GB813446A - Process for the electrolytic deposition of aluminium - Google Patents
Process for the electrolytic deposition of aluminiumInfo
- Publication number
- GB813446A GB813446A GB21284/55A GB2128455A GB813446A GB 813446 A GB813446 A GB 813446A GB 21284/55 A GB21284/55 A GB 21284/55A GB 2128455 A GB2128455 A GB 2128455A GB 813446 A GB813446 A GB 813446A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- alkyl
- compound
- anodes
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004411 aluminium Substances 0.000 title abstract 7
- 229910052782 aluminium Inorganic materials 0.000 title abstract 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract 6
- 230000008021 deposition Effects 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 239000010949 copper Substances 0.000 abstract 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003792 electrolyte Substances 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 150000002431 hydrogen Chemical class 0.000 abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- -1 quaternary ammonium halide Chemical class 0.000 abstract 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 abstract 1
- 239000005662 Paraffin oil Substances 0.000 abstract 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 1
- 230000001464 adherent effect Effects 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 150000001399 aluminium compounds Chemical class 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 238000004070 electrodeposition Methods 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000012456 homogeneous solution Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 230000000717 retained effect Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/42—Electroplating: Baths therefor from solutions of light metals
- C25D3/44—Aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
813,446. Electrodeposition of aluminium. ZIEGLER, K. July 22, 1955 [July 28, 1954; June 13, 1955], No. 21284/55. Class 41. Aluminium is electrolytically deposited from a homogeneous liquid phase electrolyte protected against the access of air and comprising (1) a compound of the formula AIR(R<SP>1</SP>) 2 in which R is alkyl and R<SP>1</SP> is alkyl, hydrogen, or halogen together with (2) a complex compound formed by said compound and either (a) a compound MeR<SP>1</SP> where Me is an alkali metal and R<SP>1</SP> is alkyl, hydrogen, or halogen, or (b) a quaternary ammonium halide. The liquid phase may be a homogeneous solution in a solvent such as toluene, methyl naphthalene, tetrahydronaphthalene, diphenyl ether, tetrahydrofurane, dioxane, dimethyl aniline, or pyridine which does not decompose the organic aluminium compound. Access of air to the electrolyte is prevented by the use of either a covering layer of paraffin oil or an inert gas, e.g. nitrogen, atmosphere. Electrolysis is effected at bath temperatures of 60‹ to 200‹ C. and adherent deposits may be produced on aluminium or copper, e.g. as wire, cathodes. Decomposition of the aluminium alkyl with anodic evolution of hydrocarbon gases and the need to replace the lost alkyl which occur with anodes of copper, iron, and platinum may be avoided by the use of aluminium anodes. In this way too foundry aluminium may be purified, impurities being retained at the anodes by bagging them.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ4338A DE1047450B (en) | 1955-06-13 | 1955-06-13 | Electrolyte for the electrolytic deposition of aluminum |
| DE130655X | 1955-06-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB813446A true GB813446A (en) | 1959-05-13 |
Family
ID=25751738
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB21284/55A Expired GB813446A (en) | 1955-06-13 | 1955-07-22 | Process for the electrolytic deposition of aluminium |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US2849349A (en) |
| BE (1) | BE540052A (en) |
| CH (1) | CH350112A (en) |
| DE (1) | DE1047450B (en) |
| FR (1) | FR1134858A (en) |
| GB (1) | GB813446A (en) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3028322A (en) * | 1962-04-03 | Malmei | ||
| DE1101772B (en) * | 1956-04-09 | 1961-03-09 | Dr E H Karl Ziegler Dr | Process and device for refining aluminum |
| DE1114816B (en) * | 1957-06-12 | 1961-10-12 | Dr Dr E H Karl Ziegler | Process and apparatus for the production of tetraethyl lead |
| BE569921A (en) * | 1957-07-31 | |||
| NL236102A (en) * | 1958-02-13 | 1900-01-01 | ||
| NL247276A (en) * | 1959-01-12 | |||
| NL251298A (en) * | 1959-05-06 | |||
| US3206522A (en) * | 1959-08-10 | 1965-09-14 | Continental Oil Co | Production of alpha-olefins |
| DE1162576B (en) * | 1959-11-07 | 1964-02-06 | Guenther Hans Dipl Chem Dr | Electrolyte and process for the production of beryllium by fused-salt electrolysis of organic beryllium compounds |
