GB834337A - Photopolymerisable compositions and elements containing the same - Google Patents
Photopolymerisable compositions and elements containing the sameInfo
- Publication number
- GB834337A GB834337A GB25584/57A GB2558457A GB834337A GB 834337 A GB834337 A GB 834337A GB 25584/57 A GB25584/57 A GB 25584/57A GB 2558457 A GB2558457 A GB 2558457A GB 834337 A GB834337 A GB 834337A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- polyvinyl
- benzoin
- propanol
- alpha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 150000002148 esters Chemical class 0.000 abstract 3
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 3
- 239000011118 polyvinyl acetate Substances 0.000 abstract 3
- 229920002554 vinyl polymer Polymers 0.000 abstract 3
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 244000028419 Styrax benzoin Species 0.000 abstract 2
- 235000000126 Styrax benzoin Nutrition 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 235000008411 Sumatra benzointree Nutrition 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000007513 acids Chemical class 0.000 abstract 2
- 229960002130 benzoin Drugs 0.000 abstract 2
- 235000019382 gum benzoic Nutrition 0.000 abstract 2
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 2
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 abstract 1
- UYBWIEGTWASWSR-UHFFFAOYSA-N 1,3-diaminopropan-2-ol Chemical compound NCC(O)CN UYBWIEGTWASWSR-UHFFFAOYSA-N 0.000 abstract 1
- RZCDMINQJLGWEP-UHFFFAOYSA-N 2-hydroxy-1,2-diphenylpent-4-en-1-one Chemical compound C=1C=CC=CC=1C(CC=C)(O)C(=O)C1=CC=CC=C1 RZCDMINQJLGWEP-UHFFFAOYSA-N 0.000 abstract 1
- DIVXVZXROTWKIH-UHFFFAOYSA-N 2-hydroxy-1,2-diphenylpropan-1-one Chemical compound C=1C=CC=CC=1C(O)(C)C(=O)C1=CC=CC=C1 DIVXVZXROTWKIH-UHFFFAOYSA-N 0.000 abstract 1
- QUOQRYLWYWHTRV-UHFFFAOYSA-N 2-hydroxyethyl 2-ethenylbenzoate Chemical class OCCOC(=O)C1=CC=CC=C1C=C QUOQRYLWYWHTRV-UHFFFAOYSA-N 0.000 abstract 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 abstract 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N 2-propanol Substances CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 1
- YMRDPCUYKKPMFC-UHFFFAOYSA-N 4-hydroxy-2,2,5,5-tetramethylhexan-3-one Chemical compound CC(C)(C)C(O)C(=O)C(C)(C)C YMRDPCUYKKPMFC-UHFFFAOYSA-N 0.000 abstract 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 abstract 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 abstract 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 1
- 229920001353 Dextrin Polymers 0.000 abstract 1
- 239000004375 Dextrin Substances 0.000 abstract 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 abstract 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 abstract 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract 1
- 108010010803 Gelatin Proteins 0.000 abstract 1
- 229920002472 Starch Polymers 0.000 abstract 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 abstract 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 238000012644 addition polymerization Methods 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- 235000012216 bentonite Nutrition 0.000 abstract 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 abstract 1
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 abstract 1
- FLHKEWQKOHJIMH-UHFFFAOYSA-N bis(ethenyl) benzene-1,3-disulfonate Chemical compound C=COS(=O)(=O)C1=CC=CC(S(=O)(=O)OC=C)=C1 FLHKEWQKOHJIMH-UHFFFAOYSA-N 0.000 abstract 1
- IHXBXGHGYCSRAP-UHFFFAOYSA-N bis(ethenyl) benzene-1,4-dicarboxylate Chemical compound C=COC(=O)C1=CC=C(C(=O)OC=C)C=C1 IHXBXGHGYCSRAP-UHFFFAOYSA-N 0.000 abstract 1
- SZARYXGAVDEJAY-UHFFFAOYSA-N bis(ethenyl) butane-1,4-disulfonate Chemical compound C=COS(=O)(=O)CCCCS(=O)(=O)OC=C SZARYXGAVDEJAY-UHFFFAOYSA-N 0.000 abstract 1
- 239000005018 casein Substances 0.000 abstract 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 1
- 235000021240 caseins Nutrition 0.000 abstract 1
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 abstract 1
- 235000019425 dextrin Nutrition 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000008273 gelatin Substances 0.000 abstract 1
- 229920000159 gelatin Polymers 0.000 abstract 1
- 235000019322 gelatine Nutrition 0.000 abstract 1
- 235000011852 gelatine desserts Nutrition 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 229960004592 isopropanol Drugs 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical class 0.000 abstract 1
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- JXICBYOSYZGESJ-UHFFFAOYSA-N n-[2-hydroxy-3-(2-methylprop-2-enoylamino)propyl]-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCC(O)CNC(=O)C(C)=C JXICBYOSYZGESJ-UHFFFAOYSA-N 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 229910000027 potassium carbonate Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 229940075554 sorbate Drugs 0.000 abstract 1
- 239000008107 starch Substances 0.000 abstract 1
- 235000019698 starch Nutrition 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/18—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to irradiated or oxidised macromolecules
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
- G03F7/033—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Glass Compositions (AREA)
Abstract
1,3 - bis - methacrylamido - 2 - propanol is prepared by acylating 1,3-diamino-2-propanol with methacrylyl chloride in the presence of aqueous potassium carbonate at 0-5 DEG C. Specifications 600,023, 741,294, 741,441, 741,470, 792,840 and 807,948 are referred to.ALSO:A photopolymerizable composition which is substantially transparent to actinic light comprises 10 to 60% by weight of an addition polymerizable ethylenically unsaturated compound having a boiling-point above 100 DEG C. at atmospheric pressure, 90 to 40% by weight of a neutral, non-ionizable polyvinyl alcohol ether, ester or acetal in which at least 70% of the structural units are vinyl alcohol units, which has a molecular weight of at least 5000 and which is soluble in water at 25 DEG C. to an extent of at least 2% by weight, and 0.01 to 5% (based on the weight of the unsaturated compound) of an addition polymerization initiator p which is essentially compatible with the other ingredients of the composition and is activatable by actinic light but is not activatable thermally at temperatures below 80 DEG C. Unsaturated compounds specified are esters and amides of acrylic and methacrylic acids, particularly esters of these acids with polyhydric alcohols and esteramides of such acids, blends of styrene with diethyl maleate or fumarate, methyl and beta-hydroxyethyl vinylbenzoates, divinyl terephthalate, divinyl benzene-1,3-disulphonate, divinyl butane-1,4-disulphonate and alpha-vinyl crotonaldehyde. Of the polyvinyl alcohol derivatives listed preferred is a partially hydrolysed polyvinyl acetate. Photoinitiators specified are diactyl, benzil, benzoin, pivaloin, benzoin methyl or ethyl ethers, alpha-methyl benzoin and alpha-allylbenzoin. The compositions may also contain compatible preformed polymers and fillers such as polyvinyl acetate and butyrate, polyvinyl formal and butyral, polyvinyl sorbate and sorbal, polyglyceryl phthalate and maleate, polymeric ethylene glycol and oxide, gelatin, starch, dextrin and casein and bentonite, silica and powdered glass. In the example a composition comprising polyvinyl acetate hydrolysed to the extent of 86 to 89%, 1.3-bis-methacrylamido-2-propanol and benzoin methyl ether is cast into a film and photopolymerized by exposure to light from mercury vapour lamps. This process is used in the preparation of relief images. Specifications 600,023, 741,294, 741,441, 741,470, 792,840 and 807,948 are referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US834337XA | 1956-08-27 | 1956-08-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB834337A true GB834337A (en) | 1960-05-04 |
Family
ID=22178295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB25584/57A Expired GB834337A (en) | 1956-08-27 | 1957-08-13 | Photopolymerisable compositions and elements containing the same |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE560154A (en) |
| FR (1) | FR1186296A (en) |
| GB (1) | GB834337A (en) |
| NL (2) | NL220139A (en) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2645113A1 (en) * | 1975-10-07 | 1977-04-14 | Murakami Screen Kk | PHOTO-SENSITIVE COMPOSITION FOR PRESSURE SCREENS |
| US4272611A (en) | 1978-10-26 | 1981-06-09 | Basf Aktiengesellschaft | Photopolymerizable composition for the production of printing plates and relief plates, and the elements produced therewith |
| US4355093A (en) | 1980-04-22 | 1982-10-19 | Basf Aktiengesellschaft | Laminate useful for the production of printing plates and relief plates |
| US4357414A (en) | 1980-04-22 | 1982-11-02 | Basf Aktiengesellschaft | Laminate useful for the production of printing plates and relief plates |
| US4517277A (en) * | 1981-11-12 | 1985-05-14 | Basf Aktiengesellschaft | Photosensitive recording material suitable for the production of printing plates and relief plates, and the production of these plates using this recording material |
| US4540743A (en) * | 1983-06-25 | 1985-09-10 | Basf Aktiengesellschaft | Acylation of polyvinyl alcohols, and photopolymerizable and/or photocrosslinkable mixtures containing products thus acylated |
| US4554240A (en) * | 1983-06-25 | 1985-11-19 | Basf Aktiengesellschaft | Photosensitive recording material which can be developed with water, for the production of printing plates, relief plates or resist images |
| US4585726A (en) * | 1983-07-08 | 1986-04-29 | Basf Aktiengesellschaft | Photopolymerizable water-soluble or water-dispersible mixture containing a salt of nitrous acid |
| US4590146A (en) * | 1983-07-08 | 1986-05-20 | Basf Aktiengesellschaft | Stabilization of photopolymerizable mixtures |
| US4652604A (en) * | 1985-08-02 | 1987-03-24 | American Hoechst Corporation | Radiation-polymerizable composition and element containing a photopolymer composition |
| US4670507A (en) * | 1985-08-02 | 1987-06-02 | American Hoechst Corporation | Resin |
| US4707437A (en) * | 1985-08-02 | 1987-11-17 | Hoechst Celanese Corporation | Radiation-polymerizable composition and element containing a photopolymer composition |
| EP0211406A3 (en) * | 1985-08-02 | 1988-08-17 | Hoechst Celanese Corporation | Photopolymerizable composition with polyvinyl acetal as a binder, and registration material prepared thereof |
| US4780392A (en) * | 1985-08-02 | 1988-10-25 | Hoechst Celanese Corporation | Radiation-polymerizable composition and element containing a photopolymerizable acrylic monomer |
| US4822720A (en) * | 1985-08-02 | 1989-04-18 | Hoechst Celanese Corporation | Water developable screen printing composition |
| US4828963A (en) * | 1981-12-10 | 1989-05-09 | Toray Industries, Inc. | Printing plate having photosensitive polymer composition |
| US4849307A (en) * | 1985-11-21 | 1989-07-18 | Basf Aktiengesellschaft | Photosensitive recording materials having a novel graft copolymer binder |
| US4895788A (en) * | 1985-08-02 | 1990-01-23 | Hoechst Celanese Corporation | Water developable lithographic composition |
| US5134053A (en) * | 1989-07-27 | 1992-07-28 | Hoechst Aktiengesellschaft | Graft polymer with unsaturated lateral chains, photosensitive mixture containing said graft polymer and recording material produced therefrom |
| WO1996018133A1 (en) * | 1994-12-06 | 1996-06-13 | Napp Systems, Inc. | High-resolution letterpress printing plates and water-soluble photopolymerizable compositions comprising a polyvinylalcohol derivative useful therefor |
| US5683837A (en) * | 1994-11-18 | 1997-11-04 | Napp Systems, Inc. | Water-soluble compositions for preparation of durable, high-resolution printing plates |
-
0
- BE BE560154D patent/BE560154A/xx unknown
- NL NL103565D patent/NL103565C/xx active
- NL NL220139D patent/NL220139A/xx unknown
-
1957
- 1957-08-13 GB GB25584/57A patent/GB834337A/en not_active Expired
- 1957-08-26 FR FR1186296D patent/FR1186296A/en not_active Expired
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2645113A1 (en) * | 1975-10-07 | 1977-04-14 | Murakami Screen Kk | PHOTO-SENSITIVE COMPOSITION FOR PRESSURE SCREENS |
| US4272611A (en) | 1978-10-26 | 1981-06-09 | Basf Aktiengesellschaft | Photopolymerizable composition for the production of printing plates and relief plates, and the elements produced therewith |
| US4355093A (en) | 1980-04-22 | 1982-10-19 | Basf Aktiengesellschaft | Laminate useful for the production of printing plates and relief plates |
| US4357414A (en) | 1980-04-22 | 1982-11-02 | Basf Aktiengesellschaft | Laminate useful for the production of printing plates and relief plates |
| US4517277A (en) * | 1981-11-12 | 1985-05-14 | Basf Aktiengesellschaft | Photosensitive recording material suitable for the production of printing plates and relief plates, and the production of these plates using this recording material |
| US4828963A (en) * | 1981-12-10 | 1989-05-09 | Toray Industries, Inc. | Printing plate having photosensitive polymer composition |
| US5023165A (en) * | 1981-12-10 | 1991-06-11 | Toray Industries, Inc. | Printing plate having photosensitive polymer composition |
| US4540743A (en) * | 1983-06-25 | 1985-09-10 | Basf Aktiengesellschaft | Acylation of polyvinyl alcohols, and photopolymerizable and/or photocrosslinkable mixtures containing products thus acylated |
| US4554240A (en) * | 1983-06-25 | 1985-11-19 | Basf Aktiengesellschaft | Photosensitive recording material which can be developed with water, for the production of printing plates, relief plates or resist images |
| US4590146A (en) * | 1983-07-08 | 1986-05-20 | Basf Aktiengesellschaft | Stabilization of photopolymerizable mixtures |
| US4585726A (en) * | 1983-07-08 | 1986-04-29 | Basf Aktiengesellschaft | Photopolymerizable water-soluble or water-dispersible mixture containing a salt of nitrous acid |
| US4822720A (en) * | 1985-08-02 | 1989-04-18 | Hoechst Celanese Corporation | Water developable screen printing composition |
| EP0211406A3 (en) * | 1985-08-02 | 1988-08-17 | Hoechst Celanese Corporation | Photopolymerizable composition with polyvinyl acetal as a binder, and registration material prepared thereof |
| US4780392A (en) * | 1985-08-02 | 1988-10-25 | Hoechst Celanese Corporation | Radiation-polymerizable composition and element containing a photopolymerizable acrylic monomer |
| US4707437A (en) * | 1985-08-02 | 1987-11-17 | Hoechst Celanese Corporation | Radiation-polymerizable composition and element containing a photopolymer composition |
| US4670507A (en) * | 1985-08-02 | 1987-06-02 | American Hoechst Corporation | Resin |
| US4895788A (en) * | 1985-08-02 | 1990-01-23 | Hoechst Celanese Corporation | Water developable lithographic composition |
| US4652604A (en) * | 1985-08-02 | 1987-03-24 | American Hoechst Corporation | Radiation-polymerizable composition and element containing a photopolymer composition |
| US4849307A (en) * | 1985-11-21 | 1989-07-18 | Basf Aktiengesellschaft | Photosensitive recording materials having a novel graft copolymer binder |
| US5134053A (en) * | 1989-07-27 | 1992-07-28 | Hoechst Aktiengesellschaft | Graft polymer with unsaturated lateral chains, photosensitive mixture containing said graft polymer and recording material produced therefrom |
| US5683837A (en) * | 1994-11-18 | 1997-11-04 | Napp Systems, Inc. | Water-soluble compositions for preparation of durable, high-resolution printing plates |
| WO1996018133A1 (en) * | 1994-12-06 | 1996-06-13 | Napp Systems, Inc. | High-resolution letterpress printing plates and water-soluble photopolymerizable compositions comprising a polyvinylalcohol derivative useful therefor |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1186296A (en) | 1959-08-19 |
| NL103565C (en) | |
| NL220139A (en) | |
| BE560154A (en) |
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