GB838378A - An improved process for the production of metals and other chemical elements of metallic character in a state of high purity - Google Patents
An improved process for the production of metals and other chemical elements of metallic character in a state of high purityInfo
- Publication number
- GB838378A GB838378A GB30735/57A GB3073557A GB838378A GB 838378 A GB838378 A GB 838378A GB 30735/57 A GB30735/57 A GB 30735/57A GB 3073557 A GB3073557 A GB 3073557A GB 838378 A GB838378 A GB 838378A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silicon
- mixture
- volatile
- production
- frequency
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229910052729 chemical element Inorganic materials 0.000 title 1
- 239000002184 metal Substances 0.000 title 1
- 150000002739 metals Chemical class 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 abstract 3
- 239000003638 chemical reducing agent Substances 0.000 abstract 2
- 239000008246 gaseous mixture Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 238000006722 reduction reaction Methods 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 239000010703 silicon Substances 0.000 abstract 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 abstract 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910003818 SiH2Cl2 Inorganic materials 0.000 abstract 1
- 229910003826 SiH3Cl Inorganic materials 0.000 abstract 1
- 229910003822 SiHCl3 Inorganic materials 0.000 abstract 1
- SLLGVCUQYRMELA-UHFFFAOYSA-N chlorosilicon Chemical compound Cl[Si] SLLGVCUQYRMELA-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000005684 electric field Effects 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 150000003377 silicon compounds Chemical class 0.000 abstract 1
- 239000005049 silicon tetrachloride Substances 0.000 abstract 1
- 230000002459 sustained effect Effects 0.000 abstract 1
- 239000003039 volatile agent Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
- B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B4/00—Electrothermal treatment of ores or metallurgical products for obtaining metals or alloys
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Silicon Compounds (AREA)
Abstract
<PICT:0838378/III/1> Non-metallic elements in a high state of purity, especially those belonging to Group IV, V and VI of the Periodic System, are prepared by passing a gaseous mixture of a volatile compound of the element and a volatile reducing agent, under reduced pressure, through a reaction chamber in which it is subjected, without the use of electrodes, to a high-frequency alternating electric field which induces electric discharges in the mixture and initiates chemical reduction at the ambient or at a moderately elevated temperature. One example quoted describes the production of silicon using the apparatus shown in which a gaseous mixture of silicon tetrachloride and hydrogen is fed from the container 1 at a pressure of 2 cm. of mercury through line 2 fitted with cocks 6 and 7 to the vessel 3 of 200 c.c. volume evacuated by pump 10. The reaction vessel 3 having a diameter of 10 cm. has a coil 4 of ten turns wound on the outside and a high-frequency continuous wave current produced by a 5 kw. generator at a frequency of 1 megacycle per second is passed through the coil to induce the electric discharge in the mixture. Silicon, formed by the reduction of the tetrachloride accumulates in the detachable bottom 3a of the reaction vessel and is removed. Other volatile silicon compounds which may be reduced include SiHCl3, SiH2Cl2, SiH3Cl or the corresponding compounds with the other halogens. A modification of the process discloses the use of ultra-high-frequencies delivered either as sustained waves or as pulse discharges by means of wave-guides.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR838378X | 1956-10-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB838378A true GB838378A (en) | 1960-06-22 |
Family
ID=9299023
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB30735/57A Expired GB838378A (en) | 1956-10-01 | 1957-10-01 | An improved process for the production of metals and other chemical elements of metallic character in a state of high purity |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB838378A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1981003168A1 (en) * | 1980-05-09 | 1981-11-12 | Motorola Inc | High pressure plasma hydrogenation of silicon tetrachloride |
| US4321246A (en) * | 1980-05-09 | 1982-03-23 | Motorola, Inc. | Polycrystalline silicon production |
| DE102009056437A1 (en) | 2009-12-02 | 2011-06-09 | Rev Renewable Energy Ventures, Inc. | A method and apparatus for the preparation of short-chain halogenated polys anes |
-
1957
- 1957-10-01 GB GB30735/57A patent/GB838378A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1981003168A1 (en) * | 1980-05-09 | 1981-11-12 | Motorola Inc | High pressure plasma hydrogenation of silicon tetrachloride |
| US4309259A (en) * | 1980-05-09 | 1982-01-05 | Motorola, Inc. | High pressure plasma hydrogenation of silicon tetrachloride |
| US4321246A (en) * | 1980-05-09 | 1982-03-23 | Motorola, Inc. | Polycrystalline silicon production |
| DE102009056437A1 (en) | 2009-12-02 | 2011-06-09 | Rev Renewable Energy Ventures, Inc. | A method and apparatus for the preparation of short-chain halogenated polys anes |
| WO2011067333A2 (en) | 2009-12-02 | 2011-06-09 | Spawnt Private S.À.R.L. | Method and device for producing short-chained halogenated polysilanes |
| US9353227B2 (en) | 2009-12-02 | 2016-05-31 | Spawnt Private S.À.R.L. | Method and device for producing short-chain halogenated polysilanes |
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