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IT1314261B1 - Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine. - Google Patents

Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine.

Info

Publication number
IT1314261B1
IT1314261B1 IT1999MI002536A ITMI992536A IT1314261B1 IT 1314261 B1 IT1314261 B1 IT 1314261B1 IT 1999MI002536 A IT1999MI002536 A IT 1999MI002536A IT MI992536 A ITMI992536 A IT MI992536A IT 1314261 B1 IT1314261 B1 IT 1314261B1
Authority
IT
Italy
Prior art keywords
olefins
catalysts
polymerization
preparation
metallocenic compounds
Prior art date
Application number
IT1999MI002536A
Other languages
English (en)
Inventor
Paolo Biagini
Roberto Santi
Giuliana Schimperna
Maria Caldararo
Giampietro Borsotti
Francesco Masi
Original Assignee
Enichem Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enichem Spa filed Critical Enichem Spa
Publication of ITMI992536A0 publication Critical patent/ITMI992536A0/it
Priority to IT1999MI002536A priority Critical patent/IT1314261B1/it
Priority to JP2001540993A priority patent/JP3921601B2/ja
Priority to EP00990617A priority patent/EP1250342B1/en
Priority to HR20020461A priority patent/HRP20020461B1/xx
Priority to ES00990617T priority patent/ES2267602T3/es
Priority to RU2002114344A priority patent/RU2238277C2/ru
Priority to SI200030892T priority patent/SI1250342T1/sl
Priority to AU30043/01A priority patent/AU777085B2/en
Priority to BRPI0016134-9A priority patent/BR0016134B1/pt
Priority to HU0203804A priority patent/HUP0203804A3/hu
Priority to KR1020027006972A priority patent/KR20020061625A/ko
Priority to MXPA02005494A priority patent/MXPA02005494A/es
Priority to PT00990617T priority patent/PT1250342E/pt
Priority to CZ20021821A priority patent/CZ20021821A3/cs
Priority to US10/148,571 priority patent/US6984703B1/en
Priority to CNB008171939A priority patent/CN100368417C/zh
Priority to SK746-2002A priority patent/SK7462002A3/sk
Priority to CA002393175A priority patent/CA2393175C/en
Priority to PCT/EP2000/011824 priority patent/WO2001040238A1/en
Priority to PL355486A priority patent/PL202964B1/pl
Priority to AT00990617T priority patent/ATE331725T1/de
Priority to DE60029137T priority patent/DE60029137T2/de
Priority to TW089125590A priority patent/TW593324B/zh
Priority to MYPI20005672A priority patent/MY134869A/en
Priority to ARP000106413A priority patent/AR031540A1/es
Publication of ITMI992536A1 publication Critical patent/ITMI992536A1/it
Priority to ZA200204342A priority patent/ZA200204342B/en
Priority to NO20022611A priority patent/NO333543B1/no
Application granted granted Critical
Publication of IT1314261B1 publication Critical patent/IT1314261B1/it

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465—Indenes; Completely or partially hydrogenated indenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
IT1999MI002536A 1999-12-03 1999-12-03 Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine. IT1314261B1 (it)

Priority Applications (27)

