JP2001321141A - Food preservative - Google Patents
Food preservativeInfo
- Publication number
- JP2001321141A JP2001321141A JP2000140177A JP2000140177A JP2001321141A JP 2001321141 A JP2001321141 A JP 2001321141A JP 2000140177 A JP2000140177 A JP 2000140177A JP 2000140177 A JP2000140177 A JP 2000140177A JP 2001321141 A JP2001321141 A JP 2001321141A
- Authority
- JP
- Japan
- Prior art keywords
- alcohol
- weight
- activated carbon
- food
- adsorbent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005452 food preservative Substances 0.000 title claims abstract description 19
- 235000019249 food preservative Nutrition 0.000 title claims abstract description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 96
- 235000019441 ethanol Nutrition 0.000 claims abstract description 82
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 55
- 239000003463 adsorbent Substances 0.000 claims abstract description 20
- 239000003398 denaturant Substances 0.000 claims abstract description 11
- 239000000796 flavoring agent Substances 0.000 claims abstract description 10
- 235000019634 flavors Nutrition 0.000 claims abstract description 9
- 239000010455 vermiculite Substances 0.000 claims description 5
- 235000019354 vermiculite Nutrition 0.000 claims description 5
- 229910052902 vermiculite Inorganic materials 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims 2
- 235000013305 food Nutrition 0.000 abstract description 14
- 239000011928 denatured alcohol Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 9
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- -1 thread Substances 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 239000003755 preservative agent Substances 0.000 description 5
- 239000006200 vaporizer Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000002335 preservative effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 235000008429 bread Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000005001 laminate film Substances 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229940123973 Oxygen scavenger Drugs 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009920 food preservation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000005068 transpiration Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は密封包装内又は密封容器
内に食品と共に封入して用いる食品保存剤の改良に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an improvement in a food preservative which is used together with food in a sealed package or a sealed container.
【０００２】[0002]
【従来の技術】パン、洋菓子、和菓子、麺類、水産食
品、畜産食品等種々の食品が密封容器、特にプラスチッ
クフィルム製袋に詰めて販売されている。これらの密封
容器には、種々の食品用保存剤が封入されているが、そ
の様な保存剤の一つとしてアルコールを多孔性吸着材中
に含浸させ、これをアルコール蒸気が透過する紙、不織
布、プラスチック製フィルム等の小袋に入れた、いわゆ
るアルコール揮散剤と呼ばれるものが知られている。ア
ルコール揮散剤は、単独での使用の他、酸素吸収剤と同
時に使用される場合があるが、その場合にはアセトアル
デヒドの発生による異臭を伴うという欠点があった。前
記欠点を改善するための方法として、特開昭62-186941
号公報、特開昭63-112970号公報に開示されるようなア
ミンを利用した方法が知られている。又、特開平8-1406
43号公報には、鉄系脱酸素剤、エチルアルコール徐放
剤、アミノ基を有する物質からなる保存剤により発生す
る物質として、アセトアルデヒド以外にもエチレンや酢
酸などの果実腐敗臭が発生することが記載され、果実腐
敗臭をも除去する保存剤として鉄系脱酸素剤、エチルア
ルコール徐放剤、アミノ基を有する物質、活性炭よりな
る食品保存剤が開示されている。2. Description of the Related Art Various foods such as bread, western confectionery, Japanese confectionery, noodles, marine foods, livestock foods and the like are sold in sealed containers, especially plastic film bags. In these sealed containers, various food preservatives are sealed, and as one of such preservatives, alcohol is impregnated in a porous adsorbent, and the porous adsorbent is impregnated with paper or non-woven fabric. What is called a so-called alcohol volatilizer in a small bag such as a plastic film is known. The alcohol volatilizer may be used alone or simultaneously with the oxygen absorbent, but in such a case, there is a drawback that an unpleasant odor is generated due to generation of acetaldehyde. As a method for improving the above-mentioned disadvantage, Japanese Patent Application Laid-Open No. 62-186941
And a method utilizing an amine as disclosed in JP-A-63-112970. Also, JP-A-8-1406
No. 43 discloses that, as a substance generated by an iron-based oxygen scavenger, a sustained-release agent of ethyl alcohol, and a preservative consisting of a substance having an amino group, fruit odor such as ethylene and acetic acid other than acetaldehyde may be generated. As a preservative that also removes fruit rot odor, a food preservative comprising an iron-based oxygen absorber, a sustained release agent of ethyl alcohol, a substance having an amino group, and activated carbon is disclosed.
