GB1492945A - Process for producing vinyl chloride - Google Patents
Process for producing vinyl chlorideInfo
- Publication number
- GB1492945A GB1492945A GB41041/74A GB4104174A GB1492945A GB 1492945 A GB1492945 A GB 1492945A GB 41041/74 A GB41041/74 A GB 41041/74A GB 4104174 A GB4104174 A GB 4104174A GB 1492945 A GB1492945 A GB 1492945A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl chloride
- earth metal
- recycled
- alkali
- catalyst composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- 239000003513 alkali Substances 0.000 abstract 2
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 2
- 239000006227 byproduct Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical class ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 abstract 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- -1 copper halide Chemical class 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 229960003750 ethyl chloride Drugs 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 150000002909 rare earth metal compounds Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/154—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of saturated hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
1492945 Vinyl chloride BRITISH PETROLEUM CO Ltd 13 Aug 1975 [20 Feb 1974] 41041/74 Heading C2C [Also in Divisions C5 and B1] A process for the production of vinyl chloride monomer comprises contacting at elevated temperature a reaction feed containing ethane, hydrogen chloride and molecular oxygen in the vapour phase with a catalyst composition comprising a copper halide, a halide of an alkali or alkaline earth metal and a rare earth metal compound deposited on activated alumina, said catalyst composition containing above 5% by weight of the alkali or alkaline earth metal in a free or combined form. Ethylene may also be present in the feed, e.g. as recycled by-product. Other by-products include ethylchloride and 1,1- and 1,2-dichloroethanes, the latter two of which may be further pyrolysed to vinyl chloride and HCl. The latter may be recovered and recycled.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB41041/74A GB1492945A (en) | 1974-09-20 | 1974-09-20 | Process for producing vinyl chloride |
| NL7510050A NL7510050A (en) | 1974-09-20 | 1975-08-26 | PROCESS FOR PREPARING VINYL CHLORIDE MONOMER. |
| DE19752540067 DE2540067A1 (en) | 1974-09-20 | 1975-09-09 | METHOD OF MANUFACTURING VINYL CHLORIDE |
| FR7528712A FR2285359A1 (en) | 1974-09-20 | 1975-09-19 | MONOMERIC VINYL CHLORIDE PRODUCTION PROCESS AND PRODUCT OBTAINED |
| JP50113537A JPS5156404A (en) | 1974-09-20 | 1975-09-19 | ENKABINIRUTANRYOTAINO SEIZOHOHO |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB41041/74A GB1492945A (en) | 1974-09-20 | 1974-09-20 | Process for producing vinyl chloride |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1492945A true GB1492945A (en) | 1977-11-23 |
Family
ID=10417842
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB41041/74A Expired GB1492945A (en) | 1974-09-20 | 1974-09-20 | Process for producing vinyl chloride |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5156404A (en) |
| DE (1) | DE2540067A1 (en) |
| FR (1) | FR2285359A1 (en) |
| GB (1) | GB1492945A (en) |
| NL (1) | NL7510050A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2236493A (en) * | 1989-10-03 | 1991-04-10 | Riken Kk | Exhaust gas purification catalyst |
| US5728905A (en) * | 1993-09-07 | 1998-03-17 | Evc Technology Ag | Vinyl chloride production process |
| US5763710A (en) * | 1993-09-07 | 1998-06-09 | Evc Technology Ag | Oxychlorination process |
| RU2133729C1 (en) * | 1993-09-07 | 1999-07-27 | ЭФК Технологи АГ | Method of catalytic oxychlorination of ethane to vinyl chloride |
| US6180841B1 (en) | 1994-10-20 | 2001-01-30 | Evc Technology Ag | Single stage fixed bed oxychlorination of ethylene |
| US6680415B1 (en) | 1999-11-22 | 2004-01-20 | Dow Global Technologies Inc. | Oxyhalogenation process using catalyst having porous rare earth halide support |
| US6797845B1 (en) | 1999-11-22 | 2004-09-28 | Dow Global Technologies Inc. | Process for vinyl chloride manufacture from ethane and ethylene with immediate HCl recovery from reactor effluent |
| US6909024B1 (en) | 1999-11-22 | 2005-06-21 | The Dow Chemical Company | Process for the conversion of ethylene to vinyl chloride and novel catalyst compositions useful for such process |
| US6933417B1 (en) | 1999-11-22 | 2005-08-23 | Dow Global Technologies Inc. | Process for vinyl chloride manufacture from ethane and ethylene with partial CHl recovery from reactor effluent |
| RU2259990C2 (en) * | 1999-11-22 | 2005-09-10 | Дау Глобал Текнолоджиз Инк. | Method for producing vinyl chloride from ethane and ethylene (variants) |
| US6984763B2 (en) | 2001-05-23 | 2006-01-10 | Dow Global Technologies Inc. | Oxidative halogenation and optional dehydrogenation of c3+hydrocarbons |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2521841C2 (en) * | 1975-05-16 | 1978-04-27 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | Process for sealing and filling joints and for coating surfaces |
| GB9318501D0 (en) * | 1993-09-07 | 1993-10-20 | Evc Tech Ag | Oxychlorination catalyst |
-
1974
- 1974-09-20 GB GB41041/74A patent/GB1492945A/en not_active Expired
-
1975
- 1975-08-26 NL NL7510050A patent/NL7510050A/en not_active Application Discontinuation
- 1975-09-09 DE DE19752540067 patent/DE2540067A1/en active Pending
- 1975-09-19 JP JP50113537A patent/JPS5156404A/en active Pending
- 1975-09-19 FR FR7528712A patent/FR2285359A1/en active Granted
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2236493A (en) * | 1989-10-03 | 1991-04-10 | Riken Kk | Exhaust gas purification catalyst |
| US5728905A (en) * | 1993-09-07 | 1998-03-17 | Evc Technology Ag | Vinyl chloride production process |
| US5763710A (en) * | 1993-09-07 | 1998-06-09 | Evc Technology Ag | Oxychlorination process |
| RU2133729C1 (en) * | 1993-09-07 | 1999-07-27 | ЭФК Технологи АГ | Method of catalytic oxychlorination of ethane to vinyl chloride |
| CN1046930C (en) * | 1993-09-07 | 1999-12-01 | Evc技术公开股份有限公司 | Oxychlorination method |
| US6180841B1 (en) | 1994-10-20 | 2001-01-30 | Evc Technology Ag | Single stage fixed bed oxychlorination of ethylene |
| US6680415B1 (en) | 1999-11-22 | 2004-01-20 | Dow Global Technologies Inc. | Oxyhalogenation process using catalyst having porous rare earth halide support |
| US6797845B1 (en) | 1999-11-22 | 2004-09-28 | Dow Global Technologies Inc. | Process for vinyl chloride manufacture from ethane and ethylene with immediate HCl recovery from reactor effluent |
| US6821924B2 (en) | 1999-11-22 | 2004-11-23 | Dow Global Technologies Inc. | Oxyhalogenation process using catalyst having porous rare earth halide support |
| US6909024B1 (en) | 1999-11-22 | 2005-06-21 | The Dow Chemical Company | Process for the conversion of ethylene to vinyl chloride and novel catalyst compositions useful for such process |
| US6933417B1 (en) | 1999-11-22 | 2005-08-23 | Dow Global Technologies Inc. | Process for vinyl chloride manufacture from ethane and ethylene with partial CHl recovery from reactor effluent |
| RU2259990C2 (en) * | 1999-11-22 | 2005-09-10 | Дау Глобал Текнолоджиз Инк. | Method for producing vinyl chloride from ethane and ethylene (variants) |
| RU2259989C2 (en) * | 1999-11-22 | 2005-09-10 | Дау Глобал Текнолоджиз Инк. | Method for producing vinyl chloride from ethane and ethylene (variants) |
| RU2265006C2 (en) * | 1999-11-22 | 2005-11-27 | Дау Глобал Текнолоджиз Инк. | Method for conversion of ethylene to vinyl chloride and novel catalytic compositions useful in indicated method |
| US6984763B2 (en) | 2001-05-23 | 2006-01-10 | Dow Global Technologies Inc. | Oxidative halogenation and optional dehydrogenation of c3+hydrocarbons |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5156404A (en) | 1976-05-18 |
| DE2540067A1 (en) | 1976-04-08 |
| NL7510050A (en) | 1976-03-23 |
| FR2285359B3 (en) | 1978-05-05 |
| FR2285359A1 (en) | 1976-04-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |