JP2003013179A - Round steel material for bearing element parts with excellent hot workability - Google Patents
Round steel material for bearing element parts with excellent hot workabilityInfo
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- JP2003013179A JP2003013179A JP2001193583A JP2001193583A JP2003013179A JP 2003013179 A JP2003013179 A JP 2003013179A JP 2001193583 A JP2001193583 A JP 2001193583A JP 2001193583 A JP2001193583 A JP 2001193583A JP 2003013179 A JP2003013179 A JP 2003013179A
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- rolling fatigue
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Abstract
(57)【要約】
【課題】軸受要素部品の用途に好適な熱間加工性に優れ
た丸鋼材の提供。
【解決手段】C:0.8〜1.2%、Si:0.2〜2.0%、Mn:0.2
〜1.5%、Cr:0.5〜2.0%、P:0.005〜0.025%、S:0.0
03〜0.015%でP(%)+2S(%):0.020〜0.040%、A
l:0.01〜0.05%、N:0.005〜0.012%、Cu≦1.0%、Ni
≦2.0%を含有し、残部はFeと不純物からなり、不純物
中のTi≦0.002%、O(酸素)≦0.0015%の丸鋼材であっ
て、その半径をRとしたとき、横断面の中心から(R/
10)までの領域に存在する偏析帯において、丸鋼材での
Cr含有量の1.3倍を超えるCr含有量となる領域の幅が、
その丸鋼材の直径の 0.0003〜0.003倍である熱間加工性
に優れた軸受要素部品用の丸鋼材。(57) [Summary] [Problem] To provide a round steel material excellent in hot workability suitable for use in bearing element parts. SOLUTION: C: 0.8-1.2%, Si: 0.2-2.0%, Mn: 0.2
-1.5%, Cr: 0.5-2.0%, P: 0.005-0.025%, S: 0.0
03 to 0.015% P (%) + 2S (%): 0.020 to 0.040%, A
l: 0.01-0.05%, N: 0.005-0.012%, Cu ≦ 1.0%, Ni
≦ 2.0%, the balance is made of Fe and impurities, and is a round steel material with Ti ≦ 0.002% and O (oxygen) ≦ 0.0015% in the impurities. (R /
In the segregation zone existing in the region up to 10),
The width of the region where the Cr content exceeds 1.3 times the Cr content is
Round steel material for bearing element parts with excellent hot workability that is 0.0003 to 0.003 times the diameter of the round steel material.
Description
【発明の詳細な説明】
【0001】
【発明の属する技術分野】本発明は、熱間加工性に優れ
た軸受要素部品用丸鋼材に関する。より詳しくは、ボー
ル、コロ、ニードル、シャフト、レースなどの軸受要素
部品の用途に好適な熱間加工性に優れた丸鋼材に関す
る。
【0002】
【従来の技術】ボール、コロ、ニードル、シャフト、レ
ースなどの軸受要素部品の素材鋼として、一般に、JIS
G 4805で規格化されたSUJ2鋼などの高炭素クロム軸
受鋼が多用されている。
【0003】上記の所謂「軸受用鋼」は、熱間圧延など
の手段で棒鋼や線材といった丸鋼材に加工された後、下
記(a)又は(b)の手法で前記各種の要素部品に仕上
げられることが多い。
【0004】(a)熱間での切断、鍛造などの加工によ
って要素部品に近い形状に成形され、その後、軟化を目
的とした球状化焼鈍を受け、次いで切削加工を施され、
更に、焼入れと低温での焼戻しによる熱処理を受けて所
望の機械的性質を付与される。
【0005】(b)軟化を目的とした球状化焼鈍を受
け、次いで冷間鍛造、冷間抽伸や切削などの加工によっ
て要素部品に成形され、更に、焼入れと低温での焼戻し
による熱処理を受けて所望の機械的性質を付与される。
【0006】このうち(a)の手法は、熱間加工で要素
部品に近い形状に成形するものであるため、冷間鍛造に
較べて複雑な形状の要素部品にも適用可能であり、又、
コストが嵩む切削加工での切削量を減らすことができ
る。したがって、近年では上記(a)の手法で軸受要素
部品が製造されることが多くなり、熱間鍛造用金型や熱
間切断用の刃の寿命を向上することが可能な熱間加工性
の優れた軸受鋼に対する要求が極めて大きくなってい
る。
【0007】
【発明が解決しようとする課題】本発明は、上記現状に
鑑みなされたもので、その目的は特別な元素を添加する
ことなく、熱間鍛造用金型や熱間切断用の刃などの工具
寿命を延長することができる、ボール、コロ、ニード
ル、シャフト、レースなどの軸受要素部品の用途に好適
な熱間加工性に優れた丸鋼材を提供することである。
【0008】ここで、「熱間加工性」は、「熱間加工用
の工具の寿命が長い場合に良好」とし、後述の実施例に
おける熱間捩り試験、すなわち、平行部の長さと直径が
それぞれ50mmと10mmの試験片を1050℃、1
100℃及び1150℃の各温度で15分保持した後、
速度300rpmで熱間捩り試験した際、上記3温度に
おける破断までの捻回数の平均値が84回以下であるこ
とを目標とする。又、各種の産業機械や自動車などに使
用される軸受には高い面圧が繰り返し作用するので、軸
受要素部品用丸鋼材は、後述の実施例における転動疲労
試験で、1.0×107 以上の転動疲労寿命を有する
ことを目標とする。
【0009】
【課題を解決するための手段】本発明の要旨は、下記の
熱間加工性に優れた軸受要素部品用丸鋼材にある。
【0010】すなわち、「質量%で、C:0.8〜1.
2%、Si:0.2〜2.0%、Mn:0.2〜1.5
%、Cr:0.5〜2.0%、P:0.005〜0.0
25%、S:0.003〜0.015%でP(%)+2
S(%):0.020〜0.040%、Al:0.01
〜0.05%、N:0.005〜0.012%、Cu:
1.0%以下、Ni:2.0%以下を含有し、残部はF
e及び不純物からなり、不純物中のTiは0.002%
以下、O(酸素)は0.0015%以下の丸鋼材であっ
て、その半径をRとしたとき、横断面の中心から(R/
10)までの領域に存在する偏析帯において、丸鋼材で
のCr含有量の1.3倍を超えるCr含有量となる領域
の幅が、その丸鋼材の直径の0.0003〜0.003
倍である熱間加工性に優れた軸受要素部品用の丸鋼
材。」である。
【0011】なお、本発明でいう「丸鋼材」とは、熱間
で加工された断面形状が円形の線材、棒鋼やビレットな
どを指し、その「横断面」とは、圧延方向や鍛造軸に垂
直に切断した面をいう。
【0012】又、「丸鋼材でのCr含有量」とは、丸鋼
材の横断面の中心から(R/2)の部位で試験片を採取
し、通常の方法によって分析した値をいう。更に、「熱
間加工性」を、「熱間加工用の工具の寿命が長い場合に
良好」とすることは既に述べたとおりである。
【0013】本発明者らは、丸鋼材の中心偏析と偏析し
た合金元素が熱間加工での工具寿命に及ぼす影響につい
て調査・研究を重ね、その結果、下記の知見を得た。
【0014】(a)一般に、熱間で引張試験した際の絞
り値が高い場合に熱間加工で割れやクラックが発生しな
いので、熱間加工性がよいとされているが、本発明に係
る軸受要素部品の素材鋼の場合、通常の熱間加工温度で
ある1000〜1250℃での引張試験の絞り値はほぼ
100%であり、熱間鍛造や熱間圧延など一般的な熱間
加工で割れやクラックが発生する可能性は極めて小さ
い。
【0015】(b)熱間での捩り試験において試験片が
破断するまでの捻回数は、本発明に係る軸受要素部品の
素材鋼でも、大きな差が生じる場合が多い。そして、こ
の捻回数は熱間加工用の工具の寿命との相関が大きく、
この捻回数を低下させた方が熱間加工用の工具の寿命が
長くなる。
【0016】(c)上記(b)における熱間捩り試験で
の破断までの捻回数を低下させるためには、P及びSの
含有量の増加、並びにCr、Cなどの中心偏析量、それ
も丸鋼材の場合には横断面の中心から(R/10)まで
の領域に存在する偏析帯におけるCr、C量を増加させ
ることが有効である。
【0017】(d)一方、軸受要素部品に大きな転動疲
労寿命を確保させるためには、P及びSの含有量の低
減、並びにCr、Cなどの中心偏析量を低減することが
有効である。
【0018】(e)上記(b)及び(c)から、熱間加
工用の工具の寿命を長くし、しかも軸受要素部品に良好
な転動疲労寿命を確保させるためには、S、Pの含有
量、及びCr、Cなどの中心偏析量をある特定の範囲に
制御することが重要である。
【0019】(f)C、Mn及びCrは中心偏析しやす
い元素であるが、このうち熱間捩り試験での破断までの
捻回数に大きく影響するのは、CとCrである。しか
し、Cは軽元素で偏析を精度よく定量することが難しい
ので、Crの偏析を定量的に評価する手法が有効であ
る。
【0020】本発明は、上記の知見に基づいて完成され
たものである。
【0021】
【発明の実施の形態】以下、本発明について詳しく説明
する。なお、化学成分の含有量の「%」は「質量%」を
意味する。
(A)丸鋼材の化学組成
C:0.8〜1.2%
焼入れと低温での焼戻しによる熱処理を行って軸受用鋼
材(軸受要素部品)に所望の機械的性質を付与させる
が、Cの含有量が0.8%未満では前記焼入れ・焼戻し
後の硬度が低く、所望の転動疲労寿命(後述の実施例に
おける転動疲労試験で、1.0×107 以上の転動疲
労寿命)が得られない。一方、Cの含有量が1.2%を
超えると、鋼の凝固時に巨大な炭化物が生成しやすくな
り、目標とする転動疲労寿命を確保させるためには高温
で長時間の均質化熱処理を行う必要が生じるのでコスト
が嵩んでしまう。したがって、Cの含有量を0.8〜
1.2%とした。なお、Cの含有量は0.8〜1.0%
とすることが好ましく、0.8〜0.9%とすれば一層
好ましい。
【0022】Si:0.2〜2.0%
Siは、転動疲労寿命を高めるのに有効な元素であるほ
か、脱酸剤として必要な元素でもある。又、Siは鋼の
焼入れ性を高める元素でもある。しかし、その含有量が
0.2%未満では前記の効果が得難い。一方、Siの含
有量が2.0%を超えると、熱間圧延後や球状化焼鈍後
に、脱スケールするために長時間を要するので生産性の
大幅な低下を招く。したがって、Siの含有量を0.2
〜2.0%とした。なお、Siの含有量は0.2〜1.
0%とすることが好ましく、0.2〜0.6%とすれば
一層好ましい。
【0023】Mn:0.2〜1.5%
Mnは、鋼の焼入れ性を向上させると同時に、Sによる
熱間脆性の防止に必要な元素である。これらの効果を発
揮させるためにはMnを0.2%以上含有させる必要が
ある。一方、Mnの含有量が1.5%を超えると、Mn
の中心偏析が顕著になり、Crの中心偏析を後述する範
囲に制御しても転動疲労寿命の低下が著しくなり、所望
の転動疲労寿命(後述の実施例における転動疲労試験
で、1.0×107 以上の転動疲労寿命)が得られな
くなる。したがって、Mnの含有量を0.2〜1.5%
とした。なお、Mn含有量の望ましい範囲は0.2〜
1.0%であり、0.2〜0.8%であれば一層望まし
い。
【0024】Cr:0.5〜2.0%
Crは、鋼の焼入れ性を向上させると同時に、熱間加工
用の工具の寿命を大きくするのに有効な元素である。し
かし、その含有量が0.5%未満の場合には、たとえC
rの中心偏析を後述する範囲に制御しても前記した熱間
捩り試験で、所望の84回以下の捻回数にはなり難く、
したがって熱間加工用の工具の長寿命化がなし難い。一
方、2.0%を超えるとCr及びCの中心偏析が顕著に
なって転動疲労寿命の低下が著しくなり、所望の転動疲
労寿命(後述の実施例における転動疲労試験で、1.0
×107 以上の転動疲労寿命)が得られなくなる。し
たがって、Crの含有量を0.5〜2.0%とした。な
お、Crの含有量は0.7〜1.5%とすることが好ま
しく、0.7〜1.2%とすれば一層好ましい。
【0025】P:0.005〜0.025%
Pは、Sと複合して熱間加工用の工具の寿命を高めるの
に有効な元素である。しかし、その含有量が0.005
%未満では、前記した熱間捩り試験で、所望の84回以
下の捻回数にはなり難く、したがって熱間加工用の工具
の長寿命化がなし難い。一方、Pは粒界に偏析して粒界
を脆化させやすい元素であり、その含有量が0.025
%を超えると、転動疲労寿命の低下が著しくなって所望
の転動疲労寿命(後述の実施例における転動疲労試験
で、1.0×107 以上の転動疲労寿命)が得られな
くなる。したがって、Pの含有量を0.005〜0.0
25%とした。なお、Pの含有量は、P(%)+2S
(%)で0.020〜0.040%を満足する必要があ
る。
【0026】S:0.003〜0.015%
Sは、Pと複合して熱間加工用の工具の寿命を高めるの
に有効な元素である。しかし、その含有量が0.003
%未満では、前記した熱間捩り試験で、所望の84回以
下の捻回数にはなり難く、したがって熱間加工用の工具
の長寿命化がなし難い。一方、SはMnと結合してMn
Sを形成し、転動疲労寿命を低下させてしまう元素であ
り、特に、その含有量が0.015%を超えると、粗大
なMnSを形成しやすくなるので転動疲労寿命の低下が
著しくなって所望の転動疲労寿命(後述の実施例におけ
る転動疲労試験で、1.0×107 以上の転動疲労寿
命)が得られない。したがって、Sの含有量を0.00
3〜0.015%とした。なお、Sの含有量は、P
(%)+2S(%)で0.020〜0.040%を満足
する必要がある。
【0027】P(%)+2S(%):0.020〜0.
040%
前述のようにPとSとは複合して熱間加工用の工具の寿
命を向上させる。しかし、P(%)+2S(%)の値が
0.020%未満の場合には、前記した熱間捩り試験
で、所望の84回以下の捻回数にはなり難く、したがっ
て熱間加工用の工具の長寿命化がなし難い。一方、P
(%)+2S(%)の値が0.040%を超えると、た
とえP及びSの含有量がそれぞれ前記した0.010〜
0.025%、0.003〜0.015%であっても、
転動疲労寿命の低下が著しくなって所望の転動疲労寿命
(後述の実施例における転動疲労試験で、1×107
以上の転動疲労寿命)が得られない。したがって、P
(%)+2S(%)の値を0.020〜0.040%と
した。
【0028】Al:0.01〜0.05%
Alは、脱酸作用を有する。更に、AlはNと結合して
AlNを形成し、結晶粒が粗大化するのを防止する作用
を有する。しかし、Alの含有量が0.01%未満では
こうした効果が得難い。一方、Alは非金属系介在物を
形成して転動疲労寿命の低下を招く元素であり、特に、
その含有量が0.05%を超えると、粗大な非金属系介
在物を形成しやすくなるので転動疲労寿命の低下が著し
くなって所望の転動疲労寿命(後述の実施例における転
動疲労試験で、1.0×107以上の転動疲労寿命)が
得られなくなる。したがって、Alの含有量を0.01
〜0.05%とした。なお、Alの含有量は0.01〜
0.04%とすることが好ましく、0.01〜0.03
%とすれば一層好ましい。
【0029】N:0.005〜0.012%
Nは、Alと結合してAlNを形成し、結晶粒が粗大化
するのを防止する作用を有する。しかし、Nの含有量が
0.005%未満ではこの効果は得難い。一方、Nの含
有量が多くなると粗大なAlNが生じやすくなり、又、
不純物元素としてのTiの含有量を後述する範囲に抑え
ても粗大なTiNが生じやすくなって、転動疲労寿命が
低下してしまう。特に、その含有量が0.012%を超
えると、転動疲労寿命の低下が著しくなって所望の転動
疲労寿命(後述の実施例における転動疲労試験で、1.
