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GB2622667B - Copper-containing hydrogenation catalysts for the hydrogenolysis of esters - Google Patents

Copper-containing hydrogenation catalysts for the hydrogenolysis of esters Download PDF

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Publication number
GB2622667B
GB2622667B GB2309826.2A GB202309826A GB2622667B GB 2622667 B GB2622667 B GB 2622667B GB 202309826 A GB202309826 A GB 202309826A GB 2622667 B GB2622667 B GB 2622667B
Authority
GB
United Kingdom
Prior art keywords
hydrogenolysis
esters
copper
hydrogenation catalysts
containing hydrogenation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
GB2309826.2A
Other versions
GB202309826D0 (en
GB2622667A (en
Inventor
Michael Small Stuart
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Publication of GB202309826D0 publication Critical patent/GB202309826D0/en
Publication of GB2622667A publication Critical patent/GB2622667A/en
Application granted granted Critical
Publication of GB2622667B publication Critical patent/GB2622667B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/392Metal surface area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/17Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/20Constitutive chemical elements of heterogeneous catalysts of Group II (IIA or IIB) of the Periodic Table
    • B01J2523/27Zinc
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/31Aluminium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
GB2309826.2A 2022-09-23 2023-06-29 Copper-containing hydrogenation catalysts for the hydrogenolysis of esters Active GB2622667B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB2213961.2A GB202213961D0 (en) 2022-09-23 2022-09-23 Copper-containing hydrogenation catalysts for the hydrogenolysis of esters

Publications (3)

Publication Number Publication Date
GB202309826D0 GB202309826D0 (en) 2023-08-16
GB2622667A GB2622667A (en) 2024-03-27
GB2622667B true GB2622667B (en) 2025-06-18

Family

ID=83978721

Family Applications (2)

Application Number Title Priority Date Filing Date
GBGB2213961.2A Ceased GB202213961D0 (en) 2022-09-23 2022-09-23 Copper-containing hydrogenation catalysts for the hydrogenolysis of esters
GB2309826.2A Active GB2622667B (en) 2022-09-23 2023-06-29 Copper-containing hydrogenation catalysts for the hydrogenolysis of esters

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GBGB2213961.2A Ceased GB202213961D0 (en) 2022-09-23 2022-09-23 Copper-containing hydrogenation catalysts for the hydrogenolysis of esters

Country Status (4)

Country Link
EP (1) EP4590432A1 (en)
CN (1) CN119855647A (en)
GB (2) GB202213961D0 (en)
WO (1) WO2024062209A1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005070537A1 (en) * 2004-01-21 2005-08-04 Avantium International B.V. Chromium-free catalysts of metalic cu and at least one second metal
WO2016059431A1 (en) * 2014-10-17 2016-04-21 Johnson Matthey Public Limited Company Catalyst and process
CN106140172A (en) * 2015-03-24 2016-11-23 南京博明科技有限责任公司 A kind of catalyst pressing liquid-phase hydrogenatin fatty alcohol be applicable to fatty acid methyl ester

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2091800A (en) 1931-09-15 1937-08-31 Rohm & Haas Method of hydrogenating esters
DE3942064A1 (en) 1989-10-04 1991-04-11 Henkel Kgaa PROCESS FOR PREPARING SAEFEFEST CATALYSTS FOR THE DIRECT HYDROGENATION OF CARBONIC ACIDS TO ALCOHOLS
GB9807131D0 (en) 1998-04-03 1998-06-03 Ici Plc Copper-containing materials
CN103657656A (en) 2013-12-02 2014-03-26 唐雅蓉 Preparation method of nickel-based catalyst
CN105363454B (en) 2014-08-27 2018-06-08 中国石油化工股份有限公司 Hydrogenation catalyst
BR112017020321B1 (en) 2015-03-26 2021-01-26 Basf Corporation catalyst, method for making a catalyst, and, process
GB201814682D0 (en) 2018-09-10 2018-10-24 Johnson Matthey Davy Technologies Ltd Process for the activation of oxidised catalysts

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005070537A1 (en) * 2004-01-21 2005-08-04 Avantium International B.V. Chromium-free catalysts of metalic cu and at least one second metal
WO2016059431A1 (en) * 2014-10-17 2016-04-21 Johnson Matthey Public Limited Company Catalyst and process
CN106140172A (en) * 2015-03-24 2016-11-23 南京博明科技有限责任公司 A kind of catalyst pressing liquid-phase hydrogenatin fatty alcohol be applicable to fatty acid methyl ester

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Applied Catalysis A: General, vol. 234, no. 1 - 2, 2002, Lindstrom B et al., Activity and characterization of Cu/Zn, Cu/Cr and Cu/Zr on gamma-alumina for methanol reforming for fuel cell vehicles, pages 111-125. *
PURE & APPLIED CHEMISTRY, vol. 84, no. 3, 2011, Liang Shuguang et al., Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the solvent and hydrogen source, pages 779-788. *

Also Published As

Publication number Publication date
GB202309826D0 (en) 2023-08-16
EP4590432A1 (en) 2025-07-30
WO2024062209A1 (en) 2024-03-28
CN119855647A (en) 2025-04-18
GB2622667A (en) 2024-03-27
GB202213961D0 (en) 2022-11-09

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