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GB962777A - Hydrogenative conversion of hydrocarbon oil with activated nickel sulfide catalysts - Google Patents

Hydrogenative conversion of hydrocarbon oil with activated nickel sulfide catalysts

Info

Publication number
GB962777A
GB962777A GB3558362A GB3558362A GB962777A GB 962777 A GB962777 A GB 962777A GB 3558362 A GB3558362 A GB 3558362A GB 3558362 A GB3558362 A GB 3558362A GB 962777 A GB962777 A GB 962777A
Authority
GB
United Kingdom
Prior art keywords
nickel
catalyst
oxide
sulphide
refractory
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3558362A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
California Research LLC
Original Assignee
California Research LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US139594A external-priority patent/US3211669A/en
Application filed by California Research LLC filed Critical California Research LLC
Publication of GB962777A publication Critical patent/GB962777A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/043—Sulfides with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28—Regeneration or reactivation
    • B01J27/30—Regeneration or reactivation of catalysts comprising compounds of sulfur, selenium or tellurium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/20—Plural distinct oxidation stages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

A process for the hydrogenative treatment of hydrocarbon oils comprises contacting the oil at elevated temperature and pressure with excess hydrogen and a catalyst comprising nickel sulphide on a refractory support, the catalyst having been activated by sequentially converting the nickel component first to NiO, then to reduced Ni, then back to NiO and finally to nickel sulphide. The refractory support is usually Al2O3 and the catalyst may additionally contain Mo. Examples describe the catalytic treatment of hydrocarbons ranging from light naphthas to heavy gas oils at temperatures from 600 DEG to 800 DEG F., pressures of 800 to 1100 p.s.i.g., and 0.3 to 7 L.H.S.V. Specification 962,778 is referred to.ALSO:A catalyst comprising nickel sulphide on a refractory oxide support is activated by sequentially converting the nickel present to nickel oxide, then to nickel, then back to nickel oxide and finally to nickel sulphide. Additionally the catalyst may contain Mo and Al2O3 is the preferred refractory oxide. However, other specified catalyst constituents are metals of Group VIII, VIa and Ib of the Periodic Table and silica, magnesia and naturally occurring clays. Examples are given. Specification 962,778 is referred to.
GB3558362A 1961-09-21 1962-09-18 Hydrogenative conversion of hydrocarbon oil with activated nickel sulfide catalysts Expired GB962777A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US139594A US3211669A (en) 1961-09-21 1961-09-21 Activating and reactivating nickel sulfide catalysts

Publications (1)

Publication Number Publication Date
GB962777A true GB962777A (en) 1964-07-01

Family

ID=22487423

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3558362A Expired GB962777A (en) 1961-09-21 1962-09-18 Hydrogenative conversion of hydrocarbon oil with activated nickel sulfide catalysts

Country Status (3)

Country Link
DE (1) DE1284951B (en)
GB (1) GB962777A (en)
NL (1) NL283487A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010072836A1 (en) * 2008-12-24 2010-07-01 Shell Internationale Research Maatschappij B.V. Process for selectively sulfiding a supported nickel catalyst
CN112337488A (en) * 2020-10-28 2021-02-09 中海油天津化工研究设计院有限公司 Nickel sulfide hydrogenation catalyst and pyrolysis gasoline hydrogenation treatment method

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2398175A (en) * 1943-05-20 1946-04-09 Shell Dev The treatment of sulphide catalysts
US2671763A (en) * 1950-12-29 1954-03-09 Allied Chem & Dye Corp Regeneration of nickel-sulfidealumina type catalysts

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010072836A1 (en) * 2008-12-24 2010-07-01 Shell Internationale Research Maatschappij B.V. Process for selectively sulfiding a supported nickel catalyst
CN112337488A (en) * 2020-10-28 2021-02-09 中海油天津化工研究设计院有限公司 Nickel sulfide hydrogenation catalyst and pyrolysis gasoline hydrogenation treatment method
CN112337488B (en) * 2020-10-28 2022-07-15 中海油天津化工研究设计院有限公司 Nickel sulfide series hydrogenation catalyst and pyrolysis gasoline hydrotreating method

Also Published As

Publication number Publication date
NL283487A (en)
DE1284951B (en) 1968-12-12

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