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GB1357335A - Hydrogen - Google Patents

Hydrogen

Info

Publication number
GB1357335A
GB1357335A GB3551370A GB3551370A GB1357335A GB 1357335 A GB1357335 A GB 1357335A GB 3551370 A GB3551370 A GB 3551370A GB 3551370 A GB3551370 A GB 3551370A GB 1357335 A GB1357335 A GB 1357335A
Authority
GB
United Kingdom
Prior art keywords
catalyst
guard
hydrogen
guard material
shift
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3551370A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3551370A priority Critical patent/GB1357335A/en
Priority to IT752271A priority patent/IT951922B/en
Priority to CA118,813A priority patent/CA945738A/en
Priority to FR7126778A priority patent/FR2103196A5/fr
Priority to DE19712136746 priority patent/DE2136746A1/en
Priority to NL7110096A priority patent/NL7110096A/xx
Priority to BE770356A priority patent/BE770356A/en
Priority to US316566A priority patent/US3922337A/en
Publication of GB1357335A publication Critical patent/GB1357335A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

1357335 Hydrogen-rich gas IMPERIAL CHEMICAL INDUSTRIES Ltd 28 June 1971 [22 July 1970] 35513/70 Heading C5E Hydrogen is produced by reacting CO with steam at under 300‹ C. over a copper containing low temperature shift catalyst in discrete pieces characterized in that the catalyst is preceded by a bed of discrete pieces of a solid guard material that is more basic than ZnO or that such catalyst and such guard material are in admixture. The guard material may comprise a basic compound (e.g. an oxide, hydroxide or carbonate) supported on a carrier (e.g. alumina). The guard material may contain 0À3 to 0À6% by weight of the basic compound while the catalyst contains less than 0À25% by weight thereof. A hydrocarbon feedstock e.g. CH 4 , butane, naphtha or refinery gas may be reacted at 600‹ to 1000‹ C. to give a gas containing CO and H 2 which is cooled to shift inlet temperature and subjected to shift conversion over a catalyst as above which is protected by said guard bed. In the examples the guard materials are NaOH on Al 2 O 3 , a mixture of NaOH, ZnO, CuO and Al 2 O 3 or nitrates of Ba, Mn, Y or La on alumina.
GB3551370A 1970-07-22 1970-07-22 Hydrogen Expired GB1357335A (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
GB3551370A GB1357335A (en) 1970-07-22 1970-07-22 Hydrogen
IT752271A IT951922B (en) 1970-07-22 1971-07-21 TATALYTIC PROCESS FOR THE PRODUCTION OF HYDROGEN FROM CARBON OXIDE AND WATER VAPOR
CA118,813A CA945738A (en) 1970-07-22 1971-07-21 Process for producing hydrogen
FR7126778A FR2103196A5 (en) 1970-07-22 1971-07-21
DE19712136746 DE2136746A1 (en) 1970-07-22 1971-07-22 Process for the production of hydrogen
NL7110096A NL7110096A (en) 1970-07-22 1971-07-22
BE770356A BE770356A (en) 1970-07-22 1971-07-22 PROCESS FOR PRODUCING HYDROGEN
US316566A US3922337A (en) 1970-07-22 1972-12-19 Hydrogen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3551370A GB1357335A (en) 1970-07-22 1970-07-22 Hydrogen

Publications (1)

Publication Number Publication Date
GB1357335A true GB1357335A (en) 1974-06-19

Family

ID=10378584

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3551370A Expired GB1357335A (en) 1970-07-22 1970-07-22 Hydrogen

Country Status (7)

Country Link
BE (1) BE770356A (en)
CA (1) CA945738A (en)
DE (1) DE2136746A1 (en)
FR (1) FR2103196A5 (en)
GB (1) GB1357335A (en)
IT (1) IT951922B (en)
NL (1) NL7110096A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2390377A1 (en) * 1977-05-09 1978-12-08 Ici Ltd PROCESS FOR OBTAINING CARBON DIOXIDE AND HYDROGEN FROM CARBON MONO-OXIDE AND WATER VAPOR
WO2001017674A1 (en) * 1999-09-06 2001-03-15 Imperial Chemical Industries Plc Guard bed containing lead compounds upstream of a bed of copper-containing catalyst to prevent its contamination by chlorine and sulphur contaminants
WO2002066156A1 (en) * 2001-02-20 2002-08-29 Johnson Matthey Plc A combination of a guard bed and a catalyst bed
WO2004014546A1 (en) * 2002-08-13 2004-02-19 Johnson Matthey Plc Combination of a guard bed and a copper-containing catalyst bed
CN101531568B (en) * 2009-04-13 2011-12-07 烟台万华聚氨酯股份有限公司 Method for synthesizing 1,6-hexamethylene glycol by using dimethyl adipate gas phase and hydrogen
WO2017072479A1 (en) * 2015-10-29 2017-05-04 Johnson Matthey Public Limited Company Water gas shift process
US10807866B2 (en) 2015-10-29 2020-10-20 Johnson Matthey Public Limited Company Water-gas shift catalyst
US11014811B2 (en) 2015-10-29 2021-05-25 Johnson Matthey Public Limited Company Water gas shift process
EP4155287A1 (en) 2021-09-23 2023-03-29 Clariant International Ltd Reactor and method for methanol synthesis

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2390377A1 (en) * 1977-05-09 1978-12-08 Ici Ltd PROCESS FOR OBTAINING CARBON DIOXIDE AND HYDROGEN FROM CARBON MONO-OXIDE AND WATER VAPOR
US7098167B2 (en) 1999-09-06 2006-08-29 Johnson Matthey Plc Guard bed containing lead compounds upstream of a bed of copper-containing catalyst to prevent its contamination by chlorine and sulphur contaminants
WO2001017674A1 (en) * 1999-09-06 2001-03-15 Imperial Chemical Industries Plc Guard bed containing lead compounds upstream of a bed of copper-containing catalyst to prevent its contamination by chlorine and sulphur contaminants
US7501112B2 (en) 1999-09-06 2009-03-10 Johnson Matthey Plc Guard bed containing lead compounds upstream of a bed of copper-containing catalyst to prevent its contamination by chlorine and sulphur contaminants
RU2238146C2 (en) * 1999-09-06 2004-10-20 Джонсон Мэтти Плс Protective layer containing lead compounds before copper-containing catalyst layer to prevent chlorine and sulfur pollution thereof
RU2275239C2 (en) * 2001-02-20 2006-04-27 Джонсон Мэтти Плс Protective layer-catalyst bed combination and a method for performing catalytic reaction using the same
US7087550B2 (en) * 2001-02-20 2006-08-08 Johnson Matthey Plc Combination of a guard bed and a catalyst bed
AU2002225185B2 (en) * 2001-02-20 2005-10-27 Johnson Matthey Plc A combination of a guard bed and a catalyst bed
WO2002066156A1 (en) * 2001-02-20 2002-08-29 Johnson Matthey Plc A combination of a guard bed and a catalyst bed
WO2004014546A1 (en) * 2002-08-13 2004-02-19 Johnson Matthey Plc Combination of a guard bed and a copper-containing catalyst bed
US7148178B2 (en) 2002-08-13 2006-12-12 Johnson Matthey Plc Combination of a guard bed and a copper-containing catalyst bed
CN101531568B (en) * 2009-04-13 2011-12-07 烟台万华聚氨酯股份有限公司 Method for synthesizing 1,6-hexamethylene glycol by using dimethyl adipate gas phase and hydrogen
WO2017072479A1 (en) * 2015-10-29 2017-05-04 Johnson Matthey Public Limited Company Water gas shift process
US10494255B2 (en) 2015-10-29 2019-12-03 Johnson Matthey Public Limited Company Water gas shift process
US10807866B2 (en) 2015-10-29 2020-10-20 Johnson Matthey Public Limited Company Water-gas shift catalyst
US11014811B2 (en) 2015-10-29 2021-05-25 Johnson Matthey Public Limited Company Water gas shift process
EP4155287A1 (en) 2021-09-23 2023-03-29 Clariant International Ltd Reactor and method for methanol synthesis
WO2023046685A1 (en) 2021-09-23 2023-03-30 Clariant International Ltd. Reactor and method for synthesizing methanol

Also Published As

Publication number Publication date
CA945738A (en) 1974-04-23
FR2103196A5 (en) 1972-04-07
DE2136746A1 (en) 1972-04-06
NL7110096A (en) 1972-01-25
BE770356A (en) 1972-01-24
IT951922B (en) 1973-07-10

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees