GB976822A - New bistriazinylaminostilbene derivatives - Google Patents
New bistriazinylaminostilbene derivativesInfo
- Publication number
- GB976822A GB976822A GB42276/62A GB4227662A GB976822A GB 976822 A GB976822 A GB 976822A GB 42276/62 A GB42276/62 A GB 42276/62A GB 4227662 A GB4227662 A GB 4227662A GB 976822 A GB976822 A GB 976822A
- Authority
- GB
- United Kingdom
- Prior art keywords
- salts
- compound
- acid
- comptroller
- directed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RWFZHFYWPYSEOZ-UHFFFAOYSA-N 1,2-diphenyl-N,N'-bis(triazin-4-yl)ethene-1,2-diamine Chemical class N1=NN=C(C=C1)NC(=C(C1=CC=CC=C1)NC1=NN=NC=C1)C1=CC=CC=C1 RWFZHFYWPYSEOZ-UHFFFAOYSA-N 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 7
- 150000003839 salts Chemical class 0.000 abstract 7
- 238000005282 brightening Methods 0.000 abstract 4
- 239000003599 detergent Substances 0.000 abstract 3
- 239000004744 fabric Substances 0.000 abstract 3
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 abstract 2
- 229920000742 Cotton Polymers 0.000 abstract 2
- 239000004952 Polyamide Substances 0.000 abstract 2
- 229920000297 Rayon Polymers 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 2
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 abstract 2
- -1 dichlorotriazinyl residue Chemical group 0.000 abstract 2
- 150000002191 fatty alcohols Chemical class 0.000 abstract 2
- 239000002657 fibrous material Substances 0.000 abstract 2
- 230000003287 optical effect Effects 0.000 abstract 2
- 229920002647 polyamide Polymers 0.000 abstract 2
- WNKQDGLSQUASME-UHFFFAOYSA-N 4-sulfophthalic acid Chemical compound OC(=O)C1=CC=C(S(O)(=O)=O)C=C1C(O)=O WNKQDGLSQUASME-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 240000008564 Boehmeria nivea Species 0.000 abstract 1
- 244000025254 Cannabis sativa Species 0.000 abstract 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 abstract 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 abstract 1
- 240000000491 Corchorus aestuans Species 0.000 abstract 1
- 235000011777 Corchorus aestuans Nutrition 0.000 abstract 1
- 235000010862 Corchorus capsularis Nutrition 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 241000219146 Gossypium Species 0.000 abstract 1
- 240000006240 Linum usitatissimum Species 0.000 abstract 1
- 235000004431 Linum usitatissimum Nutrition 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 229920001131 Pulp (paper) Polymers 0.000 abstract 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 abstract 1
- 229940081735 acetylcellulose Drugs 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical class N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 238000004061 bleaching Methods 0.000 abstract 1
- 159000000007 calcium salts Chemical class 0.000 abstract 1
- 235000009120 camo Nutrition 0.000 abstract 1
- 239000011111 cardboard Substances 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- 229920001727 cellulose butyrate Polymers 0.000 abstract 1
- 235000005607 chanvre indien Nutrition 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000007859 condensation product Substances 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 abstract 1
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 210000003746 feather Anatomy 0.000 abstract 1
- 210000004209 hair Anatomy 0.000 abstract 1
- 239000011487 hemp Substances 0.000 abstract 1
- 239000010985 leather Substances 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000123 paper Substances 0.000 abstract 1
- 239000011087 paperboard Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920000151 polyglycol Polymers 0.000 abstract 1
- 239000010695 polyglycol Substances 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000002964 rayon Substances 0.000 abstract 1
- 239000000344 soap Substances 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 239000010902 straw Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical class NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/614—Optical bleaching or brightening in aqueous solvents
- D06L4/621—Optical bleaching or brightening in aqueous solvents with anionic brighteners
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paper (AREA)
- Plural Heterocyclic Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention comprises the compound <FORM:0976822/C1/1> and its salts. The compound is prepared by reacting cyanuric chloride in any desired order of succession in the molecular ratio of 2:1:2:2 with 4,41-diaminostilbene-2:21-disulphonic acid, 1-aminobenzene-4-sulphonic acid and diethylamine. Preferably, cyanuric chloride is condensed in the molecular ratio of 2:1 with 4,41-diaminostilbene-2,21-sulphonic acid to give the compound <FORM:0976822/C1/2> which is then treated to exchange one chlorine atom in each dichlorotriazinyl residue for the residue of p-aminobenzenesulphonic acid to give the compound <FORM:0976822/C1/3> the two remaining chlorine atoms each being subsequently exchanged for a diethylamino group. An example describes the preparation of the sodium salt, other specified salts being the potassium, lithium, ammonium, amine, barium and calcium salts. The compound is an optical brightening agent (see Divisions B5, C4, C5, D1). Reference has been directed by the Comptroller to Specification 705,406.ALSO:The compound <FORM:0976822/C4-C5/1> and its salts may be used as optical brightening agents in admixture with dyestuffs or pigments, as additives to dyebaths, printing, resist or reserve pastes, or i combination with detergents such as soaps, salts of sulphonate detergents such as sulphonated 2-(higher alkyl)-benzimidazoles and salts of monocarboxylic acid esters of 4-sulphophthalic acid with higher fatty alcohols, salts of fatty alcohol sulphonates, alkylarylsulphonic acids, condensation products of higher fatty acids with aliphatic hydroxysulphonic or aminosulphonic acids, and non-ionic detergents such as polyglycol ethers derived from ethylene oxide and C8-22 fatty alcohols, alkylphenols or fatty amines. Reference has been directed by the Comptroller to Specification 705,406.ALSO:The compound <FORM:0976822/D1-D2/1> and its salts are used in admixture with chemical bleaches, as additives to bleaching baths, or for optically brightening fibrous materials. The fibrous materials may be in the form of fibres, filaments, yarns, woven or knitted fabrics, or felt. Specified materials are cotton, hemp, flax, linen, jute, ramie, rayon, viscoses, cellulose butyrate, acetylcellulose, polyesters, polyamides, feathers, hairs, pelts and hides and leather made therefrom, straw, wool, wood pulp, paper and cardboard. Examples describe the brightening of paper, bleached cotton fabric and bleached polyamide fabrics of filament or staple fibres. Reference has been directed by the Comptroller to Specification 705,406.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1401561A CH405061A (en) | 1961-12-01 | 1961-12-01 | Use of a new bistriazinylaminostilbene derivative as an optical brightening agent with the exception of the treatment of textile fibers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB976822A true GB976822A (en) | 1964-12-02 |
Family
ID=4397217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB42276/62A Expired GB976822A (en) | 1961-12-01 | 1962-11-08 | New bistriazinylaminostilbene derivatives |
Country Status (5)
| Country | Link |
|---|---|
| CH (1) | CH405061A (en) |
| DE (1) | DE1301792B (en) |
| ES (1) | ES282993A1 (en) |
| FI (1) | FI41262C (en) |
| GB (1) | GB976822A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012062411A1 (en) * | 2010-11-11 | 2012-05-18 | Clariant International Ltd | Non metal tanning |
| USRE46913E1 (en) | 2008-03-26 | 2018-06-26 | Archroma Ip Gmbh | Optical brightening compositions |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103060492B (en) * | 2012-12-28 | 2015-08-26 | 苏州瑞日纺织科技有限公司 | A kind of Multifunctional fur optical brightener and preparation method thereof |
-
1961
- 1961-12-01 CH CH1401561A patent/CH405061A/en unknown
-
1962
- 1962-11-08 GB GB42276/62A patent/GB976822A/en not_active Expired
- 1962-11-30 ES ES282993A patent/ES282993A1/en not_active Expired
- 1962-11-30 FI FI622158A patent/FI41262C/en active
- 1962-11-30 DE DEC28556A patent/DE1301792B/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE46913E1 (en) | 2008-03-26 | 2018-06-26 | Archroma Ip Gmbh | Optical brightening compositions |
| WO2012062411A1 (en) * | 2010-11-11 | 2012-05-18 | Clariant International Ltd | Non metal tanning |
| US8795390B2 (en) | 2010-11-11 | 2014-08-05 | Stahl International B.V. | Non metal tanning |
| AU2011328554B2 (en) * | 2010-11-11 | 2016-10-06 | Stahl International Bv | Non metal tanning |
Also Published As
| Publication number | Publication date |
|---|---|
| CH405061A (en) | 1965-12-31 |
| FI41262C (en) | 1969-10-10 |
| DE1301792B (en) | 1969-08-28 |
| ES282993A1 (en) | 1963-06-01 |
| FI41262B (en) | 1969-06-30 |
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