GB881801A - Non-fibrous regenerated cellulose film and process of manufacture - Google Patents
Non-fibrous regenerated cellulose film and process of manufactureInfo
- Publication number
- GB881801A GB881801A GB123460A GB123460A GB881801A GB 881801 A GB881801 A GB 881801A GB 123460 A GB123460 A GB 123460A GB 123460 A GB123460 A GB 123460A GB 881801 A GB881801 A GB 881801A
- Authority
- GB
- United Kingdom
- Prior art keywords
- film
- groups
- carbon atoms
- agent
- hydrophobic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004627 regenerated cellulose Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 abstract 6
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- 150000001412 amines Chemical class 0.000 abstract 3
- 230000002209 hydrophobic effect Effects 0.000 abstract 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 2
- 125000005529 alkyleneoxy group Chemical group 0.000 abstract 2
- 150000001408 amides Chemical class 0.000 abstract 2
- -1 chloroaryl Chemical group 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 229920002101 Chitin Polymers 0.000 abstract 1
- 239000001856 Ethyl cellulose Substances 0.000 abstract 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 239000000020 Nitrocellulose Substances 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001409 amidines Chemical class 0.000 abstract 1
- 238000004873 anchoring Methods 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 235000013871 bee wax Nutrition 0.000 abstract 1
- 239000012166 beeswax Substances 0.000 abstract 1
- 235000013877 carbamide Nutrition 0.000 abstract 1
- 235000013869 carnauba wax Nutrition 0.000 abstract 1
- 239000004203 carnauba wax Substances 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 125000004965 chloroalkyl group Chemical group 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 125000004185 ester group Chemical group 0.000 abstract 1
- 235000019325 ethyl cellulose Nutrition 0.000 abstract 1
- 229920001249 ethyl cellulose Polymers 0.000 abstract 1
- 150000002357 guanidines Chemical class 0.000 abstract 1
- 125000001165 hydrophobic group Chemical group 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 239000004922 lacquer Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229920000609 methyl cellulose Polymers 0.000 abstract 1
- 239000001923 methylcellulose Substances 0.000 abstract 1
- 235000010981 methylcellulose Nutrition 0.000 abstract 1
- 239000012170 montan wax Substances 0.000 abstract 1
- 229920001220 nitrocellulos Polymers 0.000 abstract 1
- 150000002923 oximes Chemical class 0.000 abstract 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 150000003349 semicarbazides Chemical class 0.000 abstract 1
- 150000003585 thioureas Chemical class 0.000 abstract 1
- 150000003672 ureas Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
- C08J7/065—Low-molecular-weight organic substances, e.g. absorption of additives in the surface of the article
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2301/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2301/06—Cellulose hydrate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31975—Of cellulosic next to another carbohydrate
- Y10T428/31978—Cellulosic next to another cellulosic
- Y10T428/31986—Regenerated or modified
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A non-fibrous regenerated cellulose film is passed through an aqueous bath containing as anchoring-plasticizing agent a water-soluble amide or amine containing at least 6 alkyleneoxy groups, each containing not more than 4 carbon atoms, and at least one hydrophobic substituent of at least 6 carbon atoms, and the film is dried. The term "amides" includes ureas, thioureas, carbazides and semicarbazides and the term "amines" includes amidines, guanidines, oximes and ammonium quaternaries. The number of alkyleneoxy groups may exceed 20; ethyleneoxy groups are preferred. Hydrophobic substituents specified include aryl, alkyl, aralkyl and alkaryl groups containing more than 6 carbon atoms, or chloroalkyl, chloroaryl, and ester groups. Desirably, such hydrophobic groups should contain more than 12 carbon atoms. The molecular weight of the agent preferably exceeds 5,000. The film preferably contains 10-20% of its dry weight of the agent, corresponding to impregnation to saturation with a solution containing 5-10% by weight of the agent, and has a pH of 6-8. The aqueous bath may contain other conventional agents to impart supplementary plasticization and anchoring properties to the film. Preferred anchoring-plasticizing agents include the reaction products with between 10 and 100 mols of ethylene oxide of N-2-hydroxyethylrosinamide or stearoguanimine, and of dimethyl (octadecylamidopropyl) amine. Many others are specified. After treatment the film, desirably after drying at 160-250 DEG F., may be treated on at least one side with a hydrophobic topcoat material. Those specified include nitrocellulose, cellulose acetate, methyl cellulose, polyethylene, deacetylated chitin, rubber, chlorinated rubber, rubber hydrochloride, ethyl cellulose, polybutyl methacrylate, moistureresistant lacquers, montan wax, carnauba wax and beeswax. U.S.A. Specifications 2,394,009, 2,757,102 and 2,764,507 are referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78927159 US2980554A (en) | 1959-01-27 | 1959-01-27 | Non-fibrous regenerated cellulose film containing anchoring-plasticizing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB881801A true GB881801A (en) | 1961-11-08 |
Family
ID=25147129
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB123460A Expired GB881801A (en) | 1959-01-27 | 1960-01-13 | Non-fibrous regenerated cellulose film and process of manufacture |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2980554A (en) |
| BE (1) | BE589296A (en) |
| FR (1) | FR1245448A (en) |
| GB (1) | GB881801A (en) |
| NL (1) | NL247796A (en) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3447948A (en) * | 1965-09-02 | 1969-06-03 | Fmc Corp | Resin coated cellulosic sheet having reduced tendency to accumulate an electrostatic charge |
| US3316120A (en) * | 1966-06-03 | 1967-04-25 | American Cyanamid Co | Process for preparing topcoated plasticized non-fibrous regenerated cellulose film and the resultant product |
| US3917894A (en) * | 1968-01-15 | 1975-11-04 | Tee Pak Inc | Process for coating regenerated cellulose film and the coated film |
| US3505072A (en) * | 1969-06-09 | 1970-04-07 | George B Rullman | Method and apparatus for operating a single line conveyor |
| DE3530366A1 (en) * | 1985-08-24 | 1987-02-26 | Juergen Dipl Chem Stock | PLASTIC PART AND METHOD FOR TREATING THE SURFACE OF A PLASTIC PART |
| JPH0729915B2 (en) * | 1986-02-01 | 1995-04-05 | 帝國製薬株式会社 | Sheet-shaped oral patch |
| US8663687B2 (en) | 2001-10-12 | 2014-03-04 | Monosol Rx, Llc | Film compositions for delivery of actives |
| US20070281003A1 (en) * | 2001-10-12 | 2007-12-06 | Fuisz Richard C | Polymer-Based Films and Drug Delivery Systems Made Therefrom |
| US11207805B2 (en) | 2001-10-12 | 2021-12-28 | Aquestive Therapeutics, Inc. | Process for manufacturing a resulting pharmaceutical film |
| US20110033542A1 (en) | 2009-08-07 | 2011-02-10 | Monosol Rx, Llc | Sublingual and buccal film compositions |
| US20070154527A1 (en) * | 2001-10-12 | 2007-07-05 | Monosoirx, Llc | Topical film compositions for delivery of actives |
| US8900498B2 (en) | 2001-10-12 | 2014-12-02 | Monosol Rx, Llc | Process for manufacturing a resulting multi-layer pharmaceutical film |
| US8765167B2 (en) | 2001-10-12 | 2014-07-01 | Monosol Rx, Llc | Uniform films for rapid-dissolve dosage form incorporating anti-tacking compositions |
| US20100021526A1 (en) * | 2001-10-12 | 2010-01-28 | Monosol Rx, Llc | Ph modulated films for delivery of actives |
| US8603514B2 (en) | 2002-04-11 | 2013-12-10 | Monosol Rx, Llc | Uniform films for rapid dissolve dosage form incorporating taste-masking compositions |
| US8900497B2 (en) | 2001-10-12 | 2014-12-02 | Monosol Rx, Llc | Process for making a film having a substantially uniform distribution of components |
| US7910641B2 (en) * | 2001-10-12 | 2011-03-22 | Monosol Rx, Llc | PH modulated films for delivery of actives |
| US7425292B2 (en) * | 2001-10-12 | 2008-09-16 | Monosol Rx, Llc | Thin film with non-self-aggregating uniform heterogeneity and drug delivery systems made therefrom |
| US20060039958A1 (en) * | 2003-05-28 | 2006-02-23 | Monosolrx, Llc. | Multi-layer films having uniform content |
| US7666337B2 (en) | 2002-04-11 | 2010-02-23 | Monosol Rx, Llc | Polyethylene oxide-based films and drug delivery systems made therefrom |
| US20190328679A1 (en) | 2001-10-12 | 2019-10-31 | Aquestive Therapeutics, Inc. | Uniform films for rapid-dissolve dosage form incorporating anti-tacking compositions |
| US10285910B2 (en) | 2001-10-12 | 2019-05-14 | Aquestive Therapeutics, Inc. | Sublingual and buccal film compositions |
| US7357891B2 (en) | 2001-10-12 | 2008-04-15 | Monosol Rx, Llc | Process for making an ingestible film |
| US8017150B2 (en) * | 2002-04-11 | 2011-09-13 | Monosol Rx, Llc | Polyethylene oxide-based films and drug delivery systems made therefrom |
| CA2505796C (en) * | 2002-07-22 | 2012-01-03 | Monosolrx Llc | Packaging and dispensing of rapid dissolve dosage form |
| US20070172515A1 (en) * | 2006-01-20 | 2007-07-26 | Monosolrx, Llc | Film bandage for mucosal administration of actives |
| CA2636026A1 (en) * | 2006-01-20 | 2007-07-26 | Monosol Rx, Llc | Film lined pouch and method of manufacturing this pouch |
| CN101516331A (en) * | 2006-09-20 | 2009-08-26 | 莫诺索尔克斯有限公司 | Edible water-soluble film containing a foam reducing flavoring agent |
| US20080081071A1 (en) * | 2006-09-29 | 2008-04-03 | Pradeep Sanghvi | Film Embedded Packaging and Method of Making Same |
| US8475832B2 (en) | 2009-08-07 | 2013-07-02 | Rb Pharmaceuticals Limited | Sublingual and buccal film compositions |
| ES2569339T3 (en) | 2010-06-10 | 2016-05-10 | Midatech Ltd. | Nanoparticle Film Management Systems |
| US9149959B2 (en) | 2010-10-22 | 2015-10-06 | Monosol Rx, Llc | Manufacturing of small film strips |
| US12433850B2 (en) | 2016-05-05 | 2025-10-07 | Aquestive Therapeutics, Inc. | Enhanced delivery epinephrine and prodrug compositions |
| US12427121B2 (en) | 2016-05-05 | 2025-09-30 | Aquestive Therapeutics, Inc. | Enhanced delivery epinephrine compositions |
| US11273131B2 (en) | 2016-05-05 | 2022-03-15 | Aquestive Therapeutics, Inc. | Pharmaceutical compositions with enhanced permeation |
| KR20230137362A (en) | 2016-05-05 | 2023-10-04 | 어퀘스티브 테라퓨틱스, 아이엔씨. | Enhanced delivery epinephrine compositions |
| WO2023076281A1 (en) | 2021-10-25 | 2023-05-04 | Aquestive Therapeutics, Inc. | Oral and nasal compositions and methods of treatment |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2823141A (en) * | 1953-05-08 | 1958-02-11 | Olin Mathieson | Process for coating regenerated cellulose film with resin and resulting product |
| US2763571A (en) * | 1954-03-23 | 1956-09-18 | American Cyanamid Co | Non-fibrous regenerated cellulose film carrying an anchoring agent and method of making |
-
0
- NL NL247796D patent/NL247796A/xx unknown
-
1959
- 1959-01-27 US US78927159 patent/US2980554A/en not_active Expired - Lifetime
-
1960
- 1960-01-13 GB GB123460A patent/GB881801A/en not_active Expired
- 1960-01-21 FR FR816232A patent/FR1245448A/en not_active Expired
- 1960-04-01 BE BE589296A patent/BE589296A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR1245448A (en) | 1960-11-04 |
| US2980554A (en) | 1961-04-18 |
| NL247796A (en) | 1900-01-01 |
| BE589296A (en) | 1960-10-03 |
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