JP2003104844A - Hair cosmetics - Google Patents

Abstract

(A) A polyphenol compound and (B)
Characterized by containing an alkyl glucoside and / or a polyglycerin fatty acid ester, preferably,
Further, (C) a hair cosmetic containing an anionic surfactant. [Effect] The hair cosmetic composition of the present invention can be used for perm, bleach,
Damaged by chemical treatments such as hair coloring, weakened and softened hair and naturally thin and soft hair, firmness,
It gives a firm and voluminous feel, has an excellent touch feeling with no stickiness, and suppresses the formation of precipitates such as discoloration, scum, turbidity, etc., and can ensure excellent stability quality. At the same time, it is also possible to prevent dyeing on clothing.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair cosmetic composition, and more specifically, it imparts an excellent firmness and elasticity to damaged hair and improves the treatment effect by using it as a pre-rinsing agent. It is possible,
Further, the present invention relates to a hair cosmetic composition which is excellent in stability and whose effectiveness is not impaired by storage.

[0002]

2. Description of the Related Art Hair suffers many damages due to daily hair care and make-up actions. Especially for washing hair,
The surfactant, which is the main component, elutes the sebum of the hair and the proteins that make up the hair, causing the hair to become dull or stiff, and also to cause tactile and visual damage such as extreme loss of gloss. It is known to realize.

In particular, in recent years, due to an increase in fashion awareness,
The frequency of use of cold perm, hair color, hair bleach, etc. is increasing, and chemical treatment with drugs promotes elution and structural changes of the constituent proteins of hair, which accelerates damage.

[0004] Such damaged hair has a problem that it is difficult to style because it has a reduced feeling of stiffness and elasticity, the hair flow is not adjusted, and it causes a dryness and squeak, and a cohesive feeling cannot be obtained.

[0005] In order to eliminate such a problem of damaged hair, a method mainly attempted is as a rinse agent or a treatment agent in an in bath, and in an out bath, hair water, hair foam, hair cream, etc. The products that promote the treatment effect of are mainly used. However, these are not satisfactory, because they are sticky due to lack of sustainability of effects and oil content.

On the other hand, polyphenolic compounds and vitamins represented by tannin crude drugs are excellent in astringent effect, moisturizing effect, blood circulation promoting effect, anti-inflammatory effect and the like, and have been tried for a long time to be usefully incorporated into cosmetics. However,
These polyphenolic compounds are basically unstable in the presence of oxygen, causing discoloration or precipitation of the product over time, and further, there is a major problem in ensuring the quality of the product such as dyeing on clothes. there were.

As a measure to solve the above problems, for example, in the case of a polyphenolic compound, a discoloration prevention method using a metal complex and an organic acid (Japanese Patent Laid-Open No. 63-1452).
No. 13, JP-A-64-9946), a stabilization method using an organic reducing agent (JP-A-6-239716), and a combination of a cationic polymer compound and a nonionic surfactant. The method (Japanese Patent Laid-Open No. 3-246215) is known, but further improvement of the effect has been demanded.

[0008]

SUMMARY OF THE INVENTION The present invention has been made in view of the above circumstances, and in hair cosmetics containing a polyphenol compound reactive with oxygen, damage caused by chemical treatment such as perm, bleach, and hair color. However, it gives firmness, elasticity and volume to weakened and softened hair and thin and soft hair that is naturally born, and it has an excellent tactile feel without stickiness, and discoloration, cohesion, and dyeing on clothing. It is an object of the present invention to provide a hair cosmetic composition having excellent stability over time that is free from such problems.

[0009]

Means for Solving the Problems and Modes for Carrying Out the Invention As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that polyphenol compounds as active ingredients and alkylglucosides or polyglycerin among nonionic activators. It was found that the use of a fatty acid ester can prevent discoloration, aggregation, etc. with the passage of time, and a hair cosmetic excellent in stability with the passage of time can be obtained. It was found that the use of a uniform solution containing the above as a pre-rinsing agent can further improve the treatment effect, and particularly when used as an aerosol-type hair cosmetic composition, a good foamy hair cosmetic composition can be obtained. Invented.

That is, the present invention provides a hair cosmetic comprising (A) a polyphenol compound and (B) an alkyl glucoside and / or a polyglycerin fatty acid ester. Here, the hair cosmetics,
Furthermore, it is more preferable that it contains (C) an anionic surfactant. Further, it is more preferable that the hair cosmetic composition is an aerosol type hair cosmetic composition.

The present invention will be described in more detail below. The hair cosmetic composition of the present invention comprises (A) a polyphenol compound and
(B) It contains an alkyl glucoside and / or a polyglycerin fatty acid ester. Here, the polyphenol compound is a component which has an excellent moisturizing effect and astringent effect on the skin and hair and which is reactive with oxygen.

Specific examples of the above-mentioned polyphenol compound include catechol, pyrogallol, gallic acid, caffeic acid, lacole, virobol, personol, ginkgoic acid and their derivatives, phloroglucinol derivatives,
Stilbene derivatives, rutin, quercetin, kaempferol, catechin, epicatechin, gallocatechin, epigallocatechin, genistein, soybean zein, apigenin, augonin, baicalein, and other phenolic compounds having flavonoid skeletons or derivatives thereof, catechol tannin (condensation Tannins such as type tannin) and pyrogallol tannin (hydrolyzable tannin). In addition, Assenyaku, Asuka, Veiled Beetle, Yamajiko, Younger brother cut grass, Kawamoyogi, Senzuru-Kusa, Ginkgo, Kunugi, Chestnut, Black buckthorn, Choji, Dingko, Genchoshoko, Black tea, Green tea, Koshitachi, Coffee beans, Sancha, Linden, Camellia, Ten Examples of the drug include tannin crude drugs such as quince, quince, hamamelis, peony skin, arrow wheel, tiger ear grass, apple and peach, and extracts from plants rich in tannin, or tannic acid purified from them.

As the above-mentioned polyphenolic compound used in the present invention, in addition to commercially available synthetic products, extracts from natural products and the like are used. In addition, when extracting,
It can be carried out by an ordinary method using one kind of a polar solvent such as water, ethanol, propylene glycol, butylene glycol or an arbitrary mixed solution. In the case of further purification, methods such as recrystallization from a poor solvent, column fractionation and ultrafiltration can be used.

The amount of the polyphenol compound used in the present invention in the hair cosmetic composition is not particularly limited,
Usually, 0.0001 to 10% by mass is preferable, more preferably 0.01 to 5% by mass, and further preferably 0.1 to 1% by mass with respect to the total amount of the hair cosmetic composition. If the blending amount is less than 0.0001% by mass, the effect of the present invention may not be sufficiently obtained, and if it exceeds 10% by mass, usability other than the object of the present invention, such as irritation, may be obtained. Alternatively, problems such as stiffness may occur.

The alkyl glucoside used in the present invention is preferably an alkyl glucoside having an alkyl chain of 8 to 16 carbon atoms, and specific examples thereof include coco glucoside, decyl glucoside, lauryl glucoside, and the like. They may be used alone or in combination of two or more.

When the above-mentioned alkyl glucoside is used as the component (B) of the present invention, its compounding amount is not particularly limited, but it is usually 0.1 to 5% by mass in the hair cosmetic composition. , More preferably 0.5 to 4% by mass,
More preferably, it is 1 to 3 mass%. If the blending amount is less than 0.1% by mass, stability may be problematic.
If the content exceeds 100% by weight, the hair may become sticky, resulting in a heavy finish.

The polyglycerin fatty acid ester which is the component (B) of the present invention has a polyglycerin polymerization degree of 4 to 1
0, especially 6 to 10, polyglycerin fatty acid ester having 12 to 18, especially 14 to 18 carbon atoms of fatty acid is desirable, and specifically, decaglyceryl monolaurate,
Examples thereof include decaglyceryl monomyristate and tetraglyceryl monooleate. These may be used alone or in combination of two or more.

When the above-mentioned polyglycerin fatty acid is used as the component (B) of the present invention, its blending amount is not particularly limited, but it is usually 0.1% to 5 in a hair cosmetic composition. %, More preferably 0.5 to 4% by mass, further preferably 1 to 3% by mass. The compounding amount is
If it is less than 1%, stability problems may occur.
If the content exceeds 100% by weight, the hair may become sticky, resulting in a heavy finish.

The hair cosmetic composition of the present invention is more suitable when an anionic surfactant is further added as the component (C), because a creamy foam quality is formed and the foam retention is improved. Here, the kind of the anionic surfactant is not particularly limited, but for example, N-coconut oil fatty acid acyl-L-glutamic acid monotriethanolamine solution, sodium lauryl sulfate, sodium polyoxyethylene lauryl ether sulfate, Lauroylmethyl-β-
Alanine sodium solution, N-lauroyl-N-methyl-
β-alanine triethanolamine solution and the like are preferably used, and among these, N-coconut oil fatty acid acyl-L is particularly preferable.
-Glutamic acid monotriethanolamine solution is more preferably used. You may use these individually by 1 type,
You may use it in combination of 2 or more type.

When the above-mentioned anionic surfactant is compounded as the component (C) of the present invention, the compounding amount is not particularly limited, but it is usually 0.1 to 5 in the hair cosmetic composition. Mass%, more preferably 0.5 to 4 mass%,
More preferably, it is 1 to 3 mass%. If the blending amount is too small, it may be difficult to sufficiently obtain the effect of the blending of the anionic surfactant, and if the blending amount is too large, the hair may become sticky, resulting in a heavy finish.

The hair cosmetic composition of the present invention may contain, in addition to the above-mentioned active ingredients, various additives commonly used in ordinary cosmetic compositions, if necessary, within a range that does not impair the effects of the present invention. .

Examples of the additive components include cationic surfactants such as stearyltrimethylammonium chloride, highly polymerized silicone compounds such as methylpolysiloxane, organic acids such as citric acid and succinic acid and salts thereof, and bactericides. , UV absorbers, antioxidants, higher alcohols, hydrocarbons, ester oils, colorants, fragrances, solvents (ethanol,
Water etc.), fatty acids, etc. These added ingredients are 1
They may be used alone or in combination of two or more, and may be blended at an appropriate stage of cosmetic preparation.

The hair cosmetic composition of the present invention is not particularly limited in its dosage form, but it is more preferable to prepare it as an aerosol type hair cosmetic composition. In the case of the present invention, the manufacturing method thereof is not particularly limited. However, it is more preferable to follow the manufacturing method described in Japanese Patent Application No. 11-367044, for example. That is, the hair cosmetic composition of the present invention is prepared by mixing the above components. In this case, a hair cosmetic composition containing a polyphenol compound reactive with oxygen has a dissolved oxygen concentration of 0. .0006
Mass% or less, or oxygen concentration in the headspace is 4
When the container is filled with a content of not more than mass% or a degree of devoid of −0.3 to −1 atm, a polyphenol compound reactive with oxygen can be more stably blended in the hair cosmetic composition.

When reducing the dissolved oxygen concentration in the hair cosmetic composition of the present invention, the dissolved oxygen concentration is preferably 0.0006% by mass or less, more preferably 0.0004% by mass.
The content is not more than mass%, more preferably not more than 0.0002 mass%. When reducing the oxygen concentration in the headspace, the oxygen concentration is preferably 4% by mass or less, more preferably 1% by mass or less, further preferably 0.5% by mass.
It is the following. On the other hand, when deaerating,
0.3 to -1 atm is preferable, and more preferably-
0.4 to -0.95 atm, more preferably -0.5 to
It is −0.9 atm.

The container filled with the hair cosmetic composition of the present invention is not particularly limited and may be appropriately selected depending on the form of the product. In the case of the aerosol form, a container made of metal such as aluminum or polyethylene terephthalate may be used. Filled in a plastic container. In the case of a cream or gel, it is preferable to fill the container with a high oxygen barrier property, particularly a single-layer or multi-layer tube of high-density polyethylene or polyethylene terephthalate.

As described above, the dissolved oxygen concentration in the hair cosmetic (stock solution) is 0.0006% by mass or less, the oxygen concentration in the headspace part is 4% by mass or less, and the degree of vacancy is −0. There is no particular limitation on the method for adjusting the concentration to 3 to -1 atm, but a method of filling the hair cosmetic (stock solution) in a container in the absence of oxygen is effectively adopted, as described below.

That is, in producing a hair cosmetic composition, the hair cosmetic composition containing a polyphenol compound reactive with oxygen is mixed in the absence of oxygen, and the obtained hair cosmetic composition is filled in a container. It is performed in the absence of oxygen.