【０００３】一方、アルコール揮散剤を単独で使用する
場合には、アセトアルデヒド等による異臭よりも、むし
ろアルコール自体に含まれる香気成分が問題であった。
つまり、一般にアルコール揮散剤に使用されている工業
用アルコールは、変性剤により特有の香気が付与された
変性アルコールであるため、以前からこの変性剤の香気
が食品に移行するという問題が生じていた。[0003] On the other hand, when an alcohol volatilizer is used alone, the problem is not the off-flavor due to acetaldehyde or the like, but rather the aroma component contained in the alcohol itself.
In other words, industrial alcohols that are generally used as alcohol volatile agents are denatured alcohols to which a specific fragrance is imparted by a denaturing agent, and thus a problem has arisen that the odor of this denaturing agent is transferred to food from before. .
【０００４】[0004]
【発明が解決しようとする課題】本発明は、アルコール
蒸気を利用した食品保存剤において、該食品保存剤に使
用されるアルコールに含有している変性剤の香気が、対
象となる食品に移行し難く、且つ食品本来の風味を損な
わない食品保存剤を提供することを目的とする。SUMMARY OF THE INVENTION The present invention relates to a food preservative utilizing alcohol vapor, wherein the aroma of a denaturant contained in the alcohol used in the food preservative is transferred to the target food. An object of the present invention is to provide a food preservative which is difficult and does not impair the original flavor of food.
【０００５】[0005]
【課題を解決するための手段】本発明は、エチルアルコ
ールを吸着材に吸着あるいは吸収させたアルコール吸着
体とアルコール１００重量部に対し１〜１０重量部の活
性炭からなる食品保存剤に関する。SUMMARY OF THE INVENTION The present invention relates to a food preservative comprising an alcohol adsorbent having ethyl alcohol adsorbed or absorbed on an adsorbent and 1 to 10 parts by weight of activated carbon per 100 parts by weight of alcohol.
【０００６】本発明に使用されるエチルアルコールは、
一般に専売アルコールとして販売されている工業用アル
コールであればよい。変性剤として、特に限定されない
が、フレーバーＨ−No.１，３，４，６，９〜１３，お
よびフレーバーＴ−１００〜１０３，１０７，２０１等
を規定量含有しているアルコールが例示される。特に、
食品防腐用として規定されている、特別変性アルコール
が好適に用いられる。The ethyl alcohol used in the present invention is:
Any industrial alcohol generally sold as a proprietary alcohol may be used. Examples of the denaturing agent include, but are not particularly limited to, alcohols containing specified amounts of flavor H-Nos. 1, 3, 4, 6, 9 to 13, and flavors T-100 to 103, 107, 201, and the like. . In particular,
Specially modified alcohol specified for food preservation is preferably used.
【０００７】変性アルコール中に含まれる変性剤の香気
を吸着させる活性炭としては、特別なものは必要なく、
粉末活性炭または粒状活性炭のごとき通常用いられる市
販のものが使用できるが、既に何らかの物質を吸着し吸
着力が無くなっているか、著しく低下しているような活
性炭は使用できない。As the activated carbon for adsorbing the aroma of the denaturing agent contained in the denatured alcohol, there is no particular need for activated carbon.
Commercially available products such as powdered activated carbon or granular activated carbon can be used, but activated carbon which has already adsorbed some substance and has lost its adsorbing power or has been significantly reduced cannot be used.
【０００８】活性炭の含有量としては、アルコール１０
０重量部に対し１〜１０重量部の範囲であればよい。活
性炭の含有量がアルコール１００重量部に対し１重量部
より少ないと変性剤の香気が食品に付着するのを防止す
る効果が不十分となり、１０重量部より多い場合には食
品本来の風味が損なわれ、本発明の目的が達成されな
い。[0008] The content of activated carbon is alcohol 10
It may be in the range of 1 to 10 parts by weight with respect to 0 parts by weight. If the content of activated carbon is less than 1 part by weight with respect to 100 parts by weight of alcohol, the effect of preventing the aroma of the denaturant from adhering to the food is insufficient, and if it is more than 10 parts by weight, the original flavor of the food is impaired. Therefore, the object of the present invention is not achieved.
【０００９】本発明に使用されるアルコールの吸着材と
しては、多孔性の吸着材であればよく、従来からアルコ
ール揮散剤に用いられている吸着材がいずれも好適に用
いられる。例えばバーミキュライト、二酸化珪素、タル
ク、ゼオライト、パーライト、ベントナイト、珪藻土、
アルミナ等の粉末や紙、糸、布、不織布、脱脂綿等が使
用できるが、好ましいものとしてはバーミキュライトが
あげられる。The alcohol adsorbent used in the present invention may be any porous adsorbent, and any adsorbent conventionally used for alcohol vaporizers is preferably used. For example, vermiculite, silicon dioxide, talc, zeolite, perlite, bentonite, diatomaceous earth,
Powder such as alumina, paper, thread, cloth, non-woven fabric, absorbent cotton and the like can be used, but preferred is vermiculite.
【００１０】アルコールに対する吸着材の量は限定され
ないが、アルコール吸着体の流動性が良く、且つ飛散性
が小さくなる量とするのが好ましい。The amount of the adsorbent relative to the alcohol is not limited, but it is preferable that the amount be such that the alcohol adsorbent has good fluidity and small scattering properties.
【００１１】本発明の食品保存剤は通常、アルコール蒸
気透過性の小袋に封入して使用するが、これに用いられ
る包装材は、アルコール蒸気透過性があれば良く、アル
コール蒸気透過度２０ｇ／ｍ2／２４ｈｒ／５０ＲＨ／
４０℃以上、特に１００ｇ／ｍ2／２４ｈｒ／５０ＲＨ
／４０℃以上が好適に使用できる。The food preservative of the present invention is usually used by encapsulating it in a small bag permeable to alcohol vapor. The packaging material used for the preservative only needs to be permeable to alcohol vapor, and the alcohol vapor permeability is 20 g / m2. 2 / 24hr / 50RH /
40 ° C. or higher, especially 100g / m 2 / 24hr / 50RH
/ 40 ° C or higher can be suitably used.
【００１２】かかる包装材としては、紙／有孔ポリエチ
レンラミネートフィルム、低密度ポリエチレンフィル
ム、三酢酸セルロースフィルム、ＥＶＡ（エチレン−酢
酸ビニル共重合体）フィルムなどが例示されるが、これ
らに限定されない。Examples of such packaging materials include, but are not limited to, paper / perforated polyethylene laminated films, low density polyethylene films, cellulose triacetate films, EVA (ethylene-vinyl acetate copolymer) films, and the like.
【００１３】本発明の食品保存剤の効果を最大限に発揮
するためには、活性炭が保存剤中に均一に分散した態様
とするのが好ましい。かかる態様の食品保存剤を調製す
るためには、特に予めアルコールを吸着材に吸着あるい
は吸収させたアルコール吸着体を製造し、次いで所定量
の活性炭を添加するのが好ましい。アルコール吸着体を
製造せずにアルコール、吸着材、活性炭を同時に混合し
ても目的は達せられるが、アルコールの一部が活性炭に
吸着されてしまいアルコール揮散剤としての性能が低下
し、多量の保存剤が必要となる。In order to maximize the effect of the food preservative of the present invention, it is preferable that the activated carbon is uniformly dispersed in the preservative. In order to prepare the food preservative of such an embodiment, it is particularly preferable to prepare an alcohol adsorbent in which alcohol is adsorbed or absorbed in advance by an adsorbent, and then add a predetermined amount of activated carbon. The purpose can be achieved by mixing alcohol, adsorbent, and activated carbon at the same time without producing an alcohol adsorbent, but part of the alcohol is adsorbed by activated carbon, and the performance as an alcohol vaporizer is reduced, and a large amount of storage is performed. Agent is required.
【００１４】以下、実施例をあげて本発明を説明する。Hereinafter, the present invention will be described with reference to examples.
【実施例】実施例において使用した原材料は、以下の通
りである。 （原材料） 工業用アルコール 政府公認の変性剤を含有するエチル
アルコール エタノール２００リットルつき以下の変性剤を含有する
アルコール： フレーバーＨ−No.４ １キログラム（以下、アルコー
ルＨ−No.４） フレーバーＨ−No.９ １.５キログラム（アルコールＨ
−No.９） フレーバーＨ−No.１１ １キログラム（アルコールＨ
−No.１１） をそれぞれ含有するアルコール バーミキュライト（ＪＩＳＡ５００９粒度１.２〜０.３
品） 活性炭粉状（武田薬品工業（株）製）EXAMPLES The raw materials used in the examples are as follows. (Raw materials) Industrial alcohol Ethyl alcohol containing denaturant approved by the government Alcohol containing denaturant less than 200 liters of ethanol: Flavor H-No. 1 1 kg (hereinafter, alcohol H-No. 4) Flavor H- No.9 1.5 kg (alcohol H
-No.9) Flavor H-No.11 1kg (alcohol H
-No. 11), each containing alcohol vermiculite (JISA5009 particle size 1.2 to 0.3).
