GB1367243A - Hydrodesulphurization catalyst and preparation and use thereof - Google Patents
Hydrodesulphurization catalyst and preparation and use thereofInfo
- Publication number
- GB1367243A GB1367243A GB100872A GB100872A GB1367243A GB 1367243 A GB1367243 A GB 1367243A GB 100872 A GB100872 A GB 100872A GB 100872 A GB100872 A GB 100872A GB 1367243 A GB1367243 A GB 1367243A
- Authority
- GB
- United Kingdom
- Prior art keywords
- steam
- heated
- substantially dry
- mixed
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 238000001354 calcination Methods 0.000 abstract 2
- 239000002131 composite material Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 239000000908 ammonium hydroxide Substances 0.000 abstract 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 abstract 1
- 229940010552 ammonium molybdate Drugs 0.000 abstract 1
- 235000018660 ammonium molybdate Nutrition 0.000 abstract 1
- 239000011609 ammonium molybdate Substances 0.000 abstract 1
- 239000012876 carrier material Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910021446 cobalt carbonate Inorganic materials 0.000 abstract 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 abstract 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 abstract 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
1367243 Hydrodesulphurization catalysts UNIVERSAL OIL PRODUCTS CO 10 Jan 1972 [11 Jan 1971] 1008/72 Heading B1E [Also in Division C5] A method for preparing a catalyst comprises compositing a carrier material with the precursor of at least one catalytically active metallic component selected from each of Groups V1B (i.e. the chromium group) and VIII of the Periodic Table of Elements, said precursor being in the form of one. or more thermally decomposable compounds containing one or more of said selected metals, subjecting the resulting composite, if desired after drying, to a first calcination for at least 0.5 hour in an oxidizing atmosphere containing more than 20% by volume of steam at temperature in the range from 260‹ to 371‹C, and thereafter subjecting the composite to a second calcination for a period of from 1 to 4 hours in a "substantially dry" oxidizing atmosphere and at a temperature in the range from 427‹ to 649‹C. "Substantially dry" is defined as containing not more than 10% by volume of steam. The carrier may be impregnated with solutions of the compounds or mixed with them in the dry state and extruded into particle form. In example I, alumina is impregnated with a solution of ammonium molybdate and cobalt nitrate in ammonium hydroxide, dried, heated in air containing 50% steam for one hour at 650‹F and in air containing 10%, steam for 2 hours at 1100‹F. In example IV alumina is mixed with molybdic anhydride and cobalt carbonate, and the mixture further mixed with 5% nitric acid and extruded, then heated in two stages as before. In comparative example III, catalysts are prepared as in example I but heated either (a) in "substantially dry" air or (b) in air containing about 20% of steam.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10569971A | 1971-01-11 | 1971-01-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1367243A true GB1367243A (en) | 1974-09-18 |
Family
ID=22307315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB100872A Expired GB1367243A (en) | 1971-01-11 | 1972-01-10 | Hydrodesulphurization catalyst and preparation and use thereof |
Country Status (17)
| Country | Link |
|---|---|
| JP (1) | JPS526712B1 (en) |
| BR (1) | BR7200140D0 (en) |
| CA (1) | CA967544A (en) |
| CS (1) | CS170174B2 (en) |
| DD (1) | DD95642A5 (en) |
| ES (1) | ES398632A1 (en) |
| FR (1) | FR2121654B1 (en) |
| GB (1) | GB1367243A (en) |
| HU (1) | HU167392B (en) |
| IE (1) | IE35954B1 (en) |
| IT (1) | IT948166B (en) |