Here, in the absence of oxygen, an atmosphere containing substantially no oxygen, specifically, vacuum or an inert gas atmosphere such as nitrogen gas, carbon dioxide gas, rare gas, etc. may be employed. The above-mentioned components can be mixed and filled in a container under an atmosphere. In this case, any method may be used as the method of forming the atmosphere, and there is no particular limitation. For example, there may be mentioned a method of performing vacuum vacuum, replacement with nitrogen gas, or a method of performing vacuum vacuum and then replacement with an inert gas. When manufactured by these methods, it is possible to suppress the reaction of the polyphenol compound reactive with oxygen with the dissolved oxygen in the composition and the oxygen in the head space in the container.

The degassing time is not particularly limited, and for example, the hair cosmetic (stock solution) may be filled, clinched and then degassed, or the hair cosmetic (stock solution) may be filled and gas may be filled. -It may be degassed at the same time as clinching, or a container that has been clinched and degassed may be filled with hair cosmetics (stock solution) and gas. The deaeration operation can be performed by vacuum vacuum.

In the case of preparation in the form of an aerosol, the filling of the propellant can be carried out under air, but it is desirable to carry out under vacuum or in an inert gas atmosphere such as nitrogen gas, carbon dioxide gas or rare gas.

[0031]

INDUSTRIAL APPLICABILITY According to the present invention, discoloration, precipitation and aggregation caused by the reaction of the polyphenol compound and oxygen in the product in any form of aerosol, cream, gel or liquid cosmetic composition. Is suppressed and the stability of the product becomes extremely good.

The hair cosmetic composition of the present invention imparts a firmness, elasticity and volume to hair weakened and softened by birth or thin and soft hair born by being damaged by chemical treatment such as perm, bleach, hair color, etc. It has an excellent hand feeling that is not sticky to the touch, and can suppress the generation of precipitates such as discoloration, dirt, and turbidity, and can secure excellent quality with stability. In particular, by using it as a pre-rinsing agent, it is possible to prevent dyeing on clothes.

[0033]

EXAMPLES The present invention will be described in more detail below with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples. In addition,% in the following examples indicates mass%.

The effect evaluation method in the following examples is as follows. As the storage container, a transparent pressure-resistant glass container which is generally used for an aerosol test and whose inside can be observed was used.

Presence or absence of aggregation: immediately after compounding, at 25 ° C., 50
The composition was allowed to stand at each temperature of ° C and stored, and the presence or absence of aggregation in the composition after one month was visually determined.

[0036] ◎: Not at all ○: Slight △: Somewhat ×: considerably

Presence or absence of discoloration (browning): immediately after blending, and 25
The composition was allowed to stand at each temperature of 50 ° C. and 50 ° C., and the presence or absence of discoloration in the composition after 1 month was visually determined.

[0038] ◎: Not at all ○: Slight △: Somewhat ×: considerably

Good foam quality: immediately after compounding, at 25 ° C., 50
The composition was allowed to stand at each temperature of ° C and stored, and the quality of foam in the composition after 1 month was visually evaluated.

[0040] ◎: Very good ○: good Δ: Fair ×: not good

[Examples 1 to 4 and Comparative Examples 1 to 6] The components shown in Table 1 were prepared in the form of an aerosol according to a conventional method and filled in the container. In this case, the aerosol type hair cosmetics of Examples 1 to 4 and Comparative Examples 1 to 6 were prepared by vacuum vacuuming. With respect to each hair cosmetic, the presence or absence of aggregation, the presence or absence of discoloration, and the goodness of foam quality were evaluated by the above evaluation methods. The results are also shown in Table 1.

[0042]

[Table 1] * Rexord P (manufactured by Ichimaru Falcos) ** Amisoft CT-12: N-coconut oil fatty acid acyl-L-glutamic acid monotriethanolamine solution

According to the results of Table 1, Comparative Example 2 containing a polyphenol compound and containing an amphoteric surfactant in the composition, Comparative Examples 3 to 5 containing a nonionic surfactant, and Comparative Examples containing a cationic surfactant. No. 6 has problems in stability such as aggregation and discoloration, and the foam quality is not good. Further, in Comparative Example 1 containing the polyphenol compound and containing only the anionic surfactant, there is no problem in aggregation or discoloration, but the foam quality is not good. On the other hand, Examples 1 and 2 containing a polyphenol compound and an alkyl glucoside or a polyglycerin fatty acid and Examples 3 and 4 containing a polyphenol compound and an alkyl glucoside polyglycerin fatty acid and an anionic surfactant are all aggregates and discoloration. It is recognized that there is no problem in stability and the foam quality is good.

[Examples 5-9 and Comparative Examples 7-10] Table 2
The components shown in (1) were prepared in the form of aerosol according to a conventional method and filled in the container. In this case, the aerosol type hair cosmetics of Examples 5-9 and Comparative Examples 7-10 were prepared by vacuum vacuuming. The performance of each hair cosmetic was evaluated according to the following performance evaluation method. The results are also shown in Table 2.

<Performance Evaluation Method> After shampooing a hair bundle (30 cm, 10 g) that has been subjected to a palmer treatment, 0.8 g of the hair cosmetics of Examples and Comparative Examples are applied and rinsed off,
A rinse treatment was applied. After drying with a dryer, a sensory evaluation was performed on the smoothness, moistness, dryness, dryness, firmness, finger-feeling, and non-stiffness based on the following evaluation criteria.

<Evaluation criteria> ⊚: Very good compared to rinse agent alone ○: Slightly better than rinse agent alone △: Not much changed ×: Rinse agent alone is better

[0047]

[Table 2] * Rexord P (manufactured by Ichimaru Falcos) ** Amisoft CT-12: N-coconut oil fatty acid acyl-L-glutamic acid monotriethanolamine solution

According to the results shown in Table 2, Comparative Examples 7 to 10 containing no polyphenol compound were found to have sufficient smoothness, moistness, dryness, dryness, firmness, finger-feeling, and no stiffness. However, Examples 5 to 10 containing a polyphenol compound and an alkyl glucoside or a polyglycerin fatty acid have smoothness, moistness, dryness, smoothness, finger-feeling, and no stiffness. Is found to be good.

[Example 11] Hair tonic: (Composition) Hydroxypropyl chitosan solution (chitofilmer) 5.0 Lauryl glucoside 1.0 Assembly extract 0.5 Tannin powder extracted and purified from quintile 0.1 (extraction solvent: 30% ethanol) Propylene glycol 2.0 dl-α tocopherol acetate 0.5 l-menthol 0.2 succinic acid / sodium succinate (adjusted to pH 5.0) Appropriate amount of ethanol (Vitrex denaturation: 95%) 40.0 Liquefaction Petroleum gas 10.0 Dimethyl ether 5.0 Purified water Remainder total 100.0%

(Production Method) Atmosphere during mixing: Nitrogen gas, Atmosphere during filling: After vacuum, nitrogen gas (container) polyethylene terephthalate can (oxygen concentration) Dissolved oxygen concentration in composition (%): 0.0001 Oxygen in headspace Concentration (%): 0.05

[Example 12] Skin cream (composition) cetostearyl alcohol 2.0 decaglyceryl monostearate 2.0 jojoba oil 1.0 olive squalane 2.0 3-methyl 1,3-butanediol 1.5 mono Sorbitan oleate 0.5 Liquid paraffin 5.0 Japanese pharmacopoeia tannin 1.0 Phosphoric acid / triethanolamine (adjusted to pH: 5.0) Concentrated concentrated glycerin 10.0 Purified water Remainder total 100.0%

(Manufacturing method) Mixing atmosphere (vacuum emulsifying kettle): After vacuum, nitrogen gas, further vacuum, filling atmosphere: After vacuum, nitrogen gas (container) high density polyethylene / polyethylene terephthalate laminated tube (oxygen concentration) in composition Dissolved oxygen concentration (%): 0.0001 Oxygen concentration in headspace (%): 0.07

[Example 13] Hair foam tannic acid (Lexode P, manufactured by Ichimaru Falcos) 1.0 Lauryl glucoside 1.0 Polyether-modified silicone (KF-6012) 2.0 Amphoteric polymer compound (Yukaformer 204WL) 2 .0 Stearyl trimethyl ammonium chloride 0.5 Polyoxypropylene (14) diglyceryl ether 2.0 Polyoxypropylene (40) hydrogenated castor oil 0.5 Highly polymerized methyl polysiloxane (100,000 cst) 1.0 Isotridecyl myristate 0 .5 Dibutylhydroxytoluene 0.05 Formulated perfume A (Attachment 1) 0.2 Ethanol (anhydrous: Vitrex modified) 20.0 Liquefied petroleum gas (0.4 MPa, 20 ° C.) 7.0 Purified water Remainder total 100. 0%

(Production method) Atmosphere during mixing: Nitrogen gas, Atmosphere during filling: Vacuum (Container) Aluminum can (Oxygen concentration) Dissolved oxygen concentration in composition (%) 0.0001 Oxygen concentration in headspace (%): 0.05

Example 14 Tannin Powder Extracted from Hair Gel Japanese Tea 1.0 (Extraction Solvent: 30% Ethanol) Lauryl Glucoside 1.0 Polyether Modified Silicone (KF-6004) 5.0 Amphoteric Polymer Compound (Yukaformer) 310) 2.0 Polyvinylpyrrolidone (K-30) 2.0 Tetraglyceryl monolaurate 1.5 Polyoxyethylene (40) hydrogenated castor oil 0.5 Sodium hydrogen sulfite 0.05 Carboxyvinyl polymer 0.5 Oxybenzosulfonic acid 0.1 Triethanolamine (adjusted to pH 7) Appropriate amount of mixed fragrance B (Appendix 2) 0.1 Ethanol (anhydrous: Vitrex modified) 10.0 Purified water Total balance 100.0%

(Production method) Atmosphere during mixing: nitrogen gas after vacuuming, atmosphere at filling: carbon dioxide (container) polypropylene tube (oxygen concentration) Dissolved oxygen concentration in composition (%): 0.00015 Oxygen concentration in headspace (%): 0.01

Attached Table 1 (Fragrance A) Ylang Ylang Oil 3 Lemon Oil 5 Sweet Orange Oil 10 Lavender Oil 6 Neroli Oil 2 Rose Base 5 Rose Oxide 0.1 Jasmine Base 3 Lilyal 5 Green Base 2 Petit Glen Oil 3 Muguet Base 1 Hedyon 8 Belt Fix 3 Sandalwood Oil 1 Absolute Oak Moss 1 Cis-3-Hexenyl salicylate 5 Hexylcinnamic Aldehyde 5.9 Benzyl Acetate 1 Benzyl Benzoate 1 Benzyl Salicylate 3 Pentalide 1 Carnation Base 1 Kashmeran 3 Methyl Ionone 3 Neobergamyl Nitrile Gamate 3 -9 10% DPG solution 3 Aldehyde C-10 10% DPG solution 1 Aldehyde C-12 MNA 10% PG solution 2 heliotropin 1 Dipropylene glycol 7 Total 100%

Appendix 2 (Fragrance B) Lemon oil 5 Lime oil 2 Orange oil 10 Bergamot oil 1 Grapefruit oil 2 Rose oil 1 Jasmine oil 0.4 Lavender oil 0.2 Lavandin oil 0.1 Petit grain oil 0.1 Neroli oil 0 2 Ylang-ylang oil 3 Absolute vanilla 1 Absolute oak moss 1 Sandalwood oil 1 Green base 1 Fruity base 5 Amber base 1 Linalool 2 Linalyl acetate 10 l-Menthol 5 Hedione 3 Galaxolid 5 Tonalide 5 Hexelupe 3 Isobel Cynamic aldehyde 5 Aldehyde C-8 10% DPG solution 5 Aldehyde C-10 10% DPG solution 2 Aldehyde C-12 MNA 10% DPG solution 5 Dipropylene glycol 14 Total 100 (%)

   ─────────────────────────────────────────────────── ─── Continued front page    F-term (reference) 4C083 AA112 AA122 AB012 AB352                       AC012 AC022 AC072 AC102                       AC122 AC172 AC182 AC292                       AC352 AC402 AC421 AC422                       AC432 AC442 AC471 AC472                       AC542 AC662 AC692 AC792                       AC842 AD072 AD092 AD152                       AD162 AD201 AD202 AD322                       AD532 AD662 BB05 BB35                       CC05 CC31 CC33 DD08 DD31                       DD41 EE01 EE07

Claims (3)

[Claims] 1. A polyphenol compound (A) and (B)
A hair cosmetic comprising an alkyl glucoside and / or a polyglycerin fatty acid ester. 2. The hair cosmetic composition according to claim 1, further comprising (C) an anionic surfactant. 3. An aerosol type hair cosmetic composition.
Or the hair cosmetic composition according to 2.