GB801795A - Improvements in or relating to copolymerisation - Google Patents
Improvements in or relating to copolymerisationInfo
- Publication number
- GB801795A GB801795A GB20728/56A GB2072856A GB801795A GB 801795 A GB801795 A GB 801795A GB 20728/56 A GB20728/56 A GB 20728/56A GB 2072856 A GB2072856 A GB 2072856A GB 801795 A GB801795 A GB 801795A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cobalt
- compounds
- unsaturated
- reacting
- tautomerically
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 3
- 239000010941 cobalt Substances 0.000 abstract 3
- 229910017052 cobalt Inorganic materials 0.000 abstract 3
- 150000001869 cobalt compounds Chemical class 0.000 abstract 3
- BMTAFVWTTFSTOG-UHFFFAOYSA-N Butylate Chemical compound CCSC(=O)N(CC(C)C)CC(C)C BMTAFVWTTFSTOG-UHFFFAOYSA-N 0.000 abstract 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 abstract 2
- 125000003545 alkoxy group Chemical class 0.000 abstract 2
- 150000001868 cobalt Chemical class 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 abstract 2
- 229920006305 unsaturated polyester Polymers 0.000 abstract 2
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 abstract 1
- PKQIDSVLSKFZQC-UHFFFAOYSA-N 3-oxobutanal Chemical compound CC(=O)CC=O PKQIDSVLSKFZQC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004606 Fillers/Extenders Substances 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001279 adipic acids Chemical class 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 238000005266 casting Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 abstract 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N fumaric acid group Chemical group C(\C=C\C(=O)O)(=O)O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid group Chemical group C(\C=C/C(=O)O)(=O)O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- TXXHDPDFNKHHGW-ZPUQHVIOSA-N muconic acid group Chemical group C(\C=C\C=C\C(=O)O)(=O)O TXXHDPDFNKHHGW-ZPUQHVIOSA-N 0.000 abstract 1
- 150000003022 phthalic acids Chemical class 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 150000003330 sebacic acids Chemical class 0.000 abstract 1
- 150000003442 suberic acids Chemical class 0.000 abstract 1
- 150000003444 succinic acids Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Unsaturated polyesters are copolymerized with unsaturated monomers, e.g. styrene, vinyl acetate and methyl methacrylate, in the presence of a cobalt compound selected from cobalt compounds of tautomerically reacting keto-enol compounds, cobalt carbonyl, cobalt alcoholates and cobalt salts of alkoxo acids, in amount sufficient to inhibit surface tackiness in the resulting polymer. Specified cobalt compounds are those of ethyl acetoacetate, formyl acetone, acetyl acetone and diethyl malonate, cobalt butylate and the cobalt salt of the reaction product of aluminium butylate and butyl alcohol. The alcoholates and alkoxo salts are preferably stabilized by reacting with tautomerically reacting keto-enol compounds, e.g. those listed above. The unsaturated polyesters may be prepared from maleic, fumaric, muconic, phthalic, succinic, adipic, sebacic and suberic acids and anhydrides and ethylene glycol, polyethylene glycols, propylene glycol, trimethylene glycol, 1:2-, 1:3-, 2:3- and 1:4-butanediol and 1:4-butenediol, optionally together with glycerol and trimethylolpropane, at least one of the components being unsaturated. Pigments, filters and extenders may be added and polymerization effected in the presence of a catalyst, e.g. benzoyl peroxide, to give castings and coatings.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE801796X | 1955-07-09 | ||
| DE801795X | 1955-07-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB801795A true GB801795A (en) | 1958-09-24 |
Family
ID=25948692
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB20728/56A Expired GB801795A (en) | 1955-07-09 | 1956-07-04 | Improvements in or relating to copolymerisation |
| GB4788/58A Expired GB801796A (en) | 1955-07-09 | 1956-07-04 | Improvements in or relating to copolymerisation |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4788/58A Expired GB801796A (en) | 1955-07-09 | 1956-07-04 | Improvements in or relating to copolymerisation |
Country Status (1)
| Country | Link |
|---|---|
| GB (2) | GB801795A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3361845A (en) * | 1960-02-03 | 1968-01-02 | Toyo Koatsu Ind Inc | Process for gelling unsaturated polyester resins by addition of alcoholates of aluminum and titanium |
| US3398213A (en) * | 1965-04-12 | 1968-08-20 | Norac Co | Polymerization of cobalt containing unsaturated polyester resins |
| EP0695365A4 (en) * | 1993-04-23 | 1998-07-08 | Boehringer Mannheim Corp | Extender containing polymer compositions and uses thereof |
-
1956
- 1956-07-04 GB GB20728/56A patent/GB801795A/en not_active Expired
- 1956-07-04 GB GB4788/58A patent/GB801796A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3361845A (en) * | 1960-02-03 | 1968-01-02 | Toyo Koatsu Ind Inc | Process for gelling unsaturated polyester resins by addition of alcoholates of aluminum and titanium |
| US3398213A (en) * | 1965-04-12 | 1968-08-20 | Norac Co | Polymerization of cobalt containing unsaturated polyester resins |
| EP0695365A4 (en) * | 1993-04-23 | 1998-07-08 | Boehringer Mannheim Corp | Extender containing polymer compositions and uses thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| GB801796A (en) | 1958-09-24 |
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