Product) Activated carbon powder (manufactured by Takeda Pharmaceutical Co., Ltd.)
【００１５】実施例１ （処方）表１に示した８種類の処方を有するアルコール
揮散剤内剤を調製した。所定量のバーミュキュライトに
所定量のアルコールを混合して、アルコールを吸着さ
せ、次いで活性炭を添加して混合した。なお、サンプル
１〜８の活性炭量は、アルコール１００重量部に対して
０，０.５，１，３，５，１０，２０，５０重量部とな
るように添加した。Example 1 (Formulation) An internal preparation of alcohol vaporizer having eight kinds of formulations shown in Table 1 was prepared. A predetermined amount of vermiculite was mixed with a predetermined amount of alcohol to adsorb the alcohol, and then activated carbon was added and mixed. The amounts of activated carbon of Samples 1 to 8 were added so as to be 0.5, 1, 3, 5, 10, 20, and 50 parts by weight based on 100 parts by weight of alcohol.
【００１６】[0016]
【表１】 [Table 1]
【００１７】（試験方法） １.変性剤臭の脱臭試験 上記処方を有する内剤を紙／有孔ポリエチレンラミネー
トフィルム（４０ｍｍ×６０ｍｍ）へ上記の量分包した
アルコール揮散剤１.０ｇタイプを、サンドイッチ用パ
ンまたはロールケーキとともに塩化ビニリデンコートナ
イロン／ナイロン製袋に封入した。これらを２５℃の恒
温室に２日間保管した後、袋を開封し、サンドイッチ用
パン袋内の変性アルコール臭の強さ、およびロールケー
キ袋内の食品の香りの強さを官能的に評価した。(Test Method) 1. Deodorizing test for odor of denaturing agent A 1.0 g type of alcohol volatilizing agent was prepared by packaging the above-prepared internal preparation in a paper / perforated polyethylene laminate film (40 mm × 60 mm) in the above amount. It was sealed in a vinylidene chloride-coated nylon / nylon bag together with a sandwich pan or roll cake. After these were stored in a constant temperature room at 25 ° C. for 2 days, the bags were opened, and the intensity of denatured alcohol odor in the sandwich bread bag and the intensity of food aroma in the roll cake bag were sensuously evaluated. .
【００１８】２.アルコール蒸散性の測定 上記処方を有する内剤を紙／有孔ポリエチレンラミネー
トフィルム（６０ｍｍ×６０ｍｍ）へ上記の量分包した
アルコール揮散剤２.０ｇタイプ５個ずつを２５℃、５
５％ＲＨに設定した恒温恒湿器に保管し、経時的（０、
１、２、４、８、２４時間後）に重量を測定した。その
後、各サンプルを８０℃で３時間乾燥し、∞時間後重量
とした。これらの結果から、経時的なアルコール揮散量
変化およびアルコール揮散率変化を求めた。2. Measurement of Alcohol Evaporation Property The above-prepared internal preparation was packaged in a paper / perforated polyethylene laminate film (60 mm × 60 mm) in the amount described above, and 2.0 g of the alcohol volatilizer was placed at 25 ° C. 5
Store in a thermo-hygrostat set at 5% RH and store over time (0,
After 1, 2, 4, 8, 24 hours) the weight was measured. After that, each sample was dried at 80 ° C. for 3 hours, and weighted after Δ hour. From these results, changes in the alcohol volatilization amount and changes in the alcohol volatilization rate over time were determined.
【００１９】（試験結果） １.変性剤臭の脱臭試験結果 結果を表２に示した。また、評価基準を表３に示した。
表２の結果より、内剤の活性炭含有量がアルコール１０
０重量部に対して０.５重量部で、アルコール揮散剤か
らの変性剤臭は低減し、１.０重量部以上含有させた場
合は、変性剤臭がほぼ消失した。(Test Results) 1. Results of Deodorizing Test for Modifier Odor The results are shown in Table 2. Table 3 shows the evaluation criteria.
