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GB1359367A - Layered complex metal silicate composition their preparation and use in hydrocarbon conversion reactions - Google Patents

Layered complex metal silicate composition their preparation and use in hydrocarbon conversion reactions

Info

Publication number
GB1359367A
GB1359367A GB3773871A GB3773871A GB1359367A GB 1359367 A GB1359367 A GB 1359367A GB 3773871 A GB3773871 A GB 3773871A GB 3773871 A GB3773871 A GB 3773871A GB 1359367 A GB1359367 A GB 1359367A
Authority
GB
United Kingdom
Prior art keywords
hydrocarbon conversion
preparation
metal silicate
complex metal
conversion reactions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3773871A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1359367A publication Critical patent/GB1359367A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/14—Silica and magnesia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/20—Regeneration or reactivation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/22—Magnesium silicates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/16—Clays or other mineral silicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1359367 Hydrocarbon conversion catalysts ESSO RESEARCH & ENG CO 11 Aug 1971 [31 Aug 1970 (4)] 37738/71 Heading B1E [Also in Divisions Cl and C5] A layered silicate having the formula where x is 0-1, # is 0-4, and n is 6/[a(1-x)+ bx], a and b being the valencies of M and M<SP>1</SP> resp., is used as a catalyst for hydrocarbon conversions, alone, or impregnated with another metal, and/or composited with a matrix material. M and M<SP>1</SP> may be Mg, Ni, Co. Cr, Mo, W, Pd, Pt, Al, Li, Cu, Zn, Sc, Ga, Ti, Zr, V, Mn, Fe. The silicate may be in the form of tubes or flakes. Specific silicates disclosed are Mg, Ni, Mg, with Co, Ni, Fe, Mn, Cu, Cr, Zn, Al, W, Mo, Pt and Re, Ni/W, Ni/Al, and Co/Mo. They may be impregnated with Cr, Pt, Pd, Mo, W, Ni, Co, or Re compounds, and may be formed into pellets with a binder, calcined. and the metal optionally reduced. The silicate may also be treated with AlBr 3 , AlCl 3 , or HF. The matrix material may be Al 2 O 3 -SiO 2 .
GB3773871A 1970-08-31 1971-08-11 Layered complex metal silicate composition their preparation and use in hydrocarbon conversion reactions Expired GB1359367A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US6821370A 1970-08-31 1970-08-31
US6839370A 1970-08-31 1970-08-31
US6839470A 1970-08-31 1970-08-31
US6823470A 1970-08-31 1970-08-31

Publications (1)

Publication Number Publication Date
GB1359367A true GB1359367A (en) 1974-07-10

Family

ID=27490694

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3773871A Expired GB1359367A (en) 1970-08-31 1971-08-11 Layered complex metal silicate composition their preparation and use in hydrocarbon conversion reactions

Country Status (1)

Country Link
GB (1) GB1359367A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0038682A1 (en) * 1980-04-23 1981-10-28 The British Petroleum Company p.l.c. Process for the production of synthesis gas from methanol
GB2164636A (en) * 1984-08-24 1986-03-26 British Petroleum Co Plc Synthetic smectites and their stabilised pillared analogues
EP0256185A1 (en) * 1985-07-19 1988-02-24 Exxon Research And Engineering Company Multimetallic pillared interlayered clay products and processes of making them
GB2225731A (en) * 1988-11-28 1990-06-13 Shell Int Research Stabilized magnesia-based hydrotreating catalysts and their use in catalytic processes
CN113479897A (en) * 2021-07-16 2021-10-08 常州大学 Method for preparing two-dimensional nanosheet silicate by using attapulgite and application thereof
CN114433120A (en) * 2022-02-28 2022-05-06 中国刑事警察学院 Desulfurization catalyst and preparation method and application thereof
CN116726977A (en) * 2023-05-08 2023-09-12 浙江工业大学 Bimetallic phyllosilicate catalyst based on natural zeolite and application thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0038682A1 (en) * 1980-04-23 1981-10-28 The British Petroleum Company p.l.c. Process for the production of synthesis gas from methanol
GB2164636A (en) * 1984-08-24 1986-03-26 British Petroleum Co Plc Synthetic smectites and their stabilised pillared analogues
EP0256185A1 (en) * 1985-07-19 1988-02-24 Exxon Research And Engineering Company Multimetallic pillared interlayered clay products and processes of making them
GB2225731A (en) * 1988-11-28 1990-06-13 Shell Int Research Stabilized magnesia-based hydrotreating catalysts and their use in catalytic processes
CN113479897A (en) * 2021-07-16 2021-10-08 常州大学 Method for preparing two-dimensional nanosheet silicate by using attapulgite and application thereof
CN113479897B (en) * 2021-07-16 2023-10-24 常州大学 Method for preparing two-dimensional nano sheet silicate by using attapulgite and application thereof
CN114433120A (en) * 2022-02-28 2022-05-06 中国刑事警察学院 Desulfurization catalyst and preparation method and application thereof
CN116726977A (en) * 2023-05-08 2023-09-12 浙江工业大学 Bimetallic phyllosilicate catalyst based on natural zeolite and application thereof
CN116726977B (en) * 2023-05-08 2025-09-02 浙江工业大学 Bimetallic layered silicate catalyst based on natural zeolite and its application

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Legal Events

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PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee

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