GB2311538A - Detergent compositions - Google Patents

Detergent compositions Download PDF

Info

Publication number: GB2311538A
Authority: GB; United Kingdom
Prior art keywords: acid; detergent composition; alkyl; preferred; sodium
Prior art date: 1996-03-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

GB9606757A

Other languages

English (en)

Other versions

GB9606757D0 (en

Inventor

Michael Crombie Addison

Rhona Alexandra Knox

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-03-29

Filing date

1996-03-29

Publication date

1997-10-01

1996-03-29 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

1996-03-29 Priority to GB9606757A priority Critical patent/GB2311538A/en

1996-06-05 Publication of GB9606757D0 publication Critical patent/GB9606757D0/en

1997-03-25 Priority to EP97919928A priority patent/EP0889947A4/fr

1997-03-25 Priority to PCT/US1997/004953 priority patent/WO1997036990A1/fr

1997-03-25 Priority to CA 2250293 priority patent/CA2250293A1/fr

1997-10-01 Publication of GB2311538A publication Critical patent/GB2311538A/en

Status Withdrawn legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims description 164
239000003599 detergent Substances 0.000 title claims description 75
-1 amino tricarboxylic acid Chemical class 0.000 claims description 118
150000003839 salts Chemical class 0.000 claims description 50
125000000217 alkyl group Chemical group 0.000 claims description 39
238000000034 method Methods 0.000 claims description 29
239000011734 sodium Substances 0.000 claims description 19
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 18
229910052708 sodium Inorganic materials 0.000 claims description 18
CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 16
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 16
238000004851 dishwashing Methods 0.000 claims description 16
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 15
239000001301 oxygen Substances 0.000 claims description 15
229910052760 oxygen Inorganic materials 0.000 claims description 15
229920005646 polycarboxylate Polymers 0.000 claims description 14
125000001424 substituent group Chemical group 0.000 claims description 11
229910019142 PO4 Inorganic materials 0.000 claims description 8
238000004061 bleaching Methods 0.000 claims description 8
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 7
239000010452 phosphate Substances 0.000 claims description 7
125000000547 substituted alkyl group Chemical group 0.000 claims description 5
238000010412 laundry washing Methods 0.000 claims description 2
JEOQACOXAOEPLX-WCCKRBBISA-N (2s)-2-amino-5-(diaminomethylideneamino)pentanoic acid;1,3-thiazolidine-4-carboxylic acid Chemical compound OC(=O)C1CSCN1.OC(=O)[C@@H](N)CCCN=C(N)N JEOQACOXAOEPLX-WCCKRBBISA-N 0.000 claims 2
125000000962 organic group Chemical group 0.000 claims 1
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims 1
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims 1
150000001875 compounds Chemical class 0.000 description 68
239000002243 precursor Substances 0.000 description 49
125000004432 carbon atom Chemical group C* 0.000 description 36
239000000463 material Substances 0.000 description 35
239000002689 soil Substances 0.000 description 35
239000002253 acid Substances 0.000 description 34
239000007844 bleaching agent Substances 0.000 description 30
239000004094 surface-active agent Substances 0.000 description 30
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 30
239000003795 chemical substances by application Substances 0.000 description 29
239000011248 coating agent Substances 0.000 description 29
239000000047 product Substances 0.000 description 29
239000000243 solution Substances 0.000 description 28
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 22
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 22
150000002500 ions Chemical class 0.000 description 21
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
102000004190 Enzymes Human genes 0.000 description 20
108090000790 Enzymes Proteins 0.000 description 20
229940088598 enzyme Drugs 0.000 description 20
238000000576 coating method Methods 0.000 description 19
229920001577 copolymer Polymers 0.000 description 19
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 17
229910052709 silver Inorganic materials 0.000 description 17
239000004332 silver Substances 0.000 description 17
238000005406 washing Methods 0.000 description 17
108010065511 Amylases Proteins 0.000 description 16
102000013142 Amylases Human genes 0.000 description 16
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 16
125000003118 aryl group Chemical group 0.000 description 16
235000019418 amylase Nutrition 0.000 description 15
238000005260 corrosion Methods 0.000 description 15
230000007797 corrosion Effects 0.000 description 15
235000014113 dietary fatty acids Nutrition 0.000 description 15
239000000194 fatty acid Substances 0.000 description 15
229930195729 fatty acid Natural products 0.000 description 15
229920000768 polyamine Polymers 0.000 description 15
239000000344 soap Substances 0.000 description 15
108090001060 Lipase Proteins 0.000 description 14
239000004367 Lipase Substances 0.000 description 14
102000004882 Lipase Human genes 0.000 description 14
150000001204 N-oxides Chemical class 0.000 description 14
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 14
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 14
229910001385 heavy metal Inorganic materials 0.000 description 14
239000003112 inhibitor Substances 0.000 description 14
235000019421 lipase Nutrition 0.000 description 14
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 13
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 13
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical class C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 13
108091005804 Peptidases Proteins 0.000 description 13
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 13
150000007513 acids Chemical class 0.000 description 13
235000019832 sodium triphosphate Nutrition 0.000 description 13
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
125000000129 anionic group Chemical group 0.000 description 12
150000001768 cations Chemical class 0.000 description 12
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 12
229910052757 nitrogen Inorganic materials 0.000 description 12
229920000036 polyvinylpyrrolidone Polymers 0.000 description 12
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 12
239000003352 sequestering agent Substances 0.000 description 12
229910052938 sodium sulfate Inorganic materials 0.000 description 12
235000011152 sodium sulphate Nutrition 0.000 description 12
239000010457 zeolite Substances 0.000 description 12
239000004382 Amylase Substances 0.000 description 11
101710194948 Protein phosphatase PhpP Proteins 0.000 description 11
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 11
150000008051 alkyl sulfates Chemical group 0.000 description 11
229910052681 coesite Inorganic materials 0.000 description 11
229910052906 cristobalite Inorganic materials 0.000 description 11
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
150000004967 organic peroxy acids Chemical class 0.000 description 11
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 11
150000004965 peroxy acids Chemical class 0.000 description 11
239000000377 silicon dioxide Substances 0.000 description 11
235000012239 silicon dioxide Nutrition 0.000 description 11
229910052682 stishovite Inorganic materials 0.000 description 11
229910052905 tridymite Inorganic materials 0.000 description 11
YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 10
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 10
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 10
241001122767 Theaceae Species 0.000 description 10
229910021536 Zeolite Inorganic materials 0.000 description 10
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
229910052783 alkali metal Inorganic materials 0.000 description 10
150000001408 amides Chemical class 0.000 description 10
150000004665 fatty acids Chemical class 0.000 description 10
229920000642 polymer Polymers 0.000 description 10
238000012360 testing method Methods 0.000 description 10
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 9
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
239000004365 Protease Substances 0.000 description 9
239000004115 Sodium Silicate Substances 0.000 description 9
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 9
125000002877 alkyl aryl group Chemical group 0.000 description 9
239000002518 antifoaming agent Substances 0.000 description 9
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 9
229910052911 sodium silicate Inorganic materials 0.000 description 9
229920002134 Carboxymethyl cellulose Polymers 0.000 description 8
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 8
125000002947 alkylene group Chemical group 0.000 description 8
239000011230 binding agent Substances 0.000 description 8
235000010948 carboxy methyl cellulose Nutrition 0.000 description 8
239000002270 dispersing agent Substances 0.000 description 8
150000002148 esters Chemical class 0.000 description 8
150000002191 fatty alcohols Chemical class 0.000 description 8
JPZROSNLRWHSQQ-UHFFFAOYSA-N furan-2,5-dione;prop-2-enoic acid Chemical compound OC(=O)C=C.O=C1OC(=O)C=C1 JPZROSNLRWHSQQ-UHFFFAOYSA-N 0.000 description 8
239000002245 particle Substances 0.000 description 8
241000894007 species Species 0.000 description 8
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
150000001340 alkali metals Chemical class 0.000 description 7
125000002091 cationic group Chemical group 0.000 description 7
238000013270 controlled release Methods 0.000 description 7
230000000694 effects Effects 0.000 description 7
150000002430 hydrocarbons Chemical class 0.000 description 7
229920000620 organic polymer Polymers 0.000 description 7
239000012188 paraffin wax Substances 0.000 description 7
235000021317 phosphate Nutrition 0.000 description 7
239000007787 solid Substances 0.000 description 7
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 7
150000003467 sulfuric acid derivatives Chemical class 0.000 description 7
108010059892 Cellulase Proteins 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 6
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 6
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
229920002125 Sokalan® Polymers 0.000 description 6
239000000654 additive Substances 0.000 description 6
229910052784 alkaline earth metal Inorganic materials 0.000 description 6
229910001424 calcium ion Inorganic materials 0.000 description 6
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
229940106157 cellulase Drugs 0.000 description 6
229910052736 halogen Inorganic materials 0.000 description 6
150000002367 halogens Chemical class 0.000 description 6
125000000623 heterocyclic group Chemical group 0.000 description 6
125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
230000002401 inhibitory effect Effects 0.000 description 6
239000007788 liquid Substances 0.000 description 6
239000000178 monomer Substances 0.000 description 6
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 6
229920001296 polysiloxane Polymers 0.000 description 6
239000011591 potassium Substances 0.000 description 6
229910052700 potassium Inorganic materials 0.000 description 6
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 6
229940100515 sorbitan Drugs 0.000 description 6
230000000087 stabilizing effect Effects 0.000 description 6
238000006467 substitution reaction Methods 0.000 description 6
239000003826 tablet Substances 0.000 description 6
239000003760 tallow Substances 0.000 description 6
238000012546 transfer Methods 0.000 description 6
OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical class C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 5
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 5
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 5
235000008733 Citrus aurantifolia Nutrition 0.000 description 5
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 5
239000004902 Softening Agent Substances 0.000 description 5
235000011941 Tilia x europaea Nutrition 0.000 description 5
239000012190 activator Substances 0.000 description 5
125000002723 alicyclic group Chemical group 0.000 description 5
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 5
239000011575 calcium Substances 0.000 description 5
229920002678 cellulose Chemical class 0.000 description 5
239000001913 cellulose Chemical class 0.000 description 5
235000010980 cellulose Nutrition 0.000 description 5
229960004106 citric acid Drugs 0.000 description 5
239000004927 clay Substances 0.000 description 5
238000004140 cleaning Methods 0.000 description 5
239000007859 condensation product Substances 0.000 description 5
DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 5
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
239000004744 fabric Substances 0.000 description 5
150000002194 fatty esters Chemical class 0.000 description 5
238000009472 formulation Methods 0.000 description 5
125000000524 functional group Chemical group 0.000 description 5
239000003966 growth inhibitor Substances 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
229910052739 hydrogen Inorganic materials 0.000 description 5
239000004571 lime Substances 0.000 description 5
230000003287 optical effect Effects 0.000 description 5
150000002894 organic compounds Chemical class 0.000 description 5
XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical class OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 5
239000000843 powder Substances 0.000 description 5
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
235000019795 sodium metasilicate Nutrition 0.000 description 5
239000007921 spray Substances 0.000 description 5
229910021653 sulphate ion Inorganic materials 0.000 description 5
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical class [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 4
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
TTZMPOZCBFTTPR-UHFFFAOYSA-N O=P1OCO1 Chemical compound O=P1OCO1 TTZMPOZCBFTTPR-UHFFFAOYSA-N 0.000 description 4
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
108010056079 Subtilisins Proteins 0.000 description 4
102000005158 Subtilisins Human genes 0.000 description 4
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
229910000323 aluminium silicate Inorganic materials 0.000 description 4
229940025131 amylases Drugs 0.000 description 4
125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 4
239000003945 anionic surfactant Substances 0.000 description 4
150000001450 anions Chemical group 0.000 description 4
229910052791 calcium Inorganic materials 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
239000013078 crystal Substances 0.000 description 4
150000005690 diesters Chemical class 0.000 description 4
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 4
UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
238000007046 ethoxylation reaction Methods 0.000 description 4
239000003925 fat Substances 0.000 description 4
235000019197 fats Nutrition 0.000 description 4
238000005187 foaming Methods 0.000 description 4
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
239000004615 ingredient Substances 0.000 description 4
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical class CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
239000002736 nonionic surfactant Substances 0.000 description 4
239000013110 organic ligand Substances 0.000 description 4
239000002304 perfume Substances 0.000 description 4
229920001223 polyethylene glycol Polymers 0.000 description 4
238000006116 polymerization reaction Methods 0.000 description 4
229920005989 resin Polymers 0.000 description 4
239000011347 resin Substances 0.000 description 4
229940045872 sodium percarbonate Drugs 0.000 description 4
159000000000 sodium salts Chemical class 0.000 description 4
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 4
QAEDZJGFFMLHHQ-UHFFFAOYSA-N trifluoroacetic anhydride Chemical compound FC(F)(F)C(=O)OC(=O)C(F)(F)F QAEDZJGFFMLHHQ-UHFFFAOYSA-N 0.000 description 4
229920001567 vinyl ester resin Polymers 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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239000008158 vegetable oil Substances 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
238000011179 visual inspection Methods 0.000 description 1
235000008939 whole milk Nutrition 0.000 description 1
150000003751 zinc Chemical class 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)

GB9606757A 1996-03-29 1996-03-29 Detergent compositions Withdrawn GB2311538A (en)

Priority Applications (4)

Application Number	Priority Date	Filing Date	Title
GB9606757A GB2311538A (en)	1996-03-29	1996-03-29	Detergent compositions
EP97919928A EP0889947A4 (fr)	1996-03-29	1997-03-25	Composition detergente pour lave-vaisselle
PCT/US1997/004953 WO1997036990A1 (fr)	1996-03-29	1997-03-25	Composition detergente pour lave-vaisselle
CA 2250293 CA2250293A1 (fr)	1996-03-29	1997-03-25	Composition detergente pour lave-vaisselle

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB9606757A GB2311538A (en)	1996-03-29	1996-03-29	Detergent compositions

Publications (2)

Publication Number	Publication Date
GB9606757D0 GB9606757D0 (en)	1996-06-05
GB2311538A true GB2311538A (en)	1997-10-01

Family

ID=10791349

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
GB9606757A Withdrawn GB2311538A (en)	1996-03-29	1996-03-29	Detergent compositions

Country Status (4)

Country	Link
EP (1)	EP0889947A4 (fr)
CA (1)	CA2250293A1 (fr)
GB (1)	GB2311538A (fr)
WO (1)	WO1997036990A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2013000848A1 (fr) *	2011-06-29	2013-01-03	Basf Se	Aminocarboxylates modifiés ayant une meilleure stabilité à l'entreposage et une meilleure ouvrabilité
WO2013000844A1 (fr) *	2011-06-29	2013-01-03	Basf Se	Utilisation d'aminocarboxylates dans le domaine agricole
WO2015032451A1 (fr) *	2013-09-09	2015-03-12	Ecolab Usa Inc.	Élimination synergique de taches par le biais d'une nouvelle combinaison de chélateurs
US9403731B2 (en)	2011-06-29	2016-08-02	Basf Se	Modified aminocarboxylates with improved storage stability and processability
WO2016138954A1 (fr) *	2015-03-04	2016-09-09	Ecolab Usa Inc.	Élimination synergique de salissures protéiniques au moyen d'une nouvelle combinaison de chélateurs

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102004044411A1 (de)	2004-09-14	2006-03-30	Basf Ag	Reinigungsformulierungen für die maschinelle Geschirrreinigung enthaltend hydrophob modifizierte Polycarboxylate
GB0522658D0 (en) *	2005-11-07	2005-12-14	Reckitt Benckiser Nv	Composition
ES2982202T3 (es) *	2013-09-09	2024-10-15	Ecolab Usa Inc	Método de lavado de vajilla basado en la eliminación sinérgica de manchas mediante una nueva combinación de quelantes
US20230106979A1 (en)	2020-02-28	2023-04-06	Conopco Inc., D/B/A Unilever	Dishwash detergent product

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4997587A (en) *	1988-09-02	1991-03-05	Basf Aktiengesellschaft	Washing and cleaning agents containing β-alanine-N,N-diacetic acid
WO1994029421A1 (fr) *	1993-06-16	1994-12-22	Basf Aktiengesellschaft	Utilisation de derives de glycine-n,n-acide diacetique comme agents complexants biodegradables pour des ions de metaux lourds et alcalino-terreux, et leur procede de preparation

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Publication number	Priority date	Publication date	Assignee	Title
US3721633A (en) *	1969-10-06	1973-03-20	Atlas Chem Ind	Aqueous built liquid detergents containing alkyl glycosides
DE1964026A1 (de) *	1969-12-20	1971-06-24	Henkel & Cie Gmbh	Wasch- und Reinigungsmittel
US3832309A (en) *	1971-02-01	1974-08-27	Ethyl Corp	Detergent formulations
ATA800274A (de) *	1974-10-04	1983-12-15	Henkel Kgaa	Verfahren zum waschen bzw. bleichen von textilien sowie mittel dazu
DE2535518A1 (de) *	1975-08-08	1977-02-24	Henkel & Cie Gmbh	Schaumarmes waschmittel
US4303556A (en) *	1977-11-02	1981-12-01	The Procter & Gamble Company	Spray-dried detergent compositions
US4233171A (en) *	1978-09-11	1980-11-11	Desoto, Inc.	Dishwashing detergent effective at low temperature
US4780234A (en) *	1986-05-06	1988-10-25	Staley Continental, Inc.	Built liquid laundry detergent containing alkyl glycoside surfactant
BR9408091A (pt) *	1993-11-20	1997-08-12	Unilever Nv	Processo de lavar pratos com máquina
GB9407535D0 (en) *	1994-04-13	1994-06-08	Procter & Gamble	Detergent compositions
EP0682105A3 (fr) *	1994-04-13	1997-11-05	The Procter & Gamble Company	Compositions de blanchiment
KR100249610B1 (ko) *	1995-02-28	2000-03-15	데이비드 엠 모이어	과산소 표백제 및 철, 구리 또는 망간에 대한 킬레이트화제를 함유하는 액체 조성물,및 이를 사용하여 세탁물을 예비처리하는 방법
GB2311542A (en) *	1996-03-29	1997-10-01	Procter & Gamble	Percarbonate bleach composition

1996
- 1996-03-29 GB GB9606757A patent/GB2311538A/en not_active Withdrawn
1997
- 1997-03-25 WO PCT/US1997/004953 patent/WO1997036990A1/fr not_active Ceased
- 1997-03-25 CA CA 2250293 patent/CA2250293A1/fr not_active Abandoned
- 1997-03-25 EP EP97919928A patent/EP0889947A4/fr not_active Withdrawn

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4997587A (en) *	1988-09-02	1991-03-05	Basf Aktiengesellschaft	Washing and cleaning agents containing β-alanine-N,N-diacetic acid
WO1994029421A1 (fr) *	1993-06-16	1994-12-22	Basf Aktiengesellschaft	Utilisation de derives de glycine-n,n-acide diacetique comme agents complexants biodegradables pour des ions de metaux lourds et alcalino-terreux, et leur procede de preparation

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2608221C2 (ru) *	2011-06-29	2017-01-17	Басф Се	Модифицированные аминокарбоксилаты с повышенной стабильностью при хранении и улучшенными технологическими свойствами
WO2013000844A1 (fr) *	2011-06-29	2013-01-03	Basf Se	Utilisation d'aminocarboxylates dans le domaine agricole
CN103608315A (zh) *	2011-06-29	2014-02-26	巴斯夫欧洲公司	氨基羧酸化物在农业中的用途
WO2013000848A1 (fr) *	2011-06-29	2013-01-03	Basf Se	Aminocarboxylates modifiés ayant une meilleure stabilité à l'entreposage et une meilleure ouvrabilité
CN103608315B (zh) *	2011-06-29	2017-02-08	巴斯夫欧洲公司	氨基羧酸化物在农业中的用途
US9403731B2 (en)	2011-06-29	2016-08-02	Basf Se	Modified aminocarboxylates with improved storage stability and processability
WO2015032451A1 (fr) *	2013-09-09	2015-03-12	Ecolab Usa Inc.	Élimination synergique de taches par le biais d'une nouvelle combinaison de chélateurs
JP2016534207A (ja) *	2013-09-09	2016-11-04	エコラボユーエスエーインコーポレイティド	新規なキレート化剤の組合せによる相乗的汚れ除去
CN105555930A (zh) *	2013-09-09	2016-05-04	艺康美国股份有限公司	通过新的螯合剂组合来协同去污
EP3272847A1 (fr) *	2013-09-09	2018-01-24	Ecolab USA Inc.	Élimination synergique de taches par le biais d'une nouvelle combinaison de chélateurs
CN105555930B (zh) *	2013-09-09	2018-09-28	艺康美国股份有限公司	通过新的螯合剂组合来协同去污
WO2016138954A1 (fr) *	2015-03-04	2016-09-09	Ecolab Usa Inc.	Élimination synergique de salissures protéiniques au moyen d'une nouvelle combinaison de chélateurs
US10767139B2 (en)	2015-03-04	2020-09-08	Ecolab Usa Inc.	Synergistic protein soil removal through novel chelator combination

Also Published As

Publication number	Publication date
CA2250293A1 (fr)	1997-10-09
GB9606757D0 (en)	1996-06-05
EP0889947A4 (fr)	1999-07-28
EP0889947A1 (fr)	1999-01-13
WO1997036990A1 (fr)	1997-10-09

Publication	Publication Date	Title
US6162259A (en)	2000-12-19	Machine dishwashing and laundry compositions
US6159922A (en)	2000-12-12	Bleaching composition
US6165970A (en)	2000-12-26	Detergent composition comprising acrylic acid-based polymer and amino tricarboxylic acid-based compound
GB2294268A (en)	1996-04-24	Bleaching composition for dishwasher use
US6313086B1 (en)	2001-11-06	Detergent compositions containing and effervescent
GB2311535A (en)	1997-10-01	Detergent compositions
GB2311536A (en)	1997-10-01	Dishwashing and laundry detergents
GB2311538A (en)	1997-10-01	Detergent compositions
CA2232205A1 (fr)	1998-09-20	Particule detergente
GB2311541A (en)	1997-10-01	Oxygen-releasing bleach composition
CA2250246A1 (fr)	1997-10-09	Composition de blanchiment
CA2256702A1 (fr)	1997-12-04	Compositions detergentes
CA2261904A1 (fr)	1998-02-05	Compositions detergentes
GB2325243A (en)	1998-11-18	Removing tarnish from tarnished silverware
US5843877A (en)	1998-12-01	Machine dishwashing compositions containing an oxygen bleach and a bismuth salt to reduce silver tarnishing
GB2297096A (en)	1996-07-24	Bleaching composition.
GB2309032A (en)	1997-07-16	Bismuth salts and complexes with nitrogen-free organic diphosphonic acids
WO1998000491A1 (fr)	1998-01-08	Composition detergente
GB2323372A (en)	1998-09-23	An effervescent laundry detergent composition
WO1998026039A1 (fr)	1998-06-18	Procede de fabrication de compositions detergentes se presentant sous forme de pastilles
CA2268671C (fr)	2002-12-10	Composition detergente
GB2309974A (en)	1997-08-13	Use of cellulose ethers for soil removal
CA2151659C (fr)	1999-07-20	Compositions de detergents
GB2334528A (en)	1999-08-25	Hydrogen peroxide releasing detergent composition
GB2309975A (en)	1997-08-13	Use of cellulose ethers in dishwashing

Legal Events

Date	Code	Title	Description
1998-07-15	WAP	Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)