Application Number Priority Date Filing Date Title
IT1999MI002536A IT1314261B1 (it) 1999-12-03 1999-12-03 Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine.
US10/148,571 US6984703B1 (en) 1999-12-03 2000-11-27 Bridged metallocene compounds as olefin-polymerization catalysts
CNB008171939A CN100368417C (zh) 1999-12-03 2000-11-27 作为烯烃聚合催化剂的桥连金属茂化合物
HR20020461A HRP20020461B1 (en) 1999-12-03 2000-11-27 Bridged metallocene compounds as olefin-polymerization catalysts
ES00990617T ES2267602T3 (es) 1999-12-03 2000-11-27 Compuestos de metaloceno en puente como catalizadores de la polimerizacion de olefina.
RU2002114344A RU2238277C2 (ru) 1999-12-03 2000-11-27 Металлоценовые соединения, способ их получения, катализатор для полимеризации олефинов, способ его получения, способ полимеризации олефинов
SI200030892T SI1250342T1 (sl) 1999-12-03 2000-11-27 Premostene metalocenske spojine kot katalizatorjiza polimerizacijo olefinov
AU30043/01A AU777085B2 (en) 1999-12-03 2000-11-27 Bridged metallocene compounds as olefin-polymerization catalysts
BRPI0016134-9A BR0016134B1 (pt) 1999-12-03 2000-11-27 compostos, catalisador para a polimerizaÇço de olefinas e processos a preparaÇço de compostos e de um catalisador e para a polimerizaÇço de olefinas.
HU0203804A HUP0203804A3 (en) 1999-12-03 2000-11-27 Bridged metallocene compounds as olefin-polymerization catalysts
KR1020027006972A KR20020061625A (ko) 1999-12-03 2000-11-27 올레핀 중합촉매용 메탈로센 화합물
MXPA02005494A MXPA02005494A (es) 1999-12-03 2000-11-27 Compuestos de metaloceno unidos con puente, proceso para su preparacion y su uso como catalizadores para la polimerizacion de olefinas.
PT00990617T PT1250342E (pt) 1999-12-03 2000-11-27 Compostos de metaloceno de ponte como catalisadores da polimerização de olefina
CZ20021821A CZ20021821A3 (cs) 1999-12-03 2000-11-27 Přemostěné metallocenové sloučeniny jako katalyzátory polymerace olefinů
JP2001540993A JP3921601B2 (ja) 1999-12-03 2000-11-27 オレフィン重合触媒としての橋かけメタロセン化合物
CA002393175A CA2393175C (en) 1999-12-03 2000-11-27 Bridged metallocene compounds as olefin-polymerization catalysts
AT00990617T ATE331725T1 (de) 1999-12-03 2000-11-27 Verbrückte metallocenverbindungen als olefinpolymerisationskatalysatoren
SK746-2002A SK7462002A3 (en) 1999-12-03 2000-11-27 Bridged metallocene compounds as olefin-polymerization catalysts
PCT/EP2000/011824 WO2001040238A1 (en) 1999-12-03 2000-11-27 Bridged metallocene compounds as olefin-polymerization catalysts
PL355486A PL202964B1 (pl) 1999-12-03 2000-11-27 Związek metalocenowy, sposób wytwarzania związku metalocenowego, katalizator do polimeryzacji olefin, sposób wytwarzania katalizatora do polimeryzacji olefin i sposób polimeryzacji olefin
EP00990617A EP1250342B1 (en) 1999-12-03 2000-11-27 Bridged metallocene compounds as olefin-polymerization catalysts
DE60029137T DE60029137T2 (de) 1999-12-03 2000-11-27 Verbrückte metallocenverbindungen als olefinpolymerisationskatalysatoren
TW089125590A TW593324B (en) 1999-12-03 2000-12-01 Bridged metallocene compounds, process for their preparation and their use as catalysts for the polymerization of olefins
MYPI20005672A MY134869A (en) 1999-12-03 2000-12-01 Bridged metallocene compounds, process for their preparation and their use as catalysts for the polymerization of olefins
ARP000106413A AR031540A1 (es) 1999-12-03 2000-12-04 COMPUESTOS DE METALOCENO, COMPUESTOS DE INDENILO-CICLOPENTADIENILO,UN PROCEDIMIENTO PARA PREPARAR DICHOS COMPUESTOS DE INDENILO-CICLOPENTADIENILO , UN CATALIZADOR PARA LA POLIMERIZACIoN DE OLEFINAS,UN PROCEDIMIENTO PARA LA PREPARACION DE DICHO CATALIZADOR Y UN PROCEDIMIENTO PARA LA POLIMERIZACIoN DE
ZA200204342A ZA200204342B (en) 1999-12-03 2002-05-30 Bridged metallocene compounds as olefin-polymerization catalysts.
NO20022611A NO333543B1 (no) 1999-12-03 2002-05-31 Brodannede metallocenforbindelser og fremstilling derav, olelfin-polymerisasjonskatalysatorer og deres fremstilling, og polymerisering av olefiner

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT1999MI002536A IT1314261B1 (it) 1999-12-03 1999-12-03 Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine.

Publications (3)

Publication Number Publication Date
ITMI992536A0 ITMI992536A0 (it) 1999-12-03
ITMI992536A1 ITMI992536A1 (it) 2001-06-03
IT1314261B1 true IT1314261B1 (it) 2002-12-06

Family

ID=11384070

Family Applications (1)

Application Number Title Priority Date Filing Date
IT1999MI002536A IT1314261B1 (it) 1999-12-03 1999-12-03 Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine.

Country Status (26)

Country Link
US (1) US6984703B1 (it)
EP (1) EP1250342B1 (it)
JP (1) JP3921601B2 (it)
KR (1) KR20020061625A (it)
CN (1) CN100368417C (it)
AR (1) AR031540A1 (it)
AT (1) ATE331725T1 (it)
AU (1) AU777085B2 (it)
BR (1) BR0016134B1 (it)
CA (1) CA2393175C (it)
CZ (1) CZ20021821A3 (it)
DE (1) DE60029137T2 (it)
ES (1) ES2267602T3 (it)
HR (1) HRP20020461B1 (it)
HU (1) HUP0203804A3 (it)
IT (1) IT1314261B1 (it)
MX (1) MXPA02005494A (it)
MY (1) MY134869A (it)
NO (1) NO333543B1 (it)
PL (1) PL202964B1 (it)
PT (1) PT1250342E (it)
RU (1) RU2238277C2 (it)
SK (1) SK7462002A3 (it)
TW (1) TW593324B (it)
WO (1) WO2001040238A1 (it)
ZA (1) ZA200204342B (it)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7091196B2 (en) 2002-09-26 2006-08-15 Rib-X Pharmaceuticals, Inc. Bifunctional heterocyclic compounds and methods of making and using same
EP1723159B1 (en) 2004-02-27 2019-06-12 Melinta Therapeutics, Inc. Macrocyclic compounds and methods of making and using the same
US7728086B2 (en) * 2005-03-23 2010-06-01 Basell Polyolefine Gmbh Process for the polymerization of olefins
EP2215129A2 (en) * 2007-08-27 2010-08-11 Borealis Technology OY Catalysts
EP2223944A1 (en) 2009-02-26 2010-09-01 Borealis AG Process for producing semicrystalline propylene polymers
KR101225127B1 (ko) * 2009-08-18 2013-01-22 주식회사 엘지화학 신규한 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 고리형 올레핀계 중합체의 제조방법
JP6036108B2 (ja) * 2012-03-29 2016-11-30 日本ポリエチレン株式会社 エチレン系重合体の製造方法
US10889662B2 (en) * 2014-12-12 2021-01-12 Lg Chem, Ltd. Metallocene-supported catalyst and method of preparing polyolefin using the same
CN108026199B (zh) * 2015-12-04 2020-08-11 Lg化学株式会社 制备负载型混杂茂金属催化剂的方法以及使用该方法制备的负载型混杂茂金属催化剂
CN108383862B (zh) * 2018-02-08 2021-03-30 中国石油天然气股份有限公司 一种茚并[2,1-b]吲哚基稀土金属配合物及其制备方法
US11198747B2 (en) 2018-06-04 2021-12-14 Exxonmobil Chemical Patents Inc. Catalyst systems including two hafnocene catalyst compounds
CN112334499B (zh) 2018-06-04 2023-03-24 埃克森美孚化学专利公司 具有si-si桥的茂金属
CN115710326B (zh) * 2022-10-27 2024-06-25 万华化学集团股份有限公司 一种氧芴桥连的芳氧基金属络合物催化剂及方法与应用
WO2025025413A1 (zh) * 2023-08-01 2025-02-06 中国石油化工股份有限公司 茂金属化合物、催化剂组合物、烯烃聚合方法和乙烯-环烯烃共聚物及其制备方法
WO2025080492A1 (en) * 2023-10-13 2025-04-17 ExxonMobil Technology and Engineering Company Metallocene catalyst compounds for producing polyolefins

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US5451649A (en) * 1991-05-09 1995-09-19 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
IT1256260B (it) * 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Polipropilene atattico
DE69434709T2 (de) * 1993-06-07 2006-10-19 Mitsui Chemicals, Inc. Propylenelastomere
ATE213994T1 (de) * 1995-04-11 2002-03-15 Gore & Ass Infrarotlicht-reflektierende abdeckungen
IT1275408B (it) * 1995-05-30 1997-08-05 Spherilene Spa Composti metallocenici bis-indenilici pontanti procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
DE19546501A1 (de) * 1995-12-13 1997-06-19 Hoechst Ag Metallocenverbindung
US5780659A (en) * 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes

Also Published As

Publication number Publication date
SK7462002A3 (en) 2003-02-04
ATE331725T1 (de) 2006-07-15
US6984703B1 (en) 2006-01-10
HUP0203804A3 (en) 2004-06-28
AU777085B2 (en) 2004-09-30
WO2001040238A1 (en) 2001-06-07
AU3004301A (en) 2001-06-12
HRP20020461A2 (en) 2004-04-30
ITMI992536A1 (it) 2001-06-03
JP3921601B2 (ja) 2007-05-30
CA2393175C (en) 2009-01-27
EP1250342B1 (en) 2006-06-28
MY134869A (en) 2007-12-31
PT1250342E (pt) 2006-11-30
RU2238277C2 (ru) 2004-10-20
HRP20020461B1 (en) 2005-10-31
TW593324B (en) 2004-06-21
ES2267602T3 (es) 2007-03-16
BR0016134B1 (pt) 2011-06-14
PL202964B1 (pl) 2009-08-31
NO20022611D0 (no) 2002-05-31
DE60029137D1 (de) 2006-08-10
AR031540A1 (es) 2003-09-24
NO20022611L (no) 2002-08-05
DE60029137T2 (de) 2007-05-16
EP1250342A1 (en) 2002-10-23
CZ20021821A3 (cs) 2002-10-16
CN1409718A (zh) 2003-04-09
CN100368417C (zh) 2008-02-13
MXPA02005494A (es) 2004-09-10
NO333543B1 (no) 2013-07-08
CA2393175A1 (en) 2001-06-07
HUP0203804A2 (hu) 2003-03-28
JP2003515540A (ja) 2003-05-07
BR0016134A (pt) 2002-08-20
KR20020061625A (ko) 2002-07-24
ZA200204342B (en) 2003-06-02
PL355486A1 (en) 2004-05-04
ITMI992536A0 (it) 1999-12-03

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