GB949668A - Improvements in or relating to the manufacture of diphenylolpropane - Google Patents
Improvements in or relating to the manufacture of diphenylolpropaneInfo
- Publication number
- GB949668A GB949668A GB3495162A GB3495162A GB949668A GB 949668 A GB949668 A GB 949668A GB 3495162 A GB3495162 A GB 3495162A GB 3495162 A GB3495162 A GB 3495162A GB 949668 A GB949668 A GB 949668A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diphenylolpropane
- water
- organic
- diluent
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 title abstract 7
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000003085 diluting agent Substances 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000012074 organic phase Substances 0.000 abstract 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 239000008346 aqueous phase Substances 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 abstract 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 238000010025 steaming Methods 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
- C07C37/72—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by liquid-liquid treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Diphenylolpropane is obtained by the condensation of phenol and acetone in the presence of an acid catalyst and an organic diluent that is capable of forming with water and diphenylolpropane a system of liquid phases by heating to a temperature below the boiling point of the azeotrope of the organic diluent with water, said diluent being present in a proportion amounting to between 10 and 400% of the weight of the diphenylol propane to be obtained, and after completion of the reaction water is added to the reaction mixture in an amount of between 10 and 1000% of the weight of the diphenylolpropane, the mixture is heated until it is entirely liquefied, the acidic aqueous phase is separated off from the organic phase or phases, the organic part is almost completely neutralised in contact with water and is then cooled and the crystallized diphenylolpropane is collected. Residual organic diluent present in the separated diphenylolpropane may be removed therefrom by heating and/or steaming. Suitable solvents for use in the present process are aromatic hydrocarbons such as xylene and toluene, chlorinated hydrocarbons such as monochlorobenzene, 1, 2-dichloroethane and 1, 1, 2, 2-tetrachloroethane. Specifications 428,944 and 557,976 are referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3495162A GB949668A (en) | 1962-09-13 | 1962-09-13 | Improvements in or relating to the manufacture of diphenylolpropane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3495162A GB949668A (en) | 1962-09-13 | 1962-09-13 | Improvements in or relating to the manufacture of diphenylolpropane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB949668A true GB949668A (en) | 1964-02-19 |
Family
ID=10372003
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3495162A Expired GB949668A (en) | 1962-09-13 | 1962-09-13 | Improvements in or relating to the manufacture of diphenylolpropane |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB949668A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5414150A (en) * | 1993-12-03 | 1995-05-09 | The Dow Chemical Company | Preparation of 4,4'-dihydroxy-alpha-alkylstilbenes and 4,4'-dihydroxy-alpha, alpha'-dialkylstilbenes |
| US5723693A (en) * | 1996-09-13 | 1998-03-03 | The Dow Chemical Company | Process for preparing and recovering 4,4'-dihydroxy-alpha-alkylstilbene or 4,4'-dihydroxy-alpha, alpha'dialkylstilbene |
| US5723692A (en) * | 1996-09-13 | 1998-03-03 | The Dow Chemical Company | Preparation of 4,4'-dihydroxy-'alkylstiblbene with reduced dimer formation |
-
1962
- 1962-09-13 GB GB3495162A patent/GB949668A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5414150A (en) * | 1993-12-03 | 1995-05-09 | The Dow Chemical Company | Preparation of 4,4'-dihydroxy-alpha-alkylstilbenes and 4,4'-dihydroxy-alpha, alpha'-dialkylstilbenes |
| US5475155A (en) * | 1993-12-03 | 1995-12-12 | The Dow Chemical Company | Preparation of 4,4'-dihydroxy-alpha'-dialkylstilbenes and 4, 4'-dihydroxy-alpha'-dialkylstilbenes |
| US5723693A (en) * | 1996-09-13 | 1998-03-03 | The Dow Chemical Company | Process for preparing and recovering 4,4'-dihydroxy-alpha-alkylstilbene or 4,4'-dihydroxy-alpha, alpha'dialkylstilbene |
| US5723692A (en) * | 1996-09-13 | 1998-03-03 | The Dow Chemical Company | Preparation of 4,4'-dihydroxy-'alkylstiblbene with reduced dimer formation |
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