GB1337291A - Polymerization inhibition of vinyl and vinylidene monomers - Google Patents
Polymerization inhibition of vinyl and vinylidene monomersInfo
- Publication number
- GB1337291A GB1337291A GB2490171A GB2490171A GB1337291A GB 1337291 A GB1337291 A GB 1337291A GB 2490171 A GB2490171 A GB 2490171A GB 2490171 A GB2490171 A GB 2490171A GB 1337291 A GB1337291 A GB 1337291A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- vinylidene monomers
- polymerization inhibition
- monomers
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000178 monomer Substances 0.000 title abstract 3
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title abstract 2
- 229920002554 vinyl polymer Polymers 0.000 title abstract 2
- 230000005764 inhibitory process Effects 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 3
- GOZUKDFGVNBSAZ-UHFFFAOYSA-N 2,2,5,5-tetramethylimidazolidin-4-one Chemical compound CC1(C)NC(=O)C(C)(C)N1 GOZUKDFGVNBSAZ-UHFFFAOYSA-N 0.000 abstract 1
- UZPDHDVZWBFDGC-UHFFFAOYSA-N 3,3-dimethyl-1-oxa-4-azaspiro[4.4]nonane Chemical compound N1C(C)(C)COC11CCCC1 UZPDHDVZWBFDGC-UHFFFAOYSA-N 0.000 abstract 1
- 101100167062 Caenorhabditis elegans chch-3 gene Proteins 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 230000006641 stabilisation Effects 0.000 abstract 1
- 238000011105 stabilization Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/42—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogenated Pyridines (AREA)
Abstract
1337291 Stabilization of monomers SANKYO CO Ltd 19 April 1971 [20 March 1970] 24901/71 Heading C2C [Also in Division C5] The polymerization of vinyl and vinylidene monomers is inhibited by the addition of a compound of the formula wherein R 1 and R 2 is each a C 1 -C 11 alkyl group or a phenyl group and one may be H; or R 1 and R 2 together form the group - which R 3 and R 4 have the same meaning as R 1 and R 2 , X is -(CH 2 ) 3 -, -CH 2 CO-CH 2 -, -CH 2 CH(OH)CH 2 -, -CO-NH 2 -, -CH 2 O-, or CH 2 CHCH 3 O and Y and Y 1 are H or OH. The compounds of Formula I in which X is -CH 2 O- and Y is H can be prepared by and others by Preferred specified compounds are: 1-aza-2,2- dimethyl-4-oxa-spiro[4,4]nonane and 2,2,5,5- tetramethyl-4-oxoimidazolidine.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2398770A JPS5010281B1 (en) | 1970-03-20 | 1970-03-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1337291A true GB1337291A (en) | 1973-11-14 |
Family
ID=12125914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2490171A Expired GB1337291A (en) | 1970-03-20 | 1971-04-19 | Polymerization inhibition of vinyl and vinylidene monomers |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS5010281B1 (en) |
| FR (1) | FR2084869A5 (en) |
| GB (1) | GB1337291A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999061396A1 (en) * | 1998-05-26 | 1999-12-02 | Uniroyal Chemical Company, Inc. | Method for stabilizing unsaturated organic compounds from polymerization |
| WO2000014177A1 (en) * | 1998-09-09 | 2000-03-16 | Baker Hughes Incorporated | Vinyl monomer polymerization inhibition using hindered hydroxylamines |
| BE1012727A5 (en) * | 1998-10-16 | 2001-02-06 | Ciba Sc Holding Ag | Polymerisable composition, compound contained initiators, precursors thereof, preparation and methods using. |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE49588T1 (en) * | 1984-10-10 | 1990-02-15 | Amoco Corp | METHACRYLIC ACID PURIFICATION METHOD. |
| DE19609312A1 (en) * | 1996-03-09 | 1997-09-11 | Basf Ag | Stabilized monomer composition |
| DE19725519A1 (en) * | 1997-06-17 | 1998-12-24 | Basf Ag | Mixture of substances containing compounds containing vinyl groups and stabilizers |
| WO2008093881A1 (en) * | 2007-01-31 | 2008-08-07 | Kyushu University, National University Corporation | Method for synthesis of nitroxyl radical |
-
1970
- 1970-03-20 JP JP2398770A patent/JPS5010281B1/ja active Pending
-
1971
- 1971-03-19 FR FR7109670A patent/FR2084869A5/fr not_active Expired
- 1971-04-19 GB GB2490171A patent/GB1337291A/en not_active Expired
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999061396A1 (en) * | 1998-05-26 | 1999-12-02 | Uniroyal Chemical Company, Inc. | Method for stabilizing unsaturated organic compounds from polymerization |
| US6287483B1 (en) | 1998-05-26 | 2001-09-11 | Uniroyal Chemical Company, Inc. | Method of stabilizing unsaturated organic compounds from polymerization |
| WO2000014177A1 (en) * | 1998-09-09 | 2000-03-16 | Baker Hughes Incorporated | Vinyl monomer polymerization inhibition using hindered hydroxylamines |
| US6342647B1 (en) | 1998-09-09 | 2002-01-29 | Baker Hughes Incorporated | Vinyl monomer polymerization inhibition using hindered hydroxylamines |
| BE1012727A5 (en) * | 1998-10-16 | 2001-02-06 | Ciba Sc Holding Ag | Polymerisable composition, compound contained initiators, precursors thereof, preparation and methods using. |
| US6479608B1 (en) | 1998-10-16 | 2002-11-12 | Ciba Specialty Chemicals Corporation | Heterocyclic alkoxyamines as regulators in controlled radical polymerization processes |
| ES2178908A1 (en) * | 1998-10-16 | 2003-01-01 | Ciba Sc Holding Ag | Heterocyclic alkoxyamines as regulators in controlled radical polymerization processes |
| US6664353B2 (en) | 1998-10-16 | 2003-12-16 | Ciba Specialty Chemicals Corporation | Heterocyclic alkoxyamines as regulators in controlled radical polymerization processes |
| ES2178908B1 (en) * | 1998-10-16 | 2004-04-01 | Ciba Specialty Chemicals Holding Inc. | HETEROCICLIC ALCOXIAMINS AS REGULATORS IN PROCEDURE OF CONTROLLED RADICAL POLYMERIZATION. |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5010281B1 (en) | 1975-04-19 |
| FR2084869A5 (en) | 1971-12-17 |
| DE2113246B2 (en) | 1975-09-25 |
| DE2113246A1 (en) | 1971-11-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |