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IT8050115A1 - IMPROVEMENT IN THE ABSORBENT DISPOSABLE ITEMS AND PROCEDURE FOR THEIR PRODUCTION. - Google Patents

IMPROVEMENT IN THE ABSORBENT DISPOSABLE ITEMS AND PROCEDURE FOR THEIR PRODUCTION. Download PDF

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Publication number
IT8050115A1
IT8050115A1 IT1980A50115A IT5011580A IT8050115A1 IT 8050115 A1 IT8050115 A1 IT 8050115A1 IT 1980A50115 A IT1980A50115 A IT 1980A50115A IT 5011580 A IT5011580 A IT 5011580A IT 8050115 A1 IT8050115 A1 IT 8050115A1
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IT
Italy
Prior art keywords
pulp
dye
weight
absorbent
classified
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Application number
IT1980A50115A
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Italian (it)
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IT8050115A0 (en
IT1188963B (en
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Colgate Palmolive Co
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Publication date
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Publication of IT8050115A0 publication Critical patent/IT8050115A0/en
Publication of IT8050115A1 publication Critical patent/IT8050115A1/en
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Publication of IT1188963B publication Critical patent/IT1188963B/en

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/28Colorants ; Pigments or opacifying agents
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/18Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing inorganic materials
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/20Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing organic materials
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60Optical bleaching or brightening
    • D06L4/686Fugitive optical brightening; Discharge of optical brighteners in discharge paste; Blueing; Differential optical brightening
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/30Luminescent or fluorescent substances, e.g. for optical bleaching

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Materials Engineering (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Hematology (AREA)
  • Inorganic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Paper (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
  • External Artificial Organs (AREA)
  • Absorbent Articles And Supports Therefor (AREA)

Description

DESCRIZIONE DESCRIPTION

a corredo di una domanda di brevetto per invenzione avente per titolo: accompanying a patent application for an invention entitled:

"Perf?zionamento negli articoli assorbenti a perdere e procedimento per la loro produzione" "Perf? Tioning of disposable absorbent articles and process for their production"

RIASSUNTO SUMMARY

Vengono forniti articoli assorbenti e particolarmente articoli assorbenti da gettar via dopo l'uso impiegati per assorbire fluidi corporei (ad esempio pannolini, tamponi ecc..) e che sono generalmente strutturati con un foglio superiore o con fogli superiori, una massa di materiale assorbente al disotto e un foglio posteriore per trattenere la perdita dei fluidi dall'articolo, con una massa assorbente derivata da pasta di legno termomeccanica o meccanica in cui la massa assorbente si approssima o equivale come bianchezza alla bianchezza dei prodotti in pasta chimica di legno. Ci? ? ottenuto trattando la pasta con quantit? minuscole di un sistema colorante misto cio? con quantit? ad esempio in ragione di 0,001%-0,05% in peso rispetto al peso totale della pasta. Absorbent articles and particularly absorbent articles are provided to be thrown away after use used to absorb body fluids (e.g. diapers, tampons, etc.) and which are generally structured with a topsheet or topsheet, a mass of absorbent material at the underneath and a back sheet to retain fluid loss from the article, with an absorbent mass derived from thermo-mechanical or mechanical wood pulp in which the absorbent mass approximates or is whiteness equivalent to the whiteness of chemical wood pulp products. There? ? obtained by treating the pasta with quantity? lowercase letters of a mixed coloring system that is? with quantity? for example in the ratio of 0.001% -0.05% by weight with respect to the total weight of the pasta.

La presente invenzione si riferisce a prodotti assorbenti che generalmente sono caratterizzati come prodotti a perdere o da gettar via dopo l'uso e trattare i prodotti sono i pannolini, i tamponi per l'igiene femminile, i tamponi per il ciclo mestruale e simili e in particolare la presente invenzione si riferisce a perfezionamenti riguardanti tali prodotti con l'impiego di lanugine di legno derivata da pasta meccanica o termomeccanica. La lanugine viene usata come massa assorbente principale in questi prodotti e si fa riferimento a brevetti recenti quali i brevetti statunitensi 4.069.821; 4.066.081; 4.062.362; The present invention relates to absorbent products that are generally characterized as disposable or throwaway products after use and treating products are diapers, feminine hygiene tampons, menstrual tampons and the like and in in particular, the present invention refers to improvements concerning such products with the use of wood fluff derived from mechanical or thermo-mechanical pulp. Fluff is used as the primary absorbent mass in these products and reference is made to recent patents such as US Patents 4,069,821; 4,066,081; 4,062,362;

4.060.085; 4.044.768; 4.029.101; 4.029.100 e 4.027.672 in cui la pasta di legno viene impiegata come nastro assorbente nei prodotti del tipo ivi previsto. Tali brevetti sono incorporati qui per riferimento. La pasta usata per produrre la lanugine in questi brevetti della tecnica precedente generalmente ? stata pasta chimica e tale lanugine ? un prodotto altamente imbianchito in adiempezza di circa 90 o superiore. Lo standard di bianchezza 100 viene riferito alla superficie del magnesio carbonato ed ? accettato come criterio per una eccellente bianchezza. La pasta chimica ? anche vantaggiosa per il fatto che si ottengono lunghezze di fibra ottimali dalla fonte del legno per cui si arriva ad ottenere tamponi assorbenti aventi una integrit? di struttura tollerabile (cio? resistenza meccanica e stabilit? di forma) che ? maggiormente desiderabile dato che il procedimento di formazione del tampone generalmente ? un procedimento di deposizione dall'aria. 4,060,085; 4,044,768; 4,029,101; 4,029,100 and 4,027,672 in which the wood pulp is used as an absorbent tape in products of the type specified therein. Such patents are incorporated herein by reference. The pulp used to make the fluff in these prior art patents generally? was chemical pulp and such fluff? a highly bleached product in a size of about 90 or more. The whiteness standard 100 refers to the surface of the magnesium carbonate and? accepted as a criterion for excellent whiteness. The chemical pulp? also advantageous due to the fact that optimal fiber lengths are obtained from the source of the wood so that it is possible to obtain absorbent pads having an integrity? of tolerable structure (that is mechanical resistance and stability of shape) that? more desirable since the tampon-forming process generally? a process of deposition from the air.

E' stato trovato desiderabile e vantaggioso impiegare pasta termomeccanica in strutture assorbenti da gettar via dopo l'uso a causa non solamente degli ovvi vantaggi economici ma anche a causa dei miglioramenti ottenuti nel potere assorbente. Il potere assorbente risulta dalla natura semiidrofuga di una pasta termomeccanica dovuta alla presenza di lignininaturali che comunicano una maggiore resilienza al tampone non int?ssuto e contemporanea maggiore capacit? di trattenere i liquidi. It has been found desirable and advantageous to use thermo-mechanical pulp in absorbent structures to be thrown away after use due not only to the obvious economic advantages but also to the improvements obtained in absorbency. The absorbing power results from the semi-hydrophobic nature of a thermo-mechanical paste due to the presence of natural lignin which communicate greater resilience to the non-woven pad and, at the same time, greater capacity. to retain liquids.

Uno degli svantaggi della pasta termomeccanica consiste nel "colore anomalo" del prodotto che rende i pannolini da gettar via ottenuti con tale prodotto meno desiderabili per l'utilizzatore particolarmente per quegli utilizzatori che impiegano pannolini da gettar via su bambini ove un prodotto "deve essere bianchissimo". One of the disadvantages of the thermomechanical paste consists in the "anomalous color" of the product which makes the disposable diapers obtained with this product less desirable for the user, particularly for those users who use disposable diapers on children where a product "must be very white. ".

E' stato ora trovato che la bianchezza della pasta termomeccanica e di altre paste cellulosiche di colore anomalo come ad esempio paste meccaniche e paste semi chimiche e anche paste chimiche che non sod-. disfano gli standard di bianchezza accettati, si pu? ampiamente migliorare approssimandosi alla bianchezza delle migliori paste chimiche (cio? paste prive di lignina e imbianchite) mediante trattamento della pasta preferibilmente in un impasto liquido con un sistema colorante misto che comprende (a) CI Acid Volet 49 e (b) CI Acid Violet 47 in un rapporto in peso tra (a) e (b) che va da circa 10:1 a 1:10 preferibilmente da 6:1 a 1:6, pi? preferibilmente da 4:1 a 1:4, pi? preferibilmente ancora da 3 : 1 ? 1:3 e con massima preferenza da 1:1 a 1:3 per fornire la pasta con circa lo 0,001% a circa 0,0 5% in peso di colorante rispetto al peso della pasta secca. It has now been found that the whiteness of thermo-mechanical pulp and of other cellulosic pulps of abnormal color such as mechanical pulps and semi-chemical pulps and also unsatisfactory chemical pulps. undo the accepted whiteness standards, can you? widely improve approaching the whiteness of the best chemical pastes (i.e. lignin-free and bleached pastes) by treating the paste preferably in a slurry with a mixed coloring system which includes (a) CI Acid Volet 49 and (b) CI Acid Violet 47 in a weight ratio between (a) and (b) ranging from about 10: 1 to 1:10, preferably from 6: 1 to 1: 6, plus? preferably from 4: 1 to 1: 4, plus? preferably still 3: 1? 1: 3 and most preferably 1: 1 to 1: 3 to provide the paste with about 0.001% to about 0.0 5% by weight of dye relative to the weight of the dry pasta.

Il miscuglio colorante ? convenientemente aggiunto alla pasta acquosa (di solito circa 85:90$ o pi? di residuo secco) come soluzione preferibilmente acquosa ma si pu? impiegare qualsiasi adatto solvente per il colorante (ad esempio alcool oppure alcool in soluzione acquosa). Nonostante la soluzione di colorante possa essere di qualsiasi concentrazione preferibile, generalmente si preferisce usare soluzioni diluite per evitare una colorazione eccessiva in punti localizzati della pasta che pu? dar luogo a valori di rapido esaurimento e di esaurimento abbatanza elevato del colorante dalla soluzione sul materiale cellulosico della pasta. The dye mixture? conveniently added to the aqueous paste (usually about 85: 90% or more of dry residue) as a preferably aqueous solution but it can be done. use any suitable solvent for the dye (for example alcohol or alcohol in aqueous solution). Although the dye solution can be of any preferable concentration, it is generally preferred to use diluted solutions to avoid excessive coloring in localized points of the paste which can be used. give rise to values of rapid exhaustion and high abatance exhaustion of the dye from the solution on the cellulosic material of the pulp.

Dopo, il trattamento la pasta viene manipalata in maniera, comune per formare prodotti in foglio per qualsiasi uso susseguente e in articolar la pasta pu? essere trasformata in fogli per formare cartoni da impiegare nella produzione di lanugine assorbente per i prodotti da gettar via dopo l'uso, di cui si parla precedentemente. After, the treatment the pasta is manipulated in a common way to form sheet products for any subsequent use and in articulate the pasta can be used. be transformed into sheets to form cartons to be used in the production of absorbent fluff for products to be thrown away after use, which was discussed above.

Qui di seguito si d? una illustrazione specifica della presente invenzione. Below you d? a specific illustration of the present invention.

Esempio 1. Example 1.

Ad 1,5 g della pasta di cellulosa, acquosa (pasta termochimica non privata di lignina) contenente un residuo secco cellulosico del 90% si aggiungono 50 cm3 di una soluzione colorante conten To 1.5 g of the aqueous cellulose pulp (thermochemical pulp not deprived of lignin) containing a dry cellulose residue of 90%, 50 cm3 of a coloring solution containing

(a) 7,5 mg/l di CI Acid Violet 47 e (b) 2.5mg/l di CI Acid Violet 49. Dopo l'essiccazione della pasta susseguentemente alla vagliatura per formare un foglio si trova che la riflettanza Tappi misurata comunemente su un riflettometro G.E. ? pari all'80 % mentre la riflettanza di un materiale in foglio in pasta di legno non trattata (cio? senza trattamento con il colore) similmente ha una riflettanza Tappi solamente pari al 65%. Il prodotto trattato con il colore non solamente ha una migliore riflettanza e una migliore bianchezza ma ? equivalente alla solita pasta chimica (priva di lignina) quando viene trasformata in fogli in maniera simile nonostante la presenza della lignina nel materiale costituito da pasta termomeccanica. (a) 7.5 mg / l of CI Acid Violet 47 and (b) 2.5 mg / l of CI Acid Violet 49. After drying of the paste following screening to form a sheet it is found that the Tappi reflectance commonly measured on a G.E. ? equal to 80% while the reflectance of an untreated wood pulp sheet material (ie without color treatment) similarly has a Cappi reflectance of only 65%. The color treated product not only has better reflectance and better whiteness but? equivalent to the usual chemical pulp (free of lignin) when it is transformed into sheets in a similar way despite the presence of lignin in the material consisting of thermomechanical pulp.

E' anche preferibile aggiungere una piccola quantit? di pigmento a base di titanio diossido oppure bario solfato alla pasta acquosa (carica) per imbianchire ulteriormente il prodotto. Generalmente solo quantit? piccolissime, da circa 0,01% a circa 10% in peso preferibilmente da 0,5% a circa 3% in. peso producono notevoli risultati come illustrato nell'esempio che segue. Is it also preferable to add a small amount? of pigment based on titanium dioxide or barium sulphate to the aqueous paste (filler) to further whiten the product. Generally only quantity? very small, from about 0.01% to about 10% by weight, preferably from 0.5% to about 3% by weight. weight produce remarkable results as illustrated in the example below.

Esempio II a) Si ripete l'esempio I con l'aggiunta alla soluzione di colorante di 0,5 g/l di titanio diossido. Example II a) Example I is repeated with the addition of 0.5 g / l of titanium dioxide to the dye solution.

b) Si ripete l'esempio I con l'aggiunta alla soluzione di colorante di 0,5 g/l di bario solfato. b) Example I is repeated with the addition of 0.5 g / l of barium sulphate to the dye solution.

In ciascuno degli stadi (a) e (b) il valore di riflettanza dei campioni ? l'85%. In each of the stages (a) and (b) the reflectance value of the samples? 85%.

Nonostante l'invenzione sia stata descritta con riferimento ad un miscuglio di colorante CI acid violet 47 Although the invention has been described with reference to a mixture of CI acid violet 47 dye

Claims (11)

RIVENDICAZIONI 1. Composizione colorante mista brillantare e imbianchire materiale cellulosico che comprende colorante classificato Acid Violet 47 e colorante classificato Acid Violet 49 in un rapporto in peso che va da circa 10:1 a 1:10 1. Mixed dye composition to brighten and whiten cellulosic material which includes dye classified Acid Violet 47 and dye classified Acid Violet 49 in a weight ratio ranging from about 10: 1 to 1:10 2.Composizione secondo la rivendicazione 1 in cui il rapporto va da circa 4:1a 1:4. 2. A composition according to claim 1 wherein the ratio is from about 4: 1 to 1: 4. 3.Procedimento per brillantare e imbianchire pasta cellulosica acquosa che consiste nell'aggiungere a tale pasta una soluzione della composizione secondo la rivendicazione 1. 3. Process for brightening and bleaching aqueous cellulosic pulp which consists in adding to said pulp a solution of the composition according to claim 1. 4. Procedimento secondo la rivendicazione. in cui la soluzione ? una soluzione acquosa. 4. Method according to the claim. where the solution? an aqueous solution. 5. Procedimento secondo la rivendicazione 4. in cui la concentrazione del colorante nella soluzione va da circa 0,0001% a circa 0,05% in peso. 5. A process according to claim 4 wherein the concentration of the dye in the solution ranges from about 0.0001% to about 0.05% by weight. 6. Procedimento secondo la riv?ndicazione 3 che include ulteriore aggiunta alla pasta di una quantit? che va da circa 0,01% in peso a circa 10% in peso di titanio diossido e bario solfato o relativi miscugli, 6. A process according to claim 3 which includes further addition to the paste of a quantity of ranging from about 0.01% by weight to about 10% by weight of titanium dioxide and barium sulfate or mixtures thereof, 7. Procedimento secondo la rivendicazione 1 in cui il materiale cellulosico deriva da pasta termomeccanica . 7. Process according to claim 1 wherein the cellulosic material derives from thermomechanical pulp. 8. Procedimento per produrre un prodotto assorbente adatto per assorbire fluidi corporei che consiste nel trattare una. pasta cellulosica acquosa con una somposizione secondo la rivendicazione 1, e nell'essiccare la pasta trattata e successivamente nel formare da tale pasta trattata essiccata una massa depositata dall'aria. 8. A process for producing an absorbent product suitable for absorbing body fluids which consists of treating a. aqueous cellulosic pulp with a composition according to claim 1, and in drying the treated pulp and subsequently in forming an air-deposited mass from said dried treated pulp. 9. Prodotto assorbente adatto per assorbire fluidi corporei che comprende una lanugine cellulosica, depositata dall'aria trattata con la composizione secondo la rivendicazione 1. 9. Absorbent product suitable for absorbing body fluids which comprises a cellulosic fluff, deposited by the air treated with the composition according to claim 1. 10. Prodotto, assorbente secondo la rivendicazione 9 in cui la lanugine deriva da pasta termochimica e il rapporto tra colorante classificato 49 colorante classificato 47 va da circa 4:1 a 1:4 e la lanugine contiene da circa lo 0,001% a circa lo 0,05% in peso, della composizione colorante. 10. An absorbent product according to claim 9 wherein the fluff is derived from thermochemical pulp and the ratio of classified dye 49 classified dye 47 is from about 4: 1 to 1: 4 and the fluff contains from about 0.001% to about 0 0.05% by weight of the coloring composition. 11. Prodotto da gettar via dopo l?uso adatto per assorbire, fluidi corporei e che comprende una massa assorbente per i fluidi corporei stessi, un foglio di fondo impermeabile all'acqua e un foglio superiore, il cui perfezionamento consiste nella massa assorbente secondo la rivendicazione 10. 11. Product to be disposed of after use suitable for absorbing body fluids and which comprises an absorbent mass for the body fluids themselves, a bottom sheet impermeable to water and a top sheet, the improvement of which consists in the absorbent mass according to the claim 10.
IT50115/80A 1979-11-09 1980-11-10 Absorbent article, e.g. sanitary towel IT1188963B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US9280779A 1979-11-09 1979-11-09
US20504480A 1980-11-07 1980-11-07

Publications (3)

Publication Number Publication Date
IT8050115A0 IT8050115A0 (en) 1980-11-10
IT8050115A1 true IT8050115A1 (en) 1982-05-10
IT1188963B IT1188963B (en) 1988-01-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
IT50115/80A IT1188963B (en) 1979-11-09 1980-11-10 Absorbent article, e.g. sanitary towel

Country Status (2)

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IT (1) IT1188963B (en)
NL (1) NL8006112A (en)

Also Published As

Publication number Publication date
IT8050115A0 (en) 1980-11-10
IT1188963B (en) 1988-01-28
NL8006112A (en) 1981-06-01

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