IE36374L - 4-hydroxy-benzodioxoles - Google Patents
4-hydroxy-benzodioxolesInfo
- Publication number
- IE36374L IE36374L IE720590A IE59072A IE36374L IE 36374 L IE36374 L IE 36374L IE 720590 A IE720590 A IE 720590A IE 59072 A IE59072 A IE 59072A IE 36374 L IE36374 L IE 36374L
- Authority
- IE
- Ireland
- Prior art keywords
- alkyl
- compound
- alkanoyl
- hydrogen
- benzodioxoles
- Prior art date
Links
- XRSKRSVTUVLURN-UHFFFAOYSA-N 1,3-benzodioxol-4-ol Chemical class OC1=CC=CC2=C1OCO2 XRSKRSVTUVLURN-UHFFFAOYSA-N 0.000 title abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- 125000001589 carboacyl group Chemical group 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 abstract 2
- CKDWPUIZGOQOOM-UHFFFAOYSA-N Carbamyl chloride Chemical compound NC(Cl)=O CKDWPUIZGOQOOM-UHFFFAOYSA-N 0.000 abstract 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 125000000304 alkynyl group Chemical group 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 229940079877 pyrogallol Drugs 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
1386095 4-Hydroxybenzodioxoles FISONS Ltd 25 April 1972 [4 May 1971] 12870/71 Heading C2C Pyrogallol is reacted with a ketal where R<SP>1</SP> and R<SP>2</SP> are C 1-4 alkyl or together are C 5-7 alkylene and R<SP>3</SP> and R<SP>4</SP> are C 1-4 alkyl, at at least 90‹ C., to form a compound (II) and, if desired, the latter is converted to a compound (I), where R<SP>5</SP> is hydrogen, C 1-4 alkyl or C 2-5 alkanoyl and R<SP>6</SP> is C 1-4 alkyl, C 2-4 alkenyl or C 2-4 alkynyl by reaction with an isocyanate- R<SP>6</SP>NCO, a carbamyl chloride ClCONR<SP>5</SP>R<SP>6</SP> (R<SP>5</SP> is C 2-4 alkanoyl), phosgene and then HNR<SP>5</SP>R<SP>6</SP>, or acylating a compound (I) where R<SP>5</SP> is hydrogen, made by one of the above reactions. The compounds of Formula (I) have insecticidal properties.
[GB1386095A]
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1287071A GB1386095A (en) | 1971-05-04 | 1971-05-04 | Preparation of 4-hydroxybenzodioxoles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE36374L true IE36374L (en) | 1972-11-04 |
| IE36374B1 IE36374B1 (en) | 1976-10-27 |
Family
ID=10012653
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE590/72A IE36374B1 (en) | 1971-05-04 | 1972-05-04 | Preparation of 4-hydroxybenzodioxoles |
Country Status (14)
| Country | Link |
|---|---|
| JP (1) | JPS5627517B1 (en) |
| CH (1) | CH540249A (en) |
| CS (1) | CS161946B2 (en) |
| DD (1) | DD104788A5 (en) |
| DE (1) | DE2221706C2 (en) |
| ES (2) | ES402328A1 (en) |
| FR (1) | FR2135234B1 (en) |
| GB (1) | GB1386095A (en) |
| HU (2) | HU168628B (en) |
| IE (1) | IE36374B1 (en) |
| IL (1) | IL39343A (en) |
| IT (1) | IT954963B (en) |
| NL (1) | NL179383C (en) |
| YU (1) | YU35251B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1579422A (en) * | 1976-05-08 | 1980-11-19 | Fisons Ltd | 2,2 - dimethyl-1,3 - benzodioxol - 4 - yl - n - methylcarbamate |
| EP0007398A1 (en) * | 1978-06-08 | 1980-02-06 | F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft | N-thio-N-methyl carbamic acid derivative, process for its preparation, its application and pesticides containing it |
| CN112341424B (en) * | 2020-11-20 | 2022-03-18 | 湖南海利常德农药化工有限公司 | Synthesis method of 4-hydroxy-2, 2-dimethyl-1, 3-benzodioxole |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1220056A (en) * | 1967-02-21 | 1971-01-20 | Fisons Pest Control Ltd | Substituted benzodioxoles |
-
1971
- 1971-05-04 GB GB1287071A patent/GB1386095A/en not_active Expired
-
1972
- 1972-05-03 HU HUFI557A patent/HU168628B/hu not_active IP Right Cessation
- 1972-05-03 IT IT23844/72A patent/IT954963B/en active
- 1972-05-03 IL IL39343A patent/IL39343A/en unknown
- 1972-05-03 ES ES402328A patent/ES402328A1/en not_active Expired
- 1972-05-03 HU HUFI516A patent/HU165344B/hu not_active IP Right Cessation
- 1972-05-03 FR FR7215623A patent/FR2135234B1/fr not_active Expired
- 1972-05-03 YU YU1159/72A patent/YU35251B/en unknown
- 1972-05-03 CS CS2985A patent/CS161946B2/cs unknown
- 1972-05-03 CH CH657372A patent/CH540249A/en not_active IP Right Cessation
- 1972-05-04 IE IE590/72A patent/IE36374B1/en unknown
- 1972-05-04 DD DD162749A patent/DD104788A5/xx unknown
- 1972-05-04 NL NLAANVRAGE7206043,A patent/NL179383C/en not_active IP Right Cessation
- 1972-05-04 DE DE2221706A patent/DE2221706C2/en not_active Expired
- 1972-05-04 JP JP4379272A patent/JPS5627517B1/ja active Pending
-
1974
- 1974-08-31 ES ES429711A patent/ES429711A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1386095A (en) | 1975-03-05 |
| NL179383C (en) | 1986-09-01 |
| NL7206043A (en) | 1972-11-07 |
| HU165344B (en) | 1974-08-28 |
| DE2221706A1 (en) | 1972-12-07 |
| ES402328A1 (en) | 1975-10-16 |
| CS161946B2 (en) | 1975-06-10 |
| HU168628B (en) | 1976-06-28 |
| DD104788A5 (en) | 1974-03-20 |
| NL179383B (en) | 1986-04-01 |
| YU35251B (en) | 1980-10-31 |
| IL39343A (en) | 1975-04-25 |
| ES429711A1 (en) | 1976-08-16 |
| YU115972A (en) | 1980-04-30 |
| DE2221706C2 (en) | 1985-10-03 |
| IE36374B1 (en) | 1976-10-27 |
| FR2135234A1 (en) | 1972-12-15 |
| FR2135234B1 (en) | 1978-03-03 |
| IL39343A0 (en) | 1972-07-26 |
| CH540249A (en) | 1973-08-15 |
| JPS5627517B1 (en) | 1981-06-25 |
| IT954963B (en) | 1973-09-15 |
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