0×107 以上の転動疲労寿命)が得られない。した
がって、Nの含有量を0.005〜0.0012%とし
た。
【0030】本発明の熱間加工性に優れた軸受要素部品
用の丸鋼材には、必要に応じて、Cu及びNiのいずれ
か一方又は双方を選択的に含有させることができる。す
なわち、Cu、Niの各元素を任意添加元素として添加
し、含有させてもよい。以下、任意添加元素としてのC
uとNiに関して説明する。
【0031】Cu:1.0%以下
Cuは、添加すれば、耐食性を高める作用がある。この
効果は不純物レベルの含有量であっても得られるが、よ
り顕著にその効果を得るには、Cuは0.05%以上の
含有量とすることが好ましい。しかし、その含有量が
1.0%を超えると結晶粒界に偏析して分塊圧延、熱間
圧延、熱間鍛造など熱間加工時における割れや疵の発生
が顕著になる。したがって、Cuの含有量を1.0%以
下とした。なお、添加する場合のCu含有量の好ましい
範囲は0.05〜1.0%である。
【0032】Ni:2.0%以下
Niは、添加すれば、焼入れ後のマルテンサイト中に固
溶して靱性を高める作用を有する。この効果は不純物レ
ベルの含有量であっても得られるが、より顕著にその効
果を得るには、Niは0.2%以上の含有量とすること
が好ましい。しかし、2.0%を超えて含有させても、
前記の効果は飽和し、コストが嵩むばかりである。した
がって、Niの含有量を2.0%以下とした。なお、添
加する場合のNi含有量の好ましい範囲は0.2〜2.
0%である。本発明においては、不純物元素としてのT
i及びO(酸素)の含有量を下記のとおりに制限する。
【0033】Ti:0.002%以下
Tiは、Nと結合してTiNを形成し、転動疲労寿命を
低下させてしまう。特にその含有量が0.002%を超
えると、転動疲労寿命の低下が著しくなり、所望の転動
疲労寿命(後述の実施例における転動疲労試験で、1.
0×107 以上の転動疲労寿命)が得られない。した
がって、Tiの含有量を0.002%以下とした。な
お、不純物元素としてのTiの含有量はできるだけ少な
くすることが望ましい。
【0034】O(酸素):0.0015%以下
Oは、酸化物系介在物を形成し、転動疲労寿命を低下さ
せてしまう。特にその含有量が0.0015%を超える
と転動疲労寿命の低下が著しくなり、所望の転動疲労寿
命(後述の実施例における転動疲労試験で、1.0×1
07 以上の転動疲労寿命)が得られない。したがっ
て、Oの含有量を0.0015%以下とした。なお、不
純物元素としてのOの含有量はできる限り少なくするこ
とが望ましい。
【0035】(B)丸鋼材の横断面におけるCrの偏析
帯の幅
本発明においては、丸鋼材の横断面の中心から(R/1
0)までの領域に存在する偏析帯において、丸鋼材での
Cr含有量の1.3倍を超えるCr含有量となる領域の
幅を、その丸鋼材の直径の0.0003〜0.003倍
に規定する。なお、「丸鋼材でのCr含有量」が、丸鋼
材の横断面の中心から(R/2)の部位で試験片を採取
し、通常の方法によって分析した値を指すことは既に述
べたとおりである。
【0036】ここで、丸鋼材の横断面の中心から(R/
10)までの領域に存在する偏析帯を対象とするのは、
この領域の偏析帯に着目しておけば、熱間加工用の工具
の寿命と軸受要素部品の転動疲労寿命とが評価できるた
めである。
【0037】前記した丸鋼材の横断面の中心から(R/
10)までの領域に存在する偏析帯において、丸鋼材で
のCr含有量の1.3倍を超えるCr含有量となる領域
の幅が、その丸鋼材の直径の0.0003倍未満の場合
には熱間捩り試験で所望の捻回数(後述の実施例におけ
る捩り試験での84回以下の捻回数)にはならず、した
がって熱間加工用の工具の長寿命化がなされない。一
方、丸鋼材の横断面の中心から(R/10)までの領域
に存在する偏析帯において、丸鋼材でのCr含有量の
1.3倍を超えるCr含有量となる領域の幅が、その丸
鋼材の直径の0.0030倍を超える場合には、転動疲
労寿命の低下が著しくなり、所望の転動疲労寿命(後述
の実施例における転動疲労試験で、1.0×107 以
上の転動疲労寿命)が得られない。
【0038】ここで、「丸鋼材でのCr含有量の1.3
倍を超えるCr含有量となる領域の幅」は、例えば、丸
鋼材の横断面を鏡面研磨した後、走査型電子顕微鏡(以
下、SEMという)に付属したエネルギー分散形X線分
析装置(以下、EDXという)によって決定すればよ
い。具体的には、例えば、EDXのプローブ径を1μm
とし、丸鋼材の横断面の中心部を測定開始点として「R
/10」の部位までをCrについて線分析を実施し、そ
の測定チャートを用いて、Crの分析値が丸鋼材でのC
r含有量の1.3倍以上であった箇所のうち、最も幅の
広い箇所の幅を前記「丸鋼材でのCr含有量の1.3倍
を超えるCr含有量となる領域の幅」とすればよい。
【0039】なお、「丸鋼材の横断面の中心から(R/
10)までの領域に存在する偏析帯において、丸鋼材で
のCr含有量の1.3倍を超えるCr含有量となる領域
の幅を、その丸鋼材の直径の0.0003〜0.003
倍にする」には、例えば、均質化熱処理する前の鋼塊を
丸い形状として、横断面の中心から(R/10)までの
領域に存在する偏析帯において、鋼塊でのCr含有量の
2.0倍を超えるCr含有量となる領域の幅が上記丸い
形状の鋼塊の直径の0.0002〜0.002倍であっ
た場合には、1200〜1240℃の温度域で6〜12
時間の均質化熱処理を行えばよい。ここで、「丸鋼材で
のCr含有量」と同様に、「鋼塊でのCr含有量」と
は、丸い形状の鋼塊の横断面の中心から(R/2)の部
位で試験片を採取し、通常の方法によって分析した値を
指す。
【0040】前記(A)項に記載の化学組成と本(B)
項に記載の横断面におけるCrの偏析帯の幅を有する丸
鋼材は、通常の方法で熱間鍛造や熱間切断などの加工を
施され、必要に応じて冷間加工を施された後、更に、焼
入れと低温での焼戻しによる熱処理を受けて所望の機械
的性質を有する軸受要素部品に仕上げられてから、精密
機械部品である最終製品としての軸受に組み立てられ
る。
【0041】以下、実施例により本発明を更に詳しく説
明する。
【0042】
【実施例】(実施例1)表1に示す化学組成を有するJ
IS規格のSUJ2相当鋼イを通常の方法で3トン電気
炉溶製し、均質化処理なしと、1240℃で4〜24時
間の4種類の均質化処理を行った場合の、計5種類に偏
析レベルを変化させた鋼塊を作製した。なお、上記表1
における鋼イは化学組成が本発明で規定する条件を満足
する鋼である。
【0043】
【表1】
【0044】次いで、上記各鋼塊を通常の方法で熱間鍛
造して鋼片とし、更に、熱間圧延して直径が40mmの
棒鋼とした。このようにして得た直径が40mmの棒鋼
の横断面を鏡面研磨した後、SEMに付属したEDXに
よって「直径が40mmの棒鋼でのCr含有量の1.3
倍を超えるCr含有量となる領域の幅」を下記のように
して調査した。すなわち、EDXのプローブ径を1μm
とし、前記棒鋼の横断面の中心部を測定開始点として
「R/10」の部位まで(つまり、中心から2mmの位
置まで)をCrについて線分析を3回実施し、その測定
チャートを用いて、Crの分析値が棒鋼でのCr含有量
の1.3倍以上であった箇所のうち、最も幅の広い箇所
の幅を前記「直径が40mmの棒鋼でのCr含有量の
1.3倍を超えるCr含有量となる領域の幅」として決
定した。
【0045】又、前記直径が40mmの棒鋼を、118
0℃に加熱した後、P10種の超硬刃でシャー切断した
ときの切断刃の寿命を調査した。更に、直径が40mm
の棒鋼の中心部から圧延方向に平行に、機械加工により
平行部の長さと直径がそれぞれ50mmと10mmの捩
り試験用の試験片を採取し、1050℃、1100℃及
び1150℃の各温度で15分保持した後、速度300
rpmで熱間捩り試験し、上記3温度における破断まで
の捻回数の平均値を求めた。
【0046】又、前記直径40mmの棒鋼の中心部から
圧延方向に平行に、機械加工により直径12mm、長さ
22mmの試験片を切り出し、この試験片を焼入れ、焼
戻し処理(820℃で30分保持してから油焼入れし、
160℃で1時間焼戻し)して転動疲労試験に供した。
すなわち、円筒型の転動疲労試験機を用いて、潤滑油に
#68タービン油を使用して、ヘルツ最大接触応力が5
900MPa、試験片負荷回数が46000回/分の条
件で転動疲労試験を行った。各鋼について試験片は10
個ずつとし、10個の試験片の中で最初に表面剥離をお
こしたときの回転数を「転動疲労寿命」とした。転動疲
労寿命が1.0×107 以上の場合に転動疲労特性に
優れていると評価した。
【0047】表2に、「直径が40mmの棒鋼でのCr
含有量の1.3倍を超えるCr含有量となる領域の幅」
(表中では、「Cr偏析帯の幅/直径」と記載)、切断
刃の寿命すなわち破断荷重が1個目の1.3倍となった
時点での切断個数、上記3温度における破断までの捻回
数の平均値(表中では単に「破断までの捻回数」と記
載)及び転動疲労寿命の各調査結果をまとめて示す。
【0048】
【表2】
【0049】表2から、明らかなように、化学組成及び
横断面におけるCrの偏析帯の幅が本発明で規定する条
件を満たす場合には、所望の84回以下の捻回数と1.
0×107 以上の転動疲労寿命がともに得られてい
る。
【0050】これに対して、横断面におけるCrの偏析
帯の幅が本発明で規定する条件から外れる場合には、所
望の84回以下の捻回数と1.0×107 以上の転動
疲労寿命のいずれかが所望の値に達していない。
(実施例2)表3に示す化学組成を有する鋼A〜Mを3
00kg真空炉で溶解した後、50kgの鋳型に5分湯
して、同一化学成分を有する鋼塊(インゴット)を各5
個ずつ作製した。表3における鋼B〜D、G〜H及びM
は化学組成が本発明で規定する条件を満足する鋼であ
り、一方、鋼A、E、F及びI〜Lは成分のいずれかが
本発明で規定する含有量の範囲から外れた比較例の鋼で
ある。
【0051】
【表3】【0052】上記鋼A〜Mの各5個の鋼塊のうち4個に
ついて、それぞれ電気炉を用いて均質化熱処理を行っ
た。均質化熱処理の処理条件(ヒートパターン)は下記
の4条件である。
【0053】条件W:1240℃に加熱して4時間保持
した後、炉外で放冷、
条件X:1240℃に加熱して8時間保持した後、炉外
で放冷、
条件Y:1240℃に加熱して12時間保持した後、炉
外で放冷、
条件Z:1240℃に加熱して24時間保持した後、炉
外で放冷。
【0054】次いで、各鋼についての5個の鋼塊、すな
わち上記の均質化熱処理を行った4個の鋼塊と鋳込みま
まの均質化処理なしの鋼塊の計5個の鋼塊を、1200
℃に加熱して仕上げ温度950℃で熱間鍛造し、その後
大気中で放冷して直径40mmの丸棒を得た。このよう
にして得た直径が40mmの丸棒について、Crの偏析
帯の幅を測定した。すなわち、直径が40mmの各丸棒
の横断面を鏡面研磨した後、SEMに付属したEDXに
よって「直径が40mmの丸棒でのCr含有量の1.3
倍を超えるCr含有量となる領域の幅」を下記のように
して調査した。すなわち、EDXのプローブ径を1μm
とし、前記丸棒の横断面の中心部を測定開始点として2
mmの位置までをCrについて線分析を3回実施し、そ
の測定チャートを用いて、Crの分析値が丸棒でのCr
含有量の1.3倍以上であった箇所のうち、最も幅の広
い箇所の幅を前記「直径が40mmの丸棒でのCr含有
量の1.3倍を超えるCr含有量となる領域の幅」とし
て決定した。
【0055】更に、直径が40mmの丸棒の中心部から
鍛造軸に平行に、機械加工により平行部の長さと直径が
それぞれ50mmと10mmの捩り試験用の試験片を採
取し、1050℃、1100℃及び1150℃の各温度
で15分保持した後、速度300rpmで熱間捩り試験
し、上記3温度における破断までの捻回数の平均値を求
めた。
【0056】又、前記直径40mmの丸棒の中心部から
鍛造軸に平行に、機械加工により直径12mm、長さ2
2mmの試験片を切り出し、この試験片を焼入れ、焼戻
し処理(820℃で30分保持してから油焼入れし、1
60℃で1時間焼戻し)して転動疲労試験に供した。す
なわち、円筒型の転動疲労試験機を用いて、潤滑油に#
68タービン油を使用して、ヘルツ最大接触応力が59
00MPa、試験片負荷回数が46000回/分の条件
で転動疲労試験を行った。各鋼について試験片は10個
ずつとし、10個の試験片の中で最初に表面剥離をおこ
したときの回転数を「転動疲労寿命」とした。転動疲労
寿命が1.0×107 以上の場合に転動疲労特性に優
れていると評価した。
【0057】表4〜6に、「直径が40mmの丸棒での
Cr含有量の1.3倍を超えるCr含有量となる領域の
幅」(各表中では、「Cr偏析帯の幅/直径」と記
載)、上記3温度における破断までの捻回数の平均値
(各表中では単に「破断までの捻回数」と記載)及び転
動疲労寿命の各調査結果をまとめて示す。
【0058】
【表4】【0059】
【表5】【0060】
【表6】
【0061】表4〜6から明らかなように、比較例の鋼
A及び鋼I〜Lを用いた試験番号の場合、つまり、C含
有量が0.8%を下回る鋼Aを用いた試験番号1〜5、
P含有量が0.025%を上回り、且つ「P(%)+2
S(%)」の値が0.040%を上回る鋼Iを用いた試
験番号41〜45、S含有量が0.015%を上回り、
且つ「P(%)+2S(%)」が0.040%を上回る
鋼Jを用いた試験番号46〜50、Ti含有量が0.0
02%を上回る鋼Kを用いた試験番号51〜55、及び
O(酸素)含有量が0.0015%を上回る鋼Lを用い
た試験番号56〜60は、転動疲労寿命が1.0×10
7 回に達しなていない。
【0062】上記のうち試験番号41、42、46、4
7、51及び56は、「Cr偏析帯の幅/直径」が0.
0030を超えているので転動疲労寿命が特に短い。
【0063】又、上記のうち試験番号4、5、53、5
4、59及び60は、「Cr偏析帯の幅/直径」が0.
0003を下回るため、捻り試験での破断までの捻回数
も目標の値に達していない。
【0064】比較例の鋼E及びFを用いた試験番号21
〜30の場合は、「Cr偏析帯の幅/直径」は本発明範
囲内であるものの、「P(%)+2S(%)」の値が
0.020%を下回るため、捻り試験での破断までの捻
回数が84回より多い。
【0065】上記のうち試験番号24、25、29及び
30は、「Cr偏析帯の幅/直径」が0.0003を下
回っているので、捻回数が特に大きい。
【0066】化学組成が本発明で規定する含有量の範囲
内にある鋼であっても、試験番号6、11、16、3
1、32、36及び37は、「Cr偏析帯の幅/直径」
が0.0030を上回るため、転動疲労寿命が1.0×
107 回に達しなていない。又、試験番号9、10、
14、15、20、40、64及び65は、「Cr偏析
帯の幅/直径」が0.0003を下回っているため、捩
り試験での破断までの捻回数が84回より多い。
【0067】上記の比較例に対し、本発明で規定する条
件を満たす本発明例である試験番号7、8、12、1
3、17〜19、33〜35、38、39、61、62
及び63の場合には、所望の84回以下の捻回数と1.
0×107 以上の転動疲労寿命がともに得られてい
る。
【0068】
【発明の効果】本発明の丸鋼材は、「熱間加工性」に優
れ(すなわち、「熱間加工用の工具の寿命が長い」)更
に、転動疲労寿命も長いので、ボール、コロ、ニード
ル、シャフト、レースなど軸受要素部品の素材として利
用することができる。DETAILED DESCRIPTION OF THE INVENTION
[0001]
The present invention is excellent in hot workability.
The present invention relates to a round steel material for bearing element parts. More details
Bearing elements such as ru, roller, needle, shaft, race
Concerning round steel materials with excellent hot workability suitable for parts applications
The
[0002]
[Background Art] Balls, rollers, needles, shafts,
As a material steel for bearing element parts such as
High carbon chromium shafts such as SUJ2 steel standardized by G 4805
Steel is widely used.
The so-called “bearing steel” described above is hot rolled, etc.
After being processed into round steel materials such as steel bars and wire rods,
Finishing the various element parts using the method described in (a) or (b)
Often lost.
(A) By hot cutting or forging
Is formed into a shape close to the element part, and then softening is aimed at
Subjected to targeted spheroidizing annealing, followed by cutting,
In addition, after heat treatment by quenching and tempering at low temperature,
Given the desired mechanical properties.
(B) Subjected to spheroidizing annealing for the purpose of softening
Then, by cold forging, cold drawing, cutting, etc.
Are molded into element parts, and further quenched and tempered at low temperatures.
The desired mechanical properties are imparted by the heat treatment.
Among these, the method (a) is an element in hot working.
Because it is molded into a shape close to the part, it is suitable for cold forging.
It is also applicable to element parts with more complex shapes,
It can reduce the amount of cutting in costly cutting
The Therefore, in recent years, the bearing element has been
Parts are often manufactured, hot forging dies and heat
Hot workability that can improve the life of blades for hot cutting
The demand for excellent bearing steel
The
[0007]
The present invention is based on the above situation.
The purpose was to add a special element.
Without tools such as hot forging dies and hot cutting blades
Can extend the life, ball, roller, need
Suitable for bearing element parts such as rails, shafts and races
It is to provide a round steel material excellent in hot workability.
Here, “hot workability” means “for hot work”.
It is good when the tool life is long.
Hot torsion test, i.e. the length and diameter of the parallel part
Each 50 mm and 10 mm test pieces are 1050 ° C., 1
After holding at 100 ° C and 1150 ° C for 15 minutes,
When performing a hot torsion test at a speed of 300 rpm,
The average value of the number of twists until breakage is 84 times or less.
And aim. It is also used for various industrial machines and automobiles.
Since high surface pressure acts repeatedly on the bearings used, the shaft
Round steel for receiving element parts is rolling fatigue in the examples described later.
1.0 × 10 in the test7 Has more rolling fatigue life
The goal is to.
[0009]
The gist of the present invention is as follows.
It is a round steel material for bearing element parts with excellent hot workability.
That is, “mass%, C: 0.8 to 1.
2%, Si: 0.2-2.0%, Mn: 0.2-1.5
%, Cr: 0.5-2.0%, P: 0.005-0.0
25%, S: 0.003 to 0.015% and P (%) + 2
S (%): 0.020 to 0.040%, Al: 0.01
-0.05%, N: 0.005-0.012%, Cu:
1.0% or less, Ni: 2.0% or less, with the balance being F
e and impurities, Ti in impurities is 0.002%
Hereinafter, O (oxygen) is a round steel material of 0.0015% or less.
When the radius is R, (R /
In the segregation zone existing in the area up to 10),
Region where the Cr content exceeds 1.3 times the Cr content of
The width is 0.0003 to 0.003 of the diameter of the round steel material
Round steel for bearing element parts with excellent hot workability
Wood. It is.
The "round steel material" as used in the present invention means hot
The cross-sectional shape machined in is a wire rod, steel bar or billet
The `` cross section '' refers to the rolling direction and the forging axis.
A surface cut directly.
Also, "Cr content in round steel material" means round steel
Specimen is collected at the part (R / 2) from the center of the cross section of the material
And the value analyzed by the usual method. Furthermore, "Heat
When the tool life for hot working is long,
“Good” is as described above.
The inventors of the present invention have reported that the center segregation and segregation of round steel materials.
Effects of alloying elements on tool life in hot working
As a result, the following knowledge was obtained.
(A) In general, drawing during a hot tensile test
Cracks and cracks do not occur during hot working when the
Therefore, it is said that hot workability is good.
For the material steel of bearing element parts
The drawing value of a tensile test at 1000 to 1250 ° C. is almost
100%, general hot such as hot forging and hot rolling
The possibility of cracking or cracking during processing is extremely small
Yes.
(B) In a torsion test in the hot state,
The number of twists to break is determined by the bearing element parts according to the present invention.
Even in the case of material steel, a large difference often occurs. And this
The number of twists has a large correlation with the tool life for hot working,
Lowering the number of twists will increase the tool life for hot working.
become longer.
(C) In the hot torsion test in (b) above
In order to reduce the number of twists until rupture of P and S,
Increasing the content, as well as the amount of center segregation such as Cr, C, etc.
In the case of round steel material, from the center of the cross section to (R / 10)
Increase the amount of Cr and C in the segregation zone
It is effective.
(D) On the other hand, the bearing element parts have a large rolling fatigue.
In order to ensure a working life, low P and S content
Reducing the amount of central segregation such as Cr and C
It is valid.
(E) From the above (b) and (c),
Long tool life and good for bearing element parts
In order to ensure a good rolling fatigue life,
Amount and center segregation amount of Cr, C, etc. within a certain range
It is important to control.
(F) C, Mn and Cr are easily segregated in the center.
Among these elements, of these, until the fracture in the hot torsion test
It is C and Cr that greatly affect the number of twists. Only
C is a light element and it is difficult to accurately quantify segregation.
Therefore, a method for quantitatively evaluating the segregation of Cr is effective.
The
The present invention has been completed based on the above findings.
It is a thing.
[0021]
DETAILED DESCRIPTION OF THE INVENTION The present invention will be described in detail below.
To do. In addition, “%” of the content of chemical components is “mass%”.
means.
(A) Chemical composition of round steel
C: 0.8 to 1.2%
Steel for bearings by heat treatment by quenching and tempering at low temperature
Giving the desired mechanical properties to the material (bearing element parts)
However, when the C content is less than 0.8%, the quenching and tempering is performed.
Later hardness is low, the desired rolling fatigue life (in the examples below)
1.0 × 10 in rolling fatigue test7 More rolling fatigue
Labor life) is not obtained. On the other hand, the C content is 1.2%.
Otherwise, huge carbides are likely to be generated during solidification of the steel.
In order to ensure the target rolling fatigue life,
Cost, because it will be necessary to perform long-term homogenization heat treatment
Becomes bulky. Therefore, the content of C is 0.8 to
1.2%. The C content is 0.8 to 1.0%.
If it is 0.8 to 0.9%, it is more
preferable.
Si: 0.2 to 2.0%
Si is an element effective for increasing the rolling fatigue life.
It is also an element necessary as a deoxidizer. Si is steel
It is also an element that enhances hardenability. But its content is
If it is less than 0.2%, it is difficult to obtain the above effect. On the other hand, including Si
When the content exceeds 2.0%, after hot rolling or spheroidizing annealing
In addition, since it takes a long time to descal,
Incurs a significant drop. Therefore, the Si content is 0.2.
To 2.0%. The Si content is 0.2 to 1.
0% is preferable, and 0.2 to 0.6%
Even more preferred.
Mn: 0.2 to 1.5%
Mn improves the hardenability of steel and at the same time due to S
It is an element necessary for preventing hot brittleness. It produces these effects
In order to volatilize, it is necessary to contain 0.2% or more of Mn
is there. On the other hand, if the content of Mn exceeds 1.5%, Mn
The center segregation of Cr becomes remarkable, and the center segregation of Cr is described below.
The rolling fatigue life is significantly reduced even if controlled to
Rolling fatigue life (rolling fatigue test in examples described later)
And 1.0 × 107 No more rolling fatigue life)
Become. Therefore, the Mn content is 0.2 to 1.5%.
It was. In addition, the desirable range of Mn content is 0.2 to
1.0%, more desirable if 0.2-0.8%
Yes.
Cr: 0.5 to 2.0%
Cr improves the hardenability of steel and at the same time hot working
It is an effective element to increase the tool life. Shi
However, if the content is less than 0.5%, C
Even if the center segregation of r is controlled within the range described later,
In the torsion test, it is difficult to achieve the desired number of twists of 84 times or less.
Therefore, it is difficult to extend the tool life for hot working. one
On the other hand, if it exceeds 2.0%, the center segregation of Cr and C becomes prominent.
As a result, the rolling fatigue life is significantly reduced, and the desired rolling fatigue is achieved.
Labor life (1.0% in rolling fatigue test in examples described later)
× 107 The above rolling fatigue life) cannot be obtained. Shi
Therefore, the Cr content is set to 0.5 to 2.0%. Na
The Cr content is preferably 0.7-1.5%.
If it is 0.7 to 1.2%, it is more preferable.
P: 0.005 to 0.025%
P is combined with S to increase the tool life for hot working
Is an effective element. However, its content is 0.005
Less than 84%, the above-mentioned hot torsion test is not less than 84 times desired.
The number of twists below is unlikely, so hot working tools
It is difficult to extend the service life. On the other hand, P segregates at the grain boundary and
Is an element that easily causes embrittlement, and its content is 0.025.
%, The reduction in rolling fatigue life becomes remarkable and desired.
Rolling fatigue life (rolling fatigue test in examples described later)
And 1.0 × 107 No more rolling fatigue life)
Become. Therefore, the P content is 0.005 to 0.0.
25%. The content of P is P (%) + 2S
(%) Must satisfy 0.020-0.040%
The
S: 0.003 to 0.015%
S is combined with P to increase the tool life for hot working
Is an effective element. However, its content is 0.003
Less than 84%, the above-mentioned hot torsion test is not less than 84 times desired.
The number of twists below is unlikely, so hot working tools
It is difficult to extend the service life. On the other hand, S combines with Mn to form Mn
An element that forms S and reduces the rolling fatigue life.
In particular, if its content exceeds 0.015%, it is coarse
As a result, the rolling fatigue life is reduced.
The desired rolling fatigue life (in the examples below)
1.0 × 10 in the rolling fatigue test7 More rolling fatigue life
Life) is not obtained. Therefore, the S content is 0.00
It was set to 3 to 0.015%. The S content is P
(%) + 2S (%) satisfies 0.020-0.040%
There is a need to.
P (%) + 2S (%): 0.020-0.
040%
As mentioned above, P and S are combined and the tool life for hot working
Improve life. However, the value of P (%) + 2S (%) is
In the case of less than 0.020%, the hot torsion test described above
Therefore, it is difficult to achieve the desired number of twists of 84 times or less.
Therefore, it is difficult to extend the tool life for hot working. On the other hand, P
When the value of (%) + 2S (%) exceeds 0.040%,
The contents of Toe P and S are each 0.010 to 10
Even if it is 0.025%, 0.003-0.015%,
Desirable rolling fatigue life due to significant decrease in rolling fatigue life
(In a rolling fatigue test in Examples described later, 1 × 107
The above rolling fatigue life) cannot be obtained. Therefore, P
The value of (%) + 2S (%) is 0.020 to 0.040%
did.
Al: 0.01 to 0.05%
Al has a deoxidizing action. Furthermore, Al combines with N
Action to prevent AlN formation and coarsening of crystal grains
Have However, if the Al content is less than 0.01%
Such an effect is difficult to obtain. On the other hand, Al is a non-metallic inclusion.
It is an element that causes the rolling fatigue life to decrease and, in particular,
If its content exceeds 0.05%, coarse non-metallic media
As it becomes easier to form natural objects, the rolling fatigue life is significantly reduced.
The desired rolling fatigue life (in the examples described later,
1.0 × 10 in dynamic fatigue test7The above rolling fatigue life)
It can no longer be obtained. Therefore, the content of Al is 0.01
˜0.05%. The Al content is 0.01 to
It is preferable to set it as 0.04%, 0.01-0.03
% Is more preferable.
N: 0.005 to 0.012%
N combines with Al to form AlN, resulting in coarse crystal grains
It has the effect | action which prevents doing. However, the N content is
If it is less than 0.005%, this effect is difficult to obtain. On the other hand, including N
As the amount increases, coarse AlN is likely to occur,
Limiting the content of Ti as an impurity element to the range described below
However, coarse TiN is likely to occur, and the rolling fatigue life is increased.
It will decline. In particular, its content exceeds 0.012%
In other words, the rolling fatigue life is significantly reduced and the desired rolling
Fatigue life (In rolling fatigue tests in the examples described later,
0x107 The above rolling fatigue life) cannot be obtained. did
Therefore, the N content is 0.005 to 0.0012%.
It was.
The bearing element component having excellent hot workability according to the present invention.
For round steel materials for use, either Cu or Ni
Either or both of them can be selectively contained. You
In other words, Cu and Ni elements are added as optional additional elements.
And may be included. Hereinafter, C as an optional additive element
u and Ni will be described.
Cu: 1.0% or less
If Cu is added, it has the effect of enhancing the corrosion resistance. this
The effect can be obtained even with a content level of impurities,
In order to obtain the effect more remarkably, Cu is 0.05% or more.
The content is preferable. But its content is
If it exceeds 1.0%, it segregates at the grain boundary, and it is split rolled and hot.
Generation of cracks and flaws during hot working such as rolling and hot forging
Becomes prominent. Therefore, the Cu content is 1.0% or more.
Below. In addition, Cu content is preferable when added
The range is 0.05-1.0%.
Ni: 2.0% or less
If Ni is added, it will solidify in the martensite after quenching.
It has the effect of melting and increasing toughness. This effect is due to impurity levels.
Although it can be obtained even with a bell content, the effect is more prominent.
To obtain fruit, Ni should be 0.2% or more.
Is preferred. However, even if it exceeds 2.0%,
The above effects are saturated and the cost is increased. did
Therefore, the Ni content is set to 2.0% or less. Please note that
When Ni is added, the preferable range of Ni content is 0.2-2.
0%. In the present invention, T as an impurity element
The contents of i and O (oxygen) are limited as follows.
Ti: 0.002% or less
Ti combines with N to form TiN, and has a rolling fatigue life.
It will decrease. Especially its content exceeds 0.002%
The rolling fatigue life is significantly reduced and the desired rolling
Fatigue life (In rolling fatigue tests in the examples described later,
0x107 The above rolling fatigue life) cannot be obtained. did
Therefore, the Ti content is set to 0.002% or less. Na
The content of Ti as an impurity element is as small as possible
Is desirable.
O (oxygen): 0.0015% or less
O forms oxide inclusions and reduces the rolling fatigue life.
I will let you. In particular, its content exceeds 0.0015%
The rolling fatigue life is significantly reduced and the desired rolling fatigue life
Life (1.0 × 1 in the rolling fatigue test in Examples described later)
07 The above rolling fatigue life) cannot be obtained. Therefore
Therefore, the content of O is set to 0.0015% or less. Note that
Minimize the content of O as a pure element
Is desirable.
(B) Cr segregation in the cross section of round steel material
Band width
In the present invention, from the center of the cross section of the round steel material (R / 1
In the segregation zone existing in the region up to 0),
Of the region where the Cr content exceeds 1.3 times the Cr content.
The width is 0.0003 to 0.003 times the diameter of the round steel material
Stipulate. “Cr content in round steel” is round steel.
Specimen is collected at the part (R / 2) from the center of the cross section of the material
However, it has already been mentioned that it refers to the value analyzed by the usual method.
It ’s exactly as it was.
Here, from the center of the cross section of the round steel material (R /
The target of segregation bands existing in the area up to 10)
If we focus on the segregation zone in this area, the tool for hot working
The life of rolling and the rolling fatigue life of bearing element parts can be evaluated.
It is.
From the center of the cross section of the round steel material (R /
In the segregation zone existing in the area up to 10),
Region where the Cr content exceeds 1.3 times the Cr content of
If the width is less than 0.0003 times the diameter of the round steel
In the hot torsion test, the desired number of twists (in the examples described later)
The twisting test was less than 84 times)
Therefore, the tool life for hot working is not extended. one
On the other hand, the area from the center of the cross section of the round steel material to (R / 10)
In the segregation zone present in the
The width of the region where the Cr content exceeds 1.3 times
When it exceeds 0.0030 times the diameter of steel, rolling fatigue
Decrease in work life becomes significant, and the desired rolling fatigue life (described later)
In the rolling fatigue test in Example 1, 1.0 × 107 Less than
The above rolling fatigue life) cannot be obtained.
Here, “1.3% of Cr content in round steel material”
The width of the region where the Cr content exceeds double is, for example, round
After mirror-polishing the cross section of the steel material, a scanning electron microscope (hereafter
Energy dispersive X-ray segment attached to SEM)
It can be determined by the analyzer (hereinafter referred to as EDX)
Yes. Specifically, for example, the probe diameter of EDX is 1 μm.
And the center of the cross-section of the round steel material as the measurement start point "R
Line analysis of Cr up to / 10 ”
Using the measurement chart, the analysis value of Cr is C in round steel.
Among the locations where the r content was 1.3 times or more, the widest
The width of the wide part is “1.3 times the Cr content in round steel.
The width of the region having a Cr content exceeding 50% ”may be used.
It should be noted that “from the center of the cross section of the round steel material (R /
In the segregation zone existing in the area up to 10),
Region where the Cr content exceeds 1.3 times the Cr content of
The width of the round steel product diameter is 0.0003 to 0.003
To `` double '', for example, the steel ingot before homogenization heat treatment
As a round shape, from the center of the cross section to (R / 10)
In the segregation zone present in the region, the Cr content in the steel ingot
The width of the region where the Cr content exceeds 2.0 times is round.
0.0002 to 0.002 times the diameter of the shaped steel ingot
In the case of 6-12 in the temperature range of 1200-1240 ° C.
Time homogenization heat treatment may be performed. Here, "With round steel material
"Cr content in steel ingot" as well as "Cr content in steel ingot"
Is (R / 2) from the center of the cross section of the round steel ingot
Specimens taken at
Point to.
The chemical composition described in the above item (A) and the book (B)
A circle having the width of the Cr segregation band in the transverse section
Steel is processed by hot forging and hot cutting in the usual way.
After being cold-worked as necessary,
Desired machine after heat treatment by tempering and tempering at low temperature
Precision after being finished into bearing element parts with special properties
Assembled into bearings as final products that are machine parts
The
The following examples further illustrate the present invention.
Light up.
[0042]
EXAMPLES Example 1 J having the chemical composition shown in Table 1
3 tons of electricity using IS standard SUJ2 equivalent steel
Furnace melting, no homogenization, and 4-24 hours at 1240 ° C
When the four types of homogenization are performed,
Steel ingots with different deposition levels were prepared. Table 1 above
In the case of steel ii, the chemical composition satisfies the conditions specified in the present invention.
Steel.
[0043]
[Table 1]
Next, the above steel ingots are hot forged by a normal method.
To make a steel slab, and then hot rolled to a diameter of 40 mm
Bar steel was used. Steel bar with a diameter of 40 mm obtained in this way
After mirror polishing the cross section of the EDX, attach it to the EDX attached to the SEM
Therefore, “1.3% of Cr content in a steel bar having a diameter of 40 mm.
The width of the region where the Cr content exceeds twice is as follows:
And investigated. That is, the EDX probe diameter is 1 μm.
And the center of the cross section of the steel bar as the measurement start point
Up to “R / 10” part (that is, about 2 mm from the center)
The line analysis was performed 3 times for Cr and the measurement was performed.
Using the chart, the Cr analysis value is the Cr content in the steel bar
The widest part among the parts that were 1.3 times more than
The width of the “Cr content in a steel bar having a diameter of 40 mm”
The width of the region where the Cr content exceeds 1.3 times "
Set.
The steel bar having a diameter of 40 mm is made of 118
After heating to 0 ° C, shear cutting was performed with a P10 carbide blade.
When the cutting blade life was investigated. Furthermore, the diameter is 40mm
Machined parallel to the rolling direction from the center of the steel bar
Screws with parallel part length and diameter 50mm and 10mm respectively
Specimens for sampling tests were collected and 1050 ° C, 1100 ° C and
And at a temperature of 1150 ° C. for 15 minutes,
Hot torsion test at rpm, until breaking at the above 3 temperatures
The average value of the number of twists was determined.
Further, from the central portion of the steel bar having a diameter of 40 mm.
Parallel to rolling direction, diameter 12mm, length by machining
Cut out a 22 mm test piece, quench the test piece,
Reversion treatment (holding at 820 ° C for 30 minutes, oil quenching,
Tempering at 160 ° C. for 1 hour) and subjected to a rolling fatigue test.
In other words, using a cylindrical rolling fatigue tester,
Using # 68 turbine oil, maximum Hertz contact stress is 5
900MPa, test piece loading frequency is 46000 times / minute
A rolling fatigue test was conducted. 10 specimens for each steel
Remove the surface and remove the surface first of the 10 test pieces.
The rotational speed at this time was defined as “rolling fatigue life”. Rolling fatigue
Working life is 1.0 × 107 In these cases, rolling fatigue characteristics
Evaluated as excellent.
Table 2 shows “Cr in steel bar with a diameter of 40 mm”.
Width of the region where the Cr content exceeds 1.3 times the content "
(In the table, described as “Cr segregation band width / diameter”), cutting
Blade life, that is, breaking load is 1.3 times the first one
Number of cuts at the time, twist to break at the above three temperatures
Average value (in the table, simply “number of twists until break”)
Listed) and rolling fatigue life survey results.
[0048]
[Table 2]
From Table 2, it is clear that the chemical composition and
The width of the Cr segregation band in the cross section is defined by the present invention.
If the condition is satisfied, the desired number of twists of 84 times or less and 1.
0x107 The above rolling fatigue life is obtained together.
The
In contrast, the segregation of Cr in the cross section.
If the width of the band is outside the conditions specified in the present invention,
The desired number of twists of 84 times or less and 1.0 × 107 More rolling
Any of the fatigue lives has not reached the desired value.
(Example 2) Three steels A to M having chemical compositions shown in Table 3 were used.
After melting in a 00kg vacuum furnace, 5 minutes of hot water in a 50kg mold
5 steel ingots (ingots) having the same chemical composition
Individually made. Steels B to D, G to H and M in Table 3
Is a steel whose chemical composition satisfies the conditions specified in the present invention.
On the other hand, steel A, E, F and I to L are any of the components.
In the steel of the comparative example deviating from the content range specified in the present invention.
is there.
[0051]
[Table 3]Four of the five steel ingots of steels A to M above
Next, homogenized heat treatment was performed using an electric furnace.
It was. Homogenization heat treatment conditions (heat pattern) are as follows
These four conditions.
Condition W: heated to 1240 ° C. and held for 4 hours
After cooling outside the furnace,
Condition X: heated to 1240 ° C. and held for 8 hours, then outside the furnace
Allowed to cool,
Condition Y: after heating to 1240 ° C. and holding for 12 hours, furnace
Let cool outside,
Condition Z: after heating to 1240 ° C. and holding for 24 hours, furnace
Allow to cool outside.
Next, five steel ingots for each steel,
In other words, four steel ingots that have been subjected to the above-mentioned homogenization heat treatment and casting
A total of five steel ingots without any homogenization treatment were 1200
Heated to ℃ and hot forged at a finishing temperature of 950 ℃, then
The product was allowed to cool in the atmosphere to obtain a round bar having a diameter of 40 mm. like this
The segregation of Cr in the round bar with a diameter of 40 mm
The width of the strip was measured. That is, each round bar with a diameter of 40 mm
After mirror polishing the cross section of the EDX, attach it to the EDX attached to the SEM
Therefore, “1.3% of Cr content in a round bar with a diameter of 40 mm.
The width of the region where the Cr content exceeds twice is as follows:
And investigated. That is, the EDX probe diameter is 1 μm.
2 with the center of the cross section of the round bar as the measurement start point
The line analysis was performed 3 times for Cr up to the position of mm.
Using the measurement chart, the analysis value of Cr is Cr
The widest of the locations that were 1.3 times the content
The width of a large portion is the above-mentioned “Cr content in a round bar having a diameter of 40 mm.
The width of the region where the Cr content exceeds 1.3 times the amount "
Decided.
Further, from the center of a round bar having a diameter of 40 mm.
Parallel to the forging axis, the length and diameter of the parallel part are machined.
Take 50 mm and 10 mm specimens for torsion testing, respectively.
Temperature at 1050 ° C, 1100 ° C and 1150 ° C
For 15 minutes and then hot torsion test at 300 rpm
The average value of the number of twists until rupture at the above three temperatures is obtained.
I tried.
Also, from the center of the 40 mm diameter round bar
Parallel to the forging axis, diameter 12mm, length 2 by machining
Cut out a 2mm test piece, quench and temper this test piece
Treatment (holding at 820 ° C. for 30 minutes, oil quenching, 1
Tempering at 60 ° C. for 1 hour) and subjected to a rolling fatigue test. You
In other words, using a cylindrical rolling fatigue testing machine,
Using 68 turbine oil, maximum Hertz contact stress is 59
00MPa, test piece loading frequency of 46,000 times / minute
A rolling fatigue test was conducted. 10 specimens for each steel
Each of the 10 specimens was first peeled off.
The rotational speed at the time of rolling was defined as “rolling fatigue life”. Rolling fatigue
Life is 1.0 × 107 Excellent rolling fatigue characteristics in these cases
It was evaluated that.
In Tables 4-6, “With a round bar with a diameter of 40 mm,
Of the region where the Cr content exceeds 1.3 times the Cr content.
Width ”(in each table,“ Cr segregation band width / diameter ”
The average value of the number of twists to break at the above three temperatures
(In each table, simply describe as “Number of twists until break”)
The survey results of dynamic fatigue life are summarized.
[0058]
[Table 4][0059]
[Table 5][0060]
[Table 6]
As is apparent from Tables 4-6, the steel of the comparative example
In the case of a test number using A and steels I to L, that is, including C
Test numbers 1 to 5 using steel A with an amount of less than 0.8%,
P content exceeds 0.025% and “P (%) + 2
Test using Steel I with a value of "S (%)" exceeding 0.040%
Test numbers 41-45, S content is over 0.015%,
And "P (%) + 2S (%)" exceeds 0.040%
Test number 46-50 using steel J, Ti content is 0.0
Test numbers 51-55 with steel K above 02%, and
Using steel L with O (oxygen) content exceeding 0.0015%
Test numbers 56 to 60 have a rolling fatigue life of 1.0 × 10
7 Has not reached times.
Of the above, test numbers 41, 42, 46, 4
7, 51 and 56 have a "Cr segregation band width / diameter" of 0. 0.
Since it exceeds 0030, the rolling fatigue life is particularly short.
Of the above, test numbers 4, 5, 53, 5
4, 59 and 60 have a "Cr segregation band width / diameter" of .0.
Since it is below 0003, the number of twists to break in the twist test
Even the target value has not been reached.
Test number 21 using comparative steels E and F
˜30, “Cr segregation band width / diameter” is the
Although it is within the range, the value of “P (%) + 2S (%)” is
Since it is less than 0.020%, the twist until the break in the twist test
More than 84 times.
Of the above, test numbers 24, 25, 29 and
30 is "Cr segregation band width / diameter" below 0.0003
Since it is turning, the number of twists is particularly large.
Content range defined by the present invention for chemical composition
Even if the steel is in the test number 6, 11, 16, 3
1, 32, 36 and 37 are "Cr segregation band width / diameter"
Is over 0.0030, so the rolling fatigue life is 1.0 ×
107 Has not reached times. Also, test numbers 9, 10,
14, 15, 20, 40, 64 and 65 are "Cr segregation.
Since the “width / diameter of the belt” is below 0.0003,
The number of twists until breakage in the bending test is more than 84 times.
In contrast to the above comparative example, the conditions defined in the present invention.
Test Nos. 7, 8, 12, 1 which are examples of the present invention that satisfy the conditions
3, 17-19, 33-35, 38, 39, 61, 62
And 63, the desired number of twists of 84 times or less and 1.
0x107 The above rolling fatigue life is obtained together.
The
[0068]
The round steel material of the present invention is excellent in “hot workability”.
(Ie, “long tool life for hot working”)
Also, the rolling fatigue life is long, so balls, rollers, and needles
As a material for bearing element parts such as
Can be used.
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Claims (1)
0.2〜2.0%、Mn:0.2〜1.5%、Cr:
0.5〜2.0%、P:0.005〜0.025%、
S:0.003〜0.015%でP(%)+2S
(%):0.020〜0.040%、Al:0.01〜
0.05%、N:0.005〜0.012%、Cu:
1.0%以下、Ni:2.0%以下を含有し、残部はF
e及び不純物からなり、不純物中のTiは0.002%
以下、O(酸素)は0.0015%以下の丸鋼材であっ
て、その半径をRとしたとき、横断面の中心から(R/
10)までの領域に存在する偏析帯において、丸鋼材で
のCr含有量の1.3倍を超えるCr含有量となる領域
の幅が、その丸鋼材の直径の0.0003〜0.003
倍であることを特徴とする熱間加工性に優れた軸受要素
部品用の丸鋼材。What is claimed is: 1. By mass%, C: 0.8 to 1.2%, Si:
0.2-2.0%, Mn: 0.2-1.5%, Cr:
0.5-2.0%, P: 0.005-0.025%,
S: 0.003 to 0.015% and P (%) + 2S
(%): 0.020-0.040%, Al: 0.01-
0.05%, N: 0.005 to 0.012%, Cu:
1.0% or less, Ni: 2.0% or less, with the balance being F
e and impurities, Ti in impurities is 0.002%
Hereinafter, O (oxygen) is a round steel material of 0.0015% or less, and when the radius is R, (R /
In the segregation zone existing in the region up to 10), the width of the region having a Cr content exceeding 1.3 times the Cr content in the round steel material is 0.0003 to 0.003 of the diameter of the round steel material.
Round steel material for bearing element parts with excellent hot workability characterized by being doubled.
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| JP2001193583A JP3882538B2 (en) | 2001-06-26 | 2001-06-26 | Round steel for bearing element parts formed by hot working |
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| JP2001193583A JP3882538B2 (en) | 2001-06-26 | 2001-06-26 | Round steel for bearing element parts formed by hot working |
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| JP2003013179A true JP2003013179A (en) | 2003-01-15 |
| JP3882538B2 JP3882538B2 (en) | 2007-02-21 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100832960B1 (en) | 2006-12-29 | 2008-05-27 | 주식회사 포스코 | Manufacturing method of high carbon chrome bearing steel |
| CN101709431B (en) * | 2009-12-10 | 2011-08-24 | 南京钢铁股份有限公司 | Round steel and production process thereof |
| JP2013001930A (en) * | 2011-06-14 | 2013-01-07 | Kobe Steel Ltd | Steel material for bearing having excellent rolling fatigue life |
| JP2013001931A (en) * | 2011-06-14 | 2013-01-07 | Kobe Steel Ltd | Spheroidizing heat treated steel material for bearing having excellent rolling fatigue life |
| CN103938099A (en) * | 2014-04-18 | 2014-07-23 | 人本集团有限公司 | Steel for bearing |
| CN107761004A (en) * | 2016-08-18 | 2018-03-06 | 合肥东方节能科技股份有限公司 | A kind of heat treatment method of rolling mill guiding alloy material and rolling mill guiding |
-
2001
- 2001-06-26 JP JP2001193583A patent/JP3882538B2/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100832960B1 (en) | 2006-12-29 | 2008-05-27 | 주식회사 포스코 | Manufacturing method of high carbon chrome bearing steel |
| CN101709431B (en) * | 2009-12-10 | 2011-08-24 | 南京钢铁股份有限公司 | Round steel and production process thereof |
| JP2013001930A (en) * | 2011-06-14 | 2013-01-07 | Kobe Steel Ltd | Steel material for bearing having excellent rolling fatigue life |
| JP2013001931A (en) * | 2011-06-14 | 2013-01-07 | Kobe Steel Ltd | Spheroidizing heat treated steel material for bearing having excellent rolling fatigue life |
| CN103938099A (en) * | 2014-04-18 | 2014-07-23 | 人本集团有限公司 | Steel for bearing |
| CN103938099B (en) * | 2014-04-18 | 2016-06-29 | 人本集团有限公司 | A kind of bearing steel |
| CN107761004A (en) * | 2016-08-18 | 2018-03-06 | 合肥东方节能科技股份有限公司 | A kind of heat treatment method of rolling mill guiding alloy material and rolling mill guiding |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3882538B2 (en) | 2007-02-21 |
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