GB813797A - Improvements in or relating to the polymerisation of ethylene - Google Patents
Improvements in or relating to the polymerisation of ethyleneInfo
- Publication number
- GB813797A GB813797A GB35156/56A GB3515656A GB813797A GB 813797 A GB813797 A GB 813797A GB 35156/56 A GB35156/56 A GB 35156/56A GB 3515656 A GB3515656 A GB 3515656A GB 813797 A GB813797 A GB 813797A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylene
- catalyst
- cyclohexane
- components
- aluminium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 7
- 239000005977 Ethylene Substances 0.000 title abstract 7
- 239000003054 catalyst Substances 0.000 abstract 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 6
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- 239000004411 aluminium Substances 0.000 abstract 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 4
- 229910052782 aluminium Inorganic materials 0.000 abstract 4
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 abstract 4
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 abstract 4
- 229930195733 hydrocarbon Natural products 0.000 abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 abstract 4
- 229920000642 polymer Polymers 0.000 abstract 4
- 238000002360 preparation method Methods 0.000 abstract 4
- 239000003085 diluting agent Substances 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- 239000012190 activator Substances 0.000 abstract 2
- 229910045601 alloy Inorganic materials 0.000 abstract 2
- 239000000956 alloy Substances 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 2
- 239000011651 chromium Substances 0.000 abstract 2
- 239000010949 copper Substances 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 229960002523 mercuric chloride Drugs 0.000 abstract 2
- LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 150000002894 organic compounds Chemical class 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 2
- 239000004698 Polyethylene Substances 0.000 abstract 1
- YCUVUDODLRLVIC-UHFFFAOYSA-N Sudan black B Chemical compound C1=CC(=C23)NC(C)(C)NC2=CC=CC3=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC1=CC=CC=C1 YCUVUDODLRLVIC-UHFFFAOYSA-N 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Catalysts for use in polymerizing ethylene are obtained by heating aluminium with titanium tetrachloride in the absence of ethylene, other polymerizable hydrocarbons and organic compounds which would react with the catalysts or components thereof. Pure aluminium is preferably used, but alloys with copper, nickel and chromium are applicable. Catalyst preparation may be at temperatures up to 300 DEG C., optionally in the presence of mercuric chloride as activator, and desirable molar ratios of components are given. Hydrocarbon diluents which may be present during the catalyst preparation are hexane, heptane, decahydronaphthalene, cyclohexane, cyclohexene and benzene. Catalyst residues may subsequently be destroyed and/or removed with methanolic hydrochloric acid, methanol and/or solvents such as cyclohexane.ALSO:Polyethylene is obtained by batchwise or continuous polymerization of ethylene using a preformed catalyst made by heating aluminium with titanium tetrachloride in the absence of ethylene, other polymerizable hydrocarbons and organic compounds which would react with the catalyst or its components. The aluminium is preferably in the pure state, but alloys with copper, nickel and chromium may be used; technical grade ethylene may be polymerized. Catalyst preparation may be at temperatures up to 300 DEG C., optionally in the presence of mercuric chloride as activator, and various molar ratios of components are given. Hydrocarbon diluents, preferably purified (see Example V), may be present in the preparation in the catalyst and/or during the polymerization, and specified are hexane, heptane, decahydronaphthalene, cyclohexane, cyclohexene and benzene. The polymerization, which is desirably stopped when the concentration of polymer in diluent is between 10 and 45 per cent, may alternatively be in bulk (see Example VII). The solid, linear polymers obtained may be purified with methanolic hydrochloric acid, methanol, the use of solvents such as cyclohexane, or a combination of these methods. In examples, the intermittent addition of ethylene is described and it is stated that molten polymer may be drawn into translucent filaments (Example VI). The properties of a polymer containing carbon black and Sudan black are described.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1137084T | 1955-11-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB813797A true GB813797A (en) | 1959-05-21 |
Family
ID=9640571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB35156/56A Expired GB813797A (en) | 1955-11-26 | 1956-11-16 | Improvements in or relating to the polymerisation of ethylene |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE552783A (en) |
| FR (2) | FR1137020A (en) |
| GB (1) | GB813797A (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1123474B (en) * | 1956-08-15 | 1962-02-08 | Ici Ltd | Process for the preparation of solid crystalline ethylene polymers |
| BE598132A (en) * | 1957-05-28 | |||
| US3014021A (en) * | 1957-10-30 | 1961-12-19 | Grace W R & Co | Polyethylene process |
| US3004020A (en) * | 1958-03-31 | 1961-10-10 | Eastman Kodak Co | Ethylene polymerization using a mixture of metals and a halogen as catalyst |
| US2925410A (en) * | 1958-04-03 | 1960-02-16 | Eastman Kodak Co | Catalyst containing aluminum, titanium tetrahalide, and alkali metal fluoride and olefin polymerization therewith |
| GB852921A (en) * | 1958-08-07 | 1960-11-02 | Monsanto Chemicals | Improvements relating to polymerisation |
| BE586479A (en) * | 1959-01-12 | |||
| US2976272A (en) * | 1959-02-17 | 1961-03-21 | Eastman Kodak Co | Olefin polymerization using a transition metal halide and a reduced aromatic hydrocarbon as catalyst |
| US3037008A (en) * | 1960-04-06 | 1962-05-29 | Standard Oil Co | Polymerization process |
| US3244685A (en) * | 1961-04-10 | 1966-04-05 | Petro Tex Chem Corp | Polymerization process for butene-1 |
| NL285840A (en) * | 1961-11-29 |
-
0
- BE BE552783D patent/BE552783A/xx unknown
-
1955
- 1955-11-22 FR FR1137020D patent/FR1137020A/en not_active Expired
- 1955-11-26 FR FR1137084D patent/FR1137084A/en not_active Expired
-
1956
- 1956-11-16 GB GB35156/56A patent/GB813797A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE552783A (en) | |
| FR1137084A (en) | 1957-05-23 |
| FR1137020A (en) | 1957-05-22 |
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