GB1388204A - Process for the treatment of exhausted chromium-plating solutions - Google Patents
Process for the treatment of exhausted chromium-plating solutionsInfo
- Publication number
- GB1388204A GB1388204A GB1542872A GB1542872A GB1388204A GB 1388204 A GB1388204 A GB 1388204A GB 1542872 A GB1542872 A GB 1542872A GB 1542872 A GB1542872 A GB 1542872A GB 1388204 A GB1388204 A GB 1388204A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chromium
- solution
- exhausted
- chromate
- plating solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007747 plating Methods 0.000 title abstract 5
- 238000000034 method Methods 0.000 title 1
- 239000011651 chromium Substances 0.000 abstract 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 5
- 229910052804 chromium Inorganic materials 0.000 abstract 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 4
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 4
- ABXXWVKOBZHNNF-UHFFFAOYSA-N chromium(3+);dioxido(dioxo)chromium Chemical compound [Cr+3].[Cr+3].[O-][Cr]([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Cr]([O-])(=O)=O ABXXWVKOBZHNNF-UHFFFAOYSA-N 0.000 abstract 3
- 235000019441 ethanol Nutrition 0.000 abstract 3
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- LXMQZGGLHVSEBA-UHFFFAOYSA-N chromium;trihydrate Chemical compound O.O.O.[Cr] LXMQZGGLHVSEBA-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000003792 electrolyte Substances 0.000 abstract 2
- 229960004887 ferric hydroxide Drugs 0.000 abstract 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 abstract 2
- QLOKJRIVRGCVIM-UHFFFAOYSA-N 1-[(4-methylsulfanylphenyl)methyl]piperazine Chemical compound C1=CC(SC)=CC=C1CN1CCNCC1 QLOKJRIVRGCVIM-UHFFFAOYSA-N 0.000 abstract 1
- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 abstract 1
- PMJNEQWWZRSFCE-UHFFFAOYSA-N 3-ethoxy-3-oxo-2-(thiophen-2-ylmethyl)propanoic acid Chemical compound CCOC(=O)C(C(O)=O)CC1=CC=CS1 PMJNEQWWZRSFCE-UHFFFAOYSA-N 0.000 abstract 1
- 235000010724 Wisteria floribunda Nutrition 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- JOSWYUNQBRPBDN-UHFFFAOYSA-P ammonium dichromate Chemical compound [NH4+].[NH4+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O JOSWYUNQBRPBDN-UHFFFAOYSA-P 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 abstract 1
- PXLIDIMHPNPGMH-UHFFFAOYSA-N sodium chromate Chemical compound [Na+].[Na+].[O-][Cr]([O-])(=O)=O PXLIDIMHPNPGMH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
- C02F1/683—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of complex-forming compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/16—Regeneration of process solutions
- C25D21/18—Regeneration of process solutions of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/22—Chromium or chromium compounds, e.g. chromates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Hydrology & Water Resources (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Chemical Treatment Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
1388204 Treating chromium plating solution FUJI KUROMU SHA KK 4 April 1972 [5 April 1971 14 Aug 1971 (2)] 15428/72 Heading C1A [Also in Division C7] Exhausted aqueous chromium plating solution is treated with chromium trihydroxide or an alcohol of formula ROH wherein R is an alkyl group having 1 to 3 carbon atoms (e.g. ethyl alcohol), to convert all chromium values contained in the exhausted solution to a chromium chromate complex compound containing Cr<SP>6+</SP> and Cr<SP>3+</SP> ions and to convert iron values contained in the exhausted solution to ferric hydroxide and the resulting mixture is filtered to separate the aqueous chromium chromate complex compound solution from the ferric hydroxide. The chromium trihydroxide may be employed in a stoichiometrically equivalent amount to the chromic anhydride content of the exhausted solution