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Publication number
JP2000087013A5
JP2000087013A5 JP1998258727A JP25872798A JP2000087013A5 JP 2000087013 A5 JP2000087013 A5 JP 2000087013A5 JP 1998258727 A JP1998258727 A JP 1998258727A JP 25872798 A JP25872798 A JP 25872798A JP 2000087013 A5 JP2000087013 A5 JP 2000087013A5
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Japan
Prior art keywords
water
oil repellent
repellent composition
conh
coo
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JP1998258727A
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Japanese (ja)
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JP3959864B2 (en
JP2000087013A (en
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Priority to JP25872798A priority Critical patent/JP3959864B2/en
Priority claimed from JP25872798A external-priority patent/JP3959864B2/en
Publication of JP2000087013A publication Critical patent/JP2000087013A/en
Publication of JP2000087013A5 publication Critical patent/JP2000087013A5/ja
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Claims (6)

下式１で表わされるリン酸エステル化合物を必須成分とする撥水撥油剤組成物において、下式２で表わされる含フッ素化合物および／またはリン原子を含まない含フッ素界面活性剤を含むことを特徴とする撥水撥油剤組成物。
ただし、式中の記号は以下の意味を示す。
Ｒf1、Ｒf2：それぞれ同一であっても異なっていてもよい、ポリフルオロアルキル基。
ｍ：１〜３の整数。
ｎ：０〜２の整数。ただし、（ｍ＋ｎ）は１、２、または３。
ｋ：０または１。
Ｑ: ２価有機基。
Ｙ+ ：対イオン。
Ｘ：水酸基、ハロゲン原子、Ｒ1 または−ＯＣＯＲ2 （ただし、Ｒ1 およびＲ2 はそれぞれ、水素原子、低級アルキル基、またはアルケニル基を示す。）。
Figure 2000087013
 The water / oil repellent composition comprising a phosphate ester compound represented by the following formula 1 as an essential component includes a fluorine-containing compound represented by the following formula 2 and / or a fluorine-containing surfactant containing no phosphorus atom. A water / oil repellent composition.
However, the symbols in the formulas have the following meanings.
R f1 and R f2 : Polyfluoroalkyl groups which may be the same or different.
m: An integer of 1 to 3.
n: An integer of 0-2. However, (m + n) is 1, 2, or 3.
k: 0 or 1.
Q: Divalent organic group.
Y + : counter ion.
X: a hydroxyl group, a halogen atom, R 1 or —OCOR 2 (wherein R 1 and R 2 each represent a hydrogen atom, a lower alkyl group, or an alkenyl group).
Figure 2000087013
 下式２で表わされる含フッ素化合物および／またはリン原子を含まない含フッ素界面活性剤の総量が、式１で表わされるリン酸エステル化合物に対して０．０１〜２０重量％である請求項１に記載の撥水撥油剤組成物。  2. The total amount of the fluorine-containing compound represented by the following formula 2 and / or the fluorine-containing surfactant not containing a phosphorus atom is 0.01 to 20% by weight based on the phosphate compound represented by the formula 1. The water / oil repellent composition described in 1. Ｙ+ が、［ＨＮ（Ｒ1 ）（Ｒ2 ）（Ｒ3 ）］+ （ただし、Ｒ1 、Ｒ2 、およびＲ3 は、それぞれ同一であっても異なっていてもよく、水素原子、−ＣＨ2 ＣＨ2 ＯＨ、−ＣＨ2 ＣＨ2 ＣＨ2 ＯＨ、−ＣＨ（ＣＨ3 ）ＣＨ2 ＯＨ、または−ＣＨ2 ＣＨ（ＯＨ）ＣＨ3 を示す。）である請求項１または２に記載の撥水撥油剤組成物。 Y + represents [HN (R 1 ) (R 2 ) (R 3 )] + (wherein R 1 , R 2 , and R 3 may be the same or different, and each represents a hydrogen atom,- 3 represents CH 2 CH 2 OH, —CH 2 CH 2 CH 2 OH, —CH (CH 3 ) CH 2 OH, or —CH 2 CH (OH) CH 3 ). Water / oil repellent composition . リン原子を含まない含フッ素界面活性剤が下式３で表わされる化合物である請求項１、２または３に記載の撥水撥油剤組成物。
