring may also be made from a wire mesh arranged in the cell, but in this case as well, in the present invention, a conductive film is not required for glass or plastic.

  High output cells are expensive with rare metals such as ruthenium dyes. The products for semiconductor thermoelectric generation are already on the market, but they are expensive. In the present invention, no special techniques or raw materials such as conductive film formation or rare metals are avoided and used, so the main raw material of the present invention is a layer containing titanium oxide or titanium or a titanium alloy or zinc oxide. Alternatively, rice husk is mixed in each layer of zinc or a zinc alloy-containing layer or salt, so that it can be made inexpensive and commercially available. Boron, phosphorus, etc. necessary for making P and N type semiconductors can be made into P and N type semiconductors by adding a small amount of commercially available boric acid to each layer mixed with rice husk if it is easy and good. It can be done without boron.

  For example, oolong tea leaves and other plants that are present as pigments can be pigmented, and even if they are not expensive organic pigments, regenerating batteries can be implemented. Electricity can be generated from metals used in combination with pigments, and even rare metals and powders of zircon. Anyway, a battery that can be reproduced at low cost, for example, a solar battery is possible. You can make a mixture of plants, intentionally change the mixture of plants, and make the semiconductor of titanium and zinc P-type and N-type. The change and movement of the magnetic field can be used with plants, the generation of current is increased, and the durability and sustainability are increased.

  In the semiconductor thermoelectric generator of the present invention that uses the plant itself for power generation rather than using only the pigment, the current is clearly increased even with a slight increase in temperature, so even if the temperature is not as high as 100 degrees or more. Semiconductor thermal power generation can be generated even by solar heat that is used in daily life. The effect of this invention is great. In general, in order to use semiconductor thermoelectric generation, there are special materials and complicated battery structures, and therefore, the effect that they become unnecessary is great.

  The manufacturing process also does not require a vacuum manufacturing process for producing high-purity silicon. In the present invention, in order to immediately dry each layer of the completed cell, it is also possible to place it on a hot plate at 100 degrees for a few minutes, but it is not necessary, so special equipment such as baking at high temperature Is also unnecessary. In Japan, raw rice husks can be made into the raw material of the present invention by crushing the rice husks that are familiar to them. Since the basic structure of the present invention is a simple structure of two metals and three or four layers as in claim 1 (FIG. 1), claim 2 (FIG. 2), and claim 3 (FIG. 3), it is special. No special manufacturing equipment is required, and it can be made in a private home. Even when a product is manufactured using a manufacturing apparatus of a mass production method in a factory, it is expensive and no special equipment investment is required.

  Since the present invention is a battery that can be used and regenerated if it emits light and heat, various electric products are used as heat sources in real life. In general daily life, heat is generated in various places, and by transferring the heat to metals and semiconductors, circulating renewable energy that regenerates electricity can be implemented. In the present invention, electric power can be generated even without high-temperature heat and strong light. The sun emits light and heat simultaneously on the ground, and both can be used simultaneously in the present invention.

  It is known that water and warm water are made into two layers in a water pipe and flow into the water pipe to cause semiconductor thermoelectric power generation. In such a case, the present invention simultaneously places a layer that generates power even with light at the top. Dye-sensitized solar power generation is also possible. The battery to be recycled according to the present invention can be made into a flexible shape, so it can be freely deformed according to the shape of something. It can be bent freely because it has a structure of two metals such as plate, circle and solid, and three or four layers. Depending on how the two types of metal are given different temperatures, the cells and devices shown in Figs. 1, 2, 3, and 4 can be modified depending on the idea, and a myriad of variations are possible. Moreover, semiconductor thermal power generation and dye-sensitized power generation can be performed simultaneously.

  Using rice husk as a raw material in the cell is a fire hazard, so it seems that the rice husk is easy to burn, but it is burned with kerosene and charcoal, ash and fire. However, if kerosene burns out, it will extinguish immediately. Unlike wood and charcoal, rice husk is very hard to burn. We added kerosene that was burned out about 3 times and confirmed the situation of the fire, but if only kerosene burned out, it would extinguish naturally after that. Therefore, even if it is exposed to high temperatures as solar cells, there is no need to worry about fire. It doesn't burn as much as trees. The cell of the present invention using a rice husk mixed with titanium oxide or zinc and salt is a safe and secure cell that does not cause pollution. Rice husk is also a waste. In Japan, rice husk is accompanied by rice cultivation. Effective use of this waste is also an effect of the present invention.

  The most important thing for the inventor was that even though it is well known that the expensive, silicon-based conventional solar cells continue to generate electricity for 20 years, their black and amber colors are determined. The appearance of the cell will break the old traditional streets of the Edo period. In the present invention, cells can be colored. If plant pigments or pigments are added to the layer that receives light or heat, the cells can be colored in red, blue, yellow, and green. The top transparent material can be made of ordinary glass or plastic, but they can also be patterned. Color can also be put out. This is because a conductive film is unnecessary. It can be hidden that batteries that can be regenerated even when applied to walls and roofs, both indoors and outdoors, such as solar cells.

  If mineral pigments are devised and doped to make P-type or N-type semiconductors, they generate electricity even without plants. Titanium oxide powder and zinc oxide powder of zinc white are currently used in mineral pigments as white powder, paint, and paint, but even in the present invention, it is possible to generate electricity using other mineral pigments for coloring cells. I already know. Therefore, minerals may be used separately from pigments that are processed by mixing various substances.

  A variety of minerals such as minerals containing radium with strong ionization effect, gem materials such as quartz, and other inexpensive minerals are included in one or more of the three layers of the present invention in a trace amount to make them P-type and N-type semiconductors. We know that it can be made highly efficient when added. Therefore, it is described in claim 10. When added to a layer in trace amounts, the present invention can create P-type and N-type semiconductors by combining various minerals. Various mineral shapes are used, such as solids, grains, powders, and liquids.

  Details about pigments and minerals. There are various types of pigments that can be added in the present invention. In the present invention, ceramic pigments used for coloring cobalt blue, green and reddish pink were tested. The pigment is colored because the pigment is a mixture of rock and metal, pulverized once in a mill, then drained and baked and baked to color the metal and further pulverized. So, various metals are mixed to produce a color. Copper is green, iron is dark brown, and a small amount of cobalt is added to produce a blue color. Since it is volatile, alumina is added. Add adhesive. If the iron rusts (oxidizes) on a daily basis, it turns reddish brown, and if you corrode copper, you see a green color.

  We have known that a slight amount of current flows when measuring the current of solid iodine (made by Wako Pure Chemical Industries) with a tester. Iodine tincture containing iodine was known to carry a small amount of current in micro units. For this reason, the present invention was implemented in which plants were quickly put into iodine tincture and free electrons of plants were also used for power generation. In addition, can the free electrons of metals contained in ceramic pigments used for coloring cells be used like P-type and N-type semiconductors?

  Therefore, Iodine tincture and individual color pigments were mixed quickly and measured for current. Then, unlike plants, the generation of current by the pigment could not be confirmed clearly (the current of iodine tincture was measured, but the pigment itself seems to have no current). An aqueous solution in which the pigment was dissolved in water was also measured, but no generation of current was confirmed. In the case of water alone, the current was zero even in micro units. The water itself is zero current. Even if a pigment is mixed in the water, the current is zero.

  In the present invention, in the mixture of plants, an electric current is generated. However, when the lead bar of the tester that measured the current is immediately attached to the water in another container, a large electric current is generated in the water in the other container that originally has no current. Had already discovered. So I did the same experiment. When a current was measured with a solution in which each pigment was dissolved in iodine tincture, and a tester lead rod was put on the water in another container immediately after the pigment was mixed, a large current could be measured from the water in the other container. This is because a current is generated by a change in the magnetic field. The current generated by the change in the magnetic field immediately drops to zero, but in the same experiment the current can always be measured with water mixed with pigment.

  This can be used as a method for easily producing the semiconductor P-type and N-type of the present invention. In the tester, when each pigment is mixed with iodine tincture, the pole of the lead bar is frequently replaced with the plus pole and the minus pole. Even if a minus and a tester display, this generates a large current correspondingly, and if it is a cell, it does not flow backward.

  When measuring current with 9 combinations of 3 x 3 equals, the combination of 3 types of solutions of green, blue and red brown pigments mixed with iodine tincture and 3 types of solutions of each pigment mixed with water There was a difference in the amount of current generated. Four combinations with large current generation are described below from the current measurement results of the combinations. However, it is not strictly measured.

Table 3

  In one example, it is assumed that the mixture of iodine tincture and pigment is N-type, and the aqueous solution is P-type. Combination numbers (8), (3), (5), (7), etc. gave good results. From the result, combination number (8) in one example is a mixture of iodine tincture and pink pigment (a pigment containing a lot of iron) in the layer that wants to be N-type, and water and green pigment (a lot of copper is contained in the P-type layer) When the combination is mixed, current flows through the combination.

  Originally, even if pigment is mixed, the current is zero in the aqueous solution. From this, if copper, iron, and cobalt are devised and doped in the titanium and zinc layer of the present invention, current can be generated in the semiconductor P-type and N-type winds. However, there are influences of other additives such as boric acid, plants, charcoal, and ink, and the cell does not have such a simple result.

  This utilizes the generation of a magnetic field associated with the combination of the two solutions. Although conducted not only indoors but also under sunlight, current is generated. By intentionally moving the tester's lead rod from a solution in which iodine tincture and pigment are mixed to an aqueous solution in which water and pigment are mixed, the inventor intentionally changes the magnetic field, and Fleming's law works. As a result of this change, a current was generated.

  It is a different starting method from the conventional free electron flow of dye-sensitized power generation. According to Fleming's law, when a current is generated, a magnetic field is generated along with it, and a force that moves along with the magnetic field acts. Forces that move with current and magnetic field are generated at the same time in different directions. If the magnetic field is changed intentionally, an electric current is generated accordingly. According to the law, an electric current can be generated by deliberately changing the magnetic field.

  It has been found that not only the free electrons of plants but also the generation of current can be used in the present invention by the change of the extreme magnetic field of both electrodes by the addition of this pigment. Furthermore, since there are various additives and processing for pigments, a large current can be generated by using minerals that are not pigments. The current can be generated depending on the device or improvement of adding metal to the layer in the cell. This is one of the solutions to the problem described in claim 10 and is also effective. In the present invention, it is possible to implement such a method other than plants.

  A layer of titanium or zinc mixed with ground rice husks, when they come to the top, they look like earthen walls. It can be shown as a traditional earthen wall where “straw” is mixed with old-fashioned earth where “straw” called rice husk crushed in the earthen wall is mixed. Some cells do not use the transparent glass or plastic at the top of Fig. 2 or Fig. 3, but expose the titanium or zinc layer as it is. Such usage is an old earthen wall. The name of the example is a mud wall. The present invention can be implemented as a wall as long as safety (such as applying a transparent thin film to the earth wall with epoxy resin) such as prevention of electric shock of electric current is ensured.

  It is also possible to place a wall-like or another form on the outside of the metal of the cell in which the metal is arranged one above the other. Another layer may be provided outside the metal. Since metal is carrying an electric current, it is planned to apply an exterior in the practice of the present invention. The form and state of the exterior can be implemented in various ways depending on the purpose of use. It may be a heat storage material or a heat storage layer, conversely a heat insulating material or a heat insulating layer, or a variety of building materials or wall materials. Various materials such as glass, plastic, silicon, rubber and vinyl are used for the exterior. Based on the present invention, a layer is formed on the outside for various purposes and various materials are used.

  For example, when a copper plate is applied to the lower substrate of two different metals, if it is exposed to sunlight for a long time on a midsummer day, the copper plate at the bottom of the cell will become hot, and there will be no temperature difference between the two different metals. Often decreases. In that case, a titanium or zinc layer is also formed on the outer side of the lower copper plate, and the heat and heat of the copper plate are also used. One of the reasons why the present inventor wants to improve the silicon-based solar cell is to construct a battery that regenerates while maintaining the design of the traditional cityscape and the buildings that have been preserved there. The solar cell will be installed while keeping the traditional plaster wall. When the present inventor constructs a solar cell as a solar cell, the solar cell that expresses the cherry blossom in full bloom is desired to be constructed even at a slightly higher price. The same goes for the storehouse, the storehouse, and the castle. It is the battery which this invention reproduces which can maintain the design property on a roof and a wall.

  To that end, we considered that the conductive film required for the dye-sensitized solar cell is not required for glass or plastic, so that a desired design can be applied to glass or plastic using printing technology. In that case, since the light transmittance deteriorates, it was considered to use solar heat. The solar cell that maintains this design is very important for the inventor. If the rice husk is mixed with titanium or zinc and the color is added, the crushed rice husk looks like “straw” in the earth wall, It is a solution to the problem to use raw rice husks that are not carbonized, not ashed, or just broken shells.

