JP2010097861A - Display device and plasma display panel - Google Patents

Abstract

In a plasma display device using ultraviolet light emission by discharge, discharge voltage is reduced and efficiency is improved.
A front plate and a rear plate arranged opposite to each other form a discharge space, the discharge space is filled with a discharge gas, and at least a pair of electrodes for performing display discharge; and the discharge gas It has a phosphor layer that emits visible light using ultraviolet light emission by discharge. In the discharge space, the main composition is a group II metal aluminate such as CaAl ₂ O ₄ , and the quantum efficiency is 15% or more by excitation with ultraviolet light having a wavelength in the wavelength range of 100 to 450 nm. By including the material, the sustain discharge voltage can be reduced and the efficiency can be improved.
[Selection] Figure 1

Description

  The present invention relates to a display device and a plasma display panel, and more particularly, to a plasma display panel configured using a phosphor that emits light by being excited by ultraviolet rays in a vacuum ultraviolet region, and a display device including the same.

  In recent years, there has been an increasing demand for a display device typified by a television or a personal computer monitor that is thin and does not require a large installation space. Plasma display devices (hereinafter referred to as PDP (Plasma Display Panel) devices), field emission display (FED) devices, and backlights and thin liquid crystal panels are combined as display devices that can be made thinner. Liquid crystal display (LCD) devices that constitute display devices have been actively developed.

  Among them, the PDP device is a display device including a plasma display panel (hereinafter referred to as PDP) as a light emitting device. The PDP is arranged in the micro discharge space using ultraviolet light generated in the negative glow region in the micro discharge space containing the rare gas (in the wavelength range of 146 nm and 172 nm when xenon is used as the rare gas) as an excitation source. Luminescence in the visible region is obtained by exciting the phosphor in the provided phosphor layer and promoting light emission from the phosphor. In the PDP device, the amount and color of light emission are controlled and used for display.

  In a PDP device, light emission and non-light emission in image display of a cell having an individual minute discharge space (hereinafter referred to as a discharge cell) are adjusted by accumulation of wall charges of the discharge cell. This wall charge is adjusted by generating a discharge called an address discharge before light emission. Therefore, it is very important to display an address discharge accurately in image display.

  In addition, the power consumption of the PDP device increases or decreases depending on the discharge voltage when light is emitted. The discharge voltage is also related to the cost of the drive circuit. For this reason, the discharge voltage is a very important factor in the performance of the PDP device.

  In the PDP device, by installing a specific material in the discharge space, the discharge characteristics and optical characteristics as described above can be affected. For example, the characteristics of light emitting materials such as phosphors are important. As literature regarding this type of material and technology, JP-A-2005-294255 (Patent Document 1), JP-A-2002-110051 (Patent Document 2), JP-A-2001-118511 (Patent Document 3), JP 2007-026793 (Patent Document 4), JP 11-191376 (Patent Document 5), JP 2005-26205 (Patent Document 6), and JP 2006-299098 (Patent Document). 7).

JP 2005-294255 A JP 2002-110051 A JP 2001-118511 A JP 2007-026793 A JP-A-11-191376 Japanese Patent Laid-Open No. 2005-26205 JP 2006-299098 A

  In recent years, PDP devices have been recognized for their high performance, and their use as large-sized flat panel displays and thin TVs are rapidly expanding, replacing monitors and televisions (TVs) that use cathode ray tubes. As a result, further improvement in performance has been demanded. Specifically, in order to display a high-vision by digital broadcasting or the like, it is necessary to increase the resolution. The number of display pixel lines required to support high-definition is 700 or more, and it is necessary to significantly increase the resolution compared to about 500 display lines compatible with conventional broadcasting. However, when the number of display pixel lines increases to about 700 or more, the number of cells to be discharged increases, and the burden on the circuit to be driven and the power consumption increase.

Further, in order to increase the resolution, each display pixel becomes smaller, so that it is necessary to increase the luminance, and high luminous efficiency is also required to achieve the higher luminance. As one of the methods, studies are actively made to increase the composition ratio of Xe (xenon) gas in a discharge gas containing Ne (neon) as a main component and to actively use the generated Xe ₂ molecular beam. . Although it is a technology trend of so-called “high xenon concentration” in PDP, it is usually considered to achieve high efficiency of light emission of PDP in the composition ratio region higher than the xenon gas composition ratio (about 5%) in the discharge gas. Has been made. In particular, in recent years, the composition ratio of xenon gas is at least 8% or more, the efficiency of light emission is improved, and the brightness is maintained and improved. However, increasing the xenon concentration results in an increase in discharge voltage. This increases the burden on the drive circuit and the like, increases the cost of the device, and also reduces the margin of the drive voltage, making driving difficult.

  PDP devices are increasingly used as flat TV devices that replace TV devices using cathode ray tubes from simple thin display devices. As a result, the demand for image quality is becoming higher, and it is necessary to meet the demand for higher image quality such as a reduction in screen flicker and the brightness, as well as lower power consumption and cost. In order to reduce power consumption and cost, it is important to reduce the discharge voltage.

  An object of the present invention is to improve the image quality of a display device and a PDP and increase the efficiency of discharge.

  The above and other objects and novel features of the present invention will be apparent from the description of this specification and the accompanying drawings.

  Of the inventions disclosed in the present application, the outline of typical ones will be briefly described as follows.

  According to the present invention, a front plate and a back plate arranged opposite to each other form a discharge space, the discharge space is filled with a discharge gas, and at least a pair of electrodes for performing display discharge, and the discharge gas In the display device having a fluorescent film that emits visible light using ultraviolet light emission by discharge, the display device includes a material in which charges are accumulated by voltage application or light irradiation in the discharge space. The problem can be solved. In the present application, that the material is included in the discharge space includes that the material is in contact with the discharge space.

  In the display device similar to the above, the present invention provides a material in which charges are accumulated in the discharge space, and at least a part of the accumulated charges is held for a time longer than the pulse time width of the drive voltage waveform. The above-described problem can be solved by a display device including the display device.

  Further, a typical example of the pulse time width of the drive voltage waveform is about 2 to 4 μs, and at least a part of the accumulated charge includes a material that is held for a time of 2 μs or more. In the characteristic display device, the above problem can be solved.

  In addition, in a display device characterized in that, as a specific material of the material, a material mainly composed of a group IIa metal and / or a group IIb metal aluminate is included at least in part, the above problem is solved. can do.

Further, it is more effective if the material is a material whose main composition is represented by MAl ₂ O ₄ (where M is at least one element of Mg, Ca, Zn, and Sr). In addition, it is particularly effective when the material is a material containing at least part of a material whose main composition is represented by CaAl ₂ O ₄ . At this time, CaAl ₂ O ₄ exhibits particularly good characteristics when the crystal system of the main crystal phase is monoclinic and the space group P21. In the case of having this crystal system, the diffraction line (main peak) having the highest intensity appears in the vicinity of 2θ = 30 ° when X-ray diffraction measurement is performed using CuKα rays. However, the composition mentioned above is a composition of the main component of the material, and can contain some other elements.

  When the material is used in a mixture with a phosphor, and the emission spectrum of the material is the same as that of the host phosphor, the chromaticity is not reduced or little, so Higher quantum efficiency is better. That is, when the quantum efficiency of visible light emission in the range of 450 nm to 780 nm by irradiation with ultraviolet rays of 450 nm or less is 15% or more, the luminance is prevented from being lowered to some extent, and the chromaticity is not lowered or little.

It is more effective if the weight of the material present in the phosphor layer is 1% or more and 50% or less with respect to the total weight of all the phosphors in the phosphor layer. Further, it is further preferable that the weight range is 1% or more and 20% or less. The general value of the weight of the material present in the phosphor layer is desirably 5 mg to 220 mg per 100 cm ^{2 of} panel area.

  On the contrary, when the material is mixed with a phosphor and the light emission of the material is different from that of the host phosphor, visible light in the range of 450 nm to 780 nm by irradiation with ultraviolet light of 450 nm or less is used. When the quantum efficiency of light emission is 15% or less, there is little influence on the light emission display, and a better image quality can be obtained.

  Among the inventions disclosed in the present application, effects obtained by typical ones will be briefly described as follows.

  ADVANTAGE OF THE INVENTION According to this invention, the discharge voltage in a plasma display panel can be reduced and the high-definition screen in a plasma display panel can be implement | achieved. According to the present invention, it is possible to realize a reduction in discharge voltage while suppressing a reduction in luminance.

  Hereinafter, a representative example of the embodiment of the present invention will be shown to explain the effect. The present invention is also effective in configurations other than those shown in the following examples as long as the configurations bring about similar effects. Note that components having the same function are denoted by the same reference symbols throughout the drawings for describing the embodiments, and the repetitive description thereof may be omitted.

  FIG. 8 is an exploded perspective view of the main part of the PDP 100 according to the invention, and FIGS. 9, 10 and 11 are lines AA, BB and CC, respectively, after the PDP 100 shown in FIG. 8 is assembled. FIG. 9 shows one section along the extending direction of the electrode 2, FIG. 10 shows another section along the extending direction of the electrode 2, and FIG. A cross section along the extending direction of the electrode 9 is shown.

  The PDP 100 has a structure for dealing with a so-called surface discharge PDP (reflection type AC drive), a pair of substrates 1 and 6 that are spaced apart from each other, and a pair of electrodes provided on the substrate 1. 2, a bus line (bus electrode) 3, a dielectric layer 4 and a protective film 5, and a partition (rib) 7 provided on a substrate 6, a dielectric layer 8, an electrode 9 and a phosphor layer 10 It is. The PDP 100 also includes a discharge gas (not shown) that is enclosed (filled) in a space (discharge space 11) formed between the pair of substrates 1 and 6 and generates ultraviolet rays by discharge. The discharge space in the PDP 100 is a space surrounded by the dielectric layer 8 and the protective film 5 after the pair of substrates 1 and 6 are overlapped, and the space is partitioned by the partition walls 7.

  In the PDP 100, since the substrate 1 is a front plate serving as a display surface, the substrate 1 is made of a material that transmits visible light emitted from the phosphor layer 10, and is made of, for example, high strain point glass. In addition, since the substrate 6 is a back plate, the substrate 6 is not limited to one that transmits visible light, but is made of, for example, high strain point glass like the substrate 1.

  The pair of electrodes 2 provided so as to extend in a predetermined direction on the substrate 1 are each a display electrode pair composed of a scan electrode (hereinafter referred to as a Y electrode) and a sustain electrode (hereinafter referred to as an X electrode). For example, a transparent electrode such as ITO. The bus line 3 constituting the display electrode pair is a low-resistance electrode having a narrow width in order to supplement the electrode resistance of the wide electrode 2 in order to improve luminance. For example, Ag (silver) Or it is comprised from Cu (copper) -Cr (chromium). An electrode 9 provided on the substrate 6 so as to extend in a direction intersecting with the direction in which the electrode 2 extends constitutes an address electrode (hereinafter referred to as A electrode), for example, Ag or Cu -It is composed of Cr. Write discharge is performed in the address period between the Y electrode and the A electrode, and surface discharge for display is performed in the sustain period (display period) between the Y electrode and the X electrode.

  The dielectric layer 4 provided so as to cover the pair of electrodes 2 and the dielectric layer 8 provided so as to cover the electrode 9 accumulate wall charges generated by the write discharge during the address period on the surface thereof. For example, it is comprised from low melting glass. A surface discharge is generated by the voltage due to the wall charges and the voltage applied in the sustain period, and the discharge cells (display cells) emit light.

  The protective film 5 provided so as to cover the dielectric layer 4 is for reducing sputter damage to the surface of the dielectric layer 4 at the time of discharge, and at the same time, emitting secondary electrons along with surface discharge. For example, it is composed of magnesium oxide (MgO).

  The partition walls 7 provided to separate the discharge cells and prevent color mixing with adjacent discharge cells are made of, for example, low-melting glass. The barrier ribs 7 also separate discharge cells. In other words, the barrier ribs 7 partition discharge spaces formed by the front plate (substrate 1) and the back plate (substrate 6) arranged opposite to each other. In the PDP 100 according to the present embodiment, the barrier ribs 7 have a line (stripe) structure, but may have a rectangular structure that separates the discharge cells.

  The phosphor layer 10 provided on the partition wall 7 and the dielectric layer 8 between the partition walls 7 is made of a phosphor for performing light emitting display. That is, the fluorescent substance which comprises the fluorescent substance layer 10 is excited by the vacuum ultraviolet rays with a wavelength of 146 nm and 172 nm which generate | occur | produce from discharge gas by discharge, and it is comprised so that visible light may be light-emitted.

In order to perform color display, the phosphor layer 10 is provided with phosphors of three colors of red, green, and blue. Examples of phosphors that emit light of each color include a red phosphor (Y, Gd) BO ₃ : Eu phosphor, a green phosphor Zn ₂ SiO ₄ : Mn ²⁺ phosphor, and a blue phosphor BAM ( BaMgAl ₁₀ O ₁₇ : Eu ²⁺ ) phosphor. These phosphors are often used as the main component of each color, but materials other than these may be used. In many cases, the average particle size of the phosphor is 1 to 5 μm, but phosphors having other particle sizes may be used.

As will be described in detail later, in the discharge space in this embodiment, a material in which charges are accumulated by voltage application or light irradiation, or charges are accumulated, and at least a part of the accumulated charges has a drive voltage waveform. A material that is held for a time longer than the pulse time width is included. For example, the phosphor layer 10 that is in contact with the discharge space may be a group IIa metal and / or group IIb metal aluminate, specifically MAl ₂ O ₄ (where M is Mg, Ca, Zn, Sr) together with the phosphor described above. At least one element). Thereby, it is possible to improve the image quality of the PDP 100 and increase the efficiency of discharge.

  Here, a case where an ADS (Address Display-Period Separation) method is applied will be described as an example of the gradation display method of the PDP 100 in the present embodiment. FIG. 12 is a diagram showing a sequence of voltages applied to each electrode in an ADS subfield (SF). In FIG. 12, the reference voltage (reference potential) is 0V.

  The subfield shown in FIG. 12 is one obtained by dividing one field (16.67 ms) as a plurality of subfields having a predetermined luminance ratio. In the ADS system, a plurality of subfields are selectively emitted according to an image, and a gradation is expressed by a difference in luminance. One subfield includes a reset period, an address period, and a sustain period as shown in FIG.

  In the reset period, a voltage higher than the discharge start voltage is applied between the display electrodes, and reset discharge occurs in all the discharge cells. Thereby, the wall voltage in all the discharge cells can be made substantially uniform.

  In the address period, a voltage is applied to the A electrode and the Y electrode in the discharge cell selected based on the image data. A predetermined positive voltage (address voltage) is applied to the A electrode in synchronization with the application of a predetermined negative voltage scan pulse to the Y electrode of the selected discharge cell, and an address discharge (selective discharge) occurs. . In the selected discharge cell in which the address discharge has occurred (becomes a display cell), wall charges that can be discharged when the display discharge is performed in the sustain period are accumulated. Note that an address voltage is not applied to the A electrode of a discharge cell that does not become a display cell (which becomes a non-display cell), and no address discharge occurs. For this reason, wall charges are not formed in the non-display cells, and display discharge does not occur during the sustain period.

In the sustain period, sustain pulses (sustain pulses) are alternately applied to the Y electrode and the X electrode, and a sustain discharge (display discharge) occurs. For example, if ten subfields having luminance weights based on the binary system are provided, red (R), green (G), and blue (B) discharge cells each have 2 ¹⁰ (= 1024) gradations. Luminance display can be obtained, and color display of about 1,073.74 million colors can be performed.

  The Y electrode and the X electrode are composed of a pair of adjacent electrodes 2 in FIG. 8, and light emission display is performed by a discharge (sustain discharge) between the two electrodes. The voltage for the sustain discharge is applied simultaneously in all the discharge cells. For this reason, it is necessary to select a discharge cell that discharges to emit light and a discharge cell that does not emit light. This is performed by causing a discharge between the A electrode and the Y electrode. The A electrode is the electrode 9 in FIG.

  When selecting a discharge cell to emit light, a voltage is simultaneously applied to the A electrode and the Y electrode that intersects the A electrode. Only in the discharge cells applied simultaneously, discharge occurs between the A electrode and the Y electrode (address discharge). At this time, charges are accumulated in the discharge cells. The voltage between the Y electrode and the X electrode is set to a voltage that does not start discharge by itself. The discharge is started only when the voltage due to the accumulated charges is added to the voltage between the Y electrode and the X electrode. Therefore, light emission due to the discharge occurs only in the discharge cell in which the address discharge is generated, and an image can be formed.

  In addition, since the discharge cell in which the wall charges are once formed always generates a sustain discharge thereafter, it is necessary to eliminate the wall charges in order not to emit light. Therefore, before applying the voltage for address discharge, a voltage is applied to erase wall charges in all the discharge cells. This is the reset voltage, and the time for applying this is the reset period.

  The voltage application sequence shown in FIG. 12 has a period called a subfield. One image is formed by a period called one field. In order to make a difference in luminance of each pixel that forms one image, one field is divided into, for example, about 10 subfields, and a series of discharges are performed in each subfield.

  The main object of the configuration of the present invention is to reduce the sustain discharge voltage, thereby improving the discharge efficiency and reducing the burden on the drive circuit. By adopting the configuration of the present invention, the voltage at which the sustain discharge starts can be made lower than the conventional voltage.

  Below, some examples about the factor of the effect of this invention are described. However, the factor shown here is an example, and in the present invention, the effect may be more effective than other factors. The present invention includes not only the effects of the examples given here, but also the effects of other factors obtained with materials that meet the requirements of the present invention. Moreover, the following description is schematic and the numerical formula etc. which are described with drawing or text do not represent an exact numerical value.

  A first example of the explanation of the factors of the present invention will be described. The sustain discharge voltage of the PDP 100 is mainly determined by the ease of electron emission from the protective film 5 made of, for example, MgO. In the case of the present invention, since the material of the protective film 5 is the same, the electron emission characteristic itself from the protective film 5 does not change. Therefore, it is conceivable that the discharge voltage decreases as the amount of cations or electrons in the discharge space near the surface of the protective film 5 increases. Electron emission from the protective film 5 mainly occurs when cations ionized by the discharge gas enter the protective film 5. Therefore, increasing the number of cations near the surface of the protective film 5 facilitates electron emission. Further, when the amount of electrons in the discharge space increases, the number of cations increases because the electrons collide with the discharge gas and ionize when a voltage is applied. Therefore, also in this case, electron emission becomes easy.

  In order to bring about the above effects, the material of the present invention must satisfy the following characteristics. First, 1) charge is accumulated by voltage application or light irradiation, and is positively charged or negatively charged. By using such a material for the portion other than the protective film 5 at the discharge position, positive ions are repelled in the case of positive charge, and electrons are repelled in the case of negative charge, and move away from this material. That is, it is near the protective layer at the discharge position, resulting in an increase in the amount of cations or electrons in the discharge space near the surface of the protective film 5.

  Next, 2) the above-described effect is enhanced when the charge accumulated in the material of the present invention is held for a certain period of time. That is, it is desirable that at least a part of the accumulated charge is held for a time longer than the pulse time width of the drive voltage waveform. This time is about 2 to 4 μs in a typical driving waveform. A sustain discharge occurs once in the pulse time width of the drive waveform. By maintaining the charge within this time, the movement of cations or electrons becomes remarkable, which is more effective.

  A second example of the explanation of the factors of the present invention will be described. As a factor different from the above description, the case where the charging of the material of the present invention has an effect as a direct voltage will be described with reference to FIGS. FIG. 6 is a diagram illustrating waveforms of drive voltages applied to the X electrode and the Y electrode during the sustain period, and FIG. 7 is a diagram illustrating changes in the charging state during the sustain discharge. b), (c), and (d) show the states at a, b, c, and d in FIG. 6, respectively.

  FIG. 7 shows the movement of charges in the PDP cell during the sustain discharge when the PDP emits light, and the present invention is compared with the conventional example. Here, in this invention, the material which satisfy | fills the requirements of this invention is mixed with fluorescent substance. In the conventional example, only ordinary phosphors are used. These phosphors are applied to the inside of the partition walls inside the cell, and the phosphors exist up to just below the X and Y electrodes.

  The driving voltage is lower by β in the present invention, (α−β) V in the present invention, and αV in the conventional example. FIG. 7A shows a state in which a negative voltage is applied to the X electrode and a positive voltage is applied to the Y electrode, just before the applied voltage is inverted for driving. At this time, a voltage is generated in the phosphor so as to extinguish this, and is charged to + under the X electrode and to-under the Y electrode. This is the same in the present invention and the conventional example, even though there is a difference in charge amount.

  In FIG. 7B, the applied voltage is reversed for driving, and the + voltage is applied to the X electrode and the − voltage is applied to the Y electrode. At this time, in the conventional example, the charging is reversed simultaneously with the reversal of the applied voltage, and is − under the X electrode and + under the Y electrode. On the other hand, in the present invention, since the material mixed in the phosphor retains the charge, the same state as in the state A is maintained, and it remains positively charged below the X electrode and negatively below the Y electrode.

  In this state, the discharge is started, but in the conventional example, the charging of the phosphor is reversed, and the electric potential is in the direction of eliminating the applied voltage. Here, the discharge voltage is exceeded only after the applied voltage becomes αV, and the discharge starts. On the other hand, in the present invention, since the charging of the material mixed with the phosphor is not reversed, the electric potential is in the direction applied to the applied voltage. Here, the applied voltage is β. Therefore, in the present invention, the applied voltage exceeds (α−β) V and exceeds the discharge voltage, and discharge starts.

  FIG. 7C shows a state after discharge. At this point, the present invention has caused a reversal of charging of the material mixed with the phosphor. On the other hand, in the conventional example, there is no change in charging.

  FIG. 7D shows the state immediately after the next applied voltage reversal after the discharge. At this point, in the present invention, the inversion of the material mixed in the phosphor is almost completed, and the charging is in a state substantially equivalent to the conventional example. This is a state in which the polarity of the voltage is opposite to that in the state A, and in the next applied electrode inversion, the polarity is opposite to that in the states A to D, but a discharge occurs due to the same change. This is repeated and the sustain voltage is driven.

  From the above, it can be seen that in the present invention, the drive voltage can be reduced by the voltage βV applied by charging the material mixed in the phosphor. In the above description, the material of the present invention is described as being positively or negatively charged, but this has the same effect even when charged positively or negatively. The material may be charged either positively or negatively.

  In order to bring about the above effects, the material of the present invention needs to satisfy the following characteristics. 1) Charge is accumulated by voltage application or light irradiation. 2) At least a part of the accumulated charge is held for a time longer than the pulse time width of the drive voltage waveform. This time is about 2 to 4 μs in a typical driving waveform.

  Such an effect does not depend on the type of phosphor. Moreover, although the example mixed with fluorescent substance was shown, as long as the same effect is brought about, the installation method of a material may be another method. For example, it can be installed as a lower layer of a phosphor. Moreover, it is also possible to install as a partition itself. It can also be installed inside the front plate. The partition is formed as follows. That is, a printing paste containing low melting point glass is formed by screen printing. The printed low melting point glass is sintered, and then a recess is formed by sand blasting using a blast mask. By mixing the charge storage material according to the present invention in the printing paste, the partition wall itself can have the effects of the present invention.

  The charge accumulation of the material that brings about such an effect can be easily confirmed by examining the charge amount immediately after the panel discharge. An example of the evaluation method is described. As a measuring device, an electrostatic voltmeter (electrostatic potential measuring device) or the like is used, a measuring element is applied to the back side of the panel, and a change in electrostatic potential immediately after discharge is measured. When the material of the present invention is used, the potential and the maintenance time are different from the conventional case.

  FIG. 13 is a diagram showing the configuration of the PDP apparatus 200 according to the present invention. The PDP device 100 includes a PDP 100 having an A electrode (electrode 9), a Y electrode (one of the pair of electrodes 2), and an X electrode (the other of the pair of electrodes 2), an address driving circuit 101 for driving the A electrode, The scan / sustain pulse output circuit 102 for driving the scan / sustain electrode (Y electrode 23), the sustain pulse output circuit 103 for driving the sustain electrode (X electrode 22), and these output circuits are controlled. A drive control circuit 104 and a signal processing circuit 105 for processing an input signal are provided. In addition, the plasma display apparatus 100 includes a driving power source 106 that applies a voltage to the PDP 100 and the like, and a video source 107 that generates a video signal.

  The PDP device 200 joins the electrode of the PDP 100 and the flexible substrate with an anisotropic conductive film. Thereafter, in order to improve the heat dissipation of the PDP 100, for example, a plate made of aluminum or the like is attached, and drive circuits such as the drive power source 106 and the address drive circuit 101 are incorporated on this plate, thereby completing the plasma display module. Thereafter, the plasma display device 200 is completed by performing further inspection and attaching an exterior case.

  As shown in FIG. 8, the PDP 100 is provided with the electrode 9 constituting the A electrode on the back plate (substrate 6) and the pair of electrodes 2 constituting the Y electrode and the X electrode on the front plate (substrate 1). It has become. A space (discharge space 11) sandwiched between the front plate and the back plate is partitioned by the partition walls 7, and each of the partitioned spaces constitutes a discharge cell. A discharge gas is sealed in the discharge space 11, and when a voltage is applied to the Y electrode and the X electrode, a sustain discharge occurs and ultraviolet rays are generated. Each discharge cell is coated with a phosphor that emits red, green, or blue light, and the phosphor is excited by the ultraviolet rays generated as described above, depending on the phosphor. Emits colored light. A color image can be displayed by using this light emission and selecting a discharge cell of a desired color according to the video signal.

  When the present invention is used in a PDP apparatus including a gas composed of Xe gas in an amount that the composition ratio of the discharge gas is 8% or more, the discharge voltage increased by increasing the xenon concentration is reduced and driven. Is particularly effective. In addition, the present invention is particularly effective when used in a PDP device composed of 700 or more display pixel lines, because it reduces the discharge voltage, thereby reducing the load on the drive circuit and reducing power consumption. is there.

  Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

  A PDP 100 and a PDP apparatus 200 using the same according to the present embodiment will be described with reference to FIGS. 8 to 11 and FIG. In the present embodiment, a material that satisfies the requirements of the present invention is mixed with red, green, and blue phosphors to form the phosphor layer 10.

Examples of materials that meet the requirements of the present invention include group IIa metal and / or group IIb metal aluminates, particularly CaAl ₂ O ₄ , MgAl ₂ O ₄ , ZnAl ₂ O ₄ , SrAl ₂ O ₄ , Sr ₄ Al ₁₄ O ₂₅ or the like. Moreover, these mixed crystals can also be used. At least one of these materials can be mixed in the range of 0.1 wt% to 80 wt% to produce the PDP 100 shown in FIG. Although the material composition is exemplified above, the materials to be mixed are not limited to these, and it is effective to use materials other than those described above as long as they exhibit characteristics satisfying the conditions of the present invention. Moreover, the composition raised above is a composition of the main component of the material and can contain some other elements.

Moreover, as phosphors of three colors of red, green, and blue, red phosphors are (Y, Gd) BO ₃ : Eu phosphors, green phosphors are Zn ₂ SiO ₄ : Mn ²⁺ phosphors, and blue phosphors are A BAM (BaMgAl ₁₀ O ₁₇ : Eu ²⁺ ) phosphor was used as the main component of each color. However, the effect of the present invention is also effective when other materials than these are used as the main component of each color of the phosphor.

  In the PDP 100 of the surface discharge type color PDP apparatus shown in the present embodiment, for example, a negative voltage is applied to one of the pair of display electrodes (electrode 2) (generally called a scan electrode) and the address electrode (electrode 9). A discharge is generated by applying a positive voltage (positive voltage compared to the voltage applied to the display electrode) to the other remaining display electrode (electrode 2). A wall charge is formed to assist in starting the discharge (referred to as writing). When an appropriate reverse voltage is applied between the pair of display electrodes in this state, a discharge is generated in the discharge space 11 between the pair of display electrodes (electrodes 2) via the dielectric layer 4 (and the protective film 5). appear.

  When the voltage applied to the pair of display electrodes (electrode 2) is reversed after the discharge is completed, a new discharge is generated. By repeating this, a discharge is continuously generated (this is called a sustain discharge or a display discharge).

  A manufacturing method of PDP 100 shown in the present embodiment and PDP device 200 using the same will be described. First, an address electrode (electrode 9) made of Ag (silver) or the like and a dielectric layer 4 made of a glass-based material are formed on a back plate (substrate 6). A partition wall 7 made of a material is printed on a thick film, and the partition wall 7 is formed by blast removal using a blast mask.

  Subsequently, red, green, and blue phosphor layers 10 are sequentially formed in stripes on the partition walls 7 so as to cover the groove surfaces between the corresponding partition walls 7.

  Here, each phosphor layer 10 corresponds to red, green and blue, and 40 parts by weight of red phosphor particles (60 parts by weight of vehicle) and 40 parts by weight of green phosphor particles (60 parts by weight of vehicle). And 35 parts by weight of the blue phosphor particles (65 parts by weight of the vehicle), mixed with the vehicle to form a phosphor paste, applied by screen printing, and then evaporated and evaporated of the volatile components in the phosphor paste. It is formed by burning off organic matter. The phosphor layer 10 shown in the present embodiment is composed of each phosphor particle having a median particle diameter of about 3 μm.

  Subsequently, the front substrate (substrate 1) on which the display electrode (electrode 2), the bus line 3, the dielectric layer 4 and the protective film 5 are formed and the rear substrate (substrate 6) are frit-sealed, and the inside of the panel is evacuated. After exhausting, discharge gas is injected and sealed. The discharge gas is a gas that includes xenon (Xe) gas in an amount that results in a composition ratio of 10%.

  Subsequently, by using the PDP 100 in combination with a drive circuit or the like that drives the PDP 100, as shown in FIG. 13, the PDP device 200 that is a display device configured to display an image can be manufactured. The PDP device 200 using the present invention can be a low-cost device with a low sustain discharge voltage, high discharge efficiency, and a low load on the drive circuit.

FIG. 1 shows the sustain discharge voltage of the PDP device 200 (PDP 100). Here, an example in which CaAl ₂ O ₄ , MgAl ₂ O ₄ , ZnAl ₂ O ₄ , and SrAl ₂ O ₄ is used as a material that satisfies the requirements of the present invention will be described. In FIG. 1, the horizontal axis represents the weight mixing ratio of the material of the present invention to the phosphor, and the vertical axis represents the amount of decrease in the sustain discharge voltage. Here, the amount of decrease in the sustain discharge voltage in the conventional example not including the material of the present invention is zero.

As shown in FIG. 1, it can be seen that the sustain discharge voltage is reduced by mixing. The voltage reduction effect has been also shown as the materials, particularly CaAl ₂ O ₄ is found to be significant. From FIG. 1, the effect of reducing the discharge voltage by about 1 V or more is recognized when the above material is contained in an amount of 1 wt% or more. When 5 wt% or more is included, the discharge voltage can be reduced by several volts or more. According to FIG. 1, when only the discharge voltage is considered, the effect is remarkable when the mixing amount is large. The discharge voltage decreases linearly until at least the mixing amount is about 50 wt%. That is, if the effective mixing range is about 1 wt% to 50 wt%, the effect of reducing the discharge voltage can be obtained.

  On the other hand, the light emission luminance decreases as the mixing amount increases. FIG. 3 shows the luminance when the material of the present invention is mixed with all the phosphors of red, green, and blue. FIG. 3 shows the case where the quantum efficiency of the additive material is zero. When the luminance of the PDP device 200 is reduced to about 80% or less, the influence on the image quality becomes serious. From FIG. 3, when the material of the present invention is contained in an amount of 20 wt% or more, the luminance of the PDP device 200 is about 80% or less. Therefore, more effectively, the material should contain 1 wt% to 20 wt%.

Further, in a general plasma display panel, the weight of the material of the present invention mixed and contained in the phosphor is desirably 5 mg or more and 220 mg or less per 100 cm ² of the panel area. FIG. 2 shows the relationship between the weight of the material of the present invention per 100 cm ^{2 of} panel area and the sustain discharge voltage using CaAl ₂ O ₄ as an example. An effect is recognized when 5 mg or more of the material of the present invention is contained, and a reduced voltage is sufficiently recognized up to at least about 220 mg.

The above-mentioned mixing ratio or the weight per panel area of 100 cm ² is a structure in which the material of the present invention is present in the phosphor layer 10 for performing visible light emission display in the discharge space 11. In other cases, it may be more effective to use the above range.

CaAl ₂ O ₄ used here exhibits particularly good characteristics when the crystal system of the main crystal phase is monoclinic and the space group P21. FIG. 5 shows an example of an X-ray diffraction measurement result of CaAl ₂ O ₄ used in the present invention in a θ-2θ scan with CuKα rays. It can be seen that the diffraction line (main peak) having the highest intensity appears in the vicinity of 2θ = 30 °. This measurement is possible with a general-purpose powder X-ray diffractometer.

In addition, the above materials may emit light by excitation with ultraviolet rays or the like due to addition of other elements, crystal defects, composition shifts, and the like. As a result of examination, it has been found that the voltage reduction effect in the present invention is effective regardless of light emission or non-light emission. However, in the PDP, the light emission of the phosphor for performing light emission display is adjusted for good color reproduction and moving image display, and if another light emission is added, it often has an adverse effect. As an example, by adding Eu (eurobium) to the composition of CaAl ₂ O ₄ , light is emitted in bluish purple. If this material is caused to emit light simultaneously with the green phosphor of the PDP, green light emission will contain blue-violet light emission, and the color reproducibility of green light emission will be reduced.

CaAl ₂ O ₄ obtained by adding Eu to the composition can be obtained with different emission quantum efficiencies due to the difference in the composition. The change in chromaticity value of light emission was evaluated for a mixture of CaAl ₂ O ₄ with Eu added to the composition with varying quantum efficiency mixed with a normal green phosphor at a weight ratio of 50 wt%. Luminescence by ultraviolet light was measured with a luminance meter capable of measuring chromaticity, and chromaticity values y of CIE: xy chromaticity coordinate systems were compared. FIG. 4 shows the evaluation results. It can be seen that the value of the chromaticity value y on the vertical axis decreases as the quantum efficiency of the mixed material of the present invention increases. This indicates that as the quantum efficiency increases, the amount of blue-violet light emission increases, affecting the green light emission color.

  When the chromaticity value y exceeds 0.7, the green phosphor emits green with good color reproducibility. Conversely, the lower the chromaticity value y, the green has poor color reproducibility. In the case of a plasma display, the chromaticity value y is preferably 0.7 or more. FIG. 4 shows that if the quantum efficiency is about 15% or less, the chromaticity value y is 0.7 or more, and good color reproducibility can be maintained. Therefore, when the emission spectrum of the material of the present invention is different from the emission spectrum of the host phosphor and the emission spectrum of the charge storage material according to the present invention, the quantum efficiency of light emission of the charge storage material according to the present invention should be 15% or less. Is desirable.

  The only light emission in question here is visible light that affects the display. Therefore, the quantum efficiency of visible light emission in the range of 450 nm to 780 nm by irradiation with ultraviolet light of 450 nm or less was used. In addition, the quantum efficiency of light emission of a material can be measured with a commercially available quantum efficiency measuring device.

  FIG. 4 described above is a case where the light emission by the added material is different from the emission spectrum of the host phosphor. Conversely, if the emission spectrum of the charge storage material according to the present invention matches the emission spectrum of the host phosphor, the effects of the present invention can be obtained without reducing chromaticity and luminance. In this case, it is better that the added material has a higher quantum efficiency.

FIG. 14 shows the light emission efficiency (quantum efficiency of light emission) when an additive element is added to CaAl ₂ O ₄ which is the most effective material in the present invention. FIG. 14A shows the case where Eu is added to CaAl ₂ O ₄ and the emission spectrum is bluish purple. Therefore, if CaAl ₂ O ₄ : Eu is added to the blue phosphor, the color purity (chromaticity) is not lowered, and the luminance reduction can be suppressed. In FIG. 14A, the luminous efficiency of CaAl ₂ O ₄ : Eu becomes maximum when Eu is contained in an amount of about 0.3 mol% to 0.5 mol%. Therefore, by mixing CaAl ₂ O ₄ : Eu in this range with the blue phosphor, it is possible to suppress a decrease in luminance and a decrease in chromaticity while maintaining the effects of the present invention.

In addition, a material obtained by adding Eu to CaAl ₂ O ₄ can include red light emission by treatment in an oxidizing atmosphere or the like. In this case, mixing with the red phosphor can suppress a decrease in luminance and a decrease in chromaticity while maintaining the effects of the present invention.

FIG. 14B shows a case where Tb is added to CaAl ₂ O ₄ and the emission spectrum is green. CaAl ₂ O ₄ : Tb has the highest luminous efficiency when the amount of Tb is about 6 to 8 mol%. Therefore, by mixing CaAl ₂ O ₄ : Tb in this range with the green phosphor, it is possible to suppress a decrease in luminance and a decrease in chromaticity while maintaining the effects of the present invention.

FIG. 14C shows the case where Mn is added to CaAl ₂ O ₄ and the Mn ²⁺ is contained at least partially by treatment in a reducing atmosphere or the like, and the emission spectrum is green. CaAl ₂ O ₄ : Mn ²⁺ has the highest luminous efficiency when it contains about 5 mol% to 15 mol% of Mn ²⁺ . Therefore, by adding CaAl ₂ O ₄ : Mn ²⁺ in this range to the green phosphor, it is possible to suppress a decrease in luminance and a decrease in chromaticity while maintaining the effects of the present invention.

FIG. 14D shows the case where Mn is added to CaAl ₂ O ₄ and Mn ³⁺ is contained at least partially by treatment in an oxidizing atmosphere or the like, and the emission spectrum is red. CaAl ₂ O _4: ^{Mn 3+} in an amount of ^{Mn 3+} is the most luminous efficient when containing about 1 mol% 5 mol%. Therefore, by mixing CaAl ₂ O ₄ : Mn ³⁺ in this range with the red phosphor, it is possible to suppress a decrease in luminance and a decrease in chromaticity while maintaining the effects of the present invention.

FIG. 15 shows how the luminance changes with respect to the quantum efficiency of the added CaAl ₂ O ₄ , that is, the light emission efficiency in FIG. 14 when 15 wt% of CaAl ₂ O ₄ is added to the specific phosphor. Is shown. For example, CaAl ₂ O ₄ : Eu is added to the blue phosphor, and CaAl ₂ O ₄ : Tb is added to the green phosphor. As shown in FIG. 15, as the luminous efficiency of CaAl ₂ O ₄ is increased, that is, the quantum efficiency is increased, the luminance is also increased. In this way, by adding a specific element to CaAl ₂ O ₄ and matching the emission spectrum with the host phosphor, it is possible to prevent a decrease in luminance and a decrease in chromaticity while maintaining the effects of the present invention. This effect becomes more prominent as the luminous efficiency of the additive material CaAl ₂ O ₄ is higher.

As shown in FIG. 15, when the quantum efficiency of CaAl ₂ O ₄ as an additive material exceeds 15%, the luminance can be 90% or more in the case of the phosphor alone. And as the quantum efficiency of the additive material increases, the luminance also increases. FIG. 15 shows an example in which the phosphor includes 15% of the charge storage material according to the present invention. Even if the charge storage material according to the present invention is other than 15%, the quantum efficiency of the material is shown. By making the ratio 15% or more, it is possible to suppress a decrease in luminance.

  In the PDP, when the Xe concentration is 8% or more, the sustain discharge voltage tends to increase. However, even when the Xe concentration is 8% or more, the discharge voltage is low, the efficiency is high, and the circuit cost is increased. Can be manufactured.

  Further, in a plasma display composed of 700 or more display pixel lines, power consumption increases as the number of cells increases. However, by using the present invention, a display device with reduced power consumption can be manufactured.

  In addition, PDPs can be similarly produced using phosphors having the following compositions as red, green, and blue phosphors.

In the red phosphor, one or more phosphors of (Y, Gd) BO ₃ : Eu, (Y, Gd) ₂ O ₃ : Eu, and (Y, Gd) (P, V) O ₄ : Eu are used. It is possible to include. The green phosphor may include one or more phosphors of YBO ₃ : Tb, (Y, Gd) BO ₃ : Tb, BaMgAl ₁₄ O ₂₃ : Mn, and BaAl ₁₂ O ₁₉ : Mn. Is possible. In the blue phosphor, one or more selected from the group consisting of CaMgSi ₂ O ₆ : Eu, Ca ₃ MgSi ₂ O ₈ : Eu, Ba ₃ MgSi ₂ O ₈ : Eu, and Sr ₃ MgSi ₂ O ₈ : Eu. Of blue phosphors.

  The phosphors listed above are examples of commonly used phosphors, and the effects of the present invention are effective regardless of the type of phosphor used. Even when a phosphor other than the above is used, the display device of the present invention can be manufactured.

In the above-described embodiment, the material that satisfies the requirements of the present invention (for example, CaAl ₂ O ₄ ) is mixed with the red, green, and blue phosphors for display, and the phosphor layer is configured. In the embodiment, a case where a predetermined amount is directly applied to the side surface of the partition wall will be described. The other basic structure, the phosphor material, the manufacturing method, and the PDP device 200 using the PDP 100 are the same as those in the first embodiment, and thus the description thereof is omitted.

FIG. 16 is a cross-sectional view of a main part of PDP 100 in the present embodiment corresponding to the line AA in FIG. As shown in FIG. 16, a predetermined amount of a material 12 (for example, CaAl ₂ O ₄ ) satisfying the requirements of the present invention is applied to the side surface of the partition wall 7. The material 12 can be applied by printing. Thereby, PDP 100 in the present embodiment and PDP device 200 using the same can exhibit good characteristics similar to those in the first embodiment. The amount of the charge accumulating material in this embodiment can be effective when the amount is 1 mg or more per 100 cm ² of the panel area. This is because the effect of the charge storage material is greater than when the phosphor is mixed.

In the above-described embodiment, the material that satisfies the requirements of the present invention (for example, CaAl ₂ O ₄ ) is mixed with the red, green, and blue phosphors for display, and the phosphor layer is configured. In the embodiment, a case where a predetermined amount is directly applied to a part of the protective film will be described. The other basic structure, the phosphor material, the manufacturing method, and the PDP device 200 using the PDP 100 are the same as those in the first embodiment, and thus the description thereof is omitted.

FIG. 17 is a cross-sectional view of a main part of PDP 100 in the present embodiment corresponding to the line AA in FIG. As shown in FIG. 17, a predetermined amount of a material 12 (for example, CaAl ₂ O ₄ ) that satisfies the requirements of the present invention is applied to a part of the protective film 5. Thereby, PDP 100 in the present embodiment and PDP device 200 using the same can exhibit good characteristics similar to those in the first embodiment.

In FIG. 17, the material 12 is formed by printing, for example. In FIG. 17, the material 12 is formed so as to overlap the upper surface of the barrier rib, and is formed so as to avoid the discharge region. This is because the material 12 does not prevent the discharge and, conversely, the material 12 is not damaged by the discharge. The amount of the charge accumulating material in this embodiment can be effective when the amount is 1 mg or more per 100 cm ² of the panel area. This is because the effect of the charge storage material is greater than when the phosphor is mixed.

  On the other hand, in FIG. 18, the material 12 according to the present invention is applied over the entire surface of the protective film 5 of the front plate 1. Other configurations shown in FIG. 18 are the same as those in FIG. After the product is completed, the plasma display panel is actually turned on and aged. In aging, if the discharge start time is shortened by the effect of the material 12 according to the present invention, the aging time can be shortened.

  However, in FIG. 18, the material 12 that forms the discharge space that does not overlap with the upper surface of the barrier rib 7 disappears after a certain period of time due to sputtering during discharge. Therefore, since a considerable portion of the material 12 of the present invention existing in the portion facing the discharge space is lost by the aging process, the discharge characteristics do not change greatly in actual operation.

  As mentioned above, the invention made by the present inventor has been specifically described based on the embodiment. However, the present invention is not limited to the embodiment, and various modifications can be made without departing from the scope of the invention. Needless to say.

  For example, in the above-described embodiment, the case where the partition wall structure is applied to the stripe-type AC surface discharge type PDP has been described. However, the present invention can also be applied to a box type.

It is a figure which shows the relationship between the mixing rate of electric charge storage material, and the amount of discharge voltage fall. It is a figure which shows the relationship between the quantity of the charge storage material per unit area, and discharge voltage fall amount. It is a figure which shows the relationship between the mixing rate of a charge storage material, and a brightness | luminance when a charge storage material differs from the emission spectrum of the base material of fluorescent substance. It is a figure which shows the relationship between the quantum efficiency and chromaticity of a charge storage material when a charge storage material differs from the emission spectrum of the base material of fluorescent substance. _{2 is} an X-ray diffraction chart of CaAl ₂ O ₄ . It is a drive waveform of the X electrode and the Y electrode in the sustain period. It is a figure which shows the charging condition at the time of a sustain discharge. It is a principal part disassembled perspective view of PDP. It is AA sectional drawing of FIG. It is BB sectional drawing of FIG. It is CC sectional drawing of FIG. It is the figure which showed the sequence of the voltage applied to each electrode in the subfield of an ADS system. It is a block diagram of a PDP device. It is a figure which shows the relationship between the density | concentration of the addition element of electric charge storage material, and luminous efficiency. It is a figure which shows the relationship between the quantum efficiency of a charge storage material which has an additive element, and a brightness | luminance. It is sectional drawing which shows the 2nd Example of this invention. It is sectional drawing which shows the 3rd Example of this invention. It is sectional drawing which shows the other form of the 3rd Example of this invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Substrate 2 Electrode 3 Bus line 4 Dielectric layer 5 Protective film 6 Substrate 7 Partition 8 Dielectric layer 9 Electrode 10 Phosphor layer 11 Discharge space 12 Material 100 PDP
DESCRIPTION OF SYMBOLS 101 Address drive circuit 102 Scanning / sustain pulse output circuit 103 Sustain pulse output circuit 104 Drive control circuit 105 Signal processing circuit 106 Drive power supply 107 Image source 200 PDP apparatus.

Claims (21)

The front plate and the back plate arranged opposite to each other form a discharge space, the discharge space is filled with a discharge gas, and at least a pair of electrodes for performing display discharge, and ultraviolet light emission by the discharge of the discharge gas In a plasma display panel having a phosphor layer that emits visible light using
The phosphor layer includes a material whose main composition is represented by CaAl ₂ O ₄ and which emits light with a quantum efficiency of 15% or more by excitation with ultraviolet light having a wavelength in the wavelength range of 100 to 450 nm. Characteristic plasma display panel. The phosphor layer has a main composition of CaAl ₂ O ₄ and contains at least one element of Eu, Tb, Mn, and an ultraviolet ray having a wavelength in the wavelength range of 100 to 450 nm. 2. The plasma display panel according to claim 1, comprising a material that emits light with a quantum efficiency of 15% or more by excitation with light. In the phosphor layer, the main composition is CaAl ₂ O ₄ and Eu is contained by 0.3 mol% to 0.5 mol%, and is excited by ultraviolet light having a wavelength in the wavelength range of 100 to 450 nm. The plasma display panel according to claim 2, further comprising a material that emits light with a quantum efficiency of 15% or more. In the phosphor layer, the main composition is CaAl ₂ O ₄ and Tb is contained in an amount of 6 to 8 mol%, and the quantum efficiency is increased by excitation with ultraviolet light having a wavelength in the wavelength range of 100 to 450 nm. The plasma display panel according to claim 2, comprising a material that emits light at 15% or more. In the phosphor layer, the main composition is CaAl ₂ O ₄ , and Mn is contained in an amount of 5 mol% to 15 mol%, and at least a part of the contained Mn is Mn ²⁺ , and The plasma display panel according to claim 2, comprising a material that emits light with a quantum efficiency of 15% or more by excitation with ultraviolet light having a wavelength in the wavelength range of 100 to 450 nm. In the phosphor layer, the main composition is CaAl ₂ O ₄ , and Mn is contained in an amount of 1 mol% to 5 mol%, and at least a part of the contained Mn is Mn ³⁺ , and The plasma display panel according to claim 2, comprising a material that emits light with a quantum efficiency of 15% or more by excitation with ultraviolet light having a wavelength in the wavelength range of 100 to 450 nm. In the phosphor layer, the main composition is CaAl ₂ O ₄ and Eu is contained by 0.3 mol% to 0.5 mol%, and is excited by ultraviolet light having a wavelength in the wavelength range of 100 to 450 nm. 3. The plasma display panel according to claim 2, wherein a material that emits light with a quantum efficiency of 15% or more is included in at least one of discharge cells associated with pixels that emit blue or red light. In the phosphor layer, the main composition is CaAl ₂ O ₄ and Tb is contained in an amount of 6 to 8 mol%, and the quantum efficiency is increased by excitation with ultraviolet light having a wavelength in the wavelength range of 100 to 450 nm. The plasma display panel according to claim 2, wherein a material that emits light at 15% or more is included in at least a discharge cell related to a pixel that emits green light. In the phosphor layer, the main composition is CaAl ₂ O ₄ , and Mn is contained in an amount of 5 mol% to 15 mol%, and at least a part of the contained Mn is Mn ²⁺ , and 3. A discharge cell associated with a pixel that emits green light at least contains a material that emits light with a quantum efficiency of 15% or more by excitation with ultraviolet light having a wavelength within a wavelength range of 100 to 450 nm. Plasma display panel. In the phosphor layer, the main composition is CaAl ₂ O ₄ , and Mn is contained in an amount of 1 mol% to 5 mol%, and at least a part of the contained Mn is Mn ³⁺ , and 3. A discharge cell associated with a pixel that emits red light at least contains a material that emits light with a quantum efficiency of 15% or more by excitation with ultraviolet light having a wavelength in the wavelength range of 100 to 450 nm. Plasma display panel.   11. The plasma display panel according to claim 1, wherein a ratio of the material in the phosphor layer is 1 wt% to 20 wt%. 11. The plasma display panel according to claim 1, wherein the weight of the material in the phosphor layer is 5 mg or more per 100 cm ² of the panel area. The front plate and the back plate arranged opposite to each other form a discharge space, the discharge space is filled with a discharge gas, and at least a pair of electrodes for performing display discharge, and ultraviolet light emission by the discharge of the discharge gas In a plasma display panel having a phosphor layer that emits visible light using
In the phosphor layer, the main composition is MAl ₂ O ₄ (wherein M is at least one element of Mg, Ca, Zn, and Sr), and an ultraviolet ray having a wavelength within a wavelength range of 100 to 450 nm. A plasma display panel comprising a material that emits light with a quantum efficiency of 15% or more when excited by light. The front plate and the back plate arranged opposite to each other form a discharge space, the discharge space is filled with a discharge gas, and at least a pair of electrodes for performing display discharge, and ultraviolet light emission by the discharge of the discharge gas In the display device having a phosphor layer that emits visible light by using a material, a partition wall disposed between the front plate and the back plate includes a material whose main composition is represented by CaAl ₂ O ₄ Plasma display panel. The front plate and the back plate arranged opposite to each other form a discharge space, the discharge space is filled with a discharge gas, and at least a pair of electrodes for performing display discharge, and ultraviolet light emission by the discharge of the discharge gas In a display device having a phosphor layer that emits visible light using
The phosphor or the partition wall installed between the front plate and the back plate contains CaAl ₂ O ₄ , and the CaAl ₂ O ₄ has a crystal system of monoclinic and a space group P21, and X-rays by CuKα rays A plasma display panel characterized by being formed of a material in which a diffraction line having the highest diffraction intensity appears in the vicinity of 2θ = 30 °. The front plate and the back plate arranged opposite to each other form a discharge space, the discharge space is filled with a discharge gas, and at least a pair of electrodes for performing display discharge, and ultraviolet light emission by the discharge of the discharge gas In a plasma display panel having a phosphor layer that emits visible light using
A plasma display panel characterized in that the phosphor layer contains at least part of a material mainly composed of a group IIa metal or group IIb metal aluminate. The material in which charges are accumulated by voltage application or light irradiation includes a material whose main composition is MAl ₂ O ₄ (where M is at least one element of Mg, Zn, and Sr). The display device according to claim 16. At least a pair for performing display discharge, wherein a discharge space is formed by a front plate and a back plate disposed opposite to each other, and a partition existing in the front plate and the back plate, and the discharge space is filled with a discharge gas. In the plasma display panel having the electrode and a phosphor layer that emits visible light using ultraviolet emission by discharge of the discharge gas,
The partition is coated with a material whose main composition is CaAl ₂ O ₄ and which emits light with a quantum efficiency of 15% or more by excitation with ultraviolet light having a wavelength in the wavelength range of 100 to 450 nm. A characteristic plasma display panel. A front plate and a rear plate arranged opposite to each other, and a discharge space is formed by partition walls existing in the front plate and the rear plate, the discharge space is filled with a discharge gas, At least a pair of electrodes for performing display discharge, a dielectric film covering the pair of electrodes, and a protective film are formed covering the dielectric, and visible light using ultraviolet light emission by discharge of the discharge gas In a plasma display panel having a phosphor layer emitting light,
On the protective film, a material whose main composition is represented by CaAl ₂ O ₄ and which emits light with a quantum efficiency of 15% or more by excitation with ultraviolet light having a wavelength in the wavelength range of 100 to 450 nm is applied. A plasma display panel characterized by the above.   The plasma display panel according to any one of claims 1 to 19, wherein the display device includes a gas including Xe gas in an amount such that a composition ratio of the discharge gas is 8% or more.   21. The plasma display panel according to claim 1, wherein the display device includes 700 or more display pixel lines.

Images