Ｒf3−Ｚ ・・・式３
ただし、式中の記号は以下の意味を示す。
Ｒf3：炭素数４〜１６のペルフルオロアルキル基。
Ｚ：−ＳＯ3 -Ｍ+ 、−ＳＯ2 ＮＲ4 ＣＨ2 ＣＯＯ- Ｍ+ 、−ＣＯＯ- （Ｎ+ Ｈ4 ）、−ＣＯＮＨ（ＣＨ2 ）s ＣＯＯ- Ｍ+ 、−ＣＯＮＨ（ＣＨ2 ）t Ｎ+ （ＣＨ3 ）Ｒ4 （ＣＨ2 ＣＯＯ- ）、−ＣＯＮＨ（ＣＨ2 ）t Ｎ+ （ＣＨ3 ）2 （ＣＨ2 ＣＯＯ- ）、−ＣＯＮＨ（ＣＨ2 ）s Ｏ（ＣＨ2 ）t Ｎ+ （ＣＨ3 ）（ＣＨ2 Ｒ4 ）（ＣＯＯ- ）、−ＳＯ2 ＮＲ4 （ＣＨ2 ＣＨ2 Ｏ）u Ｒ4 、−ＣＯＮＨ（ＣＨ2 ）t （Ｎ→Ｏ）（ＣＨ3 ）2 、−ＣＯＮＨ（ＣＨ2 ＣＨ2 Ｏ）u Ｒ4 、−（ＣＨ2 ）s （ＣＨ2 ＣＨ2 Ｏ）u Ｒ4 、または−ＣＨ2 ＣＨ（ＯＨ）ＣＨ2 Ｏ（ＣＨ2 ＣＨ2 Ｏ）u Ｒ4 （ただしＭは、Ｎａ、Ｋ、またはＮＨ4 、Ｒ4 は水素原子、低級アルキル基、またはヒドロキシアルキル基、ｓ、ｔは、それぞれ独立に０〜１０の整数、ｕは２〜３０の整数、を示す。）。 Water and oil repellent composition according to claim 1, 2 or 3 fluorine-containing surface active agent which does not include a phosphorus atom is a compound represented by the following formula 3.
R f3 −Z Formula 3
However, the symbols in the formulas have the following meanings.
R f3 : a perfluoroalkyl group having 4 to 16 carbon atoms.
Z: -SO 3 - M +, -SO 2 NR 4 CH 2 COO - M +, -COO - (N + H 4), - CONH (CH 2) s COO - M +, -CONH (CH 2) t N + (CH 3 ) R 4 (CH 2 COO − ), —CONH (CH 2 ) t N + (CH 3 ) 2 (CH 2 COO − ), —CONH (CH 2 ) s O (CH 2 ) t N + (CH 3 ) (CH 2 R 4 ) (COO − ), —SO 2 NR 4 (CH 2 CH 2 O) u R 4 , —CONH (CH 2 ) t (N → O) (CH 3 ) 2 , -CONH (CH 2 CH 2 O) u R 4, - (CH 2) s (CH 2 CH 2 O) u R 4 or -CH 2 CH (OH) CH 2 O (CH 2 CH 2 O) u R, 4 (wherein M is Na, K, or NH 4 , R 4 is a hydrogen atom, a lower alkyl group, or a hydroxyalkyl group, s and t are each independently an integer of 0 to 10, u represents an integer of 2 to 30) . 請求項１〜４のいずれかに記載の撥水撥油剤組成物で処理された加工紙。 Processed paper treated with water and oil repellent composition according to any one of claims 1 to 4. 請求項１〜４のいずれかに記載の撥水撥油剤組成物が処理された天然加工皮革または合成加工皮革。Natural processed leather or synthetic processed leather treated with the water / oil repellent composition according to any one of claims 1 to 4 .
JP25872798A 1998-09-11 1998-09-11 Phosphate ester water / oil repellent composition Expired - Fee Related JP3959864B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP25872798A JP3959864B2 (en) 1998-09-11 1998-09-11 Phosphate ester water / oil repellent composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP25872798A JP3959864B2 (en) 1998-09-11 1998-09-11 Phosphate ester water / oil repellent composition

Publications (3)

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JP2000087013A JP2000087013A (en) 2000-03-28
JP2000087013A5 true JP2000087013A5 (en) 2005-05-12
JP3959864B2 JP3959864B2 (en) 2007-08-15

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI282349B (en) 2003-01-24 2007-06-11 Shinetsu Chemical Co Silicone composition and paper treatment agent including the same
JP4743757B2 (en) 2004-10-22 2011-08-10 信越化学工業株式会社 Silicone paper treatment agent
JP2011173959A (en) * 2010-02-23 2011-09-08 Unimatec Co Ltd Method for producing fluorine-containing polymer latex
EP3744175B1 (en) * 2019-05-31 2024-05-29 Rolex S.A. Composition for impregnating a substrate, in particular a watchstrap

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