and the alcohol may be employed in an amount of 400 ml. per 1 kg. of chromic anhydride in the exhausted solution. The ferric hydroxide residue may be burnt to convert it to ferric oxide and the aqueous chromium chromate complex solution obtained may be recycled to the chromium plating solution or can be used as an anode electrolyte in diaphragm electrolysis employing potassium dichromate, sodium dichromate, ammonium dichromate, potassium chromate, sodium chromate or ammonium chromate alone or in admixture as the cathode electrolyte to produce regenerated chromium plating solution.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP46020308A JPS5119417B1 (en) | 1971-04-05 | 1971-04-05 | |
| JP46061782A JPS5126892B2 (en) | 1971-08-14 | 1971-08-14 | |
| JP6178171A JPS5119813B2 (en) | 1971-08-14 | 1971-08-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1388204A true GB1388204A (en) | 1975-03-26 |
Family
ID=27282981
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1542872A Expired GB1388204A (en) | 1971-04-05 | 1972-04-04 | Process for the treatment of exhausted chromium-plating solutions |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE2216393C3 (en) |
| FR (1) | FR2132449B1 (en) |
| GB (1) | GB1388204A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115928108A (en) * | 2022-12-23 | 2023-04-07 | 中国科学院青海盐湖研究所 | Method for preparing trivalent chromium compound directly by electrochemical oxidation of ferrochrome |
| WO2024130918A1 (en) * | 2022-12-23 | 2024-06-27 | 中国科学院青海盐湖研究所 | Method and apparatus for preparing trivalent chromium salt by electrochemical oxidation of ferrochrome in acidic system |
| CN119191524A (en) * | 2024-11-15 | 2024-12-27 | 重庆广仁能源装备股份有限公司 | A process for treating chromium-containing waste liquid |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4243501A (en) * | 1979-03-30 | 1981-01-06 | Michael Ladney, Jr. | Process and apparatus for the regeneration of chromic acid baths |
| DE4109434C2 (en) * | 1991-03-22 | 1993-12-23 | Ludwig Mechler Gmbh | Process for working up chromate-containing wastewaters and / or process solutions |
| CN112110487B (en) * | 2020-09-22 | 2022-07-08 | 攀钢集团研究院有限公司 | Preparation method of easily soluble chromium hydroxide |
-
1972
- 1972-04-04 GB GB1542872A patent/GB1388204A/en not_active Expired
- 1972-04-05 FR FR7211925A patent/FR2132449B1/fr not_active Expired
- 1972-04-05 DE DE19722216393 patent/DE2216393C3/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115928108A (en) * | 2022-12-23 | 2023-04-07 | 中国科学院青海盐湖研究所 | Method for preparing trivalent chromium compound directly by electrochemical oxidation of ferrochrome |
| WO2024130917A1 (en) * | 2022-12-23 | 2024-06-27 | 中国科学院青海盐湖研究所 | Method for directly preparing trivalent chromium compound by means of electrochemical oxidation of ferrochromium |
| WO2024130918A1 (en) * | 2022-12-23 | 2024-06-27 | 中国科学院青海盐湖研究所 | Method and apparatus for preparing trivalent chromium salt by electrochemical oxidation of ferrochrome in acidic system |
| US12281399B1 (en) | 2022-12-23 | 2025-04-22 | Qinghai Institute Of Salt Lakes, Chinese Academy Of Sciences | Method for directly preparing trivalent chromium compound by electrochemical oxidation of ferrochrome |
| US12312698B2 (en) | 2022-12-23 | 2025-05-27 | Qinghai Institute Of Salt Lakes, Chinese Academy Of Sciences | Method and device for preparing trivalent chromium salt by electrochemical oxidation of ferrochrome in acidic system |
| CN119191524A (en) * | 2024-11-15 | 2024-12-27 | 重庆广仁能源装备股份有限公司 | A process for treating chromium-containing waste liquid |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2132449B1 (en) | 1974-08-02 |
| DE2216393B2 (en) | 1973-11-29 |
| DE2216393C3 (en) | 1974-07-04 |
| DE2216393A1 (en) | 1972-10-26 |
| FR2132449A1 (en) | 1972-11-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |