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GB2036587A - Adsorbent regeneration and gas separation utilizing dielectric heating - Google Patents

Adsorbent regeneration and gas separation utilizing dielectric heating

Info

Publication number
GB2036587A
GB2036587A GB7921803A GB7921803A GB2036587A GB 2036587 A GB2036587 A GB 2036587A GB 7921803 A GB7921803 A GB 7921803A GB 7921803 A GB7921803 A GB 7921803A GB 2036587 A GB2036587 A GB 2036587A
Authority
GB
United Kingdom
Prior art keywords
dielectric heating
gas separation
adsorbent regeneration
utilizing dielectric
separation utilizing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB7921803A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Battelle Development Corp
Original Assignee
Battelle Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Battelle Development Corp filed Critical Battelle Development Corp
Publication of GB2036587A publication Critical patent/GB2036587A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/12Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/18Synthetic zeolitic molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3408Regenerating or reactivating of aluminosilicate molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3433Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3441Regeneration or reactivation by electric current, ultrasound or irradiation, e.g. electromagnetic radiation such as X-rays, UV, light, microwaves
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/48Sulfur dioxide; Sulfurous acid
    • C01B17/50Preparation of sulfur dioxide
    • C01B17/60Isolation of sulfur dioxide from gases
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/04Purification or separation of nitrogen
    • C01B21/0405Purification or separation processes
    • C01B21/0411Chemical processing only
    • C01B21/0422Chemical processing only by reduction
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/04Purification or separation of nitrogen
    • C01B21/0405Purification or separation processes
    • C01B21/0433Physical processing only
    • C01B21/045Physical processing only by adsorption in solids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Electromagnetism (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Water Supply & Treatment (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

Dielectric heating (microwave or radio frequency radiation) of saturated adsorbents to remove the adsorbed materials results in more rapid, efficient and safe regeneration than conventional heating. Separation of a gas mixture into two concentrated streams of its components is enabled by adsorption of one fraction by a selective adsorbent followed by removal of that fraction with dielectric heating and little or no purge gas. Useful by-products of the separation process are thereby economically recovered.
GB7921803A 1977-10-31 1978-10-25 Adsorbent regeneration and gas separation utilizing dielectric heating Withdrawn GB2036587A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US84679877A 1977-10-31 1977-10-31

Publications (1)

Publication Number Publication Date
GB2036587A true GB2036587A (en) 1980-07-02

Family

ID=25298974

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7921803A Withdrawn GB2036587A (en) 1977-10-31 1978-10-25 Adsorbent regeneration and gas separation utilizing dielectric heating

Country Status (4)

Country Link
EP (1) EP0007956A1 (en)
JP (1) JPS54500045A (en)
GB (1) GB2036587A (en)
WO (1) WO1979000251A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2477036A1 (en) * 1980-02-28 1981-09-04 Raffinage Cie Francaise Desorption of polar cpds. absorbed on molecular sieve - where sieve is heated by microwaves and simultaneously scrubbed with gas, used esp. to remove water or hydrogen sulphide from sieve
DE4009691A1 (en) * 1989-03-28 1990-10-04 Gisip Inventor Ab AIR DRYING BY MICROWAVE AND DEVICE THEREFOR
CA2244615A1 (en) * 1997-08-22 1999-02-22 Ishikawajima-Harima Heavy Industries Co., Ltd. Friction-reducing ship with compressed air generation apparatus, friction reduction apparatus and gas jetting device
DE102006062651B4 (en) 2006-11-14 2009-12-31 Helmholtz-Zentrum Für Umweltforschung Gmbh - Ufz Method and device for thermochromatographic heating of solid beds
DE102006060161A1 (en) 2006-12-18 2008-06-26 Evonik Röhm Gmbh Process for the adsorptive purification of alkyl methacrylates
FI20195941A1 (en) * 2019-11-04 2021-05-05 Soletair Power Oy Method and apparatus for recovering carbon dioxide and use of the method
EP3906995A1 (en) * 2020-05-04 2021-11-10 FRAUNHOFER-GESELLSCHAFT zur Förderung der angewandten Forschung e.V. Adsorbent material on the basis of a metal-organic framework, method for the production and use of the same

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US984498A (en) * 1908-04-07 1911-02-14 Us Smelting Refining & Mining Company Method of treating corrosive gaseous fumes or smoke.
GB207547A (en) * 1922-11-23 1924-03-20 Naamlooze Venootschap Montaan Metaalhandel
US3359707A (en) * 1960-06-15 1967-12-26 Jean Olivier Auguste Louis Method and apparatus for removing co2 and moisture from stale air
FR85066E (en) * 1964-01-07 1965-06-04 Aquitaine Petrole Process for recovering gaseous sulfur compounds contained in low concentrations in waste gases and fumes
US3608273A (en) * 1969-01-15 1971-09-28 Lowell Technological Inst Rese Apparatus and process for desorption of filter beds by electric current
DE2107717A1 (en) * 1971-02-18 1972-08-31 Bamag Verfahrenstechnik Gmbh, 6308 Butzbach Regeneration reactor for adsorbents - heated by microwave
US3864452A (en) * 1972-03-30 1975-02-04 Grace W R & Co Process for purifying sulfur compound contaminated gas streams
JPS5143395A (en) * 1974-10-14 1976-04-14 Mitsubishi Chem Ind Katsuseitanno saiseiho
JPS5143394A (en) * 1974-10-14 1976-04-14 Mitsubishi Chem Ind Katsuseitanno saiseihoho
US4038050A (en) * 1974-11-27 1977-07-26 W. R. Grace & Co. Electrical sensing and regenerating system for molecular sieve driers
JPS51145491A (en) * 1975-06-10 1976-12-14 Toru Mashida Regeneration of active carbon
US4094652A (en) * 1975-10-23 1978-06-13 W. R. Grace & Co. Electrodesorption system for regenerating a dielectric adsorbent bed

Also Published As

Publication number Publication date
EP0007956A1 (en) 1980-02-20
JPS54500045A (en) 1979-10-25
WO1979000251A1 (en) 1979-05-17

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Legal Events

Date Code Title Description
WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)