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GB1329334A - Preparation of ethylene polymer wax - Google Patents

Preparation of ethylene polymer wax

Info

Publication number
GB1329334A
GB1329334A GB1803171A GB1803171A GB1329334A GB 1329334 A GB1329334 A GB 1329334A GB 1803171 A GB1803171 A GB 1803171A GB 1803171 A GB1803171 A GB 1803171A GB 1329334 A GB1329334 A GB 1329334A
Authority
GB
United Kingdom
Prior art keywords
ethylene
solvent
compound
polymerization
wax
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1803171A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Petrochemical Industries Ltd
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP4559970A external-priority patent/JPS5440594B1/ja
Priority claimed from JP4604770A external-priority patent/JPS4837991B1/ja
Priority claimed from JP4604670A external-priority patent/JPS4841710B1/ja
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Publication of GB1329334A publication Critical patent/GB1329334A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C08F255/023—On to modified polymers, e.g. chlorinated polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/06—Oxidation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/50—Partial depolymerisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1329334 Waxy ethylene polymers MITSUI PETROCHEMICAL INDUSTRIES Ltd 28 May 1971 [29 May 1970 30 May 1970 (2)] 18031/71 Heading C3P Waxes, i.e. polymers having a viscosity average molecular weight of 400 to 20,000 and a softening point of 80-135‹ C. (other physical properties being specified) are obtained by polymerizing ethylene in the presence of hydrogen and optionally an α-olefin, in solution in a saturated hydrocarbon diluent or in the molten wax itself, using a catalyst comprising (a) a halogen compound of titanium or vanadium supported on a hydrocarbon-insoluble magnesium compound, and (b) an organoaluminium compound, the amount of aluminium in component (b) being 1-100 atoms per atom of Ti or V and being 0À01 to 10 milliequivalents per litre of polymerization solvent. The polymerization is carried out at a temperature at which the wax is molten and a pressure of 20-100 kg/cm.<SP>2</SP> gauge when a hydrocarbon solvent is used or 5-100 kg./cm.<SP>2</SP> when the solvent is molten wax. The molar composition of the vapour phase, excluding solvent vapour, is 3-90% hydrogen, 0-35% α-olefin and the remainder ethylene. The catalyst carrier may be activated by treatment with a Lewis base (ethanol being exemplified) before treatment with the Ti or V compound. Exemplified catalysts are (a) TiCl 4 or VOCl 3 supported on MgO, Mg(OH) 2 , hydrated or anhydrous MgCl 2 , or coprecipitated MgO-Al 2 O 3 , with (b) Et 3 Al or i-Bu 3 Al. Continuous polymerization of ethylene, alone or in the presence of propylene or butene-1, in hexane is described. The waxes may be modified by oxidation, preferably by passing air through the molten wax at 130-200‹ C., and the oxidized products may be reacted with maleic acid or its derivatives, e.g. the dimethyl or dioctyl ester or the anhydride.
GB1803171A 1970-05-29 1971-05-28 Preparation of ethylene polymer wax Expired GB1329334A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP4559970A JPS5440594B1 (en) 1970-05-29 1970-05-29
JP4604770A JPS4837991B1 (en) 1970-05-30 1970-05-30
JP4604670A JPS4841710B1 (en) 1970-05-30 1970-05-30

Publications (1)

Publication Number Publication Date
GB1329334A true GB1329334A (en) 1973-09-05

Family

ID=27292287

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1803171A Expired GB1329334A (en) 1970-05-29 1971-05-28 Preparation of ethylene polymer wax

Country Status (5)

Country Link
CA (1) CA987847A (en)
DE (1) DE2126725C3 (en)
FR (1) FR2092165B1 (en)
GB (1) GB1329334A (en)
NL (1) NL152567B (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0021700A1 (en) * 1979-06-11 1981-01-07 Mitsui Petrochemical Industries, Ltd. Process for preparing ethylene polymer wax
US5498809A (en) 1992-12-17 1996-03-12 Exxon Chemical Patents Inc. Polymers derived from ethylene and 1-butene for use in the preparation of lubricant dispersant additives
US5554310A (en) 1992-12-17 1996-09-10 Exxon Chemical Patents Inc. Trisubstituted unsaturated polymers
US5883196A (en) * 1995-05-24 1999-03-16 Basf Aktiengesellschaft Preparation of polyalkenylsuccinic acid derivatives and their use as fuel and lubricant additives
US5917100A (en) * 1993-01-07 1999-06-29 Clariant Gmbh Process for producing low molecular-weight poly-1-olefins
WO2008061826A1 (en) * 2006-11-25 2008-05-29 Evonik Degussa Gmbh Method for the production of synthetic polyethylene waxes with high crystallinity and low viscosity
US7563849B2 (en) 1999-06-17 2009-07-21 Mitsui Chemicals, Inc. Ethylene (co) polymer and its use
EP3730553A1 (en) * 2019-04-26 2020-10-28 Thai Polyethylene Co., Ltd. Composition comprising an oxidized polyethylene wax, a color masterbatch comprising the same,a product comprising the color masterbatch and the use of the color masterbatch
CN113563498A (en) * 2021-08-12 2021-10-29 朱孝恒 Polyethylene wax production method

