GB882569A - Liquid detergent compositions - Google Patents
Liquid detergent compositionsInfo
- Publication number
- GB882569A GB882569A GB19291/59A GB1929159A GB882569A GB 882569 A GB882569 A GB 882569A GB 19291/59 A GB19291/59 A GB 19291/59A GB 1929159 A GB1929159 A GB 1929159A GB 882569 A GB882569 A GB 882569A
- Authority
- GB
- United Kingdom
- Prior art keywords
- detergent
- abrasive
- soap
- sulphonate
- phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 239000003599 detergent Substances 0.000 title abstract 5
- 239000007788 liquid Substances 0.000 title abstract 4
- 239000000344 soap Substances 0.000 abstract 4
- 229910019142 PO4 Inorganic materials 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 3
- -1 alkali metal salt Chemical class 0.000 abstract 3
- 239000010452 phosphate Substances 0.000 abstract 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 3
- 239000000271 synthetic detergent Substances 0.000 abstract 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical compound CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 239000005639 Lauric acid Substances 0.000 abstract 1
- 239000003082 abrasive agent Substances 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 229910021538 borax Inorganic materials 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229910001651 emery Inorganic materials 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 230000002070 germicidal effect Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000003752 hydrotrope Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 229940070805 p-chloro-m-cresol Drugs 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 239000010665 pine oil Substances 0.000 abstract 1
- 239000008262 pumice Substances 0.000 abstract 1
- 229910010271 silicon carbide Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 abstract 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 abstract 1
- 235000017557 sodium bicarbonate Nutrition 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 235000017550 sodium carbonate Nutrition 0.000 abstract 1
- 229940048086 sodium pyrophosphate Drugs 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 239000004328 sodium tetraborate Substances 0.000 abstract 1
- 235000010339 sodium tetraborate Nutrition 0.000 abstract 1
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 abstract 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 abstract 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/047—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
An aqueous detergent composition comprising (a) a non-acidic alkali metal salt of a phosphoric acid having a molecular weight below 400, (b) an aniomic detergent, and (c) a fatty acid alkanolamide, contains a finely divided water-insoluble abrasive material in stable suspension. The phosphate (a), which comprises 2-45% of the liquid medium, is preferably sodium or potassium pyrophosphate or tripolyphosphate. The detergent (b) is preferably a mixture of soap with an alkylaryl sulphonate such as sodium dodecylbenzene sulphonate, an alkly sulphate, or an acylaminoalkane sulphonate, but acyl isethionates are not recommended; the weight ratios of synthetic detergent to soap should be 1:1 to 4:1. In general, component (b) should comprise 1-10% of the liquid medium, but if no soap is present, the synthetic detergent should not be less than 3%, and if no synthetic detergent is included, the soap should not be less than 1,2%. Although component (c) may consist of an isopropanolamide, a glycerolamide or a tris-(hydroxymethyl)-methylamide, it is preferred to use the mono- and di-ethanolamides of lauric acid in amounts of 1-10% of the liquid medium. The abrasive may consist of felspar, pumice, kieselguhr, emery, or carborundum, but is preferably silica, and is suitably of such a particle size that it all passes a sieve of 104 micron mesh and 80% at least passes a sieve of 53 micron mesh; coarser abrasive particles may however be used for special purposes. In general the abrasive constitutes 20-50% of the total composition. The compositions, which may also include sodium carbonate, bicarbonate and sulphate, borax, germicides such as p-chloro-m-cresol and bis- (3:5:6-trichloro-2-hydroxyphenyl)-methane perfume, such as pine oil, and colour, should not contain any hydrotrope such as sodium xylene sulphonate. The ionic components present may be used in the form of the alkali metal, ammonium, or substituted ammonium salts. The compositions are prepared by heating and stirring the phosphate with twice the weight of water to 60 DEG C., cooling to 40 DEG C., adding the solution obtained by dissolving the detergent in the rest of the water at 60 DEG C., cooling to 40 DEG C., and then adding successively the alkanolamide, the abrasive, and any other ingredients. In the Provisional Specification no limit is imposed on the molecular weight of the phosphate (a), and the alkanolamide (c) may be replaced by any non-ionic surface active agent, several of which are specified.
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DENDAT1250949D DE1250949B (en) | 1959-06-05 | Pourable scouring and cleaning agent | |
| BE591558D BE591558A (en) | 1959-06-05 | ||
| NL252319D NL252319A (en) | 1959-06-05 | ||
| NL104012D NL104012C (en) | 1959-06-05 | ||
| GB19291/59A GB882569A (en) | 1959-06-05 | 1959-06-05 | Liquid detergent compositions |
| CH636560A CH388507A (en) | 1959-06-05 | 1960-06-03 | Abrasive cleaning agent |
| FR829117A FR1260895A (en) | 1959-06-05 | 1960-06-03 | Liquid detergent compositions |
| ES0258632A ES258632A1 (en) | 1959-06-05 | 1960-06-04 | Liquid detergent compositions |
| OA50569A OA00489A (en) | 1959-06-05 | 1964-11-11 | Liquid detergent compositions. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB19291/59A GB882569A (en) | 1959-06-05 | 1959-06-05 | Liquid detergent compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB882569A true GB882569A (en) | 1961-11-15 |
Family
ID=10126955
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB19291/59A Expired GB882569A (en) | 1959-06-05 | 1959-06-05 | Liquid detergent compositions |
Country Status (7)
| Country | Link |
|---|---|
| BE (1) | BE591558A (en) |
| CH (1) | CH388507A (en) |
| DE (1) | DE1250949B (en) |
| ES (1) | ES258632A1 (en) |
| GB (1) | GB882569A (en) |
| NL (2) | NL252319A (en) |
| OA (1) | OA00489A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57100198A (en) * | 1980-12-16 | 1982-06-22 | Lion Corp | Liquid cleanser composition |
| US4530775A (en) * | 1981-11-13 | 1985-07-23 | Lever Brothers Company | Stable liquid detergent suspensions |
| LT3962B (en) | 1993-12-21 | 1996-05-27 | Albright & Wilson | Funcional fluids |
| US5698509A (en) * | 1985-02-26 | 1997-12-16 | Lever Brothers Company, Division Of Conopco, Inc. | Pourable abrasive aqueous detergent composition for cleaning hard surfaces |
| US12134114B2 (en) | 2018-11-15 | 2024-11-05 | Ecolab Usa Inc. | Acidic cleaner |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1262280A (en) * | 1968-11-06 | 1972-02-02 | Unilever Ltd | Suspending liquids |
| GB8328991D0 (en) * | 1983-10-31 | 1983-11-30 | Unilever Plc | Liquid scouring compositions |
| TR22705A (en) * | 1984-11-12 | 1988-04-13 | Unilever Nv | CARVING COMPILATIONS IN LIQUID CARE |
-
0
- BE BE591558D patent/BE591558A/xx unknown
- DE DENDAT1250949D patent/DE1250949B/en active Pending
- NL NL104012D patent/NL104012C/xx active
- NL NL252319D patent/NL252319A/xx unknown
-
1959
- 1959-06-05 GB GB19291/59A patent/GB882569A/en not_active Expired
-
1960
- 1960-06-03 CH CH636560A patent/CH388507A/en unknown
- 1960-06-04 ES ES0258632A patent/ES258632A1/en not_active Expired
-
1964
- 1964-11-11 OA OA50569A patent/OA00489A/en unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57100198A (en) * | 1980-12-16 | 1982-06-22 | Lion Corp | Liquid cleanser composition |
| US4530775A (en) * | 1981-11-13 | 1985-07-23 | Lever Brothers Company | Stable liquid detergent suspensions |
| US5698509A (en) * | 1985-02-26 | 1997-12-16 | Lever Brothers Company, Division Of Conopco, Inc. | Pourable abrasive aqueous detergent composition for cleaning hard surfaces |
| LT3962B (en) | 1993-12-21 | 1996-05-27 | Albright & Wilson | Funcional fluids |
| US12134114B2 (en) | 2018-11-15 | 2024-11-05 | Ecolab Usa Inc. | Acidic cleaner |
Also Published As
| Publication number | Publication date |
|---|---|
| BE591558A (en) | |
| OA00489A (en) | 1966-07-15 |
| NL104012C (en) | |
| NL252319A (en) | |
| DE1250949B (en) | 1967-09-28 |
| CH388507A (en) | 1965-02-28 |
| ES258632A1 (en) | 1960-12-01 |
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