| MY (1) | MY7700067A (en) |
| NL (1) | NL172832C (en) |
| PL (1) | PL77342B1 (en) |
| SU (1) | SU429572A3 (en) |
| YU (1) | YU34847B (en) |
| ZA (1) | ZA7230B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4181602A (en) | 1977-12-21 | 1980-01-01 | Standard Oil Company (Indiana) | Process for the hydrotreating of heavy hydrocarbon streams |
| US4188284A (en) * | 1977-12-21 | 1980-02-12 | Standard Oil Company (Indiana) | Process for the hydrotreating of heavy hydrocarbon streams |
| US4191635A (en) * | 1977-12-21 | 1980-03-04 | Standard Oil Company (Indiana) | Process for the cracking of heavy hydrocarbon streams |
| US4224144A (en) | 1979-03-19 | 1980-09-23 | Standard Oil Company (Indiana) | Hydrotreating a hydrocarbon stream to remove nitrogen and sulfur |
| US4306965A (en) | 1979-03-19 | 1981-12-22 | Standard Oil Company (Indiana) | Hydrotreating process |
| CN119613219A (en) * | 2025-02-13 | 2025-03-14 | 孝义市晋茂化工有限公司 | Coking crude benzene catalytic hydrofining method |
-
1972
- 1972-01-03 ZA ZA720030A patent/ZA7230B/en unknown
- 1972-01-04 IE IE9/72A patent/IE35954B1/en unknown
- 1972-01-05 ES ES398632A patent/ES398632A1/en not_active Expired
- 1972-01-07 FR FR727200428A patent/FR2121654B1/fr not_active Expired
- 1972-01-07 YU YU32/72A patent/YU34847B/en unknown
- 1972-01-07 CA CA131,924A patent/CA967544A/en not_active Expired
- 1972-01-10 CS CS141A patent/CS170174B2/cs unknown
- 1972-01-10 IT IT47640/72A patent/IT948166B/en active
- 1972-01-10 GB GB100872A patent/GB1367243A/en not_active Expired
- 1972-01-10 SU SU1737352A patent/SU429572A3/en active
- 1972-01-10 HU HUUI187A patent/HU167392B/hu unknown
- 1972-01-10 PL PL1972152840A patent/PL77342B1/pl unknown
- 1972-01-11 NL NLAANVRAGE7200426,A patent/NL172832C/en not_active IP Right Cessation
- 1972-01-11 BR BR140/72A patent/BR7200140D0/en unknown
- 1972-01-11 JP JP47004998A patent/JPS526712B1/ja active Pending
- 1972-01-11 DD DD160376A patent/DD95642A5/xx unknown
-
1977
- 1977-12-30 MY MY67/77A patent/MY7700067A/en unknown
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4181602A (en) | 1977-12-21 | 1980-01-01 | Standard Oil Company (Indiana) | Process for the hydrotreating of heavy hydrocarbon streams |
| US4188284A (en) * | 1977-12-21 | 1980-02-12 | Standard Oil Company (Indiana) | Process for the hydrotreating of heavy hydrocarbon streams |
| US4191635A (en) * | 1977-12-21 | 1980-03-04 | Standard Oil Company (Indiana) | Process for the cracking of heavy hydrocarbon streams |
| US4224144A (en) | 1979-03-19 | 1980-09-23 | Standard Oil Company (Indiana) | Hydrotreating a hydrocarbon stream to remove nitrogen and sulfur |
| US4306965A (en) | 1979-03-19 | 1981-12-22 | Standard Oil Company (Indiana) | Hydrotreating process |
| CN119613219A (en) * | 2025-02-13 | 2025-03-14 | 孝义市晋茂化工有限公司 | Coking crude benzene catalytic hydrofining method |
Also Published As
| Publication number | Publication date |
|---|---|
| AU3764772A (en) | 1973-07-12 |
| NL7200426A (en) | 1972-07-13 |
| YU3272A (en) | 1979-10-31 |
| DD95642A5 (en) | 1973-02-12 |
| ES398632A1 (en) | 1974-10-01 |
| IE35954L (en) | 1972-07-11 |
| PL77342B1 (en) | 1975-04-30 |
| FR2121654B1 (en) | 1974-06-21 |
| ZA7230B (en) | 1972-09-27 |
| IE35954B1 (en) | 1976-07-07 |
| SU429572A3 (en) | 1974-05-25 |
| FR2121654A1 (en) | 1972-08-25 |
| MY7700067A (en) | 1977-12-31 |
| NL172832B (en) | 1983-06-01 |
| DE2200269B2 (en) | 1975-12-11 |
| HU167392B (en) | 1975-09-27 |
| JPS526712B1 (en) | 1977-02-24 |
| IT948166B (en) | 1973-05-30 |
| BR7200140D0 (en) | 1973-06-14 |
| DE2200269A1 (en) | 1972-07-27 |
| CA967544A (en) | 1975-05-13 |
| NL172832C (en) | 1983-11-01 |
| YU34847B (en) | 1980-04-30 |
| CS170174B2 (en) | 1976-08-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |