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GB2010874A - Fluorinated nonionic surfactants - Google Patents

Fluorinated nonionic surfactants

Info

Publication number
GB2010874A
GB2010874A GB7847286A GB7847286A GB2010874A GB 2010874 A GB2010874 A GB 2010874A GB 7847286 A GB7847286 A GB 7847286A GB 7847286 A GB7847286 A GB 7847286A GB 2010874 A GB2010874 A GB 2010874A
Authority
GB
United Kingdom
Prior art keywords
isomer
polyether
polyester
reacting
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7847286A
Other versions
GB2010874B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/858,218 external-priority patent/US4171282A/en
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of GB2010874A publication Critical patent/GB2010874A/en
Application granted granted Critical
Publication of GB2010874B publication Critical patent/GB2010874B/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3612—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with organic compounds as principal constituents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
    • C08G65/332—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/334—Polymers modified by chemical after-treatment with organic compounds containing sulfur
    • C08G65/3342—Polymers modified by chemical after-treatment with organic compounds containing sulfur having sulfur bound to carbon and hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/338—Polymers modified by chemical after-treatment with inorganic and organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
    • C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
  • Silicon Polymers (AREA)
  • Lubricants (AREA)

Abstract

Perfluoroalkylthio-substituted half esters and amides of succinic acid having the formula <IMAGE> or its isomer, wherein Rf is perfluoroalkyl, R1 alkylene, optionally interrupted with oxygen, sulfur or nitrogen atoms, x is oxygen or NH, y is zero or 1, Q is a polyether or polyester diradical moiety having a molecular weight of 300 to 5000 or a polysiloxane having 5 to 80 repeating units and A is hydrogen, hydroxyl, amino, alkoxy, phenoxy, alkylphenoxy, dialkylamino, the group <IMAGE> or its isomer. These compounds are prepared by reacting e.g. maleic anhydride with a polyether, polyester, diamine or a polysiloxane derivative of an alcohol or primary amine and then reacting the product with a perfluoroalkyl alkylene thiol. The novel compounds are useful as surfactants with specific applications as wetting agents in coatings, waxes, emulsions, paints and resins.
GB7847286A 1977-12-07 1978-12-05 Fluorinated nonionic surfactants Expired GB2010874B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/858,218 US4171282A (en) 1977-12-07 1977-12-07 Fluorinated nonionic surfactants
US94482078A 1978-09-22 1978-09-22

Publications (2)

Publication Number Publication Date
GB2010874A true GB2010874A (en) 1979-07-04
GB2010874B GB2010874B (en) 1982-10-06

Family

ID=27127449

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7847286A Expired GB2010874B (en) 1977-12-07 1978-12-05 Fluorinated nonionic surfactants

Country Status (10)

Country Link
JP (1) JPS5484524A (en)
AU (1) AU519243B2 (en)
BR (1) BR7808012A (en)
CA (1) CA1129429A (en)
DE (1) DE2852593A1 (en)
FR (1) FR2411212A1 (en)
GB (1) GB2010874B (en)
IT (1) IT1106947B (en)
NL (1) NL7811945A (en)
NO (1) NO150683C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994012561A1 (en) * 1992-12-01 1994-06-09 Minnesota Mining And Manufacturing Company Polysiloxanes having fluoroaliphatic- and carboxyl-containing terminal groups, their preparation, and their use in treatment of fibrous substrates
WO1996009417A1 (en) * 1994-09-21 1996-03-28 Minnesota Mining And Manufacturing Company Leaching of precious metal ore with fluoroaliphatic surfactant

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5935573B2 (en) * 1980-06-28 1984-08-29 シ−アイ化成株式会社 agricultural cladding
JPS5856959A (en) * 1981-09-29 1983-04-04 Nissin Kogyo Kk Negative pressure booster
JPS6028860B2 (en) * 1981-09-29 1985-07-06 アキレス株式会社 Eggplant cultivation film
DK435881A (en) * 1981-10-01 1983-04-02 Niels Ole Vesterager WASHING ACTIVE DOSAGE UNIT, METHOD OF PREPARING IT AND THE USE OF IT
JPS5889360A (en) * 1981-11-24 1983-05-27 アキレス株式会社 Agricultural film
DE3903005A1 (en) * 1989-02-02 1990-08-16 Pfersee Chem Fab METHOD FOR THE PRODUCTION OF MODIFIED POLYSILOXANES, THE POLYSILOXANES SO MANUFACTURED, THE USE THEREOF AND THE MATERIALS SO TREATED
US5266724A (en) * 1990-09-04 1993-11-30 Matsushita Electric Industrial Co., Ltd. Fluorine-containing compounds
US5188747A (en) * 1990-09-04 1993-02-23 Matsushita Electric Industrial Co., Ltd. Fluorine-containing lubricant compounds
DE4240274B4 (en) * 1992-12-01 2004-02-12 Minnesota Mining And Manufacturing Co., Saint Paul Polysiloxanes with fluoroaliphate and carboxyl-containing terminal groups, their preparation and their use in the treatment of fiber substrates
BRPI0414883A (en) 2003-09-29 2006-12-12 Ethena Healthcare Inc composition, composition concentrate, and disinfectant and gel-like alcoholic compositions
DE102004062775A1 (en) * 2004-12-21 2006-06-29 Stockhausen Gmbh Alcoholic pump foam
MX2007010893A (en) 2005-03-07 2008-02-25 Deb Worldwide Healthcare Inc High alcohol content foaming compositions with silicone-based surfactants.
JP6198058B2 (en) * 2013-12-19 2017-09-20 Dic株式会社 Surfactant composition, coating composition, and resist composition

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4075237A (en) * 1968-04-10 1978-02-21 Geigy Chemical Corporation Perfluorinated esters of fumaric acid and certain other ethylenically unsaturated poly-basic acid and soil repellant polymers thereof
NL7204067A (en) * 1971-03-29 1972-10-03
GB1354138A (en) * 1971-10-15 1974-06-05 Ici Ltd Fluorocarbon surfactants
GB1410328A (en) * 1971-12-21 1975-10-15 Unilever Ltd Alkoxylation process
DE2238740C3 (en) * 1972-08-05 1981-07-16 Bayer Ag, 5090 Leverkusen Polyethers containing perfluoroalkyl groups and processes for their preparation and their use
US3794672A (en) * 1973-07-05 1974-02-26 Dow Corning Perfluoroalkyl silicon compounds containing sulfur
CH628247A5 (en) * 1975-01-03 1982-02-26 Ciba Geigy Ag Aqueous, film-forming concentrates for extinguishing or preventing fire with a content of non-anionic compounds containing perfluoroalkylalkylenethio groups
US4081399A (en) * 1975-09-22 1978-03-28 Ciba-Geigy Corporation Process for the preparation of concentrated solutions of fluorinated amphoteric surfactants
FR2328070A1 (en) * 1975-10-17 1977-05-13 Ugine Kuhlmann ANTI-STAIN PRODUCTS ALLOWING THE EASY REMOVAL OF SOIL IN WASHING

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994012561A1 (en) * 1992-12-01 1994-06-09 Minnesota Mining And Manufacturing Company Polysiloxanes having fluoroaliphatic- and carboxyl-containing terminal groups, their preparation, and their use in treatment of fibrous substrates
US5385999A (en) * 1992-12-01 1995-01-31 Minnesota Mining And Manufacturing Company Polysiloxanes having fluoroaliphatic- and carboxyl-containing terminal groups, their preparation, and their use in treatment of fibrous substrates
TR28384A (en) * 1992-12-01 1996-05-30 Minnesota Mining & Mfg Polysiloxanes with terminal groups containing fluoroaliphatic -and carboxyl-, their preparation, and their use in the treatment of fibrous materials.
CN1036786C (en) * 1992-12-01 1997-12-24 明尼苏达州采矿和制造公司 Polysiloxanes having fluoroaliphatic- and carboxyl-containing terminal groups, thir preparation, and their use in treatment of fibrous substrates
WO1996009417A1 (en) * 1994-09-21 1996-03-28 Minnesota Mining And Manufacturing Company Leaching of precious metal ore with fluoroaliphatic surfactant
US5612431A (en) * 1994-09-21 1997-03-18 Minnesota Mining And Manufacturing Company Leaching of precious metal ore with fluoroaliphatic surfactant
US5827348A (en) * 1994-09-21 1998-10-27 Minnesota Mining And Manufacturing Company Leaching of precious metal ore with fluoroaliphatic surfactant

Also Published As

Publication number Publication date
NO150683C (en) 1984-11-28
JPS5484524A (en) 1979-07-05
DE2852593A1 (en) 1979-06-13
NO150683B (en) 1984-08-20
DE2852593C2 (en) 1988-04-14
IT1106947B (en) 1985-11-18
BR7808012A (en) 1979-08-07
NL7811945A (en) 1979-06-11
AU519243B2 (en) 1981-11-19
CA1129429A (en) 1982-08-10
AU4225578A (en) 1979-06-14
FR2411212A1 (en) 1979-07-06
JPS632951B2 (en) 1988-01-21
IT7852206A0 (en) 1978-12-06
FR2411212B1 (en) 1983-12-16
GB2010874B (en) 1982-10-06
NO784108L (en) 1979-06-08

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee