IE38487B1 - Smoking mixtures - Google Patents
Smoking mixturesInfo
- Publication number
- IE38487B1 IE38487B1 IE1987/73A IE198773A IE38487B1 IE 38487 B1 IE38487 B1 IE 38487B1 IE 1987/73 A IE1987/73 A IE 1987/73A IE 198773 A IE198773 A IE 198773A IE 38487 B1 IE38487 B1 IE 38487B1
- Authority
- IE
- Ireland
- Prior art keywords
- acid
- cellulose
- acids
- smoking mixture
- nicotine
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 11
- 230000000391 smoking effect Effects 0.000 title abstract 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 9
- 239000002253 acid Substances 0.000 abstract 9
- 150000007513 acids Chemical class 0.000 abstract 7
- 150000001720 carbohydrates Chemical class 0.000 abstract 5
- 235000014633 carbohydrates Nutrition 0.000 abstract 5
- XYHKNCXZYYTLRG-UHFFFAOYSA-N 1h-imidazole-2-carbaldehyde Chemical compound O=CC1=NC=CN1 XYHKNCXZYYTLRG-UHFFFAOYSA-N 0.000 abstract 4
- GWYFCOCPABKNJV-UHFFFAOYSA-M 3-Methylbutanoic acid Natural products CC(C)CC([O-])=O GWYFCOCPABKNJV-UHFFFAOYSA-M 0.000 abstract 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 4
- GWYFCOCPABKNJV-UHFFFAOYSA-N beta-methyl-butyric acid Natural products CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 abstract 4
- 229920002678 cellulose Polymers 0.000 abstract 4
- 239000001913 cellulose Substances 0.000 abstract 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 abstract 4
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 abstract 3
- OVBFMEVBMNZIBR-UHFFFAOYSA-N -2-Methylpentanoic acid Natural products CCCC(C)C(O)=O OVBFMEVBMNZIBR-UHFFFAOYSA-N 0.000 abstract 3
- 241000208125 Nicotiana Species 0.000 abstract 3
- 235000002637 Nicotiana tabacum Nutrition 0.000 abstract 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 abstract 3
- 239000000440 bentonite Substances 0.000 abstract 3
- 235000012216 bentonite Nutrition 0.000 abstract 3
- 229910000278 bentonite Inorganic materials 0.000 abstract 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 abstract 3
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 3
- 239000005018 casein Substances 0.000 abstract 3
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 3
- 235000021240 caseins Nutrition 0.000 abstract 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- 239000000796 flavoring agent Substances 0.000 abstract 3
- 229960002715 nicotine Drugs 0.000 abstract 3
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 abstract 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 abstract 3
- 239000000126 substance Substances 0.000 abstract 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 2
- 244000068988 Glycine max Species 0.000 abstract 2
- 235000010469 Glycine max Nutrition 0.000 abstract 2
- 108010055615 Zein Proteins 0.000 abstract 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 2
- 239000001166 ammonium sulphate Substances 0.000 abstract 2
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 2
- 235000010216 calcium carbonate Nutrition 0.000 abstract 2
- 239000004310 lactic acid Substances 0.000 abstract 2
- 235000014655 lactic acid Nutrition 0.000 abstract 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 abstract 2
- 239000001095 magnesium carbonate Substances 0.000 abstract 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 abstract 2
- 235000014380 magnesium carbonate Nutrition 0.000 abstract 2
- 235000018102 proteins Nutrition 0.000 abstract 2
- 108090000623 proteins and genes Proteins 0.000 abstract 2
- 102000004169 proteins and genes Human genes 0.000 abstract 2
- 239000000779 smoke Substances 0.000 abstract 2
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 abstract 1
- 101100234822 Caenorhabditis elegans ltd-1 gene Proteins 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229920002472 Starch Polymers 0.000 abstract 1
- 229920002494 Zein Polymers 0.000 abstract 1
- VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229920003086 cellulose ether Polymers 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 150000002334 glycols Chemical class 0.000 abstract 1
- 239000003906 humectant Substances 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 239000011256 inorganic filler Substances 0.000 abstract 1
- 229910003475 inorganic filler Inorganic materials 0.000 abstract 1
- 229920000609 methyl cellulose Polymers 0.000 abstract 1
- 239000001923 methylcellulose Substances 0.000 abstract 1
- 235000010981 methylcellulose Nutrition 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 239000001814 pectin Substances 0.000 abstract 1
- 229920001277 pectin Polymers 0.000 abstract 1
- 235000010987 pectin Nutrition 0.000 abstract 1
- 239000001508 potassium citrate Substances 0.000 abstract 1
- 229960002635 potassium citrate Drugs 0.000 abstract 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 abstract 1
- 235000011082 potassium citrates Nutrition 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000008107 starch Substances 0.000 abstract 1
- 235000019698 starch Nutrition 0.000 abstract 1
- 239000005019 zein Substances 0.000 abstract 1
- 229940093612 zein Drugs 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/32—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by acyclic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Manufacture Of Tobacco Products (AREA)
- Paper (AREA)
Abstract
1398177 Smoking mixture IMPERIAL CHEMICAL INDUSTRIES Ltd 1 Nov 1973 [4 Dec 1972] 55833/72 Heading A2C A smoking mixture comprises a modified carbohydrate as smoke-producing fuel, nicotine, and as flavourant isovaleric acid, #- methyl valeric acid, butyric acid or a mixture of at least two of the said acids. The modified carbohydrate is preferably a thermally degraded carbohydrate, especially thermally degraded cellulose. Further modified carbohydrates are oxidised cellulose, cellulose ethers e.g. carboxymethylcellulose or its salts, and the solid condensate obtained by acid or base catalysed condensation of a compound of the formula R<SP>1</SP>COCH 2 CH 2 COR<SP>2</SP> wherein R 1 and R 2 represent hydrogen, alkyl, hydroxyalkyl or formyl. The preferred acids are isovaleric acid and #-methylvaleric acids and mixtures thereof (e.g. in a weight ratio of isovaleric acid to #- methyl valeric acid of 4:1-0.25:1). The proportion of flavourant acids is preferably 0.02- 0.2% by weight. The smoking mixture may contain inorganic fillers, film-forming binders, e.g. methyl cellulose, sodium carboxymethylcellulose, pectins, gums; humectants, e.g. glycerol, glycols; flow controlling catalysts, e.g. potassium citrate; colourants; ash cohesion agents, e.g. citric acid and bentonite; substances producing acidic matter in the smoke, e.g. volatile acids, neutral substances pyrolysing to volatile acids, or weak base acids; carbohydrates, e.g. cellulose, starch, sugar or comminuted tobacco; proteins as flavourants, preferably casein, soyabean protein-or zein. The smoking mixture may be blended with tobacco, particularly flue-cured virginia tobacco to produce blends which may contain 30-70% by weight of the smoking mixture. Specific examples 1 to 11 disclose compositions comprising, besides the acid components, α-cellulose heat-treated in the presence of ammonium sulphamate, glycerol, nicotine, lactic acid, calcium carbonate, casein, soya protein, zein protein, bentonite, ammonium sulphate, sodium carboxymethyl cellulose and magnesite, which are slurried and cast to form a film. Example 12 discloses a composition comprising oxidised cellulose, glycerol, nicotine, lactic acid, isovaleric acid, #- methyl valeric acid, calcium carbonate, bentonite, casein, ammonium sulphate, sodium carboxymethyl cellulose and magnesite.
[GB1398177A]
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5583372A GB1398177A (en) | 1972-12-04 | 1972-12-04 | Smoking mixtures |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE38487L IE38487L (en) | 1974-06-04 |
| IE38487B1 true IE38487B1 (en) | 1978-03-29 |
Family
ID=10475009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE1987/73A IE38487B1 (en) | 1972-12-04 | 1973-11-05 | Smoking mixtures |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3924644A (en) |
| JP (1) | JPS4993596A (en) |
| BE (1) | BE807936A (en) |
| CA (1) | CA997644A (en) |
| DE (1) | DE2356706A1 (en) |
| FR (1) | FR2212745A5 (en) |
| GB (1) | GB1398177A (en) |
| IE (1) | IE38487B1 (en) |
| IT (1) | IT7331585A1 (en) |
| LU (1) | LU68909A1 (en) |
| NL (1) | NL7315988A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109567253A (en) * | 2019-01-25 | 2019-04-05 | 四川三联新材料有限公司 | It is a kind of to heat do not burn raw material of cigarette formula design method and application |
| CN109588753A (en) * | 2019-01-25 | 2019-04-09 | 四川三联新材料有限公司 | It is a kind of to heat do not burn cigarette tobacco leaf formulation design method and its application |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4319591A (en) * | 1972-02-09 | 1982-03-16 | Celanese Corporation | Smoking compositions |
| US4256126A (en) * | 1978-08-02 | 1981-03-17 | Philip Morris Incorporated | Smokable material and its method of preparation |
| IL84516A0 (en) * | 1986-12-12 | 1988-04-29 | Reynolds Tobacco Co R | Smoking articles comprising impact modifying agents |
| US4830028A (en) * | 1987-02-10 | 1989-05-16 | R. J. Reynolds Tobacco Company | Salts provided from nicotine and organic acid as cigarette additives |
| US5074321A (en) * | 1989-09-29 | 1991-12-24 | R. J. Reynolds Tobacco Company | Cigarette |
| US4920990A (en) * | 1988-11-23 | 1990-05-01 | R. J. Reynolds Tobacco Company | Cigarette |
| US4942888A (en) * | 1989-01-18 | 1990-07-24 | R. J. Reynolds Tobacco Company | Cigarette |
| US5092353A (en) * | 1989-01-18 | 1992-03-03 | R. J. Reynolds Tobacco Company | Cigarette |
| US5105836A (en) * | 1989-09-29 | 1992-04-21 | R. J. Reynolds Tobacco Company | Cigarette and smokable filler material therefor |
| US5148821A (en) * | 1990-08-17 | 1992-09-22 | R. J. Reynolds Tobacco Company | Processes for producing a smokable and/or combustible tobacco material |
| US20030014947A1 (en) * | 2001-07-19 | 2003-01-23 | Sarojini Deevi | Laminated metal foil packaging material and method of making |
| US8408216B2 (en) * | 2004-12-22 | 2013-04-02 | Philip Morris Usa Inc. | Flavor carrier for use in smoking articles |
| US20070074733A1 (en) * | 2005-10-04 | 2007-04-05 | Philip Morris Usa Inc. | Cigarettes having hollow fibers |
| US8113215B2 (en) * | 2007-06-21 | 2012-02-14 | Philip Morris Usa Inc. | Smoking article filter having liquid additive containing tubes therein |
| CN102894480B (en) * | 2012-10-23 | 2014-03-05 | 肖昌义 | Cigarette filter |
| EP3534730A2 (en) * | 2016-11-04 | 2019-09-11 | British American Tobacco (Investments) Limited | Composition useful to simulate tobacco aroma |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3125098A (en) * | 1964-03-17 | osborne | ||
| US2171986A (en) * | 1937-08-13 | 1939-09-05 | Poetschke Paul | Paper and paper making |
| US2766145A (en) * | 1954-07-26 | 1956-10-09 | Reynolds Tobacco Co R | Tobacco |
| GB1113979A (en) * | 1966-05-19 | 1968-05-15 | Ici Ltd | Modified carbohydrate material for smoking mixtures |
| US3461879A (en) * | 1967-06-30 | 1969-08-19 | Celanese Corp | Oxidized cellulose tobacco substitute composition |
-
1972
- 1972-12-04 GB GB5583372A patent/GB1398177A/en not_active Expired
-
1973
- 1973-11-05 IE IE1987/73A patent/IE38487B1/en unknown
- 1973-11-13 US US415427A patent/US3924644A/en not_active Expired - Lifetime
- 1973-11-13 DE DE2356706A patent/DE2356706A1/en active Pending
- 1973-11-20 CA CA186,253A patent/CA997644A/en not_active Expired
- 1973-11-21 IT ITMI1973A31585A patent/IT7331585A1/en unknown
- 1973-11-22 NL NL7315988A patent/NL7315988A/xx unknown
- 1973-11-28 BE BE138280A patent/BE807936A/en unknown
- 1973-12-03 JP JP48135638A patent/JPS4993596A/ja active Pending
- 1973-12-03 LU LU68909A patent/LU68909A1/xx unknown
- 1973-12-03 FR FR7343066A patent/FR2212745A5/fr not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109567253A (en) * | 2019-01-25 | 2019-04-05 | 四川三联新材料有限公司 | It is a kind of to heat do not burn raw material of cigarette formula design method and application |
| CN109588753A (en) * | 2019-01-25 | 2019-04-09 | 四川三联新材料有限公司 | It is a kind of to heat do not burn cigarette tobacco leaf formulation design method and its application |
| CN109588753B (en) * | 2019-01-25 | 2021-08-13 | 四川三联新材料有限公司 | A formula design method and application of heat-not-burn tobacco leaf group |
| CN109567253B (en) * | 2019-01-25 | 2022-04-22 | 四川三联新材料有限公司 | A kind of heat-not-burn cigarette raw material formulation design method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2356706A1 (en) | 1974-06-06 |
| GB1398177A (en) | 1975-06-18 |
| IE38487L (en) | 1974-06-04 |
| FR2212745A5 (en) | 1974-07-26 |
| US3924644A (en) | 1975-12-09 |
| IT7331585A1 (en) | 1975-05-21 |
| BE807936A (en) | 1974-05-28 |
| CA997644A (en) | 1976-09-28 |
| NL7315988A (en) | 1974-06-06 |
| JPS4993596A (en) | 1974-09-05 |
| LU68909A1 (en) | 1974-02-11 |
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