[go: up one dir, main page]

IL219398A0 - Processes for making ethanol from acetic acid - Google Patents

Processes for making ethanol from acetic acid

Info

Publication number
IL219398A0
IL219398A0 IL219398A IL21939812A IL219398A0 IL 219398 A0 IL219398 A0 IL 219398A0 IL 219398 A IL219398 A IL 219398A IL 21939812 A IL21939812 A IL 21939812A IL 219398 A0 IL219398 A0 IL 219398A0
Authority
IL
Israel
Prior art keywords
processes
acetic acid
making ethanol
ethanol
making
Prior art date
Application number
IL219398A
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/588,727 external-priority patent/US8309772B2/en
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of IL219398A0 publication Critical patent/IL219398A0/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/64Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656Manganese, technetium or rhenium
    • B01J23/6567Rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0207Pretreatment of the support
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16Clays or other mineral silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
IL219398A 2009-10-26 2012-04-24 Processes for making ethanol from acetic acid IL219398A0 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/588,727 US8309772B2 (en) 2008-07-31 2009-10-26 Tunable catalyst gas phase hydrogenation of carboxylic acids
PCT/US2010/022947 WO2011053365A1 (en) 2009-10-26 2010-02-02 Processes for making ethanol from acetic acid

Publications (1)

Publication Number Publication Date
IL219398A0 true IL219398A0 (en) 2012-06-28

Family

ID=46506678

Family Applications (1)

Application Number Title Priority Date Filing Date
IL219398A IL219398A0 (en) 2009-10-26 2012-04-24 Processes for making ethanol from acetic acid

Country Status (10)

Country Link
EP (1) EP2493608A1 (en)
JP (1) JP2013508362A (en)
CN (1) CN102271805B (en)
AU (1) AU2010313767A1 (en)
BR (1) BR112012009825A2 (en)
CA (1) CA2777754A1 (en)
IL (1) IL219398A0 (en)
MX (1) MX2012004837A (en)
RU (1) RU2012121861A (en)
WO (1) WO2011053365A1 (en)

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8501652B2 (en) 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
US8309773B2 (en) 2010-02-02 2012-11-13 Calanese International Corporation Process for recovering ethanol
US8546622B2 (en) 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
US8222466B2 (en) * 2010-02-02 2012-07-17 Celanese International Corporation Process for producing a water stream from ethanol production
US8858659B2 (en) 2010-02-02 2014-10-14 Celanese International Corporation Processes for producing denatured ethanol
US8541633B2 (en) 2010-02-02 2013-09-24 Celanese International Corporation Processes for producing anhydrous ethanol compositions
WO2011097246A1 (en) * 2010-02-02 2011-08-11 Celanese International Corporation Preparation and use of a catalyst for producing ethanol comprising a crystalline support modifier
WO2011097193A2 (en) * 2010-02-02 2011-08-11 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
WO2011097220A2 (en) * 2010-02-02 2011-08-11 Celanese International Corporation Process for producing ethanol using an extractive distillation column
US8552224B2 (en) 2010-05-07 2013-10-08 Celanese International Corporation Processes for maximizing ethanol formation in the hydrogenation of acetic acid
US8575403B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
CN105837404A (en) * 2010-02-02 2016-08-10 国际人造丝公司 Process for purifying ethanol
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
US8569551B2 (en) 2010-05-07 2013-10-29 Celanese International Corporation Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process
US8680342B2 (en) 2010-05-07 2014-03-25 Celanese International Corporation Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water
US9272970B2 (en) 2010-07-09 2016-03-01 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8846988B2 (en) 2010-07-09 2014-09-30 Celanese International Corporation Liquid esterification for the production of alcohols
TW201302684A (en) 2011-04-26 2013-01-16 Celanese Int Corp Process for the production of ethanol from an acetic acid feed and a recycled ethyl acetate feed
US8927788B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Process to recover alcohol with reduced water from overhead of acid column
US8933278B2 (en) 2011-04-26 2015-01-13 Celanese International Corporation Process for producing ethanol and reducing acetic acid concentration
US9000233B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Process to recover alcohol with secondary reactors for hydrolysis of acetal
US8907141B2 (en) 2011-04-26 2014-12-09 Celanese International Corporation Process to recover alcohol with secondary reactors for esterification of acid
US9000232B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Extractive distillation of crude alcohol product
US9024082B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Using a dilute acid stream as an extractive agent
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
US8884081B2 (en) 2011-04-26 2014-11-11 Celanese International Corporation Integrated process for producing acetic acid and alcohol
US8927787B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Process for controlling a reboiler during alcohol recovery and reduced ester formation
US9024084B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Reduced energy alcohol separation process having controlled pressure
US9024085B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Process to reduce ethanol recycled to hydrogenation reactor
US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
US8877987B2 (en) 2011-08-03 2014-11-04 Celanese International Corportation Process for producing anhydrous ethanol using extractive distillation column
CA2851254A1 (en) 2011-10-05 2013-04-11 Shadi MOGHADDAS Efficient processes for large scale preparation of phophaplatins antitumor agents
US8637715B2 (en) * 2011-12-21 2014-01-28 Celanese International Corporation Catalysts comprising secondary noble metals and process for producing ethanol
US9233899B2 (en) 2011-12-22 2016-01-12 Celanese International Corporation Hydrogenation catalysts having an amorphous support
CN103282333A (en) * 2011-12-22 2013-09-04 国际人造丝公司 Ethanol process using hydrogenation catalysts having an amorphous support
US8907142B2 (en) 2011-12-29 2014-12-09 Celanese International Corporation Process for promoting catalyst activity for ethyl acetate conversion
US9079172B2 (en) 2012-03-13 2015-07-14 Celanese International Corporation Promoters for cobalt-tin catalysts for reducing alkanoic acids
US9333496B2 (en) 2012-02-29 2016-05-10 Celanese International Corporation Cobalt/tin catalyst for producing ethanol
US8455702B1 (en) 2011-12-29 2013-06-04 Celanese International Corporation Cobalt and tin catalysts for producing ethanol
US8802902B2 (en) * 2011-12-30 2014-08-12 Celanese International Corporation Pressure driven distillation for ethanol production and recovery from hydrogenation process
US8865609B2 (en) * 2012-01-06 2014-10-21 Celanese International Corporation Hydrogenation catalysts
CN103874545B (en) * 2012-01-06 2016-08-24 国际人造丝公司 Process for the production of ethanol using hydrogenation catalysts prepared from polyoxometalate precursors
US9051235B2 (en) 2012-02-07 2015-06-09 Celanese International Corporation Process for producing ethanol using a molar excess of hydrogen
US9050585B2 (en) 2012-02-10 2015-06-09 Celanese International Corporation Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol
US8927786B2 (en) * 2012-03-13 2015-01-06 Celanese International Corporation Ethanol manufacturing process over catalyst having improved radial crush strength
US9073042B2 (en) 2012-03-14 2015-07-07 Celanese International Corporation Acetic acid hydrogenation over a group VIII metal calcined catalyst having a secondary promoter
US8975452B2 (en) 2012-03-28 2015-03-10 Celanese International Corporation Process for producing ethanol by hydrocarbon oxidation and hydrogenation or hydration
CN103787827B (en) * 2012-10-31 2015-10-07 中国石油化工股份有限公司 Carboxylic acid selec-tive hydrogenation prepares the method for alcohol
CN103787828B (en) * 2012-10-31 2015-10-07 中国石油化工股份有限公司 A kind of method applied cobalt B catalyst and alcohol prepared by carboxylic acid gas phase hydrogenation
CN103170352B (en) * 2013-03-28 2015-01-14 湖南长岭石化科技开发有限公司 Sec-butyl acetate hydrogenation catalyst and preparation method and application thereof
CN104117354A (en) * 2013-04-26 2014-10-29 中国科学院大连化学物理研究所 Method for preparation of monohydric alcohol or dihydric alcohol by low temperature selective hydrogenation of organic acid water phase
CN103433039B (en) * 2013-09-11 2015-11-11 神华集团有限责任公司 A kind of preparation method of acetic ester hydrogenation catalyst
CN108358752A (en) * 2018-04-18 2018-08-03 肖锦 A kind of method of acetic acid hydrogenation ethyl alcohol
CN112469683A (en) 2018-07-23 2021-03-09 三菱化学株式会社 Method for producing alcohol and catalyst

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2882244A (en) 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US3130007A (en) 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
US4398039A (en) * 1981-05-18 1983-08-09 The Standard Oil Company Hydrogenation of carboxylic acids
GB8509530D0 (en) 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
US5149680A (en) 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters
GB8707595D0 (en) 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
US5243095A (en) * 1992-04-24 1993-09-07 Engelhard Corporation Hydrogenation catalyst, process for preparing and process for using said catalyst
US5821111A (en) 1994-03-31 1998-10-13 Bioengineering Resources, Inc. Bioconversion of waste biomass to useful products
USRE35377E (en) 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
US5977010A (en) * 1995-06-15 1999-11-02 Engelhard Corporation Shaped hydrogenation catalyst and processes for their preparation and use
US6657078B2 (en) 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US6685754B2 (en) 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
CN100537503C (en) * 2007-05-31 2009-09-09 上海华谊丙烯酸有限公司 A kind of method that glycerol hydrogenation prepares n-propanol
US7608744B1 (en) * 2008-07-31 2009-10-27 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst

Also Published As

Publication number Publication date
BR112012009825A2 (en) 2016-10-18
CN102271805B (en) 2014-07-09
EP2493608A1 (en) 2012-09-05
JP2013508362A (en) 2013-03-07
AU2010313767A2 (en) 2012-07-26
AU2010313767A1 (en) 2012-05-17
CA2777754A1 (en) 2011-05-05
CN102271805A (en) 2011-12-07
RU2012121861A (en) 2013-12-10
WO2011053365A1 (en) 2011-05-05
HK1163589A1 (en) 2012-09-14
MX2012004837A (en) 2012-05-29

Similar Documents

Publication Publication Date Title
IL219398A0 (en) Processes for making ethanol from acetic acid
ZA201202850B (en) Process for making ethanol from acetic acid using acidic catalysts
ZA201600646B (en) Process for beta-lactone production
ZA201005510B (en) Production of ethanol from methanol
IL215691A0 (en) Carboxylic acid compound
ZA201200526B (en) Method for producing formic acid
PL2449121T3 (en) Alcohol production process
EP2411351A4 (en) Process for producing cyclohexylbenzene
IL207526A0 (en) Process for preparing 2-amino-5-cyanobenzoic acid derivatives
IL220211A0 (en) Process for the preparation of 1-alkyl-/1-aryl-5-pyrazolecarboxylic acid derivatives
ZA201205234B (en) Process for the production of ethanol by hydrogenation of vaporized acetic acid
ZA201201237B (en) Process for preparing decanecarboxylic acids
ZA201106628B (en) Process for the preparation of propionic acid derivatives
IL218140A0 (en) Process for preparing 1-phenylpyrazoles
ZA201204316B (en) Improved carbonylation process
EP2456778A4 (en) Process for producing flurocytidine derivatives
PL2477964T3 (en) Process for preparing alpha-carboxamide derivatives
AP3405A (en) Method for obtaining ethanol during fermentation
IL214037A0 (en) Method for producing 2-halogenomethylphenyl acetic acid derivatives
IL214709A (en) Process for making fusidic acid cream
EP2246322A4 (en) Process for producing -fluoro- -amino acids
BRPI1013382A2 (en) hydrocarbon impurities removal from acetic acid production intermediate
HUP0900788A2 (en) Process for producing 4-bromomethyl-biphenyl derivatives
IL217495A0 (en) Process for producing thiabenzulene-propionic acid deivative
GB2480419B (en) Method for the manufacture of ethanol