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GB1430337A - Process for the manufacture of methacrylic acid and oxidation catalyst therefor - Google Patents

Process for the manufacture of methacrylic acid and oxidation catalyst therefor

Info

Publication number
GB1430337A
GB1430337A GB2333474A GB2333474A GB1430337A GB 1430337 A GB1430337 A GB 1430337A GB 2333474 A GB2333474 A GB 2333474A GB 2333474 A GB2333474 A GB 2333474A GB 1430337 A GB1430337 A GB 1430337A
Authority
GB
United Kingdom
Prior art keywords
methacrylic acid
manufacture
oxidation catalyst
catalyst therefor
methacrolein
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2333474A
Inventor
Hitoshi Shimizu
Kazuo Ishimi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kayaku Co Ltd
Original Assignee
Nippon Kayaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Priority to GB2333474A priority Critical patent/GB1430337A/en
Priority to BE6044624A priority patent/BE816016A/en
Priority to DE742429095A priority patent/DE2429095C3/en
Publication of GB1430337A publication Critical patent/GB1430337A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8874—Gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1430337 Methacrylic acid NIPPON KAYAKU KK 24 May 1974 23334/74 Heading C2C [Also in Division B1] Methacrylic acid is made by the oxidation of methacrolein with a gas comprising O 2 and preferably containing steam in the presence of a catalyst of the formula where, a=12, b=1-4, c=0À1-7, d=0À1-5, e=0-6 and g=0-3À5. The reaction may be carried out at 200-400‹ C. and a GHSV of 100- 3000 using a molar ratio of oxygen : steam : methacrolein of 0À5-16 : 1-20 : 1.
GB2333474A 1974-05-24 1974-05-24 Process for the manufacture of methacrylic acid and oxidation catalyst therefor Expired GB1430337A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB2333474A GB1430337A (en) 1974-05-24 1974-05-24 Process for the manufacture of methacrylic acid and oxidation catalyst therefor
BE6044624A BE816016A (en) 1974-05-24 1974-06-06 OXIDIZATION CATALYST TO PRODUCE METHACRYLIC ACID
DE742429095A DE2429095C3 (en) 1974-05-24 1974-06-18 Molybdenum, phosphorus, antimony, copper and optionally chromium-containing oxidation catalyst and its use for the production of methacrylic acid

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB2333474A GB1430337A (en) 1974-05-24 1974-05-24 Process for the manufacture of methacrylic acid and oxidation catalyst therefor
BE6044624A BE816016A (en) 1974-05-24 1974-06-06 OXIDIZATION CATALYST TO PRODUCE METHACRYLIC ACID
DE742429095A DE2429095C3 (en) 1974-05-24 1974-06-18 Molybdenum, phosphorus, antimony, copper and optionally chromium-containing oxidation catalyst and its use for the production of methacrylic acid

Publications (1)

Publication Number Publication Date
GB1430337A true GB1430337A (en) 1976-03-31

Family

ID=27159672

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2333474A Expired GB1430337A (en) 1974-05-24 1974-05-24 Process for the manufacture of methacrylic acid and oxidation catalyst therefor

Country Status (3)

Country Link
BE (1) BE816016A (en)
DE (1) DE2429095C3 (en)
GB (1) GB1430337A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2407022A1 (en) * 1977-10-31 1979-05-25 Nippon Kayaku Kk PROCESS AND CATALYST FOR PRODUCING METHACRYLIC ACID
US4169070A (en) 1978-04-12 1979-09-25 Halcon Research And Development Corporation Catalyst and process for producing unsaturated acids by using same
US4240930A (en) * 1979-04-06 1980-12-23 Halcon Research And Development Corp. Catalyst and process for producing methacrylic acid
US4374757A (en) 1978-12-26 1983-02-22 The Halcon Sd Group, Inc. Catalyst and process for producing methacrylic acid
US4377501A (en) 1978-12-26 1983-03-22 The Halcon Sd Group, Inc. Catalyst and process for producing methacrylic acid
US4454346A (en) * 1978-12-26 1984-06-12 The Halcon Sd Group, Inc. Process for producing methacrylic acid
US4547588A (en) * 1979-10-03 1985-10-15 The Halcon Sd Group, Inc. Process for producing methacrylic acid
US4925823A (en) * 1982-03-10 1990-05-15 Basf Aktiengesellschaft Process and catalyst for the preparation of methacrylic acid

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2407022A1 (en) * 1977-10-31 1979-05-25 Nippon Kayaku Kk PROCESS AND CATALYST FOR PRODUCING METHACRYLIC ACID
US4169070A (en) 1978-04-12 1979-09-25 Halcon Research And Development Corporation Catalyst and process for producing unsaturated acids by using same
US4374757A (en) 1978-12-26 1983-02-22 The Halcon Sd Group, Inc. Catalyst and process for producing methacrylic acid
US4377501A (en) 1978-12-26 1983-03-22 The Halcon Sd Group, Inc. Catalyst and process for producing methacrylic acid
US4454346A (en) * 1978-12-26 1984-06-12 The Halcon Sd Group, Inc. Process for producing methacrylic acid
US4240930A (en) * 1979-04-06 1980-12-23 Halcon Research And Development Corp. Catalyst and process for producing methacrylic acid
US4547588A (en) * 1979-10-03 1985-10-15 The Halcon Sd Group, Inc. Process for producing methacrylic acid
US4925823A (en) * 1982-03-10 1990-05-15 Basf Aktiengesellschaft Process and catalyst for the preparation of methacrylic acid

Also Published As

Publication number Publication date
DE2429095C3 (en) 1979-03-08
BE816016A (en) 1974-09-30
DE2429095A1 (en) 1976-01-02
DE2429095B2 (en) 1978-05-24

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee