HRP990391B1 - Activating composition of metallocene complexes in the catalysis of (co)polymerization processes of olefins - Google Patents
Activating composition of metallocene complexes in the catalysis of (co)polymerization processes of olefinsInfo
- Publication number
- HRP990391B1 HRP990391B1 HR990391A HRP990391A HRP990391B1 HR P990391 B1 HRP990391 B1 HR P990391B1 HR 990391 A HR990391 A HR 990391A HR P990391 A HRP990391 A HR P990391A HR P990391 B1 HRP990391 B1 HR P990391B1
- Authority
- HR
- Croatia
- Prior art keywords
- group
- fluorinated
- fluorine
- groups
- arf
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 230000003213 activating effect Effects 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 title 1
- 238000006555 catalytic reaction Methods 0.000 title 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 5
- 229910052731 fluorine Inorganic materials 0.000 abstract 5
- 239000011737 fluorine Substances 0.000 abstract 5
- 125000003118 aryl group Chemical group 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 230000000737 periodic effect Effects 0.000 abstract 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/16—Preparation of halogenated hydrocarbons by replacement by halogens of hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
- C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
- C07C17/266—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions of hydrocarbons and halogenated hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
- C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
- C07C17/269—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions of only halogenated hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
- C07C25/18—Polycyclic aromatic halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
- C07C25/18—Polycyclic aromatic halogenated hydrocarbons
- C07C25/22—Polycyclic aromatic halogenated hydrocarbons with condensed rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Organometalna kompozicija, pogodna da kao aktivator metalocenskog kompleksa metala iz 4. grupe periodičkog sustava elemenata formira katalizator za proces (ko)polimerizacije α-olefina, naznačenatime da se sastoji od produkta reakcije između: (A) fluoriranog organskog spoja, koji sadrži najmanje jedan di-nezasićeni krug s 5 ili 6 atoma ugljika, koji ima slijedeću formulu (I): gdje: svaka Ri grupa (i je cijeli broj od 1 do 7) je supstituent di-nezasićenog kruga, nezavisno izabranog od vodika, fluora i fluorirane ili nefluorirane alifatičkeili aromatične ugljikovodične grupe, koja ima od 1 do 20 atoma ugljika, izborno povezana s različitom Ri ugljikovodičnom grupom ćime se formira sljedeći krug, pod uvjetom da su najmanje dvije, još bolje najmanje tri od grupa R1, R2, R3, R4 ili R5, nezavisno izabrane iz grupe koja se sastoji od: fluora, ilifluorirane alkil grupe koja ima formulu -CF(R9R10), pri čemu svaka R9 ili R10 grupa može biti bilo koja od gore spomenutih Ri grupa, a najmanje jedna od njih je fluor, ili fluorirani alkil barna poziciji 1, ili fluorirana aril grupa ArF, kaošto je objašnjeno u daljem tekstu, ili fluoriranavinil grupa VF, kao što je dalje objašnjeno, ili fluorirana aril grupa ArF , supstituirana na aromatičnom prstenu s najmanje dvije grupe izabrane od fluora, -CF(R9R10) grupe kao što je gore navedeno,ili različite Arf grupe, ilifluorirana vinil grupa VF supstituirana na najmanje dvije pozicije s dvostrukim vezama s grupama izabranim od fluora, -CF(R9R10) grupe ili neke ArFf grupe kao što je gore navedeno; R8 grupa je vodik, -OH, -SH, ili zajednosa spomenutom R5 grupom formira ugljik-kisik vezu; i"m" može imati vrijednost 0 ili 1; (B) organometalni spoj koje ima slijedeću formulu (II) M' RnX(p-n) (II) gdje je: M' metal grupe 2 ili 13 periodičkog sustava elemenata; svaki R je nezavisna ugljikovodična grupa koja ima od 1 do 10 atoma ugljika; svaki X je atom halogena; "p" je valentnost od M' i uvijek je jednaka 2 za grupu 2 te 3 za grupu 13, "n" je decimalni broj koji ima vrijednost od 1 do p. Patent sadrži još 27 patentnih zahtjeva.Organometallic composition, suitable as an activator of the metallocene metal complex from the 4th group of the Periodic Table of the Elements, forming a catalyst for the process of (co) polymerization of α-olefins, characterized in that it consists of a reaction product between: (A) fluorinated organic compound containing at least one di - an unsaturated ring having 5 or 6 carbon atoms, having the following formula (I): wherein: each R 1 group (and is an integer from 1 to 7) is a substituent of a di-unsaturated ring, independently selected from hydrogen, fluorine and fluorinated or non-fluorinated an aliphatic or aromatic hydrocarbon group having from 1 to 20 carbon atoms optionally attached to a different R 1 hydrocarbon group to form the next ring, provided that at least two, more preferably at least three of the groups R 1, R 2, R 3, R 4 or R 5, independently selected from the group consisting of: fluorine, or a fluorinated alkyl group having the formula -CF (R9R10), wherein each R9 or R10 group may be any of the abovementioned R1 groups, and at least one of which is fluorine, or a fluorinated alkyl barne at position 1, or a fluorinated aryl group ArF, as explained below, or a fluorinated vinyl group VF, as further explained, or a fluorinated aryl group ArF, substituted on an aromatic ring with at least two groups selected from fluorine, -CF (R9R10) group as mentioned above, or different Arf groups, or fluorinated vinyl group VF substituted at at least two positions with double bonds with groups selected from fluorine, -CF (R9R10) group or some ArFf group as which is stated above; The R8 group is hydrogen, -OH, -SH, or together with said R5 group forms a carbon-oxygen bond; and "m" may have a value of 0 or 1; (B) an organometallic compound having the following formula (II) M 'RnX (p-n) (II) wherein: M' is a metal of group 2 or 13 of the periodic table; each R is an independent hydrocarbon group having from 1 to 10 carbon atoms; each X is a halogen atom; "p" is the valence of M 'and is always equal to 2 for group 2 and 3 for group 13, "n" is a decimal number having a value from 1 to p. The patent contains another 27 claims.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1998MI002718A IT1304181B1 (en) | 1998-12-17 | 1998-12-17 | ACTIVATING COMPOSITION OF METALLOCENIC COMPLEXES IN THE CATALYSIS OF (CO) POLYMERIZATION OF OLEFINS. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| HRP990391A2 HRP990391A2 (en) | 2000-10-31 |
| HRP990391B1 true HRP990391B1 (en) | 2006-11-30 |
Family
ID=11381260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HR990391A HRP990391B1 (en) | 1998-12-17 | 1999-12-17 | Activating composition of metallocene complexes in the catalysis of (co)polymerization processes of olefins |
Country Status (30)
| Country | Link |
|---|---|
| US (1) | US6596891B1 (en) |
| EP (1) | EP1013675B1 (en) |
| JP (1) | JP4808297B2 (en) |
| KR (1) | KR100388280B1 (en) |
| CN (1) | CN1137157C (en) |
| AR (1) | AR023354A1 (en) |
| AT (1) | ATE221545T1 (en) |
| AU (1) | AU770138B2 (en) |
| BG (1) | BG64129B1 (en) |
| BR (1) | BR9905894B1 (en) |
| CA (1) | CA2292243C (en) |
| CZ (1) | CZ300869B6 (en) |
| DE (1) | DE69902343T2 (en) |
| DK (1) | DK1013675T3 (en) |
| EA (1) | EA003246B1 (en) |
| ES (1) | ES2179594T3 (en) |
| HR (1) | HRP990391B1 (en) |
| HU (1) | HU228311B1 (en) |
| ID (1) | ID24013A (en) |
| IT (1) | IT1304181B1 (en) |
| MY (1) | MY118967A (en) |
| NO (1) | NO324453B1 (en) |
| NZ (1) | NZ501743A (en) |
| PL (1) | PL197085B1 (en) |
| PT (1) | PT1013675E (en) |
| SI (1) | SI1013675T1 (en) |
| SK (1) | SK285306B6 (en) |
| TR (1) | TR199903132A2 (en) |
| TW (1) | TW462971B (en) |
| UA (1) | UA70920C2 (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2001277556A1 (en) * | 2000-08-09 | 2002-02-18 | Bayer Aktiengesellschaft | Catalyst system for the polymerisation of olefins |
| DE10044981A1 (en) * | 2000-09-11 | 2002-03-21 | Bayer Ag | Catalyst system for the polymerization of dienes |
| ITMI20011017A1 (en) | 2001-05-17 | 2002-11-17 | Enichem Spa | PROCEDURE FOR THE PREPARATION OF EP (D) M COPOLYMERS AND ELASTOMERIC TERPOLYMERS |
| BR0211290A (en) | 2001-07-19 | 2004-09-14 | Univation Tech Llc | Low comonomer incorporation metallocene catalyst compounds |
| ITMI20011554A1 (en) | 2001-07-20 | 2003-01-20 | Enichem Spa | ACTIVATING COMPOSITION FOR THE (CO) POLYMERIZATION OF ALPHA-OLEFINS INCLUDING FLUORINATED CYCLOPENTADIENYL COMPOUNDS |
| ITMI20012516A1 (en) | 2001-11-30 | 2003-05-30 | Enichem Spa | PROCEDURE FOR THE PREPARATION OF ETHYLENE COPOLYMERS HAVING A WIDE DISTRIBUTION OF MOLECULAR WEIGHTS |
| ITMI20022054A1 (en) * | 2002-09-27 | 2004-03-28 | Polimeri Europa Spa | CATALYTIC COMPOSITION FOR THE (CO) POLYMERIZATION OF ALPHA-OLEFINS. |
| KR101186489B1 (en) * | 2008-01-07 | 2012-09-27 | 에스케이이노베이션 주식회사 | Transition metal complexes, and catalysts compositions for preparing ethylnene homopolymers or copolymers |
| KR101142115B1 (en) | 2008-01-07 | 2012-07-06 | 에스케이이노베이션 주식회사 | Transition metal complexes, catalysts composition containing the same, and methods for preparing ethylene homopolymers or copolymers of ethylene and -olefins using the same |
| JP2009249355A (en) * | 2008-04-08 | 2009-10-29 | Kanto Denka Kogyo Co Ltd | Fluorinated fluorene derivative and method for producing the same |
| KR101142117B1 (en) * | 2008-09-25 | 2012-05-09 | 에스케이이노베이션 주식회사 | Transition metal catalytic systems and methods for preparing ethylene homopolymers or copolymers of ethylene and ?-olefins using the same |
| CN111057029B (en) * | 2018-10-17 | 2021-12-10 | 北京师范大学 | Fluorine-containing cationic polymerization monomer and synthesis and application thereof |
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| US11186665B2 (en) | 2019-10-04 | 2021-11-30 | Chevron Phillips Chemical Company Lp | Catalyst composition and method for preparing polyethylene |
| EP4077414A1 (en) * | 2019-12-19 | 2022-10-26 | Dow Global Technologies LLC | Gas-phase biphenylphenol polymerization catalysts |
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