From the results shown in Table 2, the activated carbon content of the internal preparation is
At 0.5 parts by weight with respect to 0 parts by weight, the odor of the denaturant from the alcohol vaporizer was reduced, and when the content was 1.0 part by weight or more, the odor of the denaturant almost disappeared.
【００２０】また、活性炭をアルコール１００重量部に
対して３.０重量部以上含有させると、食品の香りが弱
くなり、特に２０重量部以上含有させた場合は食品の香
りがかなり減少した。以上より、活性炭含有量として
は、アルコール１００重量部に対して１.０〜１０重量
部が最も望ましいと考えられた。Further, when the activated carbon was contained in an amount of 3.0 parts by weight or more with respect to 100 parts by weight of the alcohol, the aroma of the food was weakened, and particularly when the activated carbon was contained in an amount of 20 parts by weight or more, the aroma of the food was considerably reduced. From the above, it was considered that the content of activated carbon was most preferably 1.0 to 10 parts by weight based on 100 parts by weight of alcohol.
【００２１】[0021]
【表２】 ＊アルコール１００重量部に対する活性炭の重量部[Table 2] * Parts by weight of activated carbon per 100 parts by weight of alcohol
【００２２】[0022]
【表３】 [Table 3]
【００２３】２.アルコール蒸散性の測定結果 表４、図１にアルコール揮散量の経時変化を、図２にア
ルコール揮散率変化を示した。この結果より、アルコー
ル揮散剤に所定量の活性炭を含有させたサンプル３〜８
と、活性炭を含まないサンプル１および２とでは、アル
コール蒸散性にはほとんど変化がないことがわかった。2. Measurement Results of Alcohol Evaporation Table 4 and FIG. 1 show the change of the alcohol volatilization with time, and FIG. 2 shows the change of the alcohol volatilization rate. From these results, samples 3 to 8 containing a predetermined amount of activated carbon in the alcohol volatilizer were used.
It was found that there was almost no change in the alcohol transpiration between Samples 1 and 2 containing no activated carbon.
【００２４】[0024]
【表４】 [Table 4]
【００２５】[0025]
【表５】 [Table 5]
【００２６】実施例２ （処方）表６に示した４種類の処方を有するアルコール
揮散剤内剤を調製した。Example 2 (Formulation) Alcohol vaporizer internal preparations having the four kinds of formulations shown in Table 6 were prepared.
【表６】 [Table 6]
【００２７】（実験方法）上記処方を有する内剤それぞ
れ、を紙／有孔ポリエチレンラミネートフィルム（４０
ｍｍ×６０ｍｍ）へ上記の量分包したアルコール揮散剤
を調製した。サンドイッチ用パンとともに各アルコール
揮散剤を塩化ビニリデンコートナイロン／ポリエチレン
製袋に封入した。これらを２５℃の恒温室に２日間保管
した後、袋を開封し、サンドイッチ用パン袋内の変性剤
臭の強さを官能的に評価した。(Experimental method) Each of the internal preparations having the above-mentioned formulation was applied to a paper / perforated polyethylene laminate film (40
mm × 60 mm) to prepare an alcohol volatilizer packaged in the above amount. Each alcohol vaporizer was sealed in a vinylidene chloride-coated nylon / polyethylene bag together with a sandwich pan. After these were stored in a constant temperature room at 25 ° C. for 2 days, the bags were opened, and the intensity of the odor of the denaturant in the sandwich bread bag was organoleptically evaluated.
【００２８】（実験結果）評価基準を表８に、結果を表
７に示した。この結果より、他種の変性アルコールを使
用した場合でも活性炭による変性剤臭除去の効果がある
ことがわかった。(Experimental Results) The evaluation criteria are shown in Table 8, and the results are shown in Table 7. From this result, it was found that even when another type of denatured alcohol was used, the effect of removing the odor of the denaturant by activated carbon was effective.
【００２９】[0029]
【表７】 ＊アルコール１００重量部に対する活性炭の重量部[Table 7] * Parts by weight of activated carbon per 100 parts by weight of alcohol
【００３０】[0030]
【表８】 [Table 8]
【図１】 実施例のサンプルのアルコール蒸散量の経時
変化を示すグラフである。FIG. 1 is a graph showing the change over time in the amount of alcohol evaporation of a sample of an example.
【図２】 実施例のサンプルのアルコール蒸散率の経時
変化を示すグラフである。FIG. 2 is a graph showing the change over time in the alcohol evaporation rate of a sample of an example.
