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GB2124081A - Cosmetic containing glycerol ester of polymerised rosin - Google Patents

Cosmetic containing glycerol ester of polymerised rosin Download PDF

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Publication number
GB2124081A
GB2124081A GB08320099A GB8320099A GB2124081A GB 2124081 A GB2124081 A GB 2124081A GB 08320099 A GB08320099 A GB 08320099A GB 8320099 A GB8320099 A GB 8320099A GB 2124081 A GB2124081 A GB 2124081A
Authority
GB
United Kingdom
Prior art keywords
cosmetic composition
composition according
alcohol
purpose cosmetic
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB08320099A
Other versions
GB2124081B (en
GB8320099D0 (en
Inventor
Marlene Tietjen
Tibor Goldner
Kalyan K Basak
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Revlon Inc
Original Assignee
Revlon Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Revlon Inc filed Critical Revlon Inc
Publication of GB8320099D0 publication Critical patent/GB8320099D0/en
Publication of GB2124081A publication Critical patent/GB2124081A/en
Application granted granted Critical
Publication of GB2124081B publication Critical patent/GB2124081B/en
Expired legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/08Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/10Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

A multi-purpose cosmetic composition which contains a cosmetically acceptable solvent volatile at room temperature and a glycerol ester of polymerized rosin, said composition leaving a waterproof film upon application.

Description

SPECIFICATION Multi-purpose cosmetic composition This invention relates to a multi-purpose cosmetic composition which is readily applied by spreading and leaves a waterproof film. Suitable cosmetic products which can be prepared from the composition include: hair touch-up, eyebrow coloring, eyeshadow, leg make-up, face make-up, blusher, mascara and the like.
The advantages of waterproof cosmetics which are easily applied are obvious. Waterproof cosmetics have a longer cosmetic effect than their non-waterproof counterparts since they are less susceptible to moisture from the human body or from swimming, bathing, etc. Hence, touch-ups to maintain the original effect are required less frequently. Moreover, since the present invention is easily applied, it is simpler for the consumer to achieve the desired effect.
In accordance with the present invention, the cosmetic composition is essentially in the form of a lipophylic cream gel comprising a cosmetically acceptable solvent volatile at room temperature such as petroleum distillate which is both economical and readily available, and a glycerol ester of polymerized rosin which normally exists as a mixture of the mono-, di- and tri-esters. The glycerol ester of polymerized rosin is the waterproof film-former component of the cosmetic composition. Preferred embodiments of the instant invention further comprise agents for controlling the viscosity of the product which modify the attributes of the film including plasticizers, organically modified hectorites, polymers, and any polar, cosmetically acceptable liquid and, optionally, a cosmetically acceptable waxy base.
The multi-purpose cosmetic composition of this invention preferably comprises in parts by weight: Petroleum distillate 30 -70 Glycerol ester of polymerized rosin 5-15 Oleyl alcohol 3- 6 Quaternium hectorite 3- 4 Waxy base 6- 8 The cosmetically suitable volatile solvents employed herein are hydrocarbon solvents, especially Cg to C11 iso- and straight chained paraffins having a boiling point at least about 1 00 C to about 21 5 C.
Glycerol esters of polymerized rosin which are suitable in the present invention can be prepared by methods generally known in the art. The chief constituents of rosin, which is derived from pine trees, are resin acids of the abietic and primarictypes having the general formula C1gH29COOH and a phenanthrene nucleus. Upon polymerization of rosin, heterogenous dimers are predominantly produced with lesser amounts of monomer and higher homologues. The esterification reaction conditions of the polymerized rosin are known to those skilled in the art and normally result in a mixture of mono-, di- and tri-esters which can be employed in the present invention.Glycerol esters of polymerized rosin are also readily commercially available, including the glycerol ester of polymerized rosin available under the trade name Poly-pale Ester 10 (Hercules, Inc.).
Depending on the type of cosmetic product which is prepared from the above base composition and the desired effect, color pigments, dyes, minerals, and agents to control the viscosity of the product which are generally known in the art may be added thereto.
Preferred colorants include iron oxides, titanium dioxides, ultramarine blue, titanated mica, and mica.
Agents for controlling the viscosity of the product include plasticizers, organically modified hectorites, polymers, and any polar, cosmetically suitable liquid. To plasticize and detackifythe base composition and to act as a cosolvent any fatty alcohols and/or acids known for such purposes to those skilled in the art can be utilized, but saturated or unsaturated fatty alcohols having 12 to 18 carbon atoms, e.g., linolenyl alcohol, linoleyi alcohol, oleyl alcohol, steary alcohol, cetyl alcohol and myristyl alcohol are preferred herein. Oleyl alcohol is especially preferred. Suitable organically modified hectorites include commercially available quaternium hectorites, e.g., quaternium- 18 hectorite (N.L. Chemicals).Polymers of low molecular weight are also useful for controlling viscosity, and of these, low density polyethylene (LDPE) is preferred. Examples of acceptable polar liquids for use with hectorites are lanolin, ethanol, isopropanol, and water. A particularly preferred agent for controlling viscosity of hectorite is propylene carbonate.
Any known cosmetically suitable wax, oil, semi-solid liquid or combination thereof can be used herein as a waxy base. Examples include carnauba wax, ozokerite, natural and synthetic beeswaxes, candelilla wax, isopropyi myristate, paraffin, bayberry wax, hydrogenated castor oil, vegetable oils, mineral oil, and lanolin or its derivatives. Preferred waxes are carnauba wax and ozokerite.
The above base composition and cosmetic products prepared therefrom can be prepared by any of the art-recognized techniques to obtain a uniform dispersion, e.g., by high-speed milling.
The following examples serve to illustrate specific embodiments of the present invention and not to limit the scope thereof. Unless otherwise noted, the following compositions were prepared by a high-speed mill.
The rosin ester, petroleum distillate, waxes and quaternium hectorite were charged into the mill. After the waxes were melted at 85"C and the hectorite was uniformly dispersed by high-speed milling, propylene carbonate in an amount sufficient to form a gel was added. Thereafter, colorants were added and the milling continued until a uniform dispersion was obtained. The figures indicate parts by weight.
EXAMPLE I Hafr gleamerleyebrow coloringleyeshadow Petroleum distillate 52.85 Glycerol ester of polymerized rosin 6.00 Oleyl alcohol 3.00 Ozokerite 3.00 Carnauba wax 3.00 Quaternium hectorite 3.00 Propylene carbonate 0.90 Uitramarine blue 6.00 Bismuth oxychloride 8.00 Titanated mica 14.00 Preservatives q.s.
100.00 EXAMPLE 2 Leg makeup Petroleum distillate 52.85 Glycerol ester of polymerized rosin 6.00 Oleyl alcohol 3.00 Ozokerite 3.00 Carnauba wax 3.00 Quaternium hectorite 3.00 Propylene carbonate 0.90 Titanium dioxide 10.00 Mica 10.00 Iron oxide yellow 4.00 Iron oxide red 4.00 Preservatives q.s 100.00 EXAMPLE 3 Face makeup Petroleum distillate 58.85 Glycerol ester of polymerized rosin 6.00 Oleyl alcohol 3.00 Ozokerite 3.00 Carnauba wax 3.00 Quanternium hectorite 3.00 Quanternium carbonate 0.90 Titanium dioxide 10.00 Talc 5.00 Iron oxide yellow 3.00 Iron oxide red 3.00 Iron oxide black 0.50 Preservatives q.s.
100.00 EXAMPLE 4 Blusher Petroleum distillate 52.85 Glycerol ester of polymerized rosin 6.00 Oleyl alcohol 3.00 Carnauba wax 3.00 Quaternium hectorite 3.00 Propylene hectorite 0.90 Propylene carbonate 1.10 D & Red t 7 7 1.80 Iron oxide red 1.50 Iron oxide yellow 0.60 Ultramarine blue 4.00 Bismuth oxychloride 10.00 Mica/titanium dioxide coated iron oxide yellow Preservatives q.s.
100.00 EXAMPLE 5 Mascara Petroleum distillate 53.85 Glycerol ester of polymerized rosin 12.00 Oleyl alcohol 4.00 Ozokerite 4.00 Carnauba wax 4.00 Quaternium hectorite 4.00 Propylene carbonate 1.20 Iron oxide black 15.00 Ferric ferrocyanide 0.50 Preservatives q.s.
100.00

Claims (15)

1. A multi-purpose cosmetic composition which comprises: a. a cosmetically acceptable solvent volatile at room temperature, and b. a glycerol ester of polymerized rosin.
2. A multi-purpose cosmetic composition according to claim 1 wherein the volatile solvent is petroleum distillate.
3. A multi-purpose cosmetic composition according to claim 1, which further comprises a fatty alcohol of from about 12 to about 18 carbon atoms.
4. A multi-purpose cosmetic composition according to claim 1 or 3 which further comprises an organically modified clay.
5. A multi-purpose composition according to claim 3 wherein the fatty alcohol is selected from the group consisting of linolenyl alcohol, linoleyl alcohol, oleyl alcohol, stearyl alcohol, cetyl alcohol and myristyl alcohol.
6. A multi-purpose composition according to claim 5 wherein the fatty alcohol is oleyl alcohol.
7. A multi-purpose cosmetic composition according to claim 4 wherein the organically modified clay is quaternium hectorite.
8. A multi-purpose cosmetic composition according to claim 1 or 3 which further comprises a waxy base.
9. A multi-purpose cosmetic composition according to claim 8 wherein the waxy base comprises carnauba wax and ozokerite.
10. A multi-purpose cosmetic composition according to claim 1 or 3 which further comprise colorants.
11. A multi-purpose cosmetic composition according to claim 10 wherein the colorants are color pigments, dyes and minerals.
12. A multi-purpose cosmetic composition according to claim 1 to 3 which further comprises an agent to control the viscosity of the composition.
13. A multi-purpose cosmetic composition according to claim 12 wherein said agent is propylene carbonate.
14. A multi-purpose cosmetic composition which comprises: a. 30-70 parts by weight petroleum distillate; b. 5-15 parts by weight glycerol ester of polymerized rosin; c. 3-6 parts by weight oleyl alcohol; d. 3-4 parts by weight quaternium hectorite; and e. 6-8 parts by weight waxy base.
15. A multi-purpose cosmetic composition according to claim 14 wherein the waxy base comprises carnauba wax and ozokerite.
GB08320099A 1982-07-26 1983-07-26 Cosmetic containing glycerol ester of polymerised rosin Expired GB2124081B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US40177882A 1982-07-26 1982-07-26

Publications (3)

Publication Number Publication Date
GB8320099D0 GB8320099D0 (en) 1983-08-24
GB2124081A true GB2124081A (en) 1984-02-15
GB2124081B GB2124081B (en) 1985-09-11

Family

ID=23589192

Family Applications (1)

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GB08320099A Expired GB2124081B (en) 1982-07-26 1983-07-26 Cosmetic containing glycerol ester of polymerised rosin

Country Status (3)

Country Link
CA (1) CA1204061A (en)
GB (1) GB2124081B (en)
PH (1) PH18894A (en)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0205961A3 (en) * 1985-05-29 1987-10-14 Estee Lauder Inc. Cosmetic composition
WO1991012793A1 (en) * 1990-03-01 1991-09-05 L'oreal Water resistant composition for coating eyelashes, and preparation method therefor
WO1992019215A1 (en) * 1991-04-26 1992-11-12 The Procter & Gamble Company Cosmetic waterproofing composition
US5925337A (en) * 1990-03-01 1999-07-20 L'oreal Waterproof composition for covering the eyelashes, and process for the preparation thereof
US5976195A (en) * 1996-09-06 1999-11-02 L'oreal Oxidation dye composition for keratin fibers containing an oxidation dye precursor and amphiphilic polymer
US5989295A (en) * 1996-09-06 1999-11-23 L'oreal Oxidation dye composition for keratin fibres, comprising an anionic amphiphilic polymer
US6010541A (en) * 1996-07-23 2000-01-04 L'oreal Oxidation dye composition for keratin fibers comprising a nonionic amphiphilic polymer
EP1122277A3 (en) * 2000-02-04 2002-01-02 Shin-Etsu Chemical Co., Ltd. A novel silicone compound, a powder surface-treated with this compound, and makeup containing this powder
EP1122276A3 (en) * 2000-02-01 2002-01-02 Shin-Etsu Chemical Co., Ltd. A novel silicone compound and a makeup containing this compound
US9004791B2 (en) 2010-04-30 2015-04-14 The Procter & Gamble Company Package for multiple personal care compositions
US9140681B2 (en) 2012-05-15 2015-09-22 The Procter & Gamble Company Method for quantitatively determining eyelash clumping
US9173824B2 (en) 2011-05-17 2015-11-03 The Procter & Gamble Company Mascara and applicator
US9216145B2 (en) 2009-10-27 2015-12-22 The Procter & Gamble Company Semi-permanent cosmetic concealer
US9237992B2 (en) 2009-10-27 2016-01-19 The Procter & Gamble Company Two-step mascara product
US10034829B2 (en) 2010-10-27 2018-07-31 Noxell Corporation Semi-permanent mascara compositions
WO2021240247A1 (en) 2020-05-29 2021-12-02 Industrias Alen, S.A. De C.V. Wax-like formulations of natural-origin materials and its method of preparation

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0205961A3 (en) * 1985-05-29 1987-10-14 Estee Lauder Inc. Cosmetic composition
WO1991012793A1 (en) * 1990-03-01 1991-09-05 L'oreal Water resistant composition for coating eyelashes, and preparation method therefor
FR2659011A1 (en) * 1990-03-01 1991-09-06 Oreal WATER - RESISTANT COMPOSITION FOR COATING LACQUERS, AND PROCESS FOR PREPARING THE SAME.
US5925337A (en) * 1990-03-01 1999-07-20 L'oreal Waterproof composition for covering the eyelashes, and process for the preparation thereof
WO1992019215A1 (en) * 1991-04-26 1992-11-12 The Procter & Gamble Company Cosmetic waterproofing composition
US6277155B1 (en) 1996-07-23 2001-08-21 L'oreal Oxidation dye composition for keratin fibers comprising a nonionic amphiphilic polymer
US6344063B1 (en) 1996-07-23 2002-02-05 L'oreal Oxidation dye composition for keratin fibers comprising nonionic amphiphilic polymer
US6010541A (en) * 1996-07-23 2000-01-04 L'oreal Oxidation dye composition for keratin fibers comprising a nonionic amphiphilic polymer
US5989295A (en) * 1996-09-06 1999-11-23 L'oreal Oxidation dye composition for keratin fibres, comprising an anionic amphiphilic polymer
US5976195A (en) * 1996-09-06 1999-11-02 L'oreal Oxidation dye composition for keratin fibers containing an oxidation dye precursor and amphiphilic polymer
US6074439A (en) * 1996-09-06 2000-06-13 L'oreal Oxidation dye composition for keratin fibers containing an oxidation dye precursor and an anionic amphiphilic polymer
US6527814B1 (en) 1996-09-06 2003-03-04 L'oreal S.A. Oxidation dye composition for keratin fibers, comprising an anionic amphiphilic polymer
KR100674559B1 (en) * 2000-02-01 2007-01-26 신에쓰 가가꾸 고교 가부시끼가이샤 New Silicone Compounds and Cosmetics Using the Same
US6479686B2 (en) 2000-02-01 2002-11-12 Shin-Etsu Chemical Co., Ltd. Silicon compound, and a makeup containing this compound
EP1122276A3 (en) * 2000-02-01 2002-01-02 Shin-Etsu Chemical Co., Ltd. A novel silicone compound and a makeup containing this compound
US6759031B2 (en) 2000-02-01 2004-07-06 Shi-Etsu Chemical Co., Ltd. Silicone compound, and a makeup containing this compound
US6717003B2 (en) 2000-02-04 2004-04-06 Shin-Etsu Chemical Co., Ltd. Silicone compound, a powder surface-treated with this compound, and a makeup containing this powder
EP1122277A3 (en) * 2000-02-04 2002-01-02 Shin-Etsu Chemical Co., Ltd. A novel silicone compound, a powder surface-treated with this compound, and makeup containing this powder
US9216145B2 (en) 2009-10-27 2015-12-22 The Procter & Gamble Company Semi-permanent cosmetic concealer
US9237992B2 (en) 2009-10-27 2016-01-19 The Procter & Gamble Company Two-step mascara product
US9004791B2 (en) 2010-04-30 2015-04-14 The Procter & Gamble Company Package for multiple personal care compositions
US10034829B2 (en) 2010-10-27 2018-07-31 Noxell Corporation Semi-permanent mascara compositions
US9173824B2 (en) 2011-05-17 2015-11-03 The Procter & Gamble Company Mascara and applicator
US9140681B2 (en) 2012-05-15 2015-09-22 The Procter & Gamble Company Method for quantitatively determining eyelash clumping
WO2021240247A1 (en) 2020-05-29 2021-12-02 Industrias Alen, S.A. De C.V. Wax-like formulations of natural-origin materials and its method of preparation

Also Published As

Publication number Publication date
CA1204061A (en) 1986-05-06
PH18894A (en) 1985-10-30
GB2124081B (en) 1985-09-11
GB8320099D0 (en) 1983-08-24

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19920726