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1089588A (en) * 1976-04-26 1980-11-11 Robert L. Elliott Oil-soluble addition products of an ethylene-olefin copolymer and anionically polymerizable monomer having utility as multifunctional v.i. improvers for lubricating oils

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB869492A (en) * 1960-03-21 1961-05-31 Shell Res Ltd Improvements in or relating to the low-pressure polymerisation of olefinic compoundsand catalysts therefor
FR1384630A (en) * 1962-10-02 1965-01-08 Scholven Chemie Ag Process for the preparation of waxes, from ethylene and products conforming to those obtained by said process or similar process
FR1375127A (en) * 1963-08-01 1964-10-16 Solvay Process for the polymerization and copolymerization of olefins
FR85522E (en) * 1964-03-03 1965-08-27 Solvay Process for the polymerization and copolymerization of olefins
US3400110A (en) * 1963-08-01 1968-09-03 Solvay Polymerization of olefins in the presence of a catalyst comprising an organometallic compound and the reaction product of a transition metal compound and a hydroxychloride of a bivalent metal
DE1645411B2 (en) * 1965-03-25 1974-02-07 Veba-Chemie Ag, 4660 Gelsenkirchenbuer Process for the production of polyethylene waxes
FR1516800A (en) * 1966-10-21 1968-03-15 Solvay Process for the polymerization and copolymerization of olefins.
CA920299A (en) * 1968-08-01 1973-01-30 Mitsui Petrochemical Industries Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier
FR1582942A (en) * 1968-08-26 1969-10-10
GB1189038A (en) * 1968-09-11 1970-04-22 Mitsui Petrochemical Ind Novel Process for the Polymerisation of Ethylene and Novel Catalyst for use therein
DK126901B (en) * 1968-10-09 1973-09-03 Montedison Spa Catalyst for polymerization of ethylene or copolymerization of ethylene with alpha-alkenes.

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4418184A (en) 1979-06-11 1983-11-29 Mitsui Petrochemical Industries, Ltd. Process for preparation of ethylene polymer wax
EP0021700A1 (en) * 1979-06-11 1981-01-07 Mitsui Petrochemical Industries, Ltd. Process for preparing ethylene polymer wax
US5498809A (en) 1992-12-17 1996-03-12 Exxon Chemical Patents Inc. Polymers derived from ethylene and 1-butene for use in the preparation of lubricant dispersant additives
US5554310A (en) 1992-12-17 1996-09-10 Exxon Chemical Patents Inc. Trisubstituted unsaturated polymers
US5663130A (en) 1992-12-17 1997-09-02 Exxon Chemical Patents Inc Polymers derived from ethylene and 1-butene for use in the preparation of lubricant dispersant additives
US6030930A (en) 1992-12-17 2000-02-29 Exxon Chemical Patents Inc Polymers derived from ethylene and 1-butene for use in the preparation of lubricant disperant additives
US5917100A (en) * 1993-01-07 1999-06-29 Clariant Gmbh Process for producing low molecular-weight poly-1-olefins
US5883196A (en) * 1995-05-24 1999-03-16 Basf Aktiengesellschaft Preparation of polyalkenylsuccinic acid derivatives and their use as fuel and lubricant additives
US7687579B2 (en) 1999-06-17 2010-03-30 Mitsui Chemicals, Inc. Ethylene (co) polymer and its use
US7563849B2 (en) 1999-06-17 2009-07-21 Mitsui Chemicals, Inc. Ethylene (co) polymer and its use
WO2008061826A1 (en) * 2006-11-25 2008-05-29 Evonik Degussa Gmbh Method for the production of synthetic polyethylene waxes with high crystallinity and low viscosity
CN101589072B (en) * 2006-11-25 2012-07-11 霍尼韦尔国际公司 Process for the preparation of synthetic polyethylene waxes with high crystallinity and low viscosity
US9403923B2 (en) 2006-11-25 2016-08-02 Honeywell International Inc. Process for preparing synthetic polyethylene waxes having a high crystallinity and low viscosity
EP3730553A1 (en) * 2019-04-26 2020-10-28 Thai Polyethylene Co., Ltd. Composition comprising an oxidized polyethylene wax, a color masterbatch comprising the same,a product comprising the color masterbatch and the use of the color masterbatch
WO2020216605A1 (en) * 2019-04-26 2020-10-29 Thai Polyethylene Co., Ltd. Composition comprising an oxidized polyethylene wax, a color masterbatch comprising the same, a product comprising the color masterbatch and the use of the color masterbatch
CN113383042A (en) * 2019-04-26 2021-09-10 泰国聚乙烯有限公司 Composition comprising oxidized polyethylene wax, color masterbatch comprising same, product comprising color masterbatch and use of color masterbatch
CN113563498A (en) * 2021-08-12 2021-10-29 朱孝恒 Polyethylene wax production method

Also Published As

Publication number Publication date
FR2092165A1 (en) 1972-01-21
DE2126725B2 (en) 1978-07-06
CA987847A (en) 1976-04-20
NL7107392A (en) 1971-12-01
DE2126725C3 (en) 1983-04-21
FR2092165B1 (en) 1974-03-22
NL152567B (en) 1977-03-15
DE2126725A1 (en) 1972-01-05

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years