GB2185493A - Metal halide reduction with molten sodium/potassium alloy - Google Patents
Metal halide reduction with molten sodium/potassium alloyInfo
- Publication number
- GB2185493A GB2185493A GB08701633A GB8701633A GB2185493A GB 2185493 A GB2185493 A GB 2185493A GB 08701633 A GB08701633 A GB 08701633A GB 8701633 A GB8701633 A GB 8701633A GB 2185493 A GB2185493 A GB 2185493A
- Authority
- GB
- United Kingdom
- Prior art keywords
- metal halide
- molten sodium
- potassium alloy
- halide reduction
- reducing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title 1
- 229910000799 K alloy Inorganic materials 0.000 title 1
- 229910000528 Na alloy Inorganic materials 0.000 title 1
- 229910001507 metal halide Inorganic materials 0.000 title 1
- 150000005309 metal halides Chemical class 0.000 title 1
- 239000011734 sodium Substances 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 239000003638 chemical reducing agent Substances 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052770 Uranium Inorganic materials 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/04—Dry methods smelting of sulfides or formation of mattes by aluminium, other metals or silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/04—Obtaining aluminium with alkali metals earth alkali metals included
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1263—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction
- C22B34/1268—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction using alkali or alkaline-earth metals or amalgams
- C22B34/1272—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction using alkali or alkaline-earth metals or amalgams reduction of titanium halides, e.g. Kroll process
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/14—Obtaining zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/20—Obtaining niobium, tantalum or vanadium
- C22B34/22—Obtaining vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/20—Obtaining niobium, tantalum or vanadium
- C22B34/24—Obtaining niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/30—Obtaining chromium, molybdenum or tungsten
- C22B34/36—Obtaining tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B47/00—Obtaining manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
- C22B60/0213—Obtaining thorium, uranium, or other actinides obtaining uranium by dry processes
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
A method of obtaining a desired metal, selected from the group consisting of titanium, aluminium, iron, manganese, hafnium, zirconium, tantalum, vanadium, uranium and tungsten, which comprises reacting a halide of the desired metal with an alkali metal reducing agent at a temperature at which the reducing agent is molten, in order to produce the desired metal and halide of the metal reducing agent.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/AU1985/000113 WO1986007097A1 (en) | 1985-05-27 | 1985-05-27 | Metal halide reduction with molten sodium/potassium alloy |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB8701633D0 GB8701633D0 (en) | 1987-03-04 |
| GB2185493A true GB2185493A (en) | 1987-07-22 |
| GB2185493B GB2185493B (en) | 1990-02-14 |
Family
ID=3762115
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8701633A Expired - Lifetime GB2185493B (en) | 1985-05-27 | 1985-05-27 | Metal production |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPH06104869B2 (en) |
| DE (1) | DE3590793T1 (en) |
| GB (1) | GB2185493B (en) |
| WO (1) | WO1986007097A1 (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4865644A (en) * | 1987-07-23 | 1989-09-12 | Westinghouse Electric Corporation | Superconducting niobium alloys |
| US4923531A (en) * | 1988-09-23 | 1990-05-08 | Rmi Company | Deoxidation of titanium and similar metals using a deoxidant in a molten metal carrier |
| GB9111666D0 (en) * | 1991-05-31 | 1991-07-24 | British Nuclear Fuels Plc | A method of producing uranium metal |
| AU686444B2 (en) * | 1994-08-01 | 1998-02-05 | Kroftt-Brakston International, Inc. | Method of making metals and other elements |
| RU2163936C2 (en) * | 1999-05-19 | 2001-03-10 | Евдокимов Владимир Иванович | Continuous magnesium-reduction method of titanium production |
| JP4395386B2 (en) * | 2003-10-10 | 2010-01-06 | 株式会社大阪チタニウムテクノロジーズ | Method for producing Ti or Ti alloy by circulating Ca source |
| AU2004280401C1 (en) * | 2003-10-10 | 2008-12-11 | Osaka Titanium Technologies Co., Ltd | Method for producing Ti or Ti alloy through reduction by Ca |
| JP4347089B2 (en) * | 2004-03-01 | 2009-10-21 | 株式会社大阪チタニウムテクノロジーズ | Method for producing Ti or Ti alloy by Ca reduction |
| US20080011124A1 (en) * | 2004-09-08 | 2008-01-17 | H.C. Starck Gmbh & Co. Kg | Deoxidation of Valve Metal Powders |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3951647A (en) * | 1971-10-26 | 1976-04-20 | Deepsea Ventures, Inc. | Reduction method for producing manganese metal |
| US4105192A (en) * | 1975-02-13 | 1978-08-08 | Nippon Mining Company | Process and apparatus for producing zirconium sponge |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB479014A (en) * | 1936-09-10 | 1938-01-28 | Degussa | A process for the production of metallic tiatnium |
| GB697530A (en) * | 1951-04-17 | 1953-09-23 | Ici Ltd | Production of titanium |
| GB899406A (en) * | 1959-01-15 | 1962-06-20 | Atomic Energy Authority Uk | Improvements in or relating to the production of metals |
| GB863428A (en) * | 1959-09-21 | 1961-03-22 | Dow Chemical Co | Production of titanium metal |
| JPS4863914A (en) * | 1971-12-07 | 1973-09-05 | ||
| JPS491370A (en) * | 1972-04-18 | 1974-01-08 | ||
| AU514181B2 (en) * | 1976-11-26 | 1981-01-29 | Westinghouse Electric Corporation | High temperature reactor |
| LU81469A1 (en) * | 1979-07-05 | 1981-02-03 | Luniversite Libre Bruxelles | PROCESS AND PLANT FOR THE PRODUCTION OF REACTIVE METALS BY REDUCTION OF THEIR HALIDES |
| EP0134643A3 (en) * | 1983-07-08 | 1986-12-30 | Solex Research Corporation of Japan | Preparing metallic zirconium, hafnium or titanium |
-
1985
- 1985-05-27 JP JP60502313A patent/JPH06104869B2/en not_active Expired - Lifetime
- 1985-05-27 DE DE19853590793 patent/DE3590793T1/de not_active Withdrawn
- 1985-05-27 GB GB8701633A patent/GB2185493B/en not_active Expired - Lifetime
- 1985-05-27 WO PCT/AU1985/000113 patent/WO1986007097A1/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3951647A (en) * | 1971-10-26 | 1976-04-20 | Deepsea Ventures, Inc. | Reduction method for producing manganese metal |
| US4105192A (en) * | 1975-02-13 | 1978-08-08 | Nippon Mining Company | Process and apparatus for producing zirconium sponge |
Non-Patent Citations (8)
| Title |
|---|
| AU B 13626/55 * |
| AU B 14243/52 * |
| AU B 16391/56 * |
| AU B 2299/51 * |
| AU B 25003/54 * |
| AU B 26334/57 * |
| AU B 26401/54 * |
| AU B 4415/51 * |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06104869B2 (en) | 1994-12-21 |
| JPS63500389A (en) | 1988-02-12 |
| DE3590793T1 (en) | 1987-09-17 |
| GB2185493B (en) | 1990-02-14 |
| GB8701633D0 (en) | 1987-03-04 |
| WO1986007097A1 (en) | 1986-12-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PCNP | Patent ceased through non-payment of renewal fee |