GB989212A - Process for the production of cationic exchanger resins - Google Patents
Process for the production of cationic exchanger resinsInfo
- Publication number
- GB989212A GB989212A GB1169963A GB1169963A GB989212A GB 989212 A GB989212 A GB 989212A GB 1169963 A GB1169963 A GB 1169963A GB 1169963 A GB1169963 A GB 1169963A GB 989212 A GB989212 A GB 989212A
- Authority
- GB
- United Kingdom
- Prior art keywords
- benzene
- treated
- sulphonation
- resins
- active agents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005989 resin Polymers 0.000 title abstract 3
- 239000011347 resin Substances 0.000 title abstract 3
- 125000002091 cationic group Chemical group 0.000 title abstract 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- 239000000725 suspension Substances 0.000 abstract 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- QARVLSVVCXYDNA-UHFFFAOYSA-N bromobenzene Chemical compound BrC1=CC=CC=C1 QARVLSVVCXYDNA-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 229940116441 divinylbenzene Drugs 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 2
- -1 oleum Chemical compound 0.000 abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 229920002554 vinyl polymer Polymers 0.000 abstract 2
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical group ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001491 aromatic compounds Chemical class 0.000 abstract 1
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical group C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 125000003700 epoxy group Chemical group 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000347 magnesium hydroxide Substances 0.000 abstract 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 abstract 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000391 magnesium silicate Substances 0.000 abstract 1
- 229910052919 magnesium silicate Inorganic materials 0.000 abstract 1
- 235000019792 magnesium silicate Nutrition 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical class NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 abstract 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 230000008961 swelling Effects 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Cationic exchanger resins are produced by pearl copolymerization of a mixture of one or more polyvinyl hydrocarbons and monovinyl aromatic compounds in suspension in the presence of 0.1-10% polar vinyl, epoxy group containing compounds or organic solvents and of insoluble in water inorganic suspension stabilizers and of non-ionic surface active agents, the copolymers being swollen with 15-40% of halogenated hydrocarbon, sulphonated and after removal of excess sulphonation agent, treated with steam. The copolymer may be based on styrene and divinyl benzene. The sulphonation may be carried out with sulphuric acid, oleum, chlorosulphonic acid and/or liquid sulphur trioxide. The steam treatment may be carried out at 100-250 DEG C. The suspension stabilizers may be magnesium silicate or hydroxide, hydroxy-apatite or barium sulphate and the surface active agents may be mono-fatty acid esters of polybasic watersoluble alcohols, paraffin sulphamides and polyethylene oxide. The swelling agent may be a chloro-methane, -ethane, -ethylene, -benzene or -toluene or bromobenzene. The resins may be treated with sodium sulphate or hydroxide solutions. In examples styrene and divinyl-benzene were polymerized with acrylonitrile or epichlorohydrin using dibenzoyl or dilauryl peroxide or azo-bis-isobutyric acid nitrile as catalyst.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1169963A GB989212A (en) | 1963-03-25 | 1963-03-25 | Process for the production of cationic exchanger resins |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1169963A GB989212A (en) | 1963-03-25 | 1963-03-25 | Process for the production of cationic exchanger resins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB989212A true GB989212A (en) | 1965-04-14 |
Family
ID=9991077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1169963A Expired GB989212A (en) | 1963-03-25 | 1963-03-25 | Process for the production of cationic exchanger resins |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB989212A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0185161A1 (en) * | 1984-10-25 | 1986-06-25 | Bayer Ag | Macroporous bead polymers for the purification of acarbose |
| CN114409838A (en) * | 2022-01-14 | 2022-04-29 | 王义成 | Cation exchange resin, preparation method thereof and application in recycling copper-vanadium catalyst |
-
1963
- 1963-03-25 GB GB1169963A patent/GB989212A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0185161A1 (en) * | 1984-10-25 | 1986-06-25 | Bayer Ag | Macroporous bead polymers for the purification of acarbose |
| US4666776A (en) * | 1984-10-25 | 1987-05-19 | Bayer Aktiengesellschaft | Polymers for the purification of acarbose |
| CN114409838A (en) * | 2022-01-14 | 2022-04-29 | 王义成 | Cation exchange resin, preparation method thereof and application in recycling copper-vanadium catalyst |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2500149A (en) | Sulfonation of copolymers of monovinyl-and polyvinyl-aromatic compounds | |
| GB1552060A (en) | Process for producing fluorinated copolymer having ion-exchange groups | |
| FR2161115B1 (en) | ||
| GB1116800A (en) | A process for the production of ion exchange resins | |
| GB1064425A (en) | Emulsion polymerisation process | |
| GB989212A (en) | Process for the production of cationic exchanger resins | |
| GB714367A (en) | Improvements in or relating to cation-exchange polymers | |
| GB967772A (en) | Improvements relating to polyethylene imine anion exchange resins | |
| GB1034051A (en) | Cation exchange resin and process for the manufacture thereof | |
| US3340238A (en) | Method for producing polymers of vinyl aromatic sulfonates characterized useful as flocculants | |
| GB997290A (en) | Cation exchange resins | |
| KR860004097A (en) | Process for preparing anion exchange resin with very low chlorine content | |
| JPH0741170B2 (en) | Cation exchange resin for ammonia cycle condensate polishing with selectivity for sodium | |
| KR840001185A (en) | Method for preparing cation exchange resin | |
| GB960049A (en) | Improvements in or relating to cation exchange resins | |
| FR2354348A1 (en) | SULPHONES COPOLYMERS AND STYRENE AND POLYSTYRENE CROSS-LINES AND THEIR PREPARATION PROCESS | |
| GB659775A (en) | Production of sulphonated ion exchange resins in stable granular form | |
| US2235971A (en) | Organolite | |
| GB766764A (en) | Removal of heavy metal ions from non-aqucous sulphur trioxide solutions | |
| SU146941A1 (en) | Method for producing sulfhydryl type electron exchange resins | |
| Novoselova et al. | Polypropylene fibre with graft styrene. Part 1 | |
| SU151818A1 (en) | The method of producing copolymers | |
| GB896739A (en) | Improvements in or relating to polyalkylene base material | |
| GB1065479A (en) | Process for brominating water and aqueous solutions | |
| GB1072749A (en) | Process for producing sulphonated cation exchangers |