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GB786669A - Improvements in or relating to separating and recovering acid gases from gaseous mixtures - Google Patents

Improvements in or relating to separating and recovering acid gases from gaseous mixtures

Info

Publication number
GB786669A
GB786669A GB17788/55A GB1778855A GB786669A GB 786669 A GB786669 A GB 786669A GB 17788/55 A GB17788/55 A GB 17788/55A GB 1778855 A GB1778855 A GB 1778855A GB 786669 A GB786669 A GB 786669A
Authority
GB
United Kingdom
Prior art keywords
absorption
aminoacid
acid
alkaline solution
specified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17788/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vetrocoke SpA
Original Assignee
Vetrocoke SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vetrocoke SpA filed Critical Vetrocoke SpA
Publication of GB786669A publication Critical patent/GB786669A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1475Removing carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493Selection of liquid materials for use as absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/62Carbon oxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/16Hydrogen sulfides
    • C01B17/167Separation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/50Carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/12Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
    • C10K1/124Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors containing metal compounds other than alkali- or earth-alkali carbonates, hydroxides- or oxides- or salts of inorganic acids derived from sulfur
    • C10K1/126Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors containing metal compounds other than alkali- or earth-alkali carbonates, hydroxides- or oxides- or salts of inorganic acids derived from sulfur containing As-, Sb-, Sn compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/151Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

Carbon dioxide or hydrogen sulphide is separated from a gaseous mixture, e.g. coke oven gas or ammonia synthesis gas, by an absorption-desorption process using an alkaline solution containing an aminoacid added as such or in the form of a protein, the amount of alkali present being at least 1.5 times the stoichiometric amount necessary to form a salt of the aminoacid. Absorption is preferably carried out under pressure, e.g. 12 atmospheres, and at elevated temperature, e.g. 75 DEG C. Regeneration may be effected by passing hot air or steam through the solution maintained at a temperature below its b.p. The alkaline solution may contain sodium, potassium or ammonium carbonate, phosphate, borate, arsenite or phenate or an ethanolamine. Aminoacids specified are glycin, alanine, taurine, proline and glutammic, aminobenzoic, aminonaphthenic and aminophenolic acid. Proteins specified are albumins, gelatins, animal glue, casein and h moglobin. Boric acid, silicic acid, inorganic and organic salts of zinc, selenium, tellurium, aluminium and trivalent arsenic act as synergistic agents. Specifications 391,780 and 391,786 are referred to.
GB17788/55A 1954-06-21 1955-06-20 Improvements in or relating to separating and recovering acid gases from gaseous mixtures Expired GB786669A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT336052X 1954-06-21
IT335051X 1954-12-06
IT80255X 1955-02-08

Publications (1)

Publication Number Publication Date
GB786669A true GB786669A (en) 1957-11-20

Family

ID=27272686

Family Applications (2)

Application Number Title Priority Date Filing Date
GB17788/55A Expired GB786669A (en) 1954-06-21 1955-06-20 Improvements in or relating to separating and recovering acid gases from gaseous mixtures
GB35009/55A Expired GB798856A (en) 1954-06-21 1955-12-06 Process for separating and recovering carbon dioxide from gaseous mixtures

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB35009/55A Expired GB798856A (en) 1954-06-21 1955-12-06 Process for separating and recovering carbon dioxide from gaseous mixtures

Country Status (6)

Country Link
BE (2) BE543354A (en)
CH (2) CH336052A (en)
DE (1) DE1000356B (en)
FR (2) FR1126215A (en)
GB (2) GB786669A (en)
NL (1) NL95400C (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3039845A (en) * 1958-04-25 1962-06-19 Hoechst Ag Method of regenerating absorbent solutions
US3101996A (en) * 1961-03-29 1963-08-27 Chemical Construction Corp Process for removal of acid gas from gas streams
WO2009063041A1 (en) * 2007-11-15 2009-05-22 Basf Se Method for removing carbon dioxide from fluid flows, in particular combustion exhaust gases
WO2010049739A3 (en) * 2008-10-31 2010-06-24 University Of Leeds Process for the capture of carbon dioxide
US8034166B2 (en) 2006-05-18 2011-10-11 Basf Se Carbon dioxide absorbent requiring less regeneration energy
WO2011135378A1 (en) 2010-04-28 2011-11-03 The University Of Leeds Process for the capture of carbon dioxide
US8075673B2 (en) 2005-10-20 2011-12-13 Basf Se Absorption medium and method for removing carbon dioxide from gas streams
US8398749B2 (en) 2005-12-12 2013-03-19 Basf Se Process for the recovery of carbon dioxide
CN109198492A (en) * 2018-09-20 2019-01-15 浙江工业大学 Production method and device for reducing sulfite residue in frozen shrimp meat
US11351498B2 (en) 2017-08-02 2022-06-07 C-Capture Ltd C1-C8 carboxylic acid salt solution for the absorption of CO2

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL110178C (en) * 1958-03-07 1900-01-01
BE577652A (en) * 1959-01-16 1900-01-01
US4814104A (en) * 1987-02-05 1989-03-21 Uop Tertiary alkanolamine absorbent containing an ethyleneamine promoter and its method of use
CN119015834B (en) * 2023-05-24 2025-11-21 国家能源投资集团有限责任公司 Carbon dioxide separation membrane and preparation method thereof

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3039845A (en) * 1958-04-25 1962-06-19 Hoechst Ag Method of regenerating absorbent solutions
US3101996A (en) * 1961-03-29 1963-08-27 Chemical Construction Corp Process for removal of acid gas from gas streams
US8075673B2 (en) 2005-10-20 2011-12-13 Basf Se Absorption medium and method for removing carbon dioxide from gas streams
US8398749B2 (en) 2005-12-12 2013-03-19 Basf Se Process for the recovery of carbon dioxide
US8034166B2 (en) 2006-05-18 2011-10-11 Basf Se Carbon dioxide absorbent requiring less regeneration energy
WO2009063041A1 (en) * 2007-11-15 2009-05-22 Basf Se Method for removing carbon dioxide from fluid flows, in particular combustion exhaust gases
AU2008322922B2 (en) * 2007-11-15 2013-05-30 Basf Se Method for removing carbon dioxide from fluid flows, in particular combustion exhaust gases
US8388738B2 (en) 2007-11-15 2013-03-05 Basf Se Method for removing carbon dioxide from fluid flows, in particular combustion exhaust gases
WO2010049739A3 (en) * 2008-10-31 2010-06-24 University Of Leeds Process for the capture of carbon dioxide
CN102985159A (en) * 2010-04-28 2013-03-20 利兹大学 Process for the capture of carbon dioxide
WO2011135378A1 (en) 2010-04-28 2011-11-03 The University Of Leeds Process for the capture of carbon dioxide
US11351498B2 (en) 2017-08-02 2022-06-07 C-Capture Ltd C1-C8 carboxylic acid salt solution for the absorption of CO2
US12048894B2 (en) 2017-08-02 2024-07-30 C-Capture Ltd C1—C8 carboxylic acid salt solution for the absorption of CO2
CN109198492A (en) * 2018-09-20 2019-01-15 浙江工业大学 Production method and device for reducing sulfite residue in frozen shrimp meat
CN109198492B (en) * 2018-09-20 2022-01-14 浙江工业大学 Production method and device for reducing sulfite residue in frozen shrimp meat

Also Published As

Publication number Publication date
CH336052A (en) 1959-02-15
FR1137173A (en) 1957-05-24
BE543354A (en) 1955-12-30
GB798856A (en) 1958-07-30
CH335051A (en) 1958-12-31
BE539081A (en) 1955-07-15
NL95400C (en) 1960-08-20
FR1126215A (en) 1956-11-19
DE1000356B (en) 1957-01-10

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