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GB2482531B - Adhesive composition with enhanced cure through volume - Google Patents

Adhesive composition with enhanced cure through volume

Info

Publication number
GB2482531B
GB2482531B GB1013201.7A GB201013201A GB2482531B GB 2482531 B GB2482531 B GB 2482531B GB 201013201 A GB201013201 A GB 201013201A GB 2482531 B GB2482531 B GB 2482531B
Authority
GB
United Kingdom
Prior art keywords
radically curable
component
curing
ester
metal salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
GB1013201.7A
Other versions
GB2482531A (en
GB201013201D0 (en
Inventor
Kevin Murnaghan
David Farrell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel Loctite Ireland Ltd
Original Assignee
Henkel Loctite Ireland Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Loctite Ireland Ltd filed Critical Henkel Loctite Ireland Ltd
Priority to GB1013201.7A priority Critical patent/GB2482531B/en
Publication of GB201013201D0 publication Critical patent/GB201013201D0/en
Priority to PCT/EP2011/063491 priority patent/WO2012017057A1/en
Publication of GB2482531A publication Critical patent/GB2482531A/en
Application granted granted Critical
Publication of GB2482531B publication Critical patent/GB2482531B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/10—Metal compounds
    • C08K3/11—Compounds containing metals of Groups 4 to 10 or of Groups 14 to 16 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1545—Six-membered rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Curing through large bond gaps, of approximately 0.5-1.0mm, has proven particularly challenging in the field of adhesives technology. There is difficulty associated with providing one-part adhesive formulations capable of curing through large bond gaps. Disclosed herein are radically curable compositions comprising a radically curable component, and an initiator component capable of initiating cure of the radically curable component. The initiator comprises at least one metal salt and a free radical generating component. The metal salt of the composition is chosen so that it is reduced at the surface to which it is applied. The compositions further comprise a reducing additive, such as a benzoin or ester thereof, ascorbic acid or an ester thereof, hydrazines, toluidines, tin (II) salts or compounds illustrated by two general structures disclosed within the application. Compounds according to the structures may, for example, be tocopherols, chromanols, gallic acid, tannic acid, pyrogallol or hydroquinone.
GB1013201.7A 2010-08-05 2010-08-05 Adhesive composition with enhanced cure through volume Expired - Fee Related GB2482531B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB1013201.7A GB2482531B (en) 2010-08-05 2010-08-05 Adhesive composition with enhanced cure through volume
PCT/EP2011/063491 WO2012017057A1 (en) 2010-08-05 2011-08-04 Adhesive composition with enhanced cure through volume

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1013201.7A GB2482531B (en) 2010-08-05 2010-08-05 Adhesive composition with enhanced cure through volume

Publications (3)

Publication Number Publication Date
GB201013201D0 GB201013201D0 (en) 2010-09-22
GB2482531A GB2482531A (en) 2012-02-08
GB2482531B true GB2482531B (en) 2013-11-13

Family

ID=42931253

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1013201.7A Expired - Fee Related GB2482531B (en) 2010-08-05 2010-08-05 Adhesive composition with enhanced cure through volume

Country Status (2)

Country Link
GB (1) GB2482531B (en)
WO (1) WO2012017057A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104959117B (en) * 2015-06-25 2017-05-10 福州大学 A kind of pyrogallol bonded silica gel adsorbent and its preparation method and application
WO2019178645A1 (en) * 2018-03-23 2019-09-26 Csl Limited Method of treating asthma
WO2025007195A1 (en) 2023-07-05 2025-01-09 CSL Innovation Pty Ltd Methods of treating or preventing a complication of sickle cell disease

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2279354A (en) * 1993-06-24 1995-01-04 Nat Starch Chem Corp Method of sealing leaks in underground gas mains and compositions for use therein
JPH11181360A (en) * 1997-12-18 1999-07-06 Denki Kagaku Kogyo Kk Adhesive composition, cured object, composite, and bonding method
JP2000104041A (en) * 1998-09-28 2000-04-11 Daicel Chem Ind Ltd Heat-sensitive adhesive, heat-sensitive adhesive sheet, and method for producing heat-sensitive adhesive sheet
US6214929B1 (en) * 1998-03-10 2001-04-10 Basf Aktiengesellscaft Stabilized polymer dispersions or polymer solutions, and prepared polymers obtainable therefrom
US20040077766A1 (en) * 2001-03-08 2004-04-22 Ria De Cooman Easy to manufacture meth(acrylic) adhesive compositions
US20060252866A1 (en) * 2005-05-03 2006-11-09 Xiaobin Wang Adhesives for metal bonding applications
US20070078207A1 (en) * 2005-09-30 2007-04-05 Jonn Jerry Y Stabilizer cyanoacrylate formulations
JP2007169502A (en) * 2005-12-22 2007-07-05 Nitto Denko Corp Water-dispersible acrylic pressure-sensitive adhesive composition for re-peeling and pressure-sensitive adhesive sheet
CN101368330A (en) * 2008-09-25 2009-02-18 湖南多喜爱纺织科技有限公司 Preparation method for polymer reduction nanometer silver antibiotic finishing agent and uses thereof
US20090281335A1 (en) * 2008-05-07 2009-11-12 Henkel Corporation Cure Accelerators for Anaerobic Curable Compositions
JP2009270068A (en) * 2008-05-09 2009-11-19 Denki Kagaku Kogyo Kk Adhesive for optical component
US20100081751A1 (en) * 2005-06-24 2010-04-01 Bluestar Silicones France Use of an Organopolysiloxane Composition Vulcanizable From Room Temperature To Form A Self-Adhesive Elastomer

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3970505A (en) 1973-01-15 1976-07-20 Loctite Corporation Anaerobic compositions and surface activator therefor
CA2136882A1 (en) 1993-12-20 1995-06-21 William J. Catena Structural acrylic adhesives
DE19501933A1 (en) * 1995-01-24 1996-07-25 Henkel Kgaa Aerobically curable adhesive
KR20060126838A (en) * 2004-03-09 2006-12-08 헨켈 코포레이션 Thermally Conductive Two Part Adhesive Composition
US20090288771A1 (en) 2008-05-23 2009-11-26 Loctite (R&D) Limited Surface-promoted cure of one-part radically curable compositions

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2279354A (en) * 1993-06-24 1995-01-04 Nat Starch Chem Corp Method of sealing leaks in underground gas mains and compositions for use therein
JPH11181360A (en) * 1997-12-18 1999-07-06 Denki Kagaku Kogyo Kk Adhesive composition, cured object, composite, and bonding method
US6214929B1 (en) * 1998-03-10 2001-04-10 Basf Aktiengesellscaft Stabilized polymer dispersions or polymer solutions, and prepared polymers obtainable therefrom
JP2000104041A (en) * 1998-09-28 2000-04-11 Daicel Chem Ind Ltd Heat-sensitive adhesive, heat-sensitive adhesive sheet, and method for producing heat-sensitive adhesive sheet
US20040077766A1 (en) * 2001-03-08 2004-04-22 Ria De Cooman Easy to manufacture meth(acrylic) adhesive compositions
US20060252866A1 (en) * 2005-05-03 2006-11-09 Xiaobin Wang Adhesives for metal bonding applications
US20100081751A1 (en) * 2005-06-24 2010-04-01 Bluestar Silicones France Use of an Organopolysiloxane Composition Vulcanizable From Room Temperature To Form A Self-Adhesive Elastomer
US20070078207A1 (en) * 2005-09-30 2007-04-05 Jonn Jerry Y Stabilizer cyanoacrylate formulations
JP2007169502A (en) * 2005-12-22 2007-07-05 Nitto Denko Corp Water-dispersible acrylic pressure-sensitive adhesive composition for re-peeling and pressure-sensitive adhesive sheet
US20090281335A1 (en) * 2008-05-07 2009-11-12 Henkel Corporation Cure Accelerators for Anaerobic Curable Compositions
JP2009270068A (en) * 2008-05-09 2009-11-19 Denki Kagaku Kogyo Kk Adhesive for optical component
CN101368330A (en) * 2008-09-25 2009-02-18 湖南多喜爱纺织科技有限公司 Preparation method for polymer reduction nanometer silver antibiotic finishing agent and uses thereof

Also Published As

Publication number Publication date
GB2482531A (en) 2012-02-08
WO2012017057A1 (en) 2012-02-09
GB201013201D0 (en) 2010-09-22

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee

Effective date: 20150805