HK1167676B - Gasification reactor for producing crude gas containing co or h2 - Google Patents

Description

For producing CO or H2Raw gas gasification reactor

Technical Field

The invention relates to a method for producing a catalyst containing CO or H₂A gasification reactor for the raw gas.

Background

Such gasification reactors are known, for example, from WO2009/036985a1 of the present applicant, wherein numerous other prior art documents are also mentioned in this document, for example US4474584, which relates in particular to cooling of high-temperature synthesis gas.

The present invention is directed in particular to solving the problems arising in such reactors, and is not exclusively limited to gasification reactors as described herein, but also to such plants in which similar problems as described in detail below may arise.

Such a plant must be suitable for implementing a process for high-pressure gasification/combustion of finely distributed fuels, including the partial oxidation of fuels, coal dust, finely distributed biomass, oils, tars and the like in a reactor. It also includes extracting the residue or fly ash and the produced synthesis gas or raw gas separately or together. It must be possible to cool the reaction products (gases and residues/fly ash), for example by spray quenching, blow quenching, radiant quenching, convection heating surfaces, etc., depending on the type of process used, and finally it must also be noted that the reaction products are drawn off from the pressure vessel.

In the above-mentioned WO2009/036985a1, a vortex is formed in order to be able to convert coarser particles completely and to protect critical areas of the heating surface against excessively high heat flow densities. This is achieved by a burner positioning adjustment of 1 to 20 ° in the horizontal plane. The vortex formed after leaving the gasifier must be removed again from the flow, whereby the hot, viscous slag particles are thrown against the unprotected heating surface of the protective pressure vessel and form a slag cake on the heating surface or cause damage.

A corresponding eddy-current braking device is described, for example, in DE 102009005464.2.

Disclosure of Invention

The object of the invention is to propose a solution with which on the one hand a discharged ash forming stream can be achieved and on the other hand a further residue dripping edge is provided which serves to ensure an optimum discharge of the residue.

According to the invention, in a gasifier of the type mentioned at the outset, the object is achieved in that the wall supporting the baffle below the baffle transitions via a step with a corrugated surface into a cylindrical wall of reduced diameter.

The wavy surface and the low points below the partition wall ensure that the residues can be discharged from the trough in a targeted stream, so that no closed residue film is formed.

In addition, it is provided that the reduced-diameter cylindrical wall is surrounded by a second enlarged-diameter cylindrical wall which forms a second drip edge at its end in the direction of gravity, wherein it is provided in particular that the second cylindrical wall is adjustably arranged in its vertical position relative to the first drip edge.

The term "adjustability" is used here to mean an optimum adjustment of the drip edge according to existing and operating-condition-dependent specifications. After optimization, in particular during the operation of the reactor, no further adjustability is necessary.

The invention also provides that the cylindrical second drip edge is surrounded by a further cylindrical wall of enlarged diameter which surrounds at least a part of the gas transition region. In practice, the outer cylindrical wall defines a transition into the quench zone or channel.

The invention also provides that at least one partition of the eddy current brake system is equipped with a device for measuring the heat flux density.

In one possible embodiment, the invention provides that the second cylindrical wall and the further cylindrical wall are provided with smooth, flat and corrosion-resistant surfaces, for example by using an electroplated super Ω tube arrangement, wherein the turbulence-reducing baffles, the corrugated transition surfaces and the cylindrical wall providing the first drop edge are designed as a standard tube-web-wall structure with convex pins (bestfung) and a real-pressure part (besampfang).

Drawings

Other details, features and advantages of the invention will appear from the following description taken in conjunction with the accompanying drawings. Wherein

Figure 1 shows a schematic cross-sectional view of a gasification reactor according to the invention,

FIG. 2 shows a schematic cross-sectional view of one half of a gasification reactor in the transition region from the reaction chamber to a quench chamber, which is not shown in detail, an

Fig. 3 shows a modification of the reactor region forming the transition channel with the eddy current brake.

Detailed Description

The gasification reactor shown in fig. 1 and designated as a whole by 1 has a pressure vessel 2, in which a reaction chamber 4 surrounded by a membrane wall 3 is arranged from top to bottom at a distance from the pressure vessel 2. The coolant feed line for loading the membrane wall 3 is indicated by 5. The membrane wall 3 merges via a lower cone 6 into a narrowing channel which is part of a transition region designated by 8, wherein a vortex brake 9 is shown in the narrowing transition channel 7. The drop edge in the transition zone 8, which is intended for the liquid ash in the transition zone 8 and is at a distance from the first drop edge 10 of the transition channel 7, is denoted by 10 a.

A quench chamber or channel 11 is connected to the transition zone 8, followed by a residue collection vessel 12 in a water basin 13.

As shown in fig. 2 and 3, the wall 14 provided with the partition 9 forming the eddy current brake merges into a step 15 having a wavy surface, which is shown in fig. 3, wherein the individual waves are indicated by 16. On said surface is in turn connected a smooth, diameter-changing cylindrical wall 17, which cylindrical wall 17 provides a first drop edge 18.

The transition channel 7, the structure for bundling residues comprising the transition between the wall 19 and the wall 18, is surrounded by a further cylindrical wall 19, which further cylindrical wall 19 is connected gas-tightly with a cylindrical wall 21 surrounding the transition chamber 8 via a wall plate 20 shown obliquely in fig. 2.

One particular aspect is that a cylindrical wall 19 surrounding the transition channel 7 provides a further, second drip edge, indicated at 10. According to the invention, the system of cylindrical wall 19 and wall plate 20 is adjustable or adjustable in height, which is indicated by arrow 22. The sealing or transition region of the respective pipe through which the coolant flows, which region achieves this adjustability, is only schematically illustrated in fig. 2 and designated by 23 and 24.

Fig. 2 shows only schematically that at least one of the partitions 9 of the eddy current brake can be equipped with a device 25 for measuring the heat flux density.

The described embodiments of the invention may of course be varied in many ways without departing from the basic idea of the invention. The undulations 16 in the wall steps shown in the modification of fig. 3 can be angular or curved, the distribution of the ducts can be different for the respective wall regions, and the like, depending on the application.

Claims (5)

1. For producing CO or H₂Wherein a reaction chamber is provided inside a pressure vessel, which reaction chamber is formed by a diaphragm wall through which a coolant flows and which reaction chamber has a gradually narrowing transition channel leading into a gas cooling chamber, wherein a cooled baffle plate is provided in the transition channel, which baffle plate reduces turbulence, characterized in that:

-the wall (14) supporting the diaphragm (9) below the diaphragm transitions via a step (15) with a wavy surface into a cylindrical wall (17) of reduced diameter, which cylindrical wall (17) provides a first drop edge (18);

-the reduced diameter cylindrical wall (17) is surrounded by a second enlarged diameter cylindrical wall (19) forming a second drop edge (10) on its end in the direction of gravity;

-the second cylindrical wall (19) is adjustably arranged in its vertical position with respect to the first drop edge (18).

2. A gasification reactor according to claim 1, characterised in that the cylindrical second drip edge (10) is surrounded by a further cylindrical wall (21) of increased diameter which surrounds at least a part of the gas transition zone (8) into the quench zone or channel of the gasification reactor.

3. A gasification reactor according to claim 1 or 2, characterised in that at least one partition (9) constituting the vortex brake is equipped with means for measuring the heat flow density.

4. A gasification reactor according to claim 2 wherein the second cylindrical wall (19) and the further cylindrical wall (21) are provided with smooth, flat and corrosion resistant surfaces, wherein the turbulence reducing baffle (9), the corrugated surface (16) and the cylindrical wall (17) providing the first drop edge (18) constitute a standard tube-web-wall structure with a boss portion and a compacted portion.

5. A gasification reactor according to claim 4 wherein the second cylindrical wall (19) and the further cylindrical wall (21) are provided with smooth, flat and corrosion resistant surfaces by using electroplated super Ω -tubes.