GB1235777A - Improvements in the production of alcohols - Google Patents
Improvements in the production of alcoholsInfo
- Publication number
- GB1235777A GB1235777A GB1977969A GB1977969A GB1235777A GB 1235777 A GB1235777 A GB 1235777A GB 1977969 A GB1977969 A GB 1977969A GB 1977969 A GB1977969 A GB 1977969A GB 1235777 A GB1235777 A GB 1235777A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alcohols
- boric acid
- oil layer
- hydrocarbons
- resulting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001298 alcohols Chemical class 0.000 title abstract 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 4
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 abstract 3
- 238000007254 oxidation reaction Methods 0.000 abstract 3
- 239000004327 boric acid Substances 0.000 abstract 2
- 150000001639 boron compounds Chemical class 0.000 abstract 2
- 230000003301 hydrolyzing effect Effects 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
- C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
1,235,777. Alcohols by oxidation of hydrocarbons. NIPPON SHOKUBAI KAGAKU KOGYO CO. Ltd. 17 April, 1969 [17 April, 1968], No. 19779/69. Heading C2C. A process for producing alcohols by liquid phase oxidation of aliphatic saturated hydrocarbons having 10-20 carbon atoms with a gas containing molecular oxygen in the presence of a boron compound, is improved by hydrolysing the oxidation reaction products to remove the resulting boric acid, saponifying and waterwashing the products, adding a boron compound to the resulting oil layer consisting predominantly of alcohols and unreacted hydrocarbons to convert the alcohols contained in the oil layer into their boric acid esters, distilling the oil layer to separate the unreacted hydrocarbons, hydrolysing the boric acid esters to remove the resulting boric acid and distilling the obtained oil layer to recover the alcohols.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP43025230A JPS4834571B1 (en) | 1968-04-17 | 1968-04-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1235777A true GB1235777A (en) | 1971-06-16 |
Family
ID=12160153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1977969A Expired GB1235777A (en) | 1968-04-17 | 1969-04-17 | Improvements in the production of alcohols |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS4834571B1 (en) |
| FR (1) | FR2006371A1 (en) |
| GB (1) | GB1235777A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114507117A (en) * | 2020-11-16 | 2022-05-17 | 株式会社日本触媒 | Process for producing secondary alcohol |
| CN114506853A (en) * | 2020-11-16 | 2022-05-17 | 株式会社日本触媒 | Method for producing metaboric acid, method for producing secondary alcohol using metaboric acid, and method for producing secondary alcohol |
| CN114507118A (en) * | 2020-11-16 | 2022-05-17 | 株式会社日本触媒 | Method for producing diol |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5584187U (en) * | 1979-12-21 | 1980-06-10 | ||
| JPS61882U (en) * | 1984-06-08 | 1986-01-07 | 福地農機株式会社 | Sorting machine |
| JPS61238378A (en) * | 1985-04-15 | 1986-10-23 | 田島 秀俊 | Fruit sorting method and apparatus |
| JP2021041321A (en) * | 2019-09-09 | 2021-03-18 | 株式会社日本触媒 | Extraction method of extraction object and liquid-liquid extraction column |
-
1968
- 1968-04-17 JP JP43025230A patent/JPS4834571B1/ja active Pending
-
1969
- 1969-04-17 FR FR6911932A patent/FR2006371A1/fr not_active Withdrawn
- 1969-04-17 GB GB1977969A patent/GB1235777A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114507117A (en) * | 2020-11-16 | 2022-05-17 | 株式会社日本触媒 | Process for producing secondary alcohol |
| CN114506853A (en) * | 2020-11-16 | 2022-05-17 | 株式会社日本触媒 | Method for producing metaboric acid, method for producing secondary alcohol using metaboric acid, and method for producing secondary alcohol |
| CN114507118A (en) * | 2020-11-16 | 2022-05-17 | 株式会社日本触媒 | Method for producing diol |
| CN114507118B (en) * | 2020-11-16 | 2025-08-05 | 株式会社日本触媒 | Method for producing diol |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4834571B1 (en) | 1973-10-22 |
| FR2006371A1 (en) | 1969-12-26 |
| DE1919593B2 (en) | 1973-01-18 |
| DE1919593A1 (en) | 1969-12-04 |
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