Claims (5)
は吸収させたアルコール吸着体とアルコール１００重量
部に対し１〜１０重量部の活性炭からなる食品保存剤。1. A food preservative comprising an alcohol adsorbent obtained by adsorbing or absorbing ethyl alcohol on an adsorbent and 1 to 10 parts by weight of activated carbon per 100 parts by weight of alcohol.
工業用アルコールである、請求項１に記載の食品保存
剤。2. The food preservative according to claim 1, wherein the ethyl alcohol is an industrial alcohol to which a denaturant is added.
バーＨ−No.４、Ｈ−No.９、Ｈ−No.１１のいずれかを
含有する工業用アルコールである、請求項１に記載の食
品保存剤。3. The food preservative according to claim 1, wherein ethyl alcohol is an industrial alcohol containing one of flavors H-No. 4, H-No. 9, and H-No. 11 as a denaturant. .
が、バーミキュライトである請求項１〜３に記載の食品
保存剤。4. The food preservative according to claim 1, wherein the adsorbent for adsorbing ethyl alcohol is vermiculite.
アルコール吸着体を製造し、次いでアルコール吸着体と
アルコール１００重量部に対して１〜１０重量部の活性
炭を混合する工程からなる、請求項１〜４いずれかに記
載の食品保存剤を製造する方法。5. A method for producing an alcohol adsorbent in which ethyl alcohol is adsorbed on an adsorbent, and then mixing 1 to 10 parts by weight of activated carbon with respect to 100 parts by weight of the alcohol adsorbent and 100 parts by weight of alcohol. A method for producing a food preservative according to any one of claims 1 to 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000140177A JP2001321141A (en) | 2000-05-12 | 2000-05-12 | Food preservative |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000140177A JP2001321141A (en) | 2000-05-12 | 2000-05-12 | Food preservative |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2001321141A true JP2001321141A (en) | 2001-11-20 |
Family
ID=18647512
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000140177A Pending JP2001321141A (en) | 2000-05-12 | 2000-05-12 | Food preservative |
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| Country | Link |
|---|---|
| JP (1) | JP2001321141A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007236245A (en) * | 2006-03-07 | 2007-09-20 | Ueno Fine Chem Ind Ltd | Alcohol volatile agent |
| JP2008023488A (en) * | 2006-07-24 | 2008-02-07 | Central Res Inst Of Electric Power Ind | Method and apparatus for supplying electron donor to microorganism and bioreactor using the same |
| JP2008212061A (en) * | 2007-03-05 | 2008-09-18 | Ueno Fine Chem Ind Ltd | Ethanol emitter |
| JP2011073724A (en) * | 2009-09-30 | 2011-04-14 | Dorency Kk | Alcoholic volatilization agent |
| JP2011073723A (en) * | 2009-09-30 | 2011-04-14 | Dorency Kk | Alcoholic volatilization agent |
| JP2012528586A (en) * | 2009-06-05 | 2012-11-15 | アッカエッフェ エウロペ ソチエタ ア レスポンサビリタ リミタータ | Zeolite-containing food |
| JP2017023109A (en) * | 2015-07-28 | 2017-02-02 | ドレンシー株式会社 | Quality preserving agent for food products |
-
2000
- 2000-05-12 JP JP2000140177A patent/JP2001321141A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007236245A (en) * | 2006-03-07 | 2007-09-20 | Ueno Fine Chem Ind Ltd | Alcohol volatile agent |
| JP2008023488A (en) * | 2006-07-24 | 2008-02-07 | Central Res Inst Of Electric Power Ind | Method and apparatus for supplying electron donor to microorganism and bioreactor using the same |
| JP2008212061A (en) * | 2007-03-05 | 2008-09-18 | Ueno Fine Chem Ind Ltd | Ethanol emitter |
| JP2012528586A (en) * | 2009-06-05 | 2012-11-15 | アッカエッフェ エウロペ ソチエタ ア レスポンサビリタ リミタータ | Zeolite-containing food |
| JP2011073724A (en) * | 2009-09-30 | 2011-04-14 | Dorency Kk | Alcoholic volatilization agent |
| JP2011073723A (en) * | 2009-09-30 | 2011-04-14 | Dorency Kk | Alcoholic volatilization agent |
| JP2017023109A (en) * | 2015-07-28 | 2017-02-02 | ドレンシー株式会社 | Quality preserving agent for food products |
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