| DE1170659B (en) * | 1959-12-01 | 1964-05-21 | Dr Cordes | Process for the electrolytic deposition of aluminum of high purity |
| US3028323A (en) * | 1959-12-24 | 1962-04-03 | Ethyl Corp | Manufacture of organolead products |
| US3028319A (en) * | 1960-02-01 | 1962-04-03 | Ethyl Corp | Manufacture of magnesium organo compounds |
| US3028318A (en) * | 1960-02-01 | 1962-04-03 | Ethyl Corp | Manufacture of zinc organo compounds |
| US3028320A (en) * | 1960-02-01 | 1962-04-03 | Ethyl Corp | Manufacture of tin alkyl compounds |
| DE1164101B (en) * | 1960-03-09 | 1964-02-27 | Siemens Ag | Process for the extraction of gallium or indium from the anode sludge of the electrorefining of aluminum in organometallic complex salts |
| NL134002C (en) * | 1960-06-07 | |||
| DE1236208B (en) | 1960-08-09 | 1967-03-09 | Siemens Ag | Process for fine cleaning of metallic elements from II. To ó ÷. Group of the periodic table |
| GB956990A (en) | 1960-10-29 | 1964-04-29 | Sumitomo Chemical Co | A method for manufacturing aluminum |
| DE1144490B (en) * | 1961-05-09 | 1963-02-28 | Dr E H Karl Ziegler Dr | Process for the cathodic deposition of sodium by electrolysis of organic complex compounds |
| NL278293A (en) * | 1961-05-23 | |||
| DE1146258B (en) * | 1961-06-30 | 1963-03-28 | Dr Karl Ziegler | Metal-organic electrolyte of high conductivity for the cathodic deposition of sodium |
| US3268421A (en) * | 1961-12-04 | 1966-08-23 | Nat Steel Corp | Electrodeposition of metals from a fused bath of aluminum halohydride organic complex and composition therefor |
| US3234115A (en) * | 1963-07-31 | 1966-02-08 | Ziegler Karl | Process for the electrolytic precipitation of sodium |
| DE1187380B (en) | 1963-09-13 | 1965-02-18 | Vaw Ver Aluminium Werke Ag | Electrolyte and process for the electrolytic deposition of high-purity aluminum from organometallic complex compounds |
| US3379628A (en) * | 1965-04-21 | 1968-04-23 | Continental Oil Co | Decorative etching of aluminum |
| US3409523A (en) * | 1966-03-10 | 1968-11-05 | Bell Telephone Labor Inc | Electroetching an aluminum plated semiconductor in a tetraalkylammonium hydroxide electrolyte |
| US3969195A (en) * | 1971-05-07 | 1976-07-13 | Siemens Aktiengesellschaft | Methods of coating and surface finishing articles made of metals and their alloys |
| DE3202265A1 (en) * | 1982-01-25 | 1983-07-28 | Siemens AG, 1000 Berlin und 8000 München | ELECTROLYTE FOR GALVANIC DEPOSITION OF ALUMINUM |
| DE3606325A1 (en) * | 1986-02-27 | 1987-09-03 | Talbot Waggonfab | UNDERCARRIAGE SUSPENSION FOR RAIL VEHICLES |
| DE3919068A1 (en) * | 1989-06-10 | 1990-12-13 | Studiengesellschaft Kohle Mbh | ALUMINUM ORGANIC ELECTROLYTE FOR THE ELECTROLYTIC DEPOSITION OF HIGH-PURITY ALUMINUM |
| DE3919069A1 (en) * | 1989-06-10 | 1990-12-13 | Studiengesellschaft Kohle Mbh | ALUMINUM ORGANIC ELECTROLYTE AND METHOD FOR ELECTROLYTICALLY DEPOSITING ALUMINUM |
| DE19855666A1 (en) * | 1998-12-01 | 2000-06-08 | Studiengesellschaft Kohle Mbh | Organoaluminum electrolytes and processes for electrolytic coating with aluminum or aluminum-magnesium alloys |
| US7250102B2 (en) * | 2002-04-30 | 2007-07-31 | Alumiplate Incorporated | Aluminium electroplating formulations |
| EP1518946A1 (en) * | 2003-09-27 | 2005-03-30 | Aluminal Oberflächtentechnik GmbH & Co. KG | Electrolyte for the galvanic deposition of aluminium |
| US6960677B1 (en) | 2003-10-28 | 2005-11-01 | Albemarle Corporation | Preparation of aluminates |
| DE102011055911B3 (en) * | 2011-12-01 | 2012-11-29 | Volkmar, Prof. Dr. Neubert | Process for the electrodeposition of at least one metal or semiconductor |
| JP5808866B2 (en) * | 2012-08-31 | 2015-11-10 | 株式会社日立製作所 | Non-aqueous electroplating method and non-aqueous electroplating apparatus |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2321367A (en) * | 1939-12-27 | 1943-06-08 | Hanson Van Winkle Munning Co | Anode bag |
| US2446349A (en) * | 1944-02-29 | 1948-08-03 | William Marsh Rice Inst For Th | Electrodeposition of aluminum |
| US2728718A (en) * | 1951-11-02 | 1955-12-27 | Battelle Development Corp | Aluminum coating |
-
0
- BE BE540052D patent/BE540052A/xx unknown
-
1955
- 1955-06-13 DE DEZ4338A patent/DE1047450B/en active Pending
- 1955-07-02 CH CH350112D patent/CH350112A/en unknown
- 1955-07-11 US US521424A patent/US2849349A/en not_active Expired - Lifetime
- 1955-07-20 FR FR1134858D patent/FR1134858A/en not_active Expired
- 1955-07-22 GB GB21284/55A patent/GB813446A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE540052A (en) | |
| FR1134858A (en) | 1957-04-18 |
| US2849349A (en) | 1958-08-26 |
| DE1047450B (en) | 1958-12-24 |
| CH350112A (en) | 1960-11-15 |
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