  The present invention is not limited to two types of metal and three-layer structure as in claim 1 (FIG. 1) or claim 2 (FIG. 2), but in addition to two types of metal as in claim 1 (FIG. 3). Four layers are possible, the uppermost fourth layer can be multi-layered or multi-staged, and a wire mesh can be arranged in the cell of the structure of FIGS. This is because these various battery structures assume a highly efficient power generation method when used as a power source for an electric vehicle.

  In the present invention, a layer containing titanium oxide or titanium or a titanium alloy, a layer containing zinc oxide or zinc or a zinc alloy, or a rice husk pulverized with a salt layer (in this case, the rice husk is water, other solvents, solutions The ratio of use and the ratio of the amount is not clear. Approximately, the volume ratio of each layer and crushed rice husk are carried out as much as each volume.

  The volume ratio of — (titanium oxide or titanium or titanium alloy) —to— (milled rice husk containing water etc.) — Is approximately 1: 1 to form a layer. The salt layer and the layer containing zinc oxide or zinc or a zinc alloy form the same volume ratio. I am about. In the actual implementation, when the ratio is set to about 1: 5 (in this case, the amount of rice husk is increased by about 5 times), the power generation amount is the same as the one-to-one volume ratio, but it is sustained. There seems to be no sex. Conversely, if the amount of rice husk is reduced to 3: 1 and the amount of titanium oxide or titanium or titanium alloy or zinc oxide or zinc or zinc alloy or salt is increased instead of 1: 1, the efficiency and sustainability are improved. To do.

  Do you make each layer thin? Is it thick? However, although various conditions are changed, the present invention does not limit the numerical values of the volume ratio and the quantitative ratio as the best state for all of the materials used. Although the best values such as these ratios can be clarified in the future, and more efficient cells can be realized, the present invention does not specify numerical limitation claims.

  In many implementations, the performance of the cell when the above three layers are formed on two kinds of metal with an area of about 1.5 cm each (the whole cell is 3 cm each and there is no wire mesh in this cell). The evaluation shows the maximum value of about 50mA as a primary battery. This is not a cell that weighs each material strictly, and it shows the same maximum value even if the cell is made in a smaller amount, but we do not weigh each material strictly. No.

  In the reproduction by receiving light and heat, the output of current deteriorates from this, but the reproduction has been confirmed many times. Higher output can be achieved by changing the metal used for plants. Higher output can be achieved by improving the salt layer.

  In the structure of claim 2 (FIG. 2), a layer that directly receives heat and light is formed in multiple layers, and when the uppermost layer in FIG. High output can be achieved by using multiple stages. The intent of multi-stage and multi-stage formation is realized in a multi-layer, multi-stage layer by forming a plant-incorporating layer that emits the corresponding pigment to incorporate both short and long wavelengths in order to convert all wavelengths of light into electricity Is to do. The titanium layer mixed with water and the titanium layer mixed with ethanol as a solvent containing iodine or iodide compound do not intersect, so plants can be generated in multiple layers or multiple stages according to the purpose according to the wavelength to generate electricity I know that.

  According to the interpretation unique to the present inventor, a layer of pigment, a layer of a mixture of plant and rice husk << 3 >>, a layer of a role of an electrolyte, etc. are given different meanings to be multilayered or multistaged. By assuming layers with different roles in this way, the contents of the mixture change, and various actions and effects are found, such as taking in light of different wavelengths and promoting and maintaining the regeneration of free electrons in plants.

  Nano-sized titanium oxide, etc. is white at first, but becomes transparent over time, so even multi-layer or multi-layer titanium layers can transmit light down to the bottom. Multi-layer and multi-layer are described in Example 4 (1) and Example 7 (1).

  Concentrating solar cells use a wide Fresnel lens, and by certainly collecting sunlight at one point, the amount of semiconductor used can be reduced, but to collect light at one point. The area of the Fresnel lens, which is necessary, is widely needed, and we see the power of scoring quickly, such as the paper placed under the magnifying glass, collecting sunlight at one point with a magnifying glass. A cell is required as well.

  In the present invention, a Fresnel lens is not used, and higher output can be achieved with the above improvement. First, if an improved high-efficiency organic dye is used in the present invention, a high-efficiency cell is completed.

  In the future, in the present invention, a metal mesh is simply used in a cell like a quantum lot type in the construction of a cell of 3 centimeters square, and the current generated in the cell is ordered by the mesh. All the details are taken out without waste, and we expect the maximum output of current as the power supply for electric vehicles. In other batteries and other experiments with different types of batteries and raw materials, a current of 40 mA is output in a cell (thickness of about 4 mm) with an area of about 10 yen stamp, and a wire mesh is placed in the cell and measured with a tester. Is often up to 120mA.

  When implemented with another type of battery as described above, a current of 120 mA in the area of a cell (thickness of about 4 mm) of about 10 yen stamp has a wire mesh placed in the cell, and this wire mesh increases the current. It is done. Therefore, by arranging a wire mesh and changing the content and ratio of raw materials and additives, it is possible to improve the output and improve durability in the future.

Sectional views (one example) of each cell of Example 2, Example 3 (1), Example 5, and Example 8 are battery structures according to claim 1. 1 Layer containing titanium oxide or titanium or titanium alloy (mixed with rice husks and various additions such as plant and boric acid) 2 Layer of salt (mixed with rice husks, added charcoal, ink, glue, etc.) 3 Layer containing zinc oxide or zinc or zinc alloy (Mixed rice husks and various additives such as boric acid) 4 Aluminum plate (1 example) 5 Copper plate (1 example) Sectional views (one example) of each cell of Example 1 (1), Example 3 (2), Example 6 (1) earth wall, and Example 6 (2) are battery structures according to claim 2. 1 Layer containing titanium oxide or titanium or titanium alloy (mixed with rice husks and various additions such as plant and boric acid) 2 Layer of salt (mixed with rice husks, added charcoal, ink, glue, etc.) 3 Layer containing zinc oxide or zinc or zinc alloy (Mixed rice husks and various additions such as plants and boric acid) 4 Aluminum plate (1 example) (with holes) 5 Copper plate (1 example) 6 Arrange materials such as glass or plastic arbitrarily Sectional drawing (one example) of the cell of Example 4 (3) is the battery structure of claim 3. 1 Layer containing titanium oxide or titanium or titanium alloy (similar to 1 in FIGS. 1 and 2) 1-1 Layer containing titanium oxide or titanium or titanium alloy for dye sensitization (including iodine, positions of 1-1 and 3) 2) Salt layer (similar to 2 in FIGS. 1 and 2) 3 Layer containing zinc oxide or zinc or zinc alloy (similar to 3 in FIGS. 1 and 2) 4 Aluminum plate (one example) (with holes) 5 Copper plate (example) Structure of the cross section of a cell or device for solar or solar heat power generation in the upper part with semiconductor heat generation with hot and cold water at the lower metal (the structure can be modified in one example) 1 Including titanium oxide or titanium or titanium alloy Layer (same as 1 in FIGS. 1 and 2) 2 Salt layer (same as 2 in FIGS. 1 and 2) 3 Layer containing zinc oxide or zinc or zinc alloy (same as 3 in FIGS. 1 and 2) 4 Aluminum plate ( 1 example) (with holes) 5 Copper plate (1 example) 6 Arrange materials such as glass or plastic arbitrarily 7 Aluminum plate soaked in either hot or cold water (1 example) freely deformable 8 hot water Copper plate soaked in either water or cold water (example) freely deformable No. 9, 10 Water or cold water container, equipment (one example) The front view of the cell of Example 1 (1). Front view of a cell or device that produces dye-sensitized three layers only in one part and the aluminum plate exposed in the other parts, and simultaneously performs dye-sensitized power generation and semiconductor thermoelectric power generation (example) (i) 1 Titanium oxide Or a layer containing titanium or a titanium alloy (similar to 1 in FIGS. 1 and 2) Arrangement in which materials such as glass or plastic are arranged directly above 4 Aluminum plate (1 example) (with holes in the lower part of 3 layers) 11 Light bulb ( B) Front view of Example 1 (1) (1 example) 1 Layer containing titanium oxide or titanium or titanium alloy (similar to 1 in FIGS. 1 and 2) Arrangement in which materials such as glass or plastic are arranged arbitrarily above 4 Aluminum plate (1 example) (3 layers below There is a hole in the part) Image of simultaneous regeneration with light, heat and biomass using iodine, rice husk 12 Semiconductor thermoelectric power generation (P type or N type) 13 Semiconductor thermoelectric power generation (P type or N type) 14 sensitized generator (utilizing plants and pigments and minerals) 15 dye-sensitized generator (available plants and pigments and minerals) 16 charge and discharge to cell action (including iodine, I → 3I and silicon tetraiodide I ₄ ^- 2 (Redox action of two) (Charcoal, black ink, black ink, carbon black, graphite, glue, etc. can be added) 17 Rice hulls of biomass material Sectional view of cell of Example 4 (1) 1 Layer containing titanium oxide or titanium or titanium alloy (similar to 1 in FIGS. 1 and 2) 1-1 Layer containing dye sensitized titanium oxide or titanium or titanium alloy ( (Including iodine, the positional relationship between 1-1 and 3 can be exchanged.) 2 Salt layer (similar to 2 in FIGS. 1 and 2) 3 Layer containing zinc oxide or zinc or zinc alloy (similar to 3 in FIGS. 1 and 2) 4 Aluminum plate (1 example) (with holes) 5 Copper plate (1 example) 6 Arrange materials such as glass or plastic arbitrarily 18 Wire mesh 19 Solid iodine 20 Two testers It is good to have two separate wirings, but in the tester of ▽ where the free-electron output pole is reversed, free electrons return from the upper aluminum plate to the external circuit and return to the copper plate. The free electrons from the copper plate come out to the external circuit and return to the aluminum plate. Semiconductor thermoelectric power generation and dye-sensitized power generation can be performed simultaneously, and current can be measured simultaneously with two testers. With only one wiring, current does not flow well.

  Although overlapped, the best form is as claimed, so claims are listed and explained at the same time in the drawing. [Claim 1] Using different types of metals (4 and 5 in FIG. 1) at the top and bottom in the cell, and having a layer (1 in FIG. 1) containing titanium oxide or titanium or a titanium alloy on one metal, A layer containing zinc oxide or zinc or a zinc alloy (3 in FIG. 1) is provided on another metal, and a salt layer (2 in FIG. 1) is provided between the two layers. A regenerating battery characterized by being mixed (1, 2 and 3 in FIG. 1), wherein the layer containing titanium oxide or titanium or a titanium alloy (1 in FIG. 1) as a structure and the zinc oxide or A layer containing zinc or a zinc alloy (3 in FIG. 1) produces a regenerative battery in which the upper and lower positions can be interchanged.

  2) Change the position of the three layers according to claim 1, titanium oxide or titanium or titanium alloy under one or more of glass, plastic, silicon, rubber, vinyl (6 in FIG. 2) There is a layer (1 in FIG. 2) containing a metal (4 in FIG. 2) underneath, and the metal has one or more holes, a salt layer (2 in FIG. 2), and oxidation There is a layer (3 in FIG. 2) containing zinc or zinc or a zinc alloy, and underneath it is provided with a different kind of metal (5 in FIG. 2), and rice husk is mixed in each of the above layers (FIG. 2). 2 of 1, 2 and 3), a layer containing the titanium oxide or titanium or titanium alloy (1 in FIG. 2) as a structure, and the zinc oxide or zinc or zinc alloy. Reproduction that can replace the upper and lower positional relationship with the layer (3 in Fig. 2) That the battery - to fabricate.

  (3) In addition to the three layers (1, 2, 3 in FIG. 3) according to claim 1 or 2, one layer (1-1 in FIG. 3) is added, and glass, plastic, silicon, rubber, vinyl are added. There is a layer (1-1 in FIG. 3) containing titanium oxide or titanium or a titanium alloy at the bottom of any one or more materials (6 in FIG. 3), and a metal (4 in FIG. 3) is placed below the layer. The metal has one or more holes, and further has a layer containing titanium oxide or titanium or titanium alloy (1 in FIG. 3), a layer of salt (2 in FIG. 3), zinc oxide or zinc or zinc There is a layer (3 in FIG. 3) containing an alloy, and underneath it is provided with a different kind of metal (5 in FIG. 3), and rice husks are mixed in each of the above layers (1-1 in FIG. 3). , 1, 2, 3), a layer containing the above-described titanium oxide or titanium or titanium alloy as a structure ( 3 1-1,1 of), the layer containing the zinc oxide or zinc or zinc alloy (3 in FIG. 3), the battery to be reproduced can be replaced a positional relationship between the upper and lower - fabricating.

  [Claim 4] Either one of the rice husks is crushed, the rice husks are carbonized, the rice husks are made ash, or any other state is used. A battery to be recycled as described in any of the above is manufactured.

  5) One or more iodine or iodide compounds are used in the cell (in the cell of FIGS. 1, 2, 3, 4, 5 and 7. 16 of FIG. 19) The battery to be reclaimed according to claim 4 is manufactured.

  [6] A layer containing titanium oxide or titanium or a titanium alloy, or a layer containing zinc oxide or zinc or a zinc alloy includes a salt layer containing at least one of boric acid, boron, phosphorus and sulfur. 6. A regenerative battery as claimed in claim 5 is fabricated which is added to one or more of each of the layers.

  7. A plant is mixed in one or more layers in the cell (1, 2, 3, 1-1 in each figure, 16 in FIG. 6), a plant and a metal are mixed, or a plant and a metal 7. A battery for regeneration according to claim 6, wherein the battery is mixed with iodine.

  [8] The cell according to [7], wherein one or more of charcoal, black ink, black ink, carbon black, graphite, glue, pigment, and a substance containing a chemical compound are used in the cell. Make a battery to recycle.

  (9) A battery for regeneration according to (7), in which a wire mesh (18 in FIG. 7 is an example) is arranged between the layers in the cell.

  [Claim 10] One or more of pigments, minerals, ores are used in one or more layers (1, 2, 3, 1-1 in each figure, 16 in FIG. 6) in the cell. A battery according to claim 5 is manufactured.

  (11) A battery for regeneration according to (10), in which a wire mesh is arranged between the layers in the cell, is manufactured.

  (12) A battery for regeneration according to (5) is manufactured using one or more of natural pigments, plant pigments or organic pigments.

  (13) A battery for regeneration according to (12), in which a wire mesh is arranged between the layers in the cell.

  A device in which the battery to be regenerated according to claim 5 is made into a module or an array, or a device in which the battery to be regenerated according to claim 5 is applied to a part, device, facility, equipment or product ( Figures 4 and 5 are examples.

  [Claim 15] Claims in which one or more materials of building material, wall material, heat storage material, heat insulating material, glass, plastic, silicon, rubber, vinyl, wood, metal are applied to the exterior or one side of the cell The battery to be reclaimed according to any one of items 1, 2, and 3 (FIGS. 1, 2, 2, 3, 4, 5, and 7) is manufactured.

  (16) A battery for regeneration according to any one of (1), (2) and (3) is produced, wherein one or more power generations are performed, ie, semiconductor thermal power generation or dye-sensitized power generation.

  [17] The regenerative battery according to any one of [1], [2] and [3] having a different structure in one or more layers, -Make.

  In the best mode for carrying out the invention, not only the battery to be regenerated but also the battery is implemented as an apparatus. Examples include solar cell modules, arrays, panels, earth walls, etc. It will be implemented in other parts, devices, equipment, equipment and products with plus alpha, and will be implemented in various forms for various purposes as a device with different functions regenerated by light and heat.

  In the present invention, the problem described in “Problems to be solved by the invention” is taken up that silicon, other solar cells, and other renewable batteries are expensive. In order to solve this problem, the raw materials used in Examples 1 to 10 of the present invention are made of familiar materials that can be obtained at low cost. However, the present invention cannot be realized by the following Examples 1 to 10 when a power source for an electric vehicle is produced with a battery that reproduces a desired maximum output. Although low power regeneration can be realized, the high output is not limited to the first to tenth embodiments. Therefore, the upper and lower different metals described in the claims are not limited to aluminum and copper plates described below. Only one example of a number of embodiments is described.

  The metal is described. The metal is not only a single metal of typical metal elements, transition metal elements and typical non-metal elements, but also other additives such as alloys or synthetic resins in which one or more of the above elements are mixed and combined. Also includes alloys.

  Iodine, aluminum, chromium, nickel, cobalt, manganese, molybdenum, copper, titanium, calcium, iron, tin, zinc, zirconium, lithium, panadium, cadmium, lead, gold, silver, platinum, magnesium, barium, strontium, indium, Various elements such as ruthenium, barium, silicon, oxygen, and hydrogen, or alloys of various combinations can be used. Alloys containing lithium iodide, calcium iodide, potassium iodide, sodium iodide, and various iodide metals such as nickel iodide and copper iodide, stainless steel, steel, nickel alloy, aluminum alloy, titanium alloy, zinc alloy Stainless steel, copper alloy, cobalt alloy, iron alloy, stainless steel, stainless steel, tinplate, tin, various metal plywood, zinc and titanium alloy, etc. They may be plated but not limited.

  Furthermore, other additives such as synthetic resin may be added or a coated alloy may be used. Although it is an aluminum plate mentioned in one example, since a thin plate is easily corroded by iodine, it is carried out by using a strong aluminum alloy duralumin in some cases. Metals specified for durability and high output are defined as metals including various alloys in a broad sense.

  Describe the layer. For each of the three layers, titanium oxide or titanium or titanium alloy is used, and barium titanate is also used as the titanium alloy. Various titanium alloys are also used as layers. Similarly, the layer containing zinc oxide or zinc or zinc alloy can be applied not only to zinc oxide and zinc, but also to various alloy layers with addition of typical metal elements, transition metal elements, typical non-metal elements, and the like.

  Titanium oxide or titanium alloy of the layer containing titanium or titanium alloy is, for example, iodine, aluminum, chromium, nickel, cobalt, manganese, molybdenum, copper, titanium, calcium, iron, tin, zinc, zirconium, lithium, panadium, An alloy in which various elements such as cadmium, lead, gold, silver, platinum, magnesium, barium, strontium, indium, ruthenium, sodium, barium, oxygen, hydrogen, radium, and silicon are mixed and combined with titanium. is there. Various other additives may also be included in the layer comprising titanium oxide or titanium or a titanium alloy.

  Zinc oxide or zinc alloy in a layer containing zinc or zinc alloy is also the same, for example iodine, aluminum, chromium, nickel, cobalt, manganese, molybdenum, copper, titanium, calcium, iron, tin, zinc, zirconium, lithium, Panadium, cadmium, lead, gold, silver, platinum, magnesium, barium, strontium, indium, ruthenium, sodium, barium, oxygen, hydrogen, radium, silicon and other various elements alone and various other various additives It is an alloy that is mixed with zinc and various mixtures and various combinations. Titanium layers in which one or more of titanium oxide and titanium and titanium alloys are mixed are also possible. A zinc layer in which one or more of zinc oxide, zinc and zinc alloys are mixed is also possible.

  According to the present invention, as a battery to be regenerated is increased in output and durability, the metal disposed above and below, the titanium alloy as the layer, and the raw material of the zinc alloy as the layer are changed. In the present invention, it is not limited whether titanium is an anatase type, a rutile type or another type. It is not limited whether the raw material titanium or zinc is for ceramics or dye sensitization. In the case of a high output, a titanium zinc alloy can be used for the layer so that barium titanate can be cited as an example.

  If the layer containing titanium oxide or titanium or titanium alloy that receives light or heat directly or the layer containing zinc oxide or zinc or zinc alloy is placed at the top of the cell, the top layer is Multiple layers or multiple stages can be made in one layer so that electricity can be generated by light having a wavelength of. This is not limited to the upper layer. It is envisaged that one layer is multi-layered and multi-staged in order to achieve high output in any layer inside the cell, or to make it P-type or N-type. For example, when minerals are used in the form of thin plates, such as P-type and N-type, the P-type and N-type titanium and zinc layers can be one layer, but the breakdown of one layer is multilayer and multistage. The inside of two different metals and three or four layers can be multi-layered and multi-staged in this way. Iodine is also used on the inside and part of the 3 and 4 layers as a containment layer. In this case, even one layer is multi-layered and multi-staged.

  A separator may be disposed between the layers.

  In the present invention, the rice husk is also mixed in the four layers of the battery structure consisting of two different metals and three layers according to claims 1 and 2, or two different metals and four layers according to claim 3. . In some cases, rice husks are mixed in various states. According to claim 4, the rice husks are broken, such as breaking the rice husks, carbonizing the rice husks, turning the rice husks into ash, and mixing them in different states. , Crushing, crushing, grinding, kneading, etc. The solid rice husk can then be mixed with water or iodine-containing solutions or other solutions, doped into something, processed, and so on. Other than that, it can be carried out in various ways, such as steaming, steaming, etc. There is no limitation on the form or method of use of whether the rice husk is solid or liquid.

  In the examples, iodine tincture is used as a solution, but this is used for the purpose of quick explanation, and the present invention provides a dye with iodine, an iodide compound, and a solvent as in a conventional dye-sensitized solar cell. This is because it is necessary to say that a strict electrolytic solution is not required for the redox action of the above. In addition to this redox action, the present invention places importance on the redox action of silicon tetraiodide in which iodine and silicon contained in rice husks are combined. It is not the case that only iodine tincture is implemented and specified. Commercially used iodo tincture is often used in the implementation, but not because idiotin tincture is specified, but because I want to explain the present invention quickly, I will describe the iodo tincture described below.

  Commercially available iodine tincture is a mixture of iodine, potassium iodide and ethanol. In claim 5, it is said that one or more of iodine or iodide compounds are used in the cell, but various kinds such as nickel iodide, lithium iodide, sodium iodide, calcium iodide, potassium iodide, etc. Iodide compounds can be made. Which other element, which other substance and iodine are combined to form an iodide compound is not limited.

  Many solvents other than ethanol can be implemented. Mixing one or more of acetonitrile, methoxynitrile, ethylene carbonate, propionitrile, methoxypropionitrile, propylene carbonate, etc., and also changing the ratio of the capacity, it is possible to The performance of the battery used will also change significantly. An infinite number of these combinations can be implemented.

  The present invention uses commercially available iodo tincture to demonstrate the effectiveness of the present invention. Therefore, since it is desired to first explain that the present invention is effective by using a solvent or an iodide compound as a certain material, we decided to implement and explain iodo tincture having the same action. Of course, iodine tincture is not optimal. Although proprietary mixtures other than iodine tincture have been implemented, the use of iodine tincture is not the object of the present invention.

  In order to improve performance, high output, and durability, non-iodine tinctures will be implemented, but from the following, in order to demonstrate the novelty, inventive step, and uniqueness of the present invention, one example of iodinated tincture with the same action as above Take up as. This implementation is not limited to iodine tincture. In reality, it is implemented in many combinations.

  The shape of the various raw materials may be liquids such as grains, powders or plates. Not limited. Broken rice husks, carbonized and incinerated rice husks can be mixed with other metals in manufacturing and processing. Even when a wire mesh is arranged in a cell, the type of the wire mesh is not specified. It can be made of stainless steel or other metals.

  Even when the shape of the cell and the battery to be regenerated become a device, it can change flexibly. When using the heat of a PC adapter as a power source for regeneration, when implementing the present invention on a water pipe, whether it is a cell, module or array with metal on top of the roof, or even when it is implemented on a wall The shape can be implemented flexibly. It can also be implemented like a clay wall and is not a limited embodiment of the prior art.

  In the present invention, iodine or iodide compound is important, but it is not limited how it is carried out. In the present invention, nickel iodide is used in combination with other elements and other substances. Some substances use iodine, which is easily sublimated, added to metals and other materials to maintain the effect of iodine. Iodine may be coated in various ways as a solid, but it may be paint or ink, or it may be coated with other materials such as nail polish. Carbon black ink may be used.

  Conventional pigments, organic pigments, and plants of the present invention may be used as pigments that emit free electrons. In one example, a commercially available oolong tea leaf itself is placed in a cell. In some cases, natural dyes, organic dyes, and plants are not used, and minerals can be used to generate current by simplifying the semiconductor to be P-type or N-type. As an advantage, it is durable and can be used for a long time. Of course, you may mix with a natural pigment | dye, an organic pigment | dye, and the plant of this invention. Minerals may also be used as pigments to color the cells. The output efficiency changes depending on which mineral is used. High output can be achieved if minerals containing radium are used.

  This may include a metal that activates the electrical action of the plant used in conjunction with the plant, but the efficiency of output also varies depending on the type of metal. The zircon described in the examples (in this case used in powder) is only one example. Zircon produces heat, so it's good in winter, morning and cold, but another metal may be better in hot weather. Claim 7 thus identifies iodine as well as plant and metal. For quick and high output, other metals such as lithium, gold, silver, lead, copper, iron, and cobalt may be used as the metal that activates the electrical function of the plant.

  The current and voltage output are changed depending on the purpose, and are not limited to the following examples. Examples 1 to 10 are the same as those in the case of being implemented with familiar and inexpensive raw materials. It is only an example. However, the embodiment described below provides a rechargeable battery that operates simultaneously with light and heat, and also with the light and heat of the sun, which is overflowing in daily life, and with the generation of slight heat due to the use of electrical appliances in the home. In Examples 1 to 9, in order to demonstrate that power can be generated by plants alone, the performance evaluation is a numerical value only for the use of plants without using pigments or minerals.

  Implementing the present invention by applying one or more materials of building materials, wall materials, heat storage materials, heat insulating materials, glass, plastic, silicon, rubber, vinyl, wood, metal to the exterior or one side of the cell There is also. Another material that is not conductive is attached to or installed on the bottom metal surface of the cell to prevent leakage and electric shock.

  The exterior is important. To prevent electric shock, cover the indoor / outdoor landscape and the battery to be reconstructed, the cell becomes hot under the midsummer sun. Since the solar heat can be used for the water heater, the heat of the metal of the cell lower substrate can be stored and used. A heat storage layer may be provided, or conversely, a heat insulating material may be used in order to give a temperature difference between two different metals or in a cold district or a valley of a building.

  It is possible not only to use a metal having excellent heat conductivity for the upper and lower substrates and layers of the battery in order to generate electricity with a slight heat, but also to promote power generation by stacking more highly conductive metals. Depending on the location and purpose of implementation, various materials, layers, parts, and related equipment (such as water heaters) can be installed on the top and bottom of the battery as an exterior. In the following examples, the description of the specific image of the apparatus and equipment is omitted, but the exterior and such construction are assumed.

  The whole image contains dissolved iodine in three layers, and solid iodine is placed in the cell.

(Example 1 (1))
As a mixture of plant and rice husk << 3 >>, the following mixture was produced in an approximate weight ratio. The following materials, ratios and numerical values are not limited numerical values, but in one example in which various numerical values can be changed, in this way, the regenerated battery of the present invention has only been confirmed for a long time in this example. It does not reproduce the state of the battery being regenerated.

  Furthermore, the following were mixed in the above-mentioned plant and rice husk mixture << 3 >> in an approximate weight ratio.

Mixture of plant and rice husk << 3 >>
“Chaff (broken husk, crushed in this case): 3 g vs. iodine tincture: 17 g vs. hibiscus powder (may be henna powder or other plants): 1 g vs.
A total of 22 to 17 g of zircon powder (an example of metal): 1 g was added to the following and mixed.

What is mixed in the plant and rice husk mixture << 3 >> is as follows.
“Iodine (manufactured by Wako Pure Chemical Industries, granular): 3 g against water (including trace amounts of potassium iodide and agar in water): 1 g vs. citric acid (commercial product, powder): 1 g”
The total of this mixture is 22 grams. This mixed solution is named as part B for convenience.
This iodine, water (including iodide compounds, agar), and citric acid are those that the present inventor has been conducting experiments over a long period of time as batteries that can be regenerated. It does not specify the ratio or material. You can do it without using agar.

  Titanium oxide or titanium or titanium alloy, salt, zinc oxide or zinc or zinc alloy is mixed with a small amount of the above-mentioned component B, and the layer containing titanium oxide or titanium or titanium alloy, layer of salt, zinc oxide or zinc Alternatively, a layer containing a zinc alloy is formed. In the case of an alloy of titanium oxide and an alloy of zinc, the efficiency can be further minimized by slightly changing the raw materials. Therefore, in the present invention, titanium oxide or titanium or a titanium alloy is not limited to titanium oxide. One example of an alloy is barium titanate. Similarly, in the case of a zinc alloy, a variety of various types are possible, such as zinc oxide or zinc or a zinc alloy. In the present invention, titanium alloy and zinc alloy are used as raw materials.

  Since these are listed in the examples, they are long. Therefore, in the following, a layer containing titanium oxide or titanium or a titanium alloy, a layer containing zinc oxide or zinc or a zinc alloy, abbreviated to three layers of titanium, The layer is referred to as a zinc layer. Sometimes abbreviated as titanium, salt, or zinc.

  When these three layers are formed within a range of 1 cm or 2 cm on each 3 cm cell, dozens of cells are produced with a total amount of 22 g of the mixed solution. Used below. Prepare three small trays and mix the mixture into three trays, one Sspoon.

  Titanium oxide (powder for ceramics), salt (commercially available), and zinc oxide (powder for ceramics) are put in one S spoon each in the three trays containing the divided mixture. In terms of weight, the weight of one spoonful of titanium oxide for ceramics is about 0.8 g, the weight of one S spoon of salt is about 1.5 g, and the weight of one S spoon of zinc oxide is about 1.6 g.

  In the volume ratio, each S spoon of the same amount is 1: 1: 1: 1, and in the volume ratio, the same amount of the mixed solution is mixed in three layers. Mix well in each tray to form a uniform layer. Make the viscosity of the three layers as uniform as possible. Adjust the amount to be used to make it semi-solid rather than liquid.

  About 0.07 g of boric acid (commercially available) is placed in a titanium tray. Add about 0.09 g of boric acid to the zinc tray. This quantity is ambiguous and not strictly measured, it is only described in the reference level and has changed in various implementations. More zinc is added to boric acid than titanium. Do not put boric acid in the salt tray. Mix well so that boric acid can be evenly distributed in the three layers.

  Put a very small amount of charcoal (powder that may be Bincho charcoal) into a titanium tray. In the salt and zinc trays, add a trace amount of the same amount. The amount of this charcoal is a very small amount that cannot be measured with a digital balance that can only weigh 0.00 g. Mix well.

Prepare a fourth tray separately. This is for creating P-type and N-type semiconductors by using plants. For dye-sensitized power generation. Also for semiconductor thermoelectric generation.
As a mixture of plants << 1 >>, the following mixture was made on a trial basis with a weight ratio described in (0033) of about grams. However, it is an example of gram display and not the best numerical value.

“Hibiscus powder: 0.9 g vs. iodine tincture: 5.5 g vs. henna powder: 0.3 g vs. zircon powder (an example of metal) 0.3 g”
(It is only an example because it is implemented with various plants and different numerical values. Zircon in one example of metal may be alumina, copper, iron, cobalt, and so on.)

  Make this mixture and put a spoonful of S-spoon into the fourth tray. Also put Aerosil's nano-sized titanium P25 into S-spoon (weight about 0.24g) and mix well. The volume ratio is 1: 1.

Put the above titanium paste made from the fourth tray into the first titanium tray and mix well. This titanium tray is a mixture of ceramic titanium and nano-sized titanium P25 in a volume ratio of 1: 1. This is used for the titanium layer.

  Create a square about 2 cm each spacer inside each 3 cm copper plate (thickness 0.5 mm), and layer a part of the zinc tray mixture on the copper plate 1 cm inside the spacer further inside the spacer. Deploy. This is a zinc layer. Place a small portion of the contents mixed with a salt tray on top of each other, also in layers of 1 cm. This is a salt layer. The contents of the titanium, zinc and salt trays are enough to make three identical cells, and the amount of one cell is about one-third of each tray.

  A number of small holes are drilled in each 3 cm aluminum plate (thickness 0.3 mm), and about 2 cm each spacer is made into a square, and on top of that there is a volume ratio of titanium for ceramics and nano-sized titanium P25. A small amount of the contents of the titanium tray described in the above (0187) mixed in 1 are also arranged in layers of 1 cm each. A transparent plastic plate (Pet) wider than the spacer is placed on the titanium layer.

  At the bottom of this aluminum plate, the zinc copper plate is pasted with the salt layer facing up, but the copper plate is placed with a shift of about 3 mm so that the ends of the aluminum plate and the copper plate serve as terminals.

The structure from the top is a transparent plastic, titanium layer, aluminum plate, salt layer, zinc layer, and copper plate.

  In this cell, granular iodine (manufactured by Wako Pure Chemical Industries, Ltd.) described in (0176) is contained. Granular iodine is necessary for high output. The two types of metal and three layers are firmly attached to form a cell. Seals to prevent important iodine from evaporating out of the cell. (Thickness of the cell: 3 mm) Three layers of 1 cm each are formed inside each spacer of about 2 cm in each cell of 3 cm, and the three layers may be circular or arbitrary, but the layers are formed inside the spacer. There is a part where you can see the aluminum plate without.

In order to intentionally generate semiconductor thermoelectric power using an aluminum plate without a layer, no layer is formed inside the spacer. The three-layer part is a small layer of 1 cm each. The water described in (0176) is preferably attached by evaporation to reduce hydration. Does not leak. Free electrons exit the aluminum plate (minus pole) and return to the copper plate (plus electrode). Conversely, the current exits from the copper plate (positive electrode) and returns to the aluminum plate (negative electrode).
This completes the regenerated battery.

Performance evaluation (Example 1 (1))
Connect the black test lead wire to the aluminum plate of the cell and the red test lead wire to the copper plate, and measure with a tester. Measure with the aluminum plate facing up. Immediately after creation of the cell (about 3 centimeters for each cell, 3 layers for each centimeter, only 3 centimeters thick), current 35 mA, voltage 0.35 V to 0.5 V Fluctuates within range).

  Once the tester is connected day and night, the current is used up to near zero, and the next day, when measured with the tester, it is confirmed that the current near zero has been reproduced up to 14 mA. After consuming current for several days and bringing it close to zero, it was confirmed that it would be regenerated repeatedly after being placed under the sun and regenerated one month later.

  The effective area of the three layers of this cell is 3 centimeters each (thickness 3 mm), but the 3 layers themselves are only a few centimeters each, so they are the same in a private home that does not have equipment. Under the conditions, the power generation in the effective area of each centimeter in three layers is higher than that of dye-sensitized solar cells and semiconductor thermoelectric generators.

(Example 1 (2))
The contents of the titanium tray, salt tray, and zinc tray still remain, so the same conditions, except that the cell structure is changed, the structure from the top is transparent plastic, titanium layer, The cell made into the salt layer, the aluminum plate, the zinc layer, and the copper plate was also implemented. The arrangement of the aluminum plate was changed. A salt layer was disposed under the titanium layer, and an aluminum plate, a zinc layer, and a copper plate were formed thereunder.
Such cells are also being implemented. This structure is possible in all embodiments and implementations of the present invention. However, since they overlap, this structure is implemented from the following, but is omitted in the examples.

(Example 1 (3))
Of Example 1, (1) and (2), the metal is made of stainless steel other than aluminum and copper, various alloys such as lead, tin, tinplate, plywood, steel plate, duralumin, nickel iodide and various metals. . For the titanium oxide and zinc oxide layers, various titanium alloys such as barium titanate and zinc alloys are used. Plants can be implemented with various plants such as those other than hibiscus.

  Of course, the present invention is carried out using not only plants but also natural pigments or organic pigments. Various minerals such as turquoise are added to one or more of the three layers as pigments or for the purpose of making the semiconductor P-type or N-type.

  Even if the ratio of titanium oxide for ceramics and nano-sized titanium oxide is other than 1: 1. Various ratios of other raw materials are used. Implement metal powder and other than zircon for high efficiency.

  Additives other than iodide compounds and agar are added, or in contrast, additives in that case are not used. There are also cells that are modified from (1) and (2) of Example 1 such as adding ink to salt, adding charcoal to three layers, not adding, adding starchy glue, or not adding. We are carrying out.

  In the cell, black ink, ink, or carbon black (used in ink in one example) Graphite is graphite, but it is attached to metal (in one example, the metal is colored with a pencil). In some cases, one or more of pigments, minerals, charcoal, black ink, black liquor, carbon black, graphite, glue, and those containing chemical compounds are used in the cell.

  The shape of the cell is not plate-like, but a corrugated plate-like cell made by bonding commercially available polycarbonate corrugated sheets and corrugated sheets of various alloys. ing. Since it overlaps, although the above is implemented from the following, description is abbreviate | omitted hereafter.

  For all the examples, the best regenerating battery is not implemented, but the example is described as an example. Therefore, the regenerating battery of the present invention is limited to Examples 1 to 10 only. There is no limitation.

  As described in claim 1, since two types of metals use two different types of metals, they are identified as metals, and two of the three layers are layers containing titanium oxide or titanium or a titanium alloy. It is used as a layer containing zinc oxide or zinc or a zinc alloy, but as an example, powdered titanium oxide and powdered zinc oxide are described in the examples, but their shape before forming a layer is granular It is not limited whether it is powdery or plate-like. Titanium oxide and zinc oxide for ceramics are not limited. Other titanium oxides and zinc oxides may be used. The usage form of iodine is the same, and there is no limitation on what solid, liquid, or how to coat.

  The present invention is intended to be used as a power source for an electric vehicle at the maximum output, and in this case, the embodiment is variously modified as described in (3) of the first embodiment. Since the first to tenth embodiments are duplicated, the same modified embodiments are implemented, but the description is omitted. As described in claims 1 to 27, the embodiment is implemented under a number of conditions and states in a broad concept.

  The whole picture has different metals on the top and bottom of the cell, three layers are placed between them, only the titanium layer contains iodine and iodide compounds, the salt and zinc layers directly with iodine and iodide A cell containing solid iodine, coated with oil-based paint, without any compound, between the titanium and salt layers.

Prepare three trays.
Mix a mixture of 1.5g of iodine tincture and 0.2g of rice husks in a titanium tray with the same amount of S spoonful and titanium oxide (for ceramics) in the same amount. Add a very small amount of boric acid and mix well. Add a small amount of charcoal, a small amount of starchy paste, and 0.4 g of zircon powder and mix well.

  When the mixture of oolong tea and iodine tincture is dried, it becomes a powder of oolong tea containing iodine tincture, but in order to produce a pigment, 0.1 g of the powder is mixed well. A small amount of the contents of this tray is placed on each 3 cm aluminum plate to form a titanium layer.

  In a separate container, mix a mixture of 2.5 g of crushed rice husk and 14 g of water in the same amount of 1 S spoon and 1 S spoon of zinc oxide (for ceramics) in a zinc tray. Add a very small amount of boric acid and mix well. Put a small amount of charcoal in a slightly smaller amount than the titanium tray, add a small amount of starchy paste, and mix well with 0.4 g of zircon powder. A small amount of the contents of this tray is placed on each 3 cm copper plate to form a layer of zinc.

  Mix the above-mentioned broken shell of rice husk and water in the same amount of 1 spoonful and 1 spoonful of salt in a salt tray. Do not add boric acid. Add a small amount of charcoal to a little smaller amount than the titanium tray, and mix well with a small amount of starchy paste. A small amount of the contents of this tray is layered over the zinc layer to form a salt layer.

  Five solid iodine grains coated with oily paint are placed on the salt layer. The aluminum plate and the copper plate are bonded to each other so that the outside of the cell is an aluminum plate or a copper plate. (Cell thickness 2.5 mm) Titanium, zinc, and salt trays are available in quantities that allow the same three cells to be made, and the amount of one cell is about one-third of each tray. The cell has a spacer and is sealed.

  Battery structure of aluminum plate, titanium layer, solid iodine grain, salt layer, zinc layer, copper plate.

Performance evaluation (Example 2)
Current (current of about 3 centimeters in each cell, 3 layers only 2 centimeters each, thickness 2.5 mm) Current 33 mA Maximum current 50 mA Voltage 0.5 V The voltage increases upon receiving light and varies within the range of about 0.35 V to 0.5 V every time it is measured.

  The cell is not regenerated with light, and is regenerated with semiconductor thermal power generation. On midsummer days, it is naturally regenerated by solar heat. The use of plants in the cell is in this case the effect of sensitizing semiconductor thermoelectric generation. The top and bottom of the cell are an aluminum plate and a copper plate, but if it is applied to the roof and the aluminum plate is facing the sun, it becomes a battery that can be regenerated by solar heat. In high-temperature tropics, it is a useful renewable battery.

(Example 3 (1))
The whole picture is a cell using carbonized or incinerated rice husk. Carbonized or incinerated rice husk and water are mixed in three layers, and about three solid iodines (manufactured by Wako Pure Chemical Industries, Inc., granular) are placed per cell, thereby containing iodine in the three layers. The outside of the cell has 2 types of metal and 3 layers inside. Below is a material that only makes one cell.

  The implementation of carbonized and incinerated rice husk is only this Example 3, and in other implementations, the rice husk is broken into layers and mixed with the layer, so it is not carbonized and incinerated.

Mix 0.04g of carbonized or incinerated rice husk with 0.24g of water. (This water should be water mixed with rice husk and water.
Prepare three trays and mix the water and carbonized or incinerated rice husks into three equal parts.

  Put 0.06g of Aerosil nano-sized titanium oxide P25 in one tray and add salt (commercially available ink to salt first). 0.29g of ink (contains chemical compounds that become conductive thin film, chemical compounds), and put 0.25g of zinc oxide (powder for ceramics) in the third tray. ,mix well.

  Put a very small amount of boric acid in a titanium and zinc tray and mix well. Do not put boric acid in the salt tray. Add a little bit of charcoal (powder that may be Bincho charcoal) to a trace amount of titanium tray, and add a very small amount of the same amount to the salt tray and zinc tray and mix well. Put a small amount of starchy paste in three trays and mix well.

  Put a small amount of hibiscus powder in a titanium tray and mix a little zircon powder at that time. Put a small amount of oolong tea (commercially available powdered tea leaves from a bag) soaked with iodine tincture in a zinc tray, and at the same time add a small amount of zircon powder and mix well.

  Place all the contents of the titanium tray in layers on each 2.5 cm aluminum plate. Place all the contents of the zinc tray in layers on each copper plate of 2.5 cm, and layer all the contents of the salt tray on top of each other, and then add individual iodine (Wako Pure Chemical Industries) on the salt layer. (3) Laminate the two kinds of metals with the aluminum and copper plates facing out so that the three layers are inside. (Cell thickness 2.5 mm) This cell also has a spacer and is sealed. The aluminum plate is the negative pole and the copper plate is the positive pole. The metal may be a combination of stainless steel, lead, iron, etc. as long as different types are used, and is not limited to an aluminum plate or a copper plate. Nickel iodide may be used.

  The structure of the battery is aluminum plate, titanium layer, three granular solid iodine, salt layer, zinc layer, copper plate. The positions of the titanium layer and the zinc layer may be interchanged.

Performance evaluation (Example 3 (1))
Immediately after production of the cell (about 3 centimeters of each cell, 3 layers are 1.5 centimeters each, 3 mm thick), current 40 mA, voltage 0.35 V to 0.5 V (varies within the range for each measurement). Even if the current is consumed, it is regenerated with heat.

  In the implementation of the present invention, it can be confirmed that in most cells, when a metal is placed over a fire, the current increases immediately after semiconductor thermoelectric power generation. Even with sunlight and room light, it regenerates due to the heat of midsummer, although it is moderate. However, the current decreases after a few days. Since the outside of the cell is metal, it is not intended for reproduction with light. The purpose is to regenerate with heat sources such as electric products that produce heat and sunlight.

  Since the three layers are not directly exposed to light, the use of plants in the cell in this case has the effect of promoting semiconductor thermoelectric generation. Previously, experiments that did not use rice husks in the cell did not immediately generate electricity with sunlight, so the use of plants and rice husks has proven effective in semiconductor thermoelectric generation. This cell carbonizes and ashes the rice husks, but there is no difference in performance from the cell of the rice husks that just broke the shells.

(Example 3 (2))
The whole picture is a cell using carbonized or incinerated rice husk. Arrange the material such as glass or plastic arbitrarily on the top that receives light and heat, and there is a layer of titanium or zinc to dye sensitize directly underneath, there is a metal with a hole directly under it, and two layers A cell with a different kind of metal at the bottom, sandwiched between them.

  Although the amount of material used is somewhat larger than that of Example 3 (1), it is almost the same as (3) of Example 3 and only the structure is changed.

  A large number of holes are made in each 3 cm aluminum plate, the titanium layer of Example 3 (1) is formed on the aluminum plate, and a transparent plastic is disposed on the titanium layer. The zinc layer of Example 3 (1) was placed on each 3 cm copper plate, the salt layer of Example 3 (1) was placed thereon, and Example 3 (1) was placed on the salt layer. Three solid iodine (made by Wako Pure Chemical Industries, granular) are arranged. The copper plate is placed at the bottom so that the solid iodine contacts under the aluminum plate with holes, and is pasted to the aluminum plate. (Cell thickness 3 mm) The cell has a spacer and is sealed.

  The top is a transparent plastic, titanium layer, aluminum plate (with holes in the plate), granular solid iodine, salt layer, zinc layer, copper plate structure.

Performance evaluation (Example 3 (2))
Current (currently 25 mA, voltage 0.35 V) immediately after the creation of the cell (about 3 cm for each cell, 3 layers only for 2 cm each, thickness 3 mm). The voltage is about 0.35V to 0.5V (varies within that range for each measurement).

  It aims to regenerate with heat and light. Even if the current is consumed, it is regenerated with sunlight. Reproduce clearly in strong sunlight rather than room light. 10mA is playing. Although the rice husk of this cell is carbonized or incinerated, there is no difference in performance from the cell of the rice husk that only broke the shell. The effectiveness and differentiation of husks and rice husks that have broken shells, and the effectiveness of ashing, are not yet clear.

(Example 4 (1))
The whole picture has different metals on the top and bottom of the cell, 3 layers are placed between them, and each layer is mixed with crushed rice husks (not carbonized or incinerated). A titanium layer is further formed on the upper metal for dye sensitization. It has a three-layer structure between one layer and two kinds of metals, and a wire mesh (stainless steel) is also arranged. The uppermost dye sensitizing titanium layer is multilayer.

  Prepare three trays. In a titanium tray, mix the same amount of a mixture of broken rice husks and water into one S spoon and the same S spoonful of titanium oxide (for ceramics). Add a very small amount of boric acid and mix well. Add a small amount of charcoal, add a small amount of starchy paste, put hibiscus powder roughly, add 0.07 g of zircon powder and mix well.

  A small amount of the contents of this tray is placed on a 3 cm aluminum plate with many holes to form a titanium layer. Four solid iodine grains coated with oily white paint are placed on the titanium layer. There are also three times. In addition, a large stainless steel wire net that protrudes outside the cell is placed on solid iodine.

  In a zinc tray, mix the same amount of 1 sspoon with a mixture of broken rice husks and water, and 1 Spoon of zinc oxide (for ceramics). Add a very small amount of boric acid and mix well. Put a small amount of charcoal in a slightly smaller amount than the titanium tray, add a small amount of starchy paste, add 0.07 g of zircon powder, and mix well. A small amount of the contents of this tray is placed on each 3 cm copper plate to form a layer of zinc.

  In a salt tray, mix the above-mentioned broken rice husk and water mixture of shells with an equal amount of 1 spoon of S spoon and 1 spoon of S spoon with the same amount of salt. Do not add boric acid. Add a small amount of charcoal to a little smaller amount than the titanium tray, and mix well with a small amount of starchy paste. A small amount of the contents of this tray is layered over the zinc layer to form a salt layer.

  The contents of the titanium, zinc and salt trays are enough to make three identical cells, and the amount of one cell is about one-third of each tray. The aluminum plate and the copper plate are bonded to each other so that the above three layers are inside the cell and the outside is an aluminum plate and a copper plate.

  For dye sensitization, the first dye layer and the second dye layer described below are stacked on the outer upper aluminum plate, and the first dye layer and the second dye layer are again stacked twice. Place clear plastic on it. The cell has a spacer and is sealed.

  As for the contents of the first layer of pigment, add a mixture of 0.95 g of rice husk, 5.62 g of iodine tincture, 0.34 g of hibiscus powder and 0.34 g of zircon to a tray and put 1 S spoon. Mix the same amount of the same S spoonful of nano-sized titanium oxide P25 (Aerosil). Add a very small amount of boric acid and mix well. Add a small amount of charcoal and mix well. A small amount of this content is formed on the aluminum plate as the pigment first layer. Nano-sized titanium P25 is very thin even if it is a layer, so it becomes a thin layer even if it is multi-layered or multi-staged.

  The contents of the second dye layer are mixed with 0.9 g of hibiscus powder and 5.5 g of water, and a mixture of 0.33 g of henna and 0.13 g of zircon is placed in a tray with a spoonful of S spoon. Mix the same amount of the same S spoonful with the nano-sized titanium oxide. A small amount of this content is used as a dye second layer, and a dye first layer and a dye second layer are formed on an aluminum plate.

The nano-sized titanium P25 is very thin even if it is a layer, so that it becomes a thin layer even if it is four layers of the first dye layer, the second dye layer, the first dye layer, and the second dye layer, or multiple layers.
This is not limited to the upper layer. It is envisaged that one layer is multi-layered and multi-staged in order to achieve high output in any layer inside the cell, or to make it P-type or N-type. For example, when minerals are used in the form of thin plates, such as P-type and N-type, the P-type and N-type titanium and zinc layers can be one layer, but the breakdown of one layer is multilayer and multistage. The inside of two different metals and three or four layers can be multi-layered and multi-staged in this way.

Cell thickness 5mm, transparent plastic, titanium layer for dye sensitization (this titanium layer is 4 layers), aluminum plate, titanium layer, solid iodine grains, wire mesh, salt layer, zinc This is a battery structure of a copper plate.

  This cell can be wired in various ways. Wiring is performed with the aluminum plate as described above as the negative electrode and the copper plate as the positive electrode. However, another wiring can be applied at the same time. Wire with copper plate as negative pole and stainless steel wire mesh as positive pole. The current flow is reversed in this case. Two currents can be confirmed using two testers.

  If the two different wirings are made simultaneously, the cell flows a current better. Although a small amount of current is regenerated, the copper plate serving as both the negative and positive poles has the potential for unknown progress. The three-pole two-layer battery has already been patented, but it does not use rice husk.

  The method of dye-sensitized power generation is also as per Gretzel's patent. In the present invention, dye sensitization is performed, but it is no longer a power generation method as per Gretzel's patent. There are two different current flows: when generating electricity with light, free electrons flow from the aluminum plate to the external circuit, and for semiconductor thermoelectric power generation, free electrons from the lower copper plate due to the relationship between the copper plate and the stainless steel wire mesh. In theory, semiconductor thermoelectric power generation and dye-sensitized power generation are known to have opposite poles, so in the present invention, both different power generations are performed simultaneously. This is proof that

Performance evaluation (Example 4 (1))
Immediately after the production of the cell (about 3 centimeters of each cell, the 3 layer part is only 2 centimeters each, thickness 5 mm), current 40 mA, voltage 0.5 V. The voltage varies from 0.35V to 0.5V within the measurement range. Even if the current is consumed, it is regenerated with light and heat. Reproduced not only with sunlight but also with solar heat generated simultaneously with midsummer light. However, the current decreases after a few days.

(Example 4 (2))
A cell in which the dye sensitizing titanium layer of Example 4 (1) is a dye first layer, the dye second layer and the upper titanium layer are two layers, and a wire mesh is housed in the cell. In Example 4 (1), the wire mesh has gone out of the cell.

(Example 4 (3))
A cell in which the dye first layer and the dye second layer of the dye sensitizing titanium layer of Example 4 (1) are mixed as one layer, and there is no wire mesh. 3 layers between 1 layer and 2 kinds of metals, no wire mesh.

  The overall picture is a cell that has been devised and modified in various ways for the purpose of creating P-type and N-type semiconductors using only plants. Battery structure with three layers between upper and lower metals.

  In the titanium layer, mix for ceramics titanium = mixture of plant and rice husk << 3 >>, and for nano-sized titanium oxide = mixture of plant mixture << 1 >> << 5 >>. I'm trying to make it an N-type.

  The zinc layer is mixed with zinc oxide = the modified form << 4 >> of the plant and rice husk mixture << 3 >>, and then the modified form << 6 >> of the plant mixture << 1 >> is mixed to make a P-type.

  These << 1 >>, << 2 >>, << 3 >>, << 4 >>, << 5 >>, << 6 >> molds can be arbitrarily prototyped and are not limited or specified. The numbering is just a guide and there is no difference in the contents, but in this implementation, the battery to be regenerated is confirmed.

  Put the following-plant and rice husk mixture << 3 >> in a layer of titanium (for pottery) and make it N-type.

-Mixture of plant and rice husk "3"-
"Chaff: 3 (reference weight 0.9 g) vs. iodine tincture: 17 (reference weight 5.6 g) vs. hibiscus powder (may be henna powder or other plants): 1 (reference weight 0. 3g) vs. zircon powder (an example of metal): 1 (reference weight 0.3 g) "

  In a separate tray, put the following-"Vegetable mixture << 1 >> modified type << 5 >>" into a layer of nano-sized titanium oxide (Aerosil Co., Ltd.) and make it an N type.

-Variant of plant mixture << 1 >><< 5 >>
"Rosehip powder (replaced with hibiscus powder): 7 (reference weight 0.9 g) vs. iodine tincture: 42 (reference weight 5.6 g) vs. henna powder: 2 (reference weight 0 .3g) vs. zircon powder (an example of metal): 1 (reference weight 0.1 g) "
(It is only an example because the modified type is replaced with another plant and various numerical values. It is only an example. Zircon in one example of metal may be alumina, copper, iron, cobalt, and so on.)

  Prepare four trays. Put titanium (for pottery) into a titanium tray and mix the same amount of the same S spoonful with the above-mentioned mixture of plant and rice husk << 3 >>. Put the same amount of S-spoon of nano-sized titanium oxide (Aerosil Co.) in the same titanium tray as above, and the same amount of S-spoon in the same way as the above-mentioned plant mixture << 1 >> mix.

  Mix the above two trays together in one tray and mix well. Add 0.03 g of boric acid and mix well. Add a small amount of charcoal and mix well. Place a small amount of the contents of this tray on a 3 cm aluminum plate to form a titanium layer.

  Put the following in the layer of zinc oxide (for pottery)-"Plant and rice husk mixture" 3 "modified type" 4 "-and make it P-type.

―Plant and rice husk mixture 《3》 variant 《4》 ―
“Plant and rice husk mixture << 3 >> plus henna: 1 (reference weight 0.3 g)”.
"Chaff: 3 (reference weight 0.9 g) vs. iodine tincture: 17 (reference weight 5.6 g) vs. hibiscus powder (may be henna powder or other plants): 1 (reference weight 0. 3g) vs. zircon powder (an example of metal): 1 (reference weight 0.3 g) "
Plus "Henna: 1 (reference weight 0.3g)"

  Put the following-"Plant mixture << 1 >> modified type << 6 >>" into the layer of zinc (for ceramics) and make it P-type.

-Variant of plant mixture << 1 >><< 6 >>
“Chaff: 3 (reference weight 0.9 g) vs. iodine tincture: 17 (reference weight 5.6 g) vs. hibiscus and rosepip powder (replaced with hibiscus powder)
: 7 (reference weight 0.9 g) vs. henna powder: 2 (reference weight 0.3 g) vs. mixture of plant and rice husk << 3 >> (do not put zircon, put in instead)
: 1 (weight of reference 0.1g) "
(Although it is a modified type, it is only an example because it is replaced with different materials, different plants, different numerical values, etc., so it is only an example. Zircon in one example of metal may be alumina, copper, iron, cobalt. From the following The same is true.)

  In the zinc tray, mix the same amount of S-spoon and zinc oxide (for pottery) with the same amount-the plant-rice husk mixture << 3 >> variant << 4 >>. In addition, add 1 spoon of S-spoon of the modified version of plant mixture << 1 >> as described above.

  Add very small amount of boric acid 0.07g and mix well. Put a small amount of charcoal in a little amount than the titanium tray, mix well, and place a small amount of the contents of this tray on each copper plate 3 cm to make a layer of zinc. In a salt tray, mix a mixture of broken rice husk and water in an equal amount of 1 spoonful of S-spoon and 1 spoonful of salt. Do not add boric acid. Add a small amount of charcoal to the titanium tray and mix well. A small amount of the contents of this tray is layered over the zinc layer to form a salt layer. The contents of the titanium, zinc and salt trays are enough to make three identical cells, and the amount of one cell is about one-third of each tray.

  Four solid iodine grains coated with oily paint are placed on the salt layer. The aluminum plate and the copper plate are bonded to each other so that the outside of the cell is an aluminum plate or a copper plate. (Cell thickness 2.5 mm) The cell has a spacer and is sealed. Battery structure with three layers between upper and lower metals.

Performance evaluation (Example 5)
Immediately after production of the cell (about 3 centimeters of each cell, 3 layers are only 1.5 centimeters each, thickness 2.5 mm), current 40 mA, voltage 0.5 V. The voltage varies from 0.35V to 0.5V within the measurement range. Even if the current is consumed, it is regenerated with heat.

  Regenerate with solar heat. However, the current decreases after a few days. Since the outside is a metal, it is not regenerated with light. Semiconductor thermal power generation. Since the three layers are not directly exposed to light, the use of plants in the cell in this case serves to promote semiconductor thermoelectric generation even at low temperatures (air temperatures). I changed plants variously for the purpose of making semiconductor P-type and N-type with plants, but I can feel the effect. I realized that even if I change the powder of plants and metal, I can generate electricity. Water and iodine in the cell are indispensable for outputting current, but the current flow can be influenced by the above-described devices of plants.

(Example 6 (1))
This embodiment is named a clay wall. The overall image is a battery structure with one layer for reproduction that receives light and heat at the top, and two layers between two types of metals at the bottom. A cell that does not cover the top of the cell with glass or other materials to make it the earth wall itself. The titanium layer is exposed to the outside.

  Different from other cells. A battery that regenerates the appearance of the real earth wall as if it were like straw, with the chaff inside the titanium layer looked like a straw so that it would look like a real earth wall without using transparent plastic or glass at the top . The color of the earth wall can be changed by adding pigments and pigments. If white pigment is mixed, it can be seen as white plaster. The battery to be regenerated can be completely hidden. If you want to prevent electric shock, you can maintain the old townscape. To prevent electric shock, a thin film of epoxy resin is planned.

  Soak a small amount of water in the chaff that broke the shell, and mix well. The grains and powder of the rice husks that broke the shells are further kneaded with water to further crush the shell cells, and the water-containing rice husks are turned into a solid semi-solid like clay instead of mud. The point is to mix well until it becomes clay. Put hibiscus powder and zircon powder in it and mix well. Prepare three trays.

  In a titanium tray, mix nanosized titanium P25 and the clay-like rice husks in a volume ratio of 1 to 2/3 and mix well. Add a very small amount of boric acid and mix well. A small amount of the contents of this tray is placed on an aluminum plate with many holes, 3 cm each, to form a layer of titanium that is directly exposed to light and heat. In this cell, a transparent material such as transparent glass or plastic is not disposed, and this titanium layer is used as a soil wall.

  In a zinc tray, mix zinc oxide with the above clay-like rice husk in a volume ratio of 1 to 2/3 and mix well. Add a little more boric acid than titanium tray. A small amount of the contents of this tray are placed on each 3 cm copper plate to form a layer of zinc.

  Mix the salt-like rice husk previously mixed with the sumi ink in the salt tray in a volume ratio of 1 to 2/3 and mix well. Do not add boric acid. A small amount of the contents of this tray is placed on the zinc layer to form a salt layer. A mixture of titanium, zinc and salt trays is used in a thicker layer than usual. (Cell thickness 3mm)

  Immerse a solid grain of iodine in black ink and place it on a salt layer with three grains of iodine coated with black ink that has been dried for about half a day. The aluminum plate and the copper plate are attached with a slight shift so that iodine particles are arranged directly below the aluminum plate with the titanium layer at the top. The cell has a spacer.

  Even if the current was measured with a tester using this as a cell, no current was output, so the cell was opened after one day, and four more iodine particles coated with black ink were placed. Iodine grains that have been soaked in the ink from the previous day and have sufficiently absorbed the ink. Iodine, which was soaked in the ink and sufficiently sucked the ink, immediately changed the color of the lower white paper to black. Iodine that absorbed the ink was scattered and diffused in the surrounding air, and a black pattern containing ink was drawn widely on white paper. For some time, iodine knew that the starch reaction would stain paper brown, but discovered that the chemical reaction between ink and iodine is more powerful.

  Battery structure of titanium layer, aluminum plate (with many holes), 7 iodine grains, salt layer, zinc layer, copper plate.

Performance evaluation (Example 6 (1), earth wall)
Immediately after the production of the cell (about 3 centimeters of each cell, the 3 layer part is only 1.5 centimeters, each 3 mm thick), the current is 2 mA, the voltage is 0.35 V. The voltage varies from 0.35V to 0.5V within the measurement range. At a later date, the current is measured by about 10 mA, but it decreases. If a cell is placed at the window, it will be gentle even in sunlight and indoor light, but it will regenerate due to the heat of midsummer. Even if the current is used up to zero, it is regenerating about 5mA. It was found that the cell was regenerated without completely sealing it. This does not cover the cell with a transparent material of glass or plastic. It has been demonstrated that a battery that can be regenerated is possible even in the case of a soil wall without sealing.

(Example 6 (2))
A small amount of water is soaked in a rice husk crushed as in Example 6 (1) and mixed well. The powder of the rice husk that broke the shell is further kneaded with water, and the cells of the shell are further crushed to make the rice husk containing water instead of mud into a solid semi-solid like clay. The point is to make it clay. Add the ink to clay husk and mix well. Rice husk turns black. A cell that uses the clay-like rice husk containing the ink for three layers will be implemented. (Thickness of each 3 cm cell: 4 mm) It was carried out whether or not the cell layer could be regenerated with light and heat by utilizing the conductivity of the black liquor even if there was no moisture. In another implementation, the carbon black of the ink was used instead of the ink, but this effect was not clear.

  Black ink (commercially available) is a product that retains electrical conductivity even after drying and no longer being liquid. Contains chemical compounds. I knew that when I put this commercial product on ordinary glass and dried it, the ink became a film on the glass and I could easily make conductive glass. In order to add conductivity to the salt that has been mixed with the salt and water has disappeared, it has become possible to add ink to the salt layer, and it is also used for the titanium layer on the aluminum plate and the zinc layer on the copper plate.

  Divide the clay-like rice husk mixed with this ink liquid into three equal parts on a titanium, salt, and zinc tray and mix the same amount of titanium oxide, salt, and zinc oxide.

  Hibiscus powder, zircon powder and boric acid as plants were put only in the titanium tray, and this was used as a titanium layer with transparent Pet plastic placed on top.

  About three iodine particles dipped in the ink and sufficiently sucked the ink were placed on the salt layer. By placing it in the cell, we are also trying to use the power of iodine combined with ink. These are cells. In this way, it is carried out in various cases, such as putting ink in three layers. Various combinations of using or not using glue can be made, and it has been confirmed that the battery to be regenerated can also be created in the cell in that case.

  Battery structure of transparent Pet plastic, titanium layer, aluminum plate, iodine grain, salt layer, zinc layer, copper plate. In Example 6 (2), reproduction is performed, but the current to be reproduced decreases as time passes.

(Example 7 (1))
The overall image is a battery structure with one layer at the top (for dye sensitization, this layer is multi-layered or multi-staged), and two layers between two types of metals at the bottom. Transparent glass is used at the top. Unlike other cells, a wire mesh is placed between the salt and zinc layers. The mixture (named part B) produced in Example 1 is used again. 100% nano-sized titanium oxide titanium layer using both water and iodine tincture in solution in the cell. A plant mixture << 2 >> is also used, in which hibiscus powder is mixed with water.

  Three trays prepared with this 22 gram mixture used in Example 1 (named Part B) are separated.

  In a titanium tray, mix this liquid mixture (part B) with the same amount of 1 spoonful of S spoon and the same amount of 1 spoonful of nanosized titanium oxide. Add a very small amount of boric acid (0.04g) and mix well. Add a little more charcoal. This is the dye first layer. In a separate titanium tray, mix the following plant mixture << 2 >> in an equal amount of 1 S spoon and 1 S spoon of nano-sized titanium oxide. This is the dye second layer.

-Mixture of plants "2"-
“Hibiscus powder: 7 (reference weight 0.9 g) vs. water: 42 (reference weight 5.5 g) vs. henna powder: 2 (reference weight 0.3 g) vs. zircon powder (metal An example): 1 (reference weight 0.1 g) "
(It is only an example because it is implemented with various plants and different numerical values. Zircon in one example of metal may be alumina, copper, iron, cobalt, and so on.)

  Create a dye first layer on an aluminum plate with a large number of holes of 3 cm each, and then overlay the second dye layer, the first dye layer, and the second dye layer on top of each other to form the upper titanium layer. Or, it is multistage and transparent glass is arranged on it.

  In a zinc tray, mix the same amount of the above mixture (part B) with one S spoon and the same amount of zinc (for ceramics) with one S spoon. Add very small amount of boric acid 0.07g and mix well. Add a small amount of charcoal to the titanium tray and mix well. A small amount of the contents of this tray is placed on each 3 cm copper plate (painted on a copper plate) into a zinc layer. A wire mesh that can be placed in the cell is placed on the zinc layer.

  In a salt tray, mix the same amount of the above mixture (part B) with 1 spoon of S spoon and the same amount of S spoon with the same salt. Do not add boric acid. Add a small amount of charcoal to the titanium tray and mix well. A small amount of the contents of this tray is layered on a zinc wire mesh to form a salt layer. The contents of the titanium, zinc and salt trays are enough to make three identical cells, and the amount of one cell is about one-third of each tray.

  The copper plate with the metal mesh and zinc oxide layers is bonded to each other so that the lower part of the aluminum plate having the titanium layer formed into a multi-layer or multi-stage and the salt layer are in contact with each other. (Thickness of each 3 cm cell is 4 mm) The cell has a spacer and is sealed.

  The battery structure is made of transparent glass, titanium layer (multilayer or multistage), aluminum plate, salt layer, wire mesh, zinc layer, and copper plate.

Performance evaluation (Example 7 (1))
From current 45 mA to maximum current 50 mA voltage 0.35 V immediately after creation of the cell (3 cm for each cell, 3 layers for each 2 cm, thickness 3 mm). The voltage increases upon receiving light, and varies within the range of 0.35 V to 0.5 V every time it is measured. Although it is measured with a tester immediately after the cell is created, the current does not rise immediately but increases over time. In current, it was the highest current. Then the current drops. Regenerate with light and heat.

(Example 7 (2))
Part B is put into three trays for one S spoon, and each tray is filled with the same amount of nano-sized titanium oxide, salt, and zinc in one S spoon.

  Put 0.04g of boric acid and a small amount of charcoal in a titanium tray. Put a small amount of charcoal in a salt tray less than the titanium layer. Put a small amount of boric acid 0.07g and charcoal in a zinc tray smaller than the titanium layer, and mix well in each tray. A small amount of the contents in this tray is used for the layer.

  It is a battery structure of transparent glass, dye first layer titanium layer, aluminum plate (with many holes), salt layer, wire mesh, zinc layer, and copper plate. (Thickness of each 3 cm cell 3 mm)

  The overall picture shows two types of metal, upper and lower, and a three-layer battery structure between them. Iodine is not used for the three layers, and granular iodine coated with aqueous paint is placed between the layers.

Prepare three trays.
In a titanium tray, mix the same amount of a mixture of broken rice husks and water into one S spoon and the same S spoonful of titanium oxide (for ceramics). Add a very small amount of boric acid and mix well. Add a small amount of charcoal, a small amount of starchy paste, and put the hibiscus powder in a large amount and mix well. A small amount of the contents of this tray is placed on each 3 cm aluminum plate to form a titanium layer.

  In a zinc tray, mix the same amount of a mixture of broken rice husks and water with 1 spoon of S spoon and the same amount of 1 spoon of zinc oxide (for ceramics). Add a very small amount of boric acid and mix well. Add a small amount of charcoal to a little smaller amount than the titanium tray, and mix well with a small amount of starchy paste. A small amount of the contents of this tray is placed on each 3 cm copper plate to form a layer of zinc.

Two solid iodine grains coated with aqueous paint are placed on the zinc layer.
In a salt tray, mix a mixture of broken rice husk and water in an equal amount of 1 spoonful of S-spoon and 1 spoonful of salt. Do not add boric acid. Add a small amount of charcoal to a little smaller amount than the titanium tray, and mix well with a small amount of starchy paste. A small amount of the contents of this tray is overlaid on the titanium layer to form a salt layer. The contents of the titanium, zinc and salt trays are enough to make three identical cells, and the amount of one cell is about one-third of each tray.

The aluminum plate and the copper plate are bonded to each other so that the outside of the cell is an aluminum plate or a copper plate. (Cell thickness 2.5mm)
The cell has a spacer.

  In order to dry the layers in the cell early, place the cell on a hot plate, bake at 100 degrees for 2 minutes, and after 2 minutes, leave it on the hot plate for 18 minutes. Remove from hot plate after 18 minutes. Battery structure with three layers between upper and lower metals.

Performance evaluation (Example 8)
Immediately after the cell (about 3 centimeters in each cell, the three layer part is 1.5 centimeters in thickness, 2.5 mm in thickness), since it is baked, the resistance is large and the current is zero, but the current gradually flows. Current 40mA Voltage 0.5V. The voltage increases upon receiving light, and varies within the range of 0.35 V to 0.5 V every time it is measured. Regenerate with heat.

  The overall image is a battery structure with one layer at the top, two types of metal at the bottom, and two layers between them. A cell that uses a lot of water. Iodine is not used for the three layers, and granular iodine coated with aqueous paint is placed between the layers.

Prepare four trays.
In a titanium tray, mix the same amount of a mixture of broken rice husks and water into one S spoon and the same S spoonful of titanium oxide (for ceramics). Add a very small amount of boric acid and mix well. Add a small amount of charcoal and mix a small amount of starchy paste. This is the dye first layer.

  In a separate tray, mix the same amount of a mixture of broken rice husks and water with one spoonful of S spoon and the same size of one spoonful of nanosized titanium oxide P25. Add a very small amount of boric acid and mix well. Add a little charcoal and mix well with 0.13 g of hibiscus powder and 0.00 g of zircon powder that cannot be measured. This is the dye second layer.

  The first dye layer and the second dye layer are mixed to form one layer, which is placed on a 3 cm aluminum plate to form a titanium layer.

  In a zinc tray, mix a mixture of broken rice husk and water in an equal amount of 1 spoonful of S spoon and the same amount of 1 spoonful of zinc (for ceramics). Add a very small amount of boric acid and mix well. Add a small amount of charcoal to a little smaller amount than the titanium tray, and mix well with a small amount of starchy paste. A small amount of the contents of this tray is placed on each 3 cm copper plate to form a layer of zinc.

  In a salt tray, mix a mixture of broken rice husk and water in an equal amount of 1 spoonful of S-spoon and 1 spoonful of salt. Do not add boric acid. Add a small amount of charcoal to a little smaller amount than the titanium tray, and mix well with a small amount of starchy paste. A small amount of the contents of this tray is layered over the zinc layer to form a salt layer. The contents of the titanium, zinc and salt trays are enough to make three identical cells, and the amount of one cell is about one-third of each tray.

Four solid iodine grains coated with aqueous paint are placed on the salt layer.
The copper plate is attached with a slight shift so that the iodine particles are arranged directly below the aluminum plate with the titanium layer facing up. (Cell thickness 4 mm) The cell has a spacer and is sealed. I can see the water remaining in the cell. A battery structure with one layer at the top and two layers between the two metals at the bottom.

Performance evaluation (Example 9)
Current (currently 20 mA, voltage 0.35 V) immediately after the cell (about 3 cm each cell, 3 layer part is only 2 cm each, thickness 4 mm). The voltage increases upon receiving light, and varies within the range of 0.35 V to 0.5 V every time it is measured. Measured with a tester, but there is a lot of water and the current is difficult to increase. After consumption of the current to near zero, it was regenerated several times up to 7 mA, but when the water runs out, the current cannot be clearly confirmed. Other cells regenerate even if there is no water in the cell.

(1) As an example, the present invention is carried out in various ways by adding pigments to the present invention so that the titanium layer and the zinc layer can be made into a semiconductor P-type or N-type by doping with ceramic pigments. In the cells of Examples 1 to 9, the present invention is carried out by adding pigments to one or more of the three layers with reference to (0104) and coloring them. However, there is an influence of other additives such as boric acid, plants, charcoal, and ink, and the cell does not have a simple result as shown in this table.
In the examples, the top is a commercially available transparent polycarbonate corrugated plate, the upper aluminum plate is transformed into a corrugated plate, and the bottom metal is a commercially available corrugated metal plywood. It is implemented in.

  In this Example 10, the iron powder (reddish color) that has been oxidized (rusted) has been doped in the cell for some time, but there is also the influence of other additives, There are adjustments with additives.

  (2) Since there is a difference in the amount of power generation due to the difference in the combination of metals, a mineral containing a metal element instead of a pigment is added in the present invention for various implementations. Minerals such as amethyst are pulverized and doped into the layers for various purposes. Further, in Examples 1 to 9, the present invention is variously carried out by adding minerals to one or more of the three layers with reference to (0104). Minerals are sometimes contained in ores, and some ores contain metal, and ores are sometimes implemented.

  The present invention can be produced with a simple battery structure that can be carried out even in a private house, and without using any special equipment with familiar raw materials. Since rice husk is used as a raw material, effective utilization of waste rice husk generated after threshing can be realized.

  In the present invention, the best numerical values are not specified for the raw materials and their use ratios. Simple examples of all the familiar raw materials generate electricity simultaneously with heat and light, demonstrating that semiconductor thermoelectric power generation and dye-sensitized power generation can be realized simultaneously. It explains that batteries that can be regenerated with rice husks and plant pigments and pigments can be manufactured. The present invention is completely new.

  In the future, the best raw materials and their use ratio will be clarified, efficiency and durability will be improved, and the product price can be produced at a low price. The present invention can be expected as an industrially effective new energy to be regenerated.

FIG.
1 Layer containing titanium oxide or titanium or titanium alloy
2 Salt layer
3 Layer containing zinc oxide or zinc or zinc alloy
4 Aluminum plate (one example)
5 Copper plate (one example)
FIG.
1 Layer containing titanium oxide or titanium or titanium alloy
2 Salt layer
3 Layer containing zinc oxide or zinc or zinc alloy
4 Aluminum plate (one example)
5 Copper plate (one example)
6 Arrange materials such as glass or plastic arbitrarily
FIG.
1 Layer containing titanium oxide or titanium or titanium alloy
1-1 Layer containing dye-sensitized titanium oxide or titanium or titanium alloy
2 Salt layer
3 Layer containing zinc oxide or zinc or zinc alloy
4 Aluminum plate (one example)
5 Copper plate (one example)
FIG.
1 Layer containing titanium oxide or titanium or titanium alloy
2 Salt layer
3 Layer containing zinc oxide or zinc or zinc alloy
4 Aluminum plate (one example)
5 Copper plate (one example)
6 Arrange materials such as glass or plastic arbitrarily
7 Aluminum plate soaked in either hot or cold water (example)
8 Copper plate soaked in either hot or cold water (one example)
9, 10 Water or cold water container, equipment (one example)
FIG.
(A) 1 Layer containing titanium oxide or titanium or titanium alloy
Arrangement to place any material such as glass or plastic directly above
4 Aluminum plate (one example)
11 Light bulb
(B) 1 Titanium oxide or a layer containing titanium or a titanium alloy
Arrangement to place any material such as glass or plastic directly above 4 Aluminum plate (example)
FIG.
12 Semiconductor thermal power generation
13 Semiconductor thermal power generation
14 Dye-sensitized power generation
15 Dye-sensitized power generation
16 Battery action to charge and discharge
17 Rice hulls of biomass material
FIG.
1 Layer containing titanium oxide or titanium or titanium alloy
1-1 Layer containing dye-sensitized titanium oxide or titanium or titanium alloy
2 Salt layer
3 Layer containing zinc oxide or zinc or zinc alloy
4 Aluminum plate (one example)
5 Copper plate (one example)
6 Arrange materials such as glass or plastic arbitrarily
18 Wire mesh
19 Solid iodine
20 2 testers

When these three layers are formed within a range of 1 cm or 2 cm on each 3 cm cell, dozens of cells are produced with a total amount of 22 g of mixed liquid (part B). A small amount of liquid is used below. Prepare three small trays and mix the mixture into three trays, one Sspoon.

About 0.07 g of boric acid (commercially available) is placed in a titanium tray. Add about 0.09 g of boric acid to the zinc tray. This quantity is ambiguous and not strictly measured, it is only described in the reference level and has changed in various implementations. More zinc is added to boric acid than titanium. Do not put boric acid in the salt tray. Occasionally boric acid is also added to the salt layer, and in this case, the boric acid is mixed well so that the boric acid can be uniformly arranged in the three layers.

"Hibiscus powder: 0.9 g vs. tincture: 5.5 g vs. Henna powder (which is an example of a metal) 0.3g versus zircon powder 0.3g"
(It is only one example because it is replaced with another plant and different numerical values. Zircon in one example of metal may be alumina, copper, iron, cobalt, and so on.)

Making the mixture (also a mixture), fourth trays mixture S spoon put one cup in the likewise S spoonful (weight about 0 to titanium P25 of Aerosil Co. nanosize its tray. 24g) Add and mix well. The volume ratio is 1: 1.

Inside each copper plate of 3 cm (thickness 0.5 mm), about 2 cm each spacer is made into a square, and the contents of the zinc tray on the copper plate (the mixture mixed in each tray is for distinction, 1 part of the content) (in other words, the contents) are arranged in layers of 1 cm each further inside the spacer. This is a zinc layer. Place a small portion of the contents mixed with a salt tray on top of each other, also in layers of 1 cm. This is a salt layer. The contents of the titanium, zinc and salt trays are enough to make three identical cells, and the amount of one cell is about one-third of each tray.

In this cell, granular iodine (manufactured by Wako Pure Chemical Industries, Ltd.) described in ( 0175 ) is contained. Granular iodine is necessary for high output. The two types of metal and three layers are firmly attached to form a cell. Seals to prevent important iodine from evaporating out of the cell. (Thickness of the cell: 3 mm) Three layers of 1 cm each are formed inside each spacer of about 2 cm in each cell of 3 cm, and the three layers may be circular or arbitrary, but the layers are formed inside the spacer. There is a part where you can see the aluminum plate without.

In order to intentionally generate semiconductor thermoelectric power using an aluminum plate without a layer, no layer is formed inside the spacer. The three-layer part is a small layer of 1 cm each. The water described in ( 0175 ) is preferably evaporated and evaporated to reduce hydration. Does not leak. Free electrons exit the aluminum plate (minus pole) and return to the copper plate (plus electrode). Conversely, the current exits from the copper plate (positive electrode) and returns to the aluminum plate (negative electrode). This completes the regenerated battery.

Of course, the present invention is carried out using natural pigments or organic pigments instead of plants. Various minerals such as turquoise are added to one or more of the three layers as pigments or for the purpose of making the semiconductor P-type or N-type.

(Example 3 (1))
The whole picture is a cell using carbonized or incinerated rice husk. Carbonized or incinerated rice husk and water are mixed in three layers, and about three solid iodines (manufactured by Wako Pure Chemical Industries, Inc., granular) are placed per cell, thereby containing iodine in the three layers. The outside of the cell has 2 types of metal and 3 layers inside. Below is a material that only makes one cell.

-Variant of plant mixture << 1 >><< 6 >>
“Chaff: 3 (reference weight 0.9 g) vs. iodine tincture: 17 (reference weight 5.6 g) vs. hibiscus and rosepip powder (replaced with hibiscus powder)
: 7 (reference weight 0.9 g) vs. henna powder: 2 (reference weight 0.3 g) vs. mixture of plant and rice husk << 3 >> (do not put zircon, put in instead)
: 1 (weight of reference 0.1g) "
(Although it is a modified type, it is replaced with another material such as raw materials, different plants, and different values, so it is only one example . Zircon in one example of metal may be alumina, copper, iron, cobalt.) It is the same from.)

Claims (27)

  Layers containing different types of metals on the top and bottom of the cell, comprising a layer containing titanium oxide or titanium or titanium alloy on one metal, and a layer containing zinc oxide or zinc or zinc alloy on the other metal A regenerating battery characterized in that there is a salt layer between the two layers, and a rice husk is mixed in each layer, and the layer containing titanium oxide or titanium or a titanium alloy as a structure; and The layer containing zinc oxide or zinc or a zinc alloy is a regenerative battery in which the upper and lower positional relationships can be interchanged.   The position of the three layers according to claim 1 is changed, and there is a layer containing titanium oxide or titanium or a titanium alloy at the bottom of any one or more of glass, plastic, silicon, rubber and vinyl, and a metal is placed below the layer. The metal has one or more holes, a layer of salt, and a layer containing zinc oxide or zinc or a zinc alloy, with a different kind of metal underneath, A regenerating battery characterized in that each layer is mixed with rice husks, the layer containing titanium oxide or titanium or titanium alloy as a structure, and the layer containing zinc oxide or zinc or zinc alloy A regenerative battery that can change the position of the top and bottom.   In addition to the three layers according to claim 1 or 2, one layer is added, and there is a layer containing titanium oxide or titanium or a titanium alloy under one or more materials of glass, plastic, silicon, rubber and vinyl. A metal is placed underneath, and the metal has one or more holes, and further includes a layer containing titanium oxide or titanium or a titanium alloy, a layer of salt, and a layer containing zinc oxide or zinc or a zinc alloy. There is a different type of metal from above and a regenerative battery characterized in that rice husks are mixed in each of the layers, and a layer containing the titanium oxide or titanium or titanium alloy as a structure. And a layer containing zinc oxide or zinc or a zinc alloy is a regenerative battery in which the upper and lower positional relationships can be interchanged.   The rice husk is crushed, the rice husk is carbonized, the rice husk is made ash, or is in a different state, or any one or more rice husks are used. The battery to be regenerated as described.   5. A regenerating battery according to claim 4, wherein one or more of iodine or iodide compounds are used in the cell.   Each of the above-mentioned layers including a layer containing titanium oxide or titanium or a titanium alloy, or a layer containing zinc oxide or zinc or a zinc alloy containing at least one of boric acid, boron, phosphorus and sulfur in a salt layer The regenerating battery according to claim 5, wherein the regenerating battery is added to one or more.   The battery to be regenerated according to claim 6, wherein plants are mixed in one or more layers in the cell, plants and metals are mixed, or plants, metals and iodine are mixed.   The regenerative battery according to claim 7, wherein at least one of charcoal, black ink, black ink, carbon black, graphite, glue, pigment, and a substance containing a chemical compound is used in the cell. .   The regenerating battery according to claim 7, wherein a wire mesh is disposed between the layers in the cell.   The regenerative battery according to claim 5, wherein at least one of a pigment, a mineral and an ore is used in one or more layers in the cell.   The regenerative battery according to claim 10, wherein a wire mesh is arranged between the layers in the cell.   6. The regenerating battery according to claim 5, wherein at least one of a natural pigment, a plant pigment, and an organic pigment is used.   The regenerating battery according to claim 12, wherein a wire mesh is disposed between the layers in the cell.   A device in which the battery to be regenerated according to claim 5 is made into a module or an array, or a device in which the battery to be regenerated according to claim 5 is applied to a part, device, facility, equipment, or product.   The exterior or exterior of the cell is provided with one or more materials of building material, wall material, heat storage material, heat insulating material, glass, plastic, silicon, rubber, vinyl, wood, metal on the exterior. 4. The battery to be recycled according to any one of 3).   The regenerative battery according to any one of claims 1, 2, and 3, which generates one or more power sources of semiconductor thermoelectric power generation or dye-sensitized power generation.   The regenerative battery according to any one of claims 1, 2, and 3, wherein one or more layers are multi-layered or multi-staged with different configurations.   Layers containing different types of metals on the top and bottom of the cell, comprising a layer containing titanium oxide or titanium or titanium alloy on one metal, and a layer containing zinc oxide or zinc or zinc alloy on the other metal A method of manufacturing a regenerative battery in which a salt layer is provided between the two layers, and a rice husk is mixed in each layer, the layer containing titanium oxide or titanium or a titanium alloy as a structure, and the oxidation The layer containing zinc or zinc or a zinc alloy is a manufacturing method of a battery to be regenerated, in which the upper and lower positions can be interchanged.   The position of the three layers according to claim 18 is changed, and there is a layer containing titanium oxide or titanium or a titanium alloy at the bottom of any one or more of glass, plastic, silicon, rubber, and vinyl, and a metal is placed below the layer. The metal has one or more holes, a layer of salt, and a layer containing zinc oxide or zinc or a zinc alloy, with a different kind of metal underneath, In the method for manufacturing a regenerated battery in which rice husk is mixed in each layer, the layer containing titanium oxide or titanium or titanium alloy as a structure and the layer containing zinc oxide or zinc or zinc alloy are positioned above and below the layer. A method of manufacturing a battery to be regenerated that can change the relationship.   In addition to the three layers according to claim 18 or 19, one layer is added, and there is a layer containing titanium oxide or titanium or a titanium alloy under one or more materials of glass, plastic, silicon, rubber and vinyl. A metal is placed underneath, and the metal has one or more holes, and further includes a layer containing titanium oxide or titanium or a titanium alloy, a layer of salt, and a layer containing zinc oxide or zinc or a zinc alloy. There is a different type of metal below the upper layer, and a method for producing a regenerating battery in which rice husk is mixed in each of the layers, the layer containing the titanium oxide or titanium or titanium alloy as a structure, and The layer containing zinc oxide or zinc or a zinc alloy is a method for producing a regenerated battery in which the upper and lower positional relationships can be interchanged.   The rice husk is crushed, the rice husk is carbonized, the rice husk is made ash, or is in a different state, or any one or more rice husks are used. A method for producing the regenerated battery as described.   The method for producing a regenerative battery according to claim 21, wherein one or more of iodine or an iodide compound is used in the cell.   One or more of boric acid, boron, phosphorus, sulfur, plants, pigments, minerals, charcoal, ink, ink, carbon black, graphite, glue, and chemical compounds in the cell The method for producing a regenerating battery according to claim 22 being used.   The method for producing a regenerative battery according to claim 23, wherein a wire mesh is arranged between the layers in the cell.   The method for producing a regenerating battery according to claim 22, wherein at least one of a natural pigment, a plant pigment, and an organic pigment is used.   26. The method for producing a regenerative battery according to claim 25, wherein a wire mesh is arranged between the layers in the cell. The exterior or one side of the cell is provided with one or more materials of building material, wall material, heat storage material, heat insulating material, glass, plastic, silicon, rubber, vinyl, wood, metal on the exterior. 21. A method for manufacturing a battery to be regenerated according to any one of 20.