GB1340025A - Thermoplastic compositions - Google Patents
Thermoplastic compositionsInfo
- Publication number
- GB1340025A GB1340025A GB2674171*A GB2674171A GB1340025A GB 1340025 A GB1340025 A GB 1340025A GB 2674171 A GB2674171 A GB 2674171A GB 1340025 A GB1340025 A GB 1340025A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methacrylate
- acrylate
- stage
- styrene
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 7
- 229920001169 thermoplastic Polymers 0.000 title abstract 4
- 239000004416 thermosoftening plastic Substances 0.000 title abstract 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 14
- 239000000178 monomer Substances 0.000 abstract 11
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 6
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 abstract 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 5
- 229920000642 polymer Polymers 0.000 abstract 5
- 229920005601 base polymer Polymers 0.000 abstract 4
- FQMIAEWUVYWVNB-UHFFFAOYSA-N 3-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OC(C)CCOC(=O)C=C FQMIAEWUVYWVNB-UHFFFAOYSA-N 0.000 abstract 3
- -1 aralkyl acrylates Chemical class 0.000 abstract 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 abstract 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 abstract 2
- HGBBKKWVSQBIMM-UHFFFAOYSA-N 2-pyrrolidin-1-yl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine Chemical compound O1C(C)(C)C(C)(C)OB1C1=CC=C(N2CCCC2)N=C1 HGBBKKWVSQBIMM-UHFFFAOYSA-N 0.000 abstract 2
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 abstract 2
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 abstract 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical group CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- 239000004971 Cross linker Substances 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 229920000578 graft copolymer Polymers 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229940063557 methacrylate Drugs 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract 1
- 239000002861 polymer material Substances 0.000 abstract 1
- 239000004926 polymethyl methacrylate Substances 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
1340025 Multi-stage graft polymers ROHM & HAAS CO 19 April 1971 [13 April 1970] 26741/71 Heading C3G A multi-stage sequentially produced polymer comprises (A) a first elastomeric portion polymerized from a monomer mix comprising at least 50% by weight of one or more alkyl or aralkyl acrylates, 0À05-5À0% by weight of one or more cross-linking monomers, 0À05-5À0% by weight of one or more graft-linking monomers having two or more addition polymerizable unsaturated groups which participate in the polymerization reaction at substantially different rates, adapted to attach the elastomeric phase to the rigid phase defined hereinafter, 0-10À0% by weight hydrophilic monomer or non-hydrophilic monomer which is converted to hydrophilic mers in the elastomeric portion, the balance, if any, of said monomer mix being composed of one or more other copolymerizable ethylenically unsaturated monomars; and (B) a final, rigid thermoplastic portion polymerized, in the presence of said elastomeric portion, from a monomer mix comprising at least 50% by weight alkyl methacrylate, wherein said elastomeric portion and said thermoplastic portion have a minimum attachment level as hereinbefore defined of 20%. The multi-stage polymer material may be prepared by emulsion polymerization of an appropriate monomer charge to form the elastomeric portion and then continuing the emulsion polymerization with the addition of the monomer mix constituting the rigid portion material. The polymerization reactions may be initiated by either thermal or redox type initiator systems and conven- tional emulsifiers may also be present. Numerous examples of all the different monomer units are given. The composition of the multi-stage polymers in the specific examples (1-6) all of which refer to two-stage polymers is as follows: (1) a base polymer of butyl acrylate ("acrylate"), 1,3-butylene glycol diacrylate ("crosslinker"), allyl methacrylate ("graft-linker"), and styrene acrylonitrile, hydroxy ethyl acrylate or methacrylamide units on to which is grafted monomer units of methyl methacrylate ; (2) a base polymer of butyl acrylate, 1,3, butylene glycol diacrylate, allyl methacrylate, styrene hydroxyethyl acrylate, hydroxyethyl methacrylate or acrylamide on to which is grafted methyl methacrylate hydroxyethyl methacrylate; (3) a base polymer of butyl i acrylate, 1,3-butylene diacrylate, allyl meth- acrylate, styrene, and either methacrylamide, N-ispropyl acrylamide or hydroxy propyl methacrylate on to which is grafted methyl methacrylate; and (4), (5), (6) a base polymer of butyl acrylate, 1,3-butylene glycol diacrylate, allyl methacrylate, styrene, hydroxypropyl methacrylate, ethylthioethyl methacrylate on to which is grafted a mixture of methyl methacrylate and methyl acrylate. Examples (8) and (9) refer to three stage polymers in which the 1st stage is constituted of butyl acrylate, styrene, ethylthioethyl methacrylate, butylene glycol diacrylate and allyl methacrylate; the 2nd stage of styrene, butyl acrylate, divinyl benzene and allyl methacrylate; and the 3rd stage (rigid portion) of either (a) methyl methacrylate, styrene and methyl acrylate or (b) methyl methacrylate, α-methyl styrene and methyl acrylate. The multi-stage polymer may be blended with a rigid thermoplastic polymer such as poly- (methyl methacrylate), copolymer of methyl methacrylate and ethyl acrylate, and vinyl halide homo- or co-polymers. In addition lubricants, dyes, fillers and plasticizers may be incorporated.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2799670A | 1970-04-13 | 1970-04-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1340025A true GB1340025A (en) | 1973-12-05 |
Family
ID=21840986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2674171*A Expired GB1340025A (en) | 1970-04-13 | 1971-04-19 | Thermoplastic compositions |
Country Status (10)
| Country | Link |
|---|---|
| AU (1) | AU2759171A (en) |
| BE (1) | BE763809A (en) |
| BR (1) | BR7102116D0 (en) |
| DE (1) | DE2116653A1 (en) |
| ES (1) | ES390495A1 (en) |
| FR (1) | FR2092389A5 (en) |
| GB (1) | GB1340025A (en) |
| IL (1) | IL36593A0 (en) |
| NL (1) | NL7104937A (en) |
| ZA (1) | ZA712265B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2253689A1 (en) * | 1971-11-05 | 1973-05-10 | Rohm & Haas | THERMOPLASTIC PLASTIC COMPOUND |
| US4255308A (en) | 1979-07-12 | 1981-03-10 | E. I. Du Pont De Nemours And Company | Water based acrylic lacquer composition |
| EP0110123A1 (en) * | 1982-10-28 | 1984-06-13 | Mitsubishi Rayon Co., Ltd. | Delustering thermoplastic resin compostion |
| EP0143991A3 (en) * | 1983-11-02 | 1986-10-08 | Mitsubishi Rayon Co. Ltd. | Impact-resistant methacrylic resin composition |
| EP0182558A3 (en) * | 1984-11-12 | 1987-07-15 | Mitsubishi Rayon Co. Ltd. | Non-rigid vinyl chloride polymer resin composition |
| US7829610B2 (en) | 2002-08-19 | 2010-11-09 | Ticona Gmbh | Impact-resistant polyoxymethylene molding compositions, use thereof and moldings produced therefrom |
| WO2017213827A1 (en) | 2016-06-06 | 2017-12-14 | Baxter International Inc. | Methods of improving adhesion of non-di-(2-ethylhexyl)phthalate polyvinyl chloride to an acrylic- or abs-based polymer |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS515674B2 (en) * | 1972-05-26 | 1976-02-21 | ||
| DE2444584C3 (en) * | 1974-09-18 | 1982-01-21 | Basf Ag, 6700 Ludwigshafen | Thermoplastic polyester molding compounds |
| US4152495A (en) * | 1976-04-06 | 1979-05-01 | Rohm And Haas Company | Foamed thermoplastic resin composition containing multiple stage polymeric modifiers |
| DE2749579A1 (en) * | 1977-11-05 | 1979-05-10 | Basf Ag | PROCESS FOR THE PRODUCTION OF MIXED GRAFT POLYMERISATES |
| FR2610328B1 (en) * | 1987-01-30 | 1989-08-25 | Charbonnages Ste Chimique | INTERPOLYMER STRENGTHENING MATERIAL OF RIGID THERMOPLASTIC MATRICES, PREPARATION THEREOF AND CORRESPONDING REINFORCED COMPOSITIONS |
| DE19617068A1 (en) * | 1996-04-29 | 1997-10-30 | Basf Ag | Molded parts made from thermoplastic molding compounds |
| FR2831546B1 (en) * | 2001-10-31 | 2007-03-23 | Atofina | THERMOPLASTIC POLYMER MATERIAL FOR AUDIO AND / OR OPTICAL INFORMATION RECORDING MEDIA |
| FR2833962A1 (en) * | 2001-12-21 | 2003-06-27 | Atofina | Discs for audio and/or optical data recording comprise two molded discs bonded together with an adhesive comprising methyl methacrylate and (meth)acrylic acid |
-
1971
- 1971-03-03 FR FR7107305A patent/FR2092389A5/fr not_active Expired
- 1971-03-04 BE BE763809A patent/BE763809A/en not_active IP Right Cessation
- 1971-04-06 DE DE19712116653 patent/DE2116653A1/en active Pending
- 1971-04-08 ZA ZA712265A patent/ZA712265B/en unknown
- 1971-04-12 BR BR2116/71A patent/BR7102116D0/en unknown
- 1971-04-12 IL IL36593A patent/IL36593A0/en unknown
- 1971-04-13 AU AU27591/71A patent/AU2759171A/en not_active Expired
- 1971-04-13 ES ES390495A patent/ES390495A1/en not_active Expired
- 1971-04-13 NL NL7104937A patent/NL7104937A/xx unknown
- 1971-04-19 GB GB2674171*A patent/GB1340025A/en not_active Expired
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2253689A1 (en) * | 1971-11-05 | 1973-05-10 | Rohm & Haas | THERMOPLASTIC PLASTIC COMPOUND |
| US4255308A (en) | 1979-07-12 | 1981-03-10 | E. I. Du Pont De Nemours And Company | Water based acrylic lacquer composition |
| EP0110123A1 (en) * | 1982-10-28 | 1984-06-13 | Mitsubishi Rayon Co., Ltd. | Delustering thermoplastic resin compostion |
| EP0143991A3 (en) * | 1983-11-02 | 1986-10-08 | Mitsubishi Rayon Co. Ltd. | Impact-resistant methacrylic resin composition |
| EP0182558A3 (en) * | 1984-11-12 | 1987-07-15 | Mitsubishi Rayon Co. Ltd. | Non-rigid vinyl chloride polymer resin composition |
| US7829610B2 (en) | 2002-08-19 | 2010-11-09 | Ticona Gmbh | Impact-resistant polyoxymethylene molding compositions, use thereof and moldings produced therefrom |
| WO2017213827A1 (en) | 2016-06-06 | 2017-12-14 | Baxter International Inc. | Methods of improving adhesion of non-di-(2-ethylhexyl)phthalate polyvinyl chloride to an acrylic- or abs-based polymer |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2759171A (en) | 1972-10-19 |
| DE2116653A1 (en) | 1971-10-28 |
| NL7104937A (en) | 1971-10-15 |
| ES390495A1 (en) | 1974-05-16 |
| FR2092389A5 (en) | 1972-01-21 |
| BR7102116D0 (en) | 1973-03-08 |
| ZA712265B (en) | 1972-05-31 |
| IL36593A0 (en) | 1971-06-23 |
| BE763809A (en) | 1971-09-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |