GB865698A - Process for the extraction and recovery of aromatic hydrocarbons from a liquid hydrocarbon mixture - Google Patents
Process for the extraction and recovery of aromatic hydrocarbons from a liquid hydrocarbon mixtureInfo
- Publication number
- GB865698A GB865698A GB424359A GB424359A GB865698A GB 865698 A GB865698 A GB 865698A GB 424359 A GB424359 A GB 424359A GB 424359 A GB424359 A GB 424359A GB 865698 A GB865698 A GB 865698A
- Authority
- GB
- United Kingdom
- Prior art keywords
- stripping zone
- solvent
- extraction
- extract
- feed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000605 extraction Methods 0.000 title abstract 6
- 229930195733 hydrocarbon Natural products 0.000 title abstract 5
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 5
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000007788 liquid Substances 0.000 title 1
- 238000011084 recovery Methods 0.000 title 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 12
- 239000002904 solvent Substances 0.000 abstract 4
- 238000009835 boiling Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 abstract 1
- 238000012856 packing Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 abstract 1
- 238000009834 vaporization Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
- C10G21/06—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
- C10G21/12—Organic compounds only
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Aromatic hydrocarbons are recovered from hydrocarbon mixtures by introducing the mixture into a counterflow multistage extraction system operated at 140-170 DEG C and employing a solvent boiling in the range of 225-295 DEG C. and containing dissolved water in an amount of not more than 2% by weight; cooling the solvent-extract phase by at least 15 DEG C to 115-150 DEG C; introducing the extract without appreciable flash vapourisation into a stripping zone operated at at least 1,5 atmospheres absolute, a top temperature of 115-150 DEG C and a bottom temperature of at least 165 DEG C; condensing the vapours, removing all water separating as a separate phase and recycling the remainder to the extraction system either at the end where the extract is withdrawn and/or at an intermediate point; and distilling the bottoms from the stripping zone at less than 0,5 atmosphere absolute and a bottom temperature of at least 145 DEG C. and at least 10 DEG C lower than the bottom temperature of the stripping zone. The solvent may be diethylene and/or dipropylene glycol or sulfolane. The process is particularly suitable for catalytic reformates having a final boiling point not higher than 220 DEG C and a lower cutting point about 100 DEG C. The volumetric ratio of solvent to hydrocarbon may be between 3:1 and 8:1 and the ratio of top product from the stripping zone to hydrocarbon feed may be between 0,2 and 0,7:1. The extraction may be effected in a column containing packing or sieve plates, a rotating disc contactor or a number of mixer-settler units, the number of theoretical stages being at least 5. The feed may be introduced at the first or second theoretical stage. Top product from the stripping zone is also preferably introduced at the first or second stage. The pressure in the stripping zone, and the temperature of the feed to it, should be regulated so that the weight ratio of vapour in the extract to fresh feed to the extraction system is below 1:10 and preferably no vapour is present. The difference between top and bottom temperatures in the stripping zone is preferably at least 40 DEG C, maintained by a reboiler. The bottoms from the stripping zone is distilled to separate hydrocarbons and solvent which is recycled to the extraction using live steam. Specification 739,200 is referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB424359A GB865698A (en) | 1959-02-06 | 1959-02-06 | Process for the extraction and recovery of aromatic hydrocarbons from a liquid hydrocarbon mixture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB424359A GB865698A (en) | 1959-02-06 | 1959-02-06 | Process for the extraction and recovery of aromatic hydrocarbons from a liquid hydrocarbon mixture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB865698A true GB865698A (en) | 1961-04-19 |
Family
ID=9773429
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB424359A Expired GB865698A (en) | 1959-02-06 | 1959-02-06 | Process for the extraction and recovery of aromatic hydrocarbons from a liquid hydrocarbon mixture |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB865698A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0043267A1 (en) * | 1980-06-30 | 1982-01-06 | Union Carbide Corporation | Method of separating aromatic and nonaromatic hydrocarbons in mixed hydrocarbon feeds |
| EP0043685A1 (en) * | 1980-06-30 | 1982-01-13 | Union Carbide Corporation | Method of separating aromatic and nonaromatic hydrocarbons in mixed hydrocarbon feeds |
| US4571295A (en) * | 1983-05-13 | 1986-02-18 | Union Carbide Corporation | Aromatic/nonaromatic separations |
| US4781820A (en) * | 1985-07-05 | 1988-11-01 | Union Carbide Corporation | Aromatic extraction process using mixed polyalkylene glycols/glycol ether solvents |
-
1959
- 1959-02-06 GB GB424359A patent/GB865698A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0043267A1 (en) * | 1980-06-30 | 1982-01-06 | Union Carbide Corporation | Method of separating aromatic and nonaromatic hydrocarbons in mixed hydrocarbon feeds |
| EP0043685A1 (en) * | 1980-06-30 | 1982-01-13 | Union Carbide Corporation | Method of separating aromatic and nonaromatic hydrocarbons in mixed hydrocarbon feeds |
| US4571295A (en) * | 1983-05-13 | 1986-02-18 | Union Carbide Corporation | Aromatic/nonaromatic separations |
| US4781820A (en) * | 1985-07-05 | 1988-11-01 | Union Carbide Corporation | Aromatic extraction process using mixed polyalkylene glycols/glycol ether solvents |
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