GB816683A - Improvements in detergent compositions - Google Patents
Improvements in detergent compositionsInfo
- Publication number
- GB816683A GB816683A GB4853/56A GB485356A GB816683A GB 816683 A GB816683 A GB 816683A GB 4853/56 A GB4853/56 A GB 4853/56A GB 485356 A GB485356 A GB 485356A GB 816683 A GB816683 A GB 816683A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- benzyl
- ethenoxy
- toluene
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 239000003599 detergent Substances 0.000 title abstract 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- -1 ethenoxy units Chemical group 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 abstract 3
- 229940073608 benzyl chloride Drugs 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 2
- 150000003863 ammonium salts Chemical class 0.000 abstract 2
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 239000011591 potassium Substances 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- LVAOBEYIJJPYNL-UHFFFAOYSA-N 2-[(1-sulfonaphthalen-2-yl)methyl]naphthalene-1-sulfonic acid Chemical compound C1=CC2=CC=CC=C2C(S(=O)(=O)O)=C1CC1=CC=C(C=CC=C2)C2=C1S(O)(=O)=O LVAOBEYIJJPYNL-UHFFFAOYSA-N 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 229920000388 Polyphosphate Polymers 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 abstract 1
- 150000004703 alkoxides Chemical class 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 238000004851 dishwashing Methods 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 abstract 1
- 239000001205 polyphosphate Substances 0.000 abstract 1
- 235000011176 polyphosphates Nutrition 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Liquid detergent compositions comprise, by weight, (a) 2-30 per cent, preferably 5-15 per cent, of the benzyl ether of octylphenoxypolyethenoxyethanol containing 12-30, preferably 16, ethenoxy units, either (b) 1-10 per cent, preferably 3-7 per cent, of the sodium, potassium, or ammonium salt of methylene bis-(naphthalene sulphonic acid), or (c) 0.5-15 per cent, preferably 0.5-3 per cent, of the sodium, potassium, or ammonium salt of one or more fatty acids containing 12-18 carbon atoms, or both (b) and (c), and (d) water to make up 100 per cent. The compositions may additionally contain up to 10 per cent, preferably 2-7 per cent, of tetrapotassium polyphosphate and up to 10 per cent, preferably 3-7 per cent, of one or more octylphenoxypolyethenoxyethanols containing 7-20, preferably 7.5-9.7, ethenoxy units. The compositions are said to be of particular use in dishwashing machines.ALSO:The benzyl ethers of octylphenoxy-polyethenoxyethanols containing 12-30 ethenoxy groups are prepared by reacting the appropriate octylphenoxypolyethenoxyethanol in an atmosphere of nitrogen and in an inert solvent, such as benzene, toluene, or xylene, with benzyl chloride or bromide in the presence of a strong base, for example an alkali or alkaline-earth metal hydroxide or an alkali-metal lower alkoxide, at a temperature of 50-200 DEG C., preferably 100-150 DEG C. Details are given of the preparation of the ether containing 15 ethenoxy groups, wherein the appropriate condensate is mixed at 100 DEG C. with sodium hydroxide in an atmosphere of nitrogen until all the hydroxide has dissolved. Benzyl chloride is then gradually introduced, after which the reaction mixture is maintained at 100-110 DEG C. for 3 hours. Toluene and water are then added and the mixture boiled, after which it is allowed to separate into 2 layers. The upper layer is steam stripped to remove toluene, benzyl chloride, and benzyl alcohol, and the remaining required product dried at 100 DEG C. and 2 mm. pressure, and finally filtered.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US492306A US2913416A (en) | 1955-03-04 | 1955-03-04 | Liquid detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB816683A true GB816683A (en) | 1959-07-15 |
Family
ID=23955764
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4853/56A Expired GB816683A (en) | 1955-03-04 | 1956-02-16 | Improvements in detergent compositions |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US2913416A (en) |
| DE (1) | DE1015973B (en) |
| FR (1) | FR1147166A (en) |
| GB (1) | GB816683A (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1088173B (en) * | 1958-01-29 | 1960-09-01 | Boehme Fettchemie Gmbh | Dishwashing liquid |
| NL262189A (en) * | 1960-03-09 | |||
| NL263962A (en) * | 1964-06-25 | |||
| NL89736C (en) * | 1973-03-15 | |||
| GB1565735A (en) * | 1977-05-10 | 1980-04-23 | Colgate Palmolive Co | Cleaning compositions |
| US4492646A (en) * | 1980-02-05 | 1985-01-08 | The Procter & Gamble Company | Liquid dishwashing detergent containing anionic surfactant, suds stabilizer and highly ethoxylated nonionic drainage promotor |
| GB8810188D0 (en) * | 1988-04-29 | 1988-06-02 | Unilever Plc | Detergent composition |
| FR2929954B1 (en) * | 2008-04-09 | 2010-04-30 | Rhodia Operations | AQUEOUS TREATMENT COMPOSITION INHIBITING CORROSION AND ACID ATTACK ON METAL SURFACES |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2555285A (en) * | 1951-05-29 | Detergent composition | ||
| US2856434A (en) * | 1958-10-14 | Ochjchz | ||
| US2089569A (en) * | 1932-03-02 | 1937-08-10 | Gen Aniline Works Inc | Addition products of glycide to organic compounds |
| US2178831A (en) * | 1938-04-26 | 1939-11-07 | Rohm & Haas | Aromatic polyalkylene ethers |
| US2543744A (en) * | 1946-04-04 | 1951-03-06 | Gen Aniline & Film Corp | Nonfoaming soap composition |
| US2560839A (en) * | 1947-07-24 | 1951-07-17 | Gen Aniline & Film Corp | Detergent composition |
| US2596091A (en) * | 1950-03-28 | 1952-05-13 | Rohm & Haas | Nonionic surface-active agents |
-
1955
- 1955-03-04 US US492306A patent/US2913416A/en not_active Expired - Lifetime
-
1956
- 1956-02-16 GB GB4853/56A patent/GB816683A/en not_active Expired
- 1956-02-28 DE DER18398A patent/DE1015973B/en active Pending
- 1956-03-03 FR FR1147166D patent/FR1147166A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US2913416A (en) | 1959-11-17 |
| DE1015973B (en) | 1957-09-19 |
| FR1147166A (en) | 1957-11-20 |
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