GB2196548A

GB2196548A - Colloidal grout mixing

Info

Publication number: GB2196548A
Application number: GB08723792A
Authority: GB
Inventors: John Isherwood; Gary Christian; Timothy James Wearden
Original assignee: British Nuclear Fuels PLC
Current assignee: Sellafield Ltd
Priority date: 1986-10-28
Filing date: 1987-10-09
Publication date: 1988-05-05
Anticipated expiration: 2007-10-09
Also published as: JPS63112107A; GB8625715D0; GB2196548B; FR2605788A1; JP2815857B2; GB8723792D0; FR2605788B1; DE3736145C2; DE3736145A1

Description

GB2196548A 1

SPECIFICATION

Colloidal grout mixing This invention relates to colloidal grout mixing and apparatus therefor, and more particularly but 5 not exclusively, to a method and apparatus for mixing colloidal grouts in a system for immobilis ing solid radioactive waste.

The term -colloidal grout- is used herein to describe cementitious grouts prepared using colloidal type mixers. These grouts are not colloidal in the strict scientific sense although they undoubtedly contain some colloidal size material. 10 The properties which make colloidal grouts specially suited to high quality grouting applications (eg. grouting of prestressed concrete members, and in the immobilisation of radioactive waste) are minimal bleed (ie. water ejection from the grout), segregation and filtration (ie. particles filtering out or depositing), and the ability to displace water. This ensures that good penetration of fine fissures is achieved, and that voids initially filled with cement grout remain fully grouted 15 following hydration of the cement.

Many types of grout mixers are known, including paddle and colloidal mixers. Paddle mixers simply mix grout by means of a rotating paddle which throws the grout against baffles attached to the side of a mixing tank, and are usually used for grouts having water/cement ratios greater than 0.5. Colloidal mixers provide a grout of higher quality, and work by subjecting cement 20 particles in water to a high shearing action, thus removing any air attached to the particles and ensuring thorough wetting of the particles. The shearing force in such colloidal mixers is some times supplied by rotating rollers, but usually by an impeller which rotates at high speed.

The above known colloidal grout mixers have a number of drawbacks. Firstly, most are usually only capable of mixing relatively small quantites of grout and those of higher capacity require a 25 high energy input. This leads to an unacceptable temperature rise (eg. above 3WC) during mixing of the grout and can lead to the formation of microcracks in the grout when fully hydrated.

Also, the high shear action of the mixer, means that a second tank is needed for grout hold-up prior to distribution by a non-shear pump, since pumping from the mixer would produce exces sive additional shear and so adversely affect the grout properties. 30 The present invention, therefore, in one aspect provides a method of mixing a colloidal grout, the method comprising, feeding a measured quantity of water into a cylindrical vessel, rotating a paddle means having a plurality of paddle members at a relatively high speed in the vessel, the paddle members being positioned relative to the base of the vessel and having a shape and a dimension relative to the internal radius of the vessel such as to produce a high shear region 35 near the base and a vortex in the water, and feeding a measured quantity of grout materials downwardly into the vortex so as to mix the grout materials and thereby produce a colloidal grout.

Preferably, the paddle means is subsequently rotated at a relatively low speed so as to maintain the colloidal grout mobile in the vessel. 40 According to another aspect of the invention, a colloidal grout mixing apparatus comprises a cylindrical mixing vessel, an outlet port at or near the base of the vessel, a non-shear pump means for discharging mixed grout from the outlet port, and a mixing means having two speeds and extending into the vessel, the mixing means including a shaft aligned substantially co-axially with the longitudinal axis of the vessel and a paddle means mounted on the shaft, the paddle 45 means comprising a plurality of paddle members each having a shape adapted to cause substan tial outward radial displacement therefrom as the shaft rotates, each paddle member being positioned at substantially the same distance above the base of the vessel and having a radial dimension relative to the internal radius of the vessel such that in operation at the faster of the two speeds, the paddle means produces a vortex in liquid in the vessel and a high shear region 50 near the base, and at the lower of the two speeds maintains a colloidal grout in the vessel mobile.

Preferably, the base is of dished form, and the paddle means is located relative to the base such as to provide a region of substantially uniform swirling near the base.

A recirculation circuit may be provided between the pump means and the vessel, for the 55 recirculation of grout materials/water mixture discharged from the vessel. The invention further includes a system for immobilising radioactive waste, comprising a colloidal grout mixing appara tus in accordance with the invention, a vibratory platform for supporting a container for radio active waste, and a discharge duct adapted to connect between the pump means and the container. Preferably, the system includes a pressurised gas source connectable to the discharge 60 duct.

The invention will now be further described by way of example only with reference to the Figure in the accompanying drawing, which shows a side diagrammatic representation of a system for immobilising radioactive waste and incorporating a grout mixing apparatus of the invention. 65 2 GB2196548A 2 Referring to the Figure, a cylindrical vessel 10 is shown with a dished base 12, and is supported through load cells 11 from radial projections 13. A top entry mixer 14 extends into the vessel 10 and has a paddle mixer 18 mounted on a shaft 20 aligned substantially coaxially with the longitudinal axis of the vessel 10 and arranged to be driven by a two-speed electric motor 22. The paddle mixer 18 is located near the base 12, and is adapted to produce a high 5 shear region thereat when the motor 22 is at the higher speed. The radial dimensions of the paddle mixer 18 are such as to produce a vortex in liquid (not shown) in the vessel 10 at this higher speed. Inlets 28, 29 for grout materials and water respectively locate above the vessel 10, and a discharge duct 30 from the base 12 connects through a shut-off valve 32 to a non- shear pump 34 such as a peristaltic pump or a Mono pump which discharges through a duct 36 10 to a two-way valve 38. A duct 42 from the valve 38 is connected to the side of the vessel 10 at two vertically displaced, injection ports 46, 48 respectively. A duct 50 from the valve 38 connects with a three-way valve 52 having one duct 54 connected to a three-way valve 56, another duct 58 leading to a grout dump (not shown), and a third duct 60 connected to settling tanks (not shown). The valve 56 has a duct 62 which leads to a drum 64 containing radioactive 15 waste (not shown) and mounted on a vibratory platform 66. A compressed air duct 68 dis charges into the valve 56, and a return duct 70 extends from the valve 56 to the vessel 10.

In operation, using the load cells 11 to monitor the required weights, firstly water is fed through the duct 29, then the motor 22 is operated at its higher speed, so that a vortex is produced in the water by the rotation of the paddle mixer 18. Pre-mixed grout materials are fed 20 through the duct 28 into the vortex and the high shear region produced by the paddle mixer 18 so that the grout materials are thoroughly wetted. When mixing of the grout materials and water has formed a colloidal grout, the motor 22 is run at its lower speed to keep the colloidal grout mobile without any additional shearing action on the colloidal grout. In order to optimise the mixing regime in the vessel 10, the grout materials and water may be recirculated through the 25 duct 30, and the duct 42, and injected through the ports 46, 48 into the vessel 10 until mixing is complete.

When the colloidal grout is required, the valve 32 is opened and the pump 34 discharges the grout through the duct 54, the valve 56 and the duct 62 to the drum 64, the amount of grout discharged being monitored by the load cells 11 and excess grout being returned to the vessel 30 by the duct 70. The drum 64 is vibrated by the platform 66 to assist infilling of the colloidal grout into the fissures and crevices of the radioactive waste in the drum 64, and compressed air through the ducts 68, 62 aids injection of the grout into the drum 64.

An internal spray ring (not shown) is fitted inside the vessel 10 to wash down the interior of the vessel 10, the valve 52 being selected to dump either surplus colloidal grout from the vessel 35 through the duct 58, or washdown liquid from the vessel 10 through the duct 60 to the settling tanks. The vessel 10 is desirably constructed from stainless steel to assist washdown.

Use of the dished base 12 is advantageous in that it results in fairly uniform swirling near the base 12. Instead of discharging through the parts 46, 48, the duct 42 may extend (not shown) above the vessel 10 and discharge downwardly into the vessel 10 at a position displaced from 40 and on the opposite side of the shaft 20 to the duct 28.

It has been found that with a paddle mixer 18 having a diameter D and a vessel 10 having an internal diameter T, optimum performance of the apparatus has been obtained when D 7 45 T 16 When D=35 cm, optimum height of the paddle mixer 18 is between 30-43 cm above the base of the vessel 10, preferably about 35 cm. 50 A suitable paddle mixer, for example Model R100, obtained from Lightnin Mixers Ltd, Poynton, Cheshire, England, or Mixing Equipment Co, Rochester, New York 14603, USA, may be oper ated at from 380 to 466 rpm for mixing and about 180-210 rpm for maintaining the colloidal grout mobile. Such a paddle mixer has flat paddles aligned in longitudinal axial planes with respect to the shaft 20 and located all at the same height above the base of the vessel 10. 55 The grout mixing apparatus of the invention has been used to produce colloidal grouts which remain workable for up to 21 hours.

2 Suitable grout materials for the immobilisation of radioactive waste might have a grout base of ground blast furnace slag (BFS)/ordinary Portland cement (OPC), in a proportion of 70-90% BFS by weight but a ratio 75 BFS/25 OPC by weight is preferred. A water/solid ratio of between 60 0.31 to 0.35 by weight is desirable, preferably 0.33 .02. For a water/solid ratio of 0.33, chilled water at about 8'C should be used to prevent excessive temperature rise of the grout as it is kept mobile for up to 21 hours. A lower water/solid ratio of 0.31 would require the use of 2 chilled water at about 5'C to prevent excessive temperature rise. An acceptable maximum temperature of the grout is about 30'C. When the grout is to be used soon after it has been 65 3 GB2196548A 3 mixed, the use of chilled water should not be necessary. Conventional equipment (not shown) may be used to produce the chilled water required.

Pulverised fuel ash (PFA) and OPC is another cementitious mixture that might be used, particularly for immobilising plutonium contaminated waste materials when proportions of be tween 70% and 80% PFA with a water to solids ratio of 0.41 to 0.50 might be used. A 5 preferred OPC should have relatively low (CaO), SiO, balanced by S'02 to reduce the energy of the reaction between the OPC and water.

For grouts used in immobilising radioactive waste:

(i) the OPC should comply with British Standard 12:1978 which is incorporated by reference herein and preferably with further compliance with the following limits: 10 weight% tricalcium silicate - 48-55 dicalcium silicate - 12-24 tricalcium aluminate - 9-11 15 tetracalcium aluminoferrite - 5-11 Na,0 equivalent = Na20+0.658K20 max 0.8% by weight Chloride (water soluble) max 30 ppm Surface area 350 30 sq metres/kg 20 (ii) The BFS should comply with the draft British Standard BS6699 which is incorporated by reference herein, and preferably with further compliance with the following limits:

weight% 25 Fe203 0.80% max A1,0, 15 max Na20 0.6 max K20 1.0 max Chloride (water soluble) 30 ppm max 30 Surface area 340 30 sq metres/kg Density 2.90-2.95 g/CM3 Loss on ignition not exceeding 0% by weight (iii) The PFA should comply with BS 3892 Part 1:1982 which is incorporated by reference 35 herein and preferably with further compliance with the following limits:

weight% Na,0 equivalent (water soluble) 0.20 max Chloride (water soluble) 0.003 max 40 Colour index 7 max Density 2.0 g/CM3min Although the invention has been described in relation to mixing a colloidal grout for use in immobilising radioactive waste, grouts produced by the invention might also have applications in 45 the civil engineering and construction industries.

Claims

1. A colloidal grout mixing apparatus comprising a cylindrical mixing vessel, an outlet port at or near the base of the vessel, and a non-shear pump means for discharging mixed grout from 50 the outlet port, wherein there is provided a mixing means having two speeds and extending into the vessel, the mixing means including a shaft aligned substantially coaxially with the longitudinal axis of the vessel and a paddle means mounted on the shaft, the paddle means comprising a plurality of paddle members each having a shape adapted to cause substantial outward radial displacement therefrom as the shaft rotates, each paddle member being positioned at substan- 55 tially the same distance above the base of the vessel and having a radial dimension relative to the internal radius of the vessel such that in operation, at the faster of the two speeds, the paddle means produces a vortex in liquid in the vessel and a high shear region near the base, and at the lower of the two speeds maintains a colloidal grout in the vessel mobile.

2. An apparatus as claimed in Claim 1, wherein the base is of dished form, and the paddle 60 means is located relative to the base such as to provide a region of substantially uniform swirling near the base.

3. An apparatus as claimed in Claim 2, wherein the paddle members are between 30 to 41 cm above the base of the vessel.

4. An apparatus as claimed in any one of the preceding Claims, wherein the ratio: 65 4 GB2196548A 4 radius of paddle members 7 internal radius of the vessel 16

5 5. An apparatus as claimed in any one of the preceding Claims wherein the diameter of the paddle members is substantially the same as the height of the paddle members above the base.

6. An apparatus as claimed in any one of the preceding Claims, wherein the paddle members are of flat form and lie in respective longitudinal axial planes with respect to the shaft.

7. An apparatus as claimed in any one of the preceding Claims, wherein load cells support 10 the vessel so as to monitor the weight of material fed into and discharged from the vessel.

8. An apparatus as claimed in any one of the preceding Claims, wherein a recirculation circuit is provided between the pump means and the vessel, for the recirculation of grout materials/ water mixture discharged from the vessel.

9. An apparatus as claimed in Claim 8, wherein the recirculation circuit connects to the side 15 of the vessel.

10. A system for immobilising radioactive waste including a colloidal grout mixing apparatus as claimed in any one of the preceding Claims, and further comprising a vibratory platform for supporting a container for radioactive waste, and a discharge duct adapted to connect between the pump means and the container for infilling the container with colloidal grout from the mixing 20 apparatus.

11. A system as claimed in Claim 10, wherein a pressurized gas source is connectable to the discharge duct to assist the infilling of the container.

12. A method of mixing a colloidal grout, the method comprising feeding a measured quan- tity of water into a cylindrical vessel, rotating a paddle means having a plurality of paddle 25 members at a relatively high speed in the vessel, the paddle members being positioned relative to the base of the vessel and having a shape and a radial dimension relative to the internal radius of the vessel such as to produce a high shear region near the base and vortex in the water, feeding a measured quantity of grout materials downwardly into the vortex so as to mix the grout materials and the water and thereby produce a colloidal grout, and subsequently 30 rotating the paddle means at a relatively low speed so as to maintain the colloidal grout mobile in the vessel.

13. A method as claimed in Claim 12, wherein the grout materials comprise a mixture comprising 70% to 90% by weight ground blast furnace slag and ordinary Portland cement, and the measured quantities are such as to produce a water/solids ratio of between 0.31 to 0.35 by 35 weight.

14. A method as claimed in Claim 13, wherein the mixture comprises 75% by weight of ground blast furnace slag.

15. A method as claimed in Claim 13 or Claim 14, wherein the water/solids ratio is 0.33 0.02 by weight. 40

16. A method as claimed in any one of Claims 13 to 15, wherein the cement comprises:

tricalcium silicate - 48-55% by weight dicalcium silicate - 12-24% by weight tricalcium aluminate - 9-11 % by weight 45 tetracalcium aluminoferrite 5-11 % by weight

17. A method as claimed in any one of Claims 13 to 16, wherein the blast furnace slag comprises:

50 Fe,O, 0.80% max by weight A1203 15 max by weight Na20 0.6 max by weight K20 1.0 max by weight 55

18. A method as claimed in Claim 12 wherein the grout materials comprise a mixture comprising 70 to 80% by weight pulverised fuel ash and ordinary Portland cement, and the measured quantities are such that a colloidal grout is produced having a water/solids ratio of between 0.41 to 0.50 by weight.

19. A colloidal grout mixing apparatus substantially as hereinbefore described with reference 60 to the accompanying drawings.

20. A system for immobilising radioactive waste substantially as hereinbefore described with reference to the accompanying drawing.

21. A method of mixing a colloidal grout as claimed in Claim 12 and substantially as hereinbefore described with reference to the accompanying drawing. 65 GB2196548A 5

22. A colloidal grout produced by the method as claimed in any one of Claims 12 to 18, or Claim 21.

Published 1988 at The Patent Office, State House, 66/71 High Holborn, London WC 1 R 4TP. Further copies may be obtained from The Patent Office, Sales Branch, St Mary Cray, Orpington, Kent BR5 3RD. Printed by Burgess & Son (Abingdon) Ltd. Con. 1/87.