GB1235650A - Alkylhydroxythiolobenzoic acid esters and compositions stabilised thereby - Google Patents
Alkylhydroxythiolobenzoic acid esters and compositions stabilised therebyInfo
- Publication number
- GB1235650A GB1235650A GB2069870A GB2069870A GB1235650A GB 1235650 A GB1235650 A GB 1235650A GB 2069870 A GB2069870 A GB 2069870A GB 2069870 A GB2069870 A GB 2069870A GB 1235650 A GB1235650 A GB 1235650A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon atoms
- group
- alkyl group
- alkylhydroxythiolobenzoic
- acid esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 4
- 150000002148 esters Chemical class 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 11
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- HAQZWTGSNCDKTK-UHFFFAOYSA-N 2-(3-sulfanylpropanoyloxy)ethyl 3-sulfanylpropanoate Chemical compound SCCC(=O)OCCOC(=O)CCS HAQZWTGSNCDKTK-UHFFFAOYSA-N 0.000 abstract 1
- AXWKRUFUAGYTHB-UHFFFAOYSA-N 2-butylbenzenethiol Chemical group CCCCC1=CC=CC=C1S AXWKRUFUAGYTHB-UHFFFAOYSA-N 0.000 abstract 1
- ACBOBKJKSFYJML-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;2-sulfanylpropanoic acid Chemical compound CC(S)C(O)=O.CC(S)C(O)=O.CC(S)C(O)=O.CCC(CO)(CO)CO ACBOBKJKSFYJML-UHFFFAOYSA-N 0.000 abstract 1
- AIPCSKRJJOUNEM-UHFFFAOYSA-N 3,5-ditert-butyl-4-hydroxybenzoyl chloride Chemical compound CC(C)(C)C1=CC(C(Cl)=O)=CC(C(C)(C)C)=C1O AIPCSKRJJOUNEM-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- VDKDFKRKAPXHBH-UHFFFAOYSA-N [3-(2-sulfanylpropanoyloxy)-2,2-bis(2-sulfanylpropanoyloxymethyl)propyl] 2-sulfanylpropanoate Chemical compound CC(S)C(=O)OCC(COC(=O)C(C)S)(COC(=O)C(C)S)COC(=O)C(C)S VDKDFKRKAPXHBH-UHFFFAOYSA-N 0.000 abstract 1
- 125000006177 alkyl benzyl group Chemical group 0.000 abstract 1
- 125000005037 alkyl phenyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/38—Thiocarbonic acids; Derivatives thereof, e.g. xanthates ; i.e. compounds containing -X-C(=X)- groups, X being oxygen or sulfur, at least one X being sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C327/00—Thiocarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,235,650. Alkylhydroxythiolobenzoic acid esters. J. R. GEIGY A.G. 29 April, 1970, No. 20698/70. Heading C2C. [Also in Division C3] The invention relates to alkylhydroxythiolobenzoic acid esters of the general formula in which P is 1 to 4, R 1 is an alkyl group having 1 to 5 carbon atoms, R 2 is an alpha-branched alkyl group having 3 to 8 carbon atoms and the sum of the carbon atoms of R 1 and R 2 are at most 10 and, R is an alkyl group having 1 to 22 carbon atoms, a thia-alkyl group having 2 to 20 carbon atoms, the benzyl group, an alkylbenzyl group having 8 to 15 carbon atoms, the phenyl group, an alkylphenyl group having 7 to 14 carbon atoms, the groups wherein y is 1 to 6 and A is an alkyl group having 1 to 18 carbon atoms, an alkylene group having 2 to 14 carbon atoms, an alkanetriyl group having 3 to 14 carbon atoms or an alkanetetrayl group having 4 to 14 carbon atoms. The compounds may be prepared by reacting a mercaptan of the formula R-[SH] p with an equivalent amount of a dialkyl-hydroxybenzoyl chloride preferably in the presence of an acid binding agent such as pyridine and optionally an inert solvent such as benzene, xylene, toluene, &c. Many examples are given including the reaction of 3,5 - ditertiarybutyl - 4 - hydroxybenzoyl chloride with trimethylol propane-tris-(mercapto propionate), ethylene glycol bis-(mercapto propionate), pentaerythritol tetrakis-(mercapto propionate), dodecyl mercaptan, and 4 tertiary butyl thiophenol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2069870A GB1235650A (en) | 1970-04-29 | 1970-04-29 | Alkylhydroxythiolobenzoic acid esters and compositions stabilised thereby |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2069870A GB1235650A (en) | 1970-04-29 | 1970-04-29 | Alkylhydroxythiolobenzoic acid esters and compositions stabilised thereby |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1235650A true GB1235650A (en) | 1971-06-16 |
Family
ID=10150200
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2069870A Expired GB1235650A (en) | 1970-04-29 | 1970-04-29 | Alkylhydroxythiolobenzoic acid esters and compositions stabilised thereby |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1235650A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2165867A1 (en) * | 1971-11-15 | 1973-08-10 | Chevron Res | |
| EP0004762A3 (en) * | 1978-03-31 | 1979-10-31 | The B.F. GOODRICH Company | Diester and polymeric compositions containing it |
-
1970
- 1970-04-29 GB GB2069870A patent/GB1235650A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2165867A1 (en) * | 1971-11-15 | 1973-08-10 | Chevron Res | |
| EP0004762A3 (en) * | 1978-03-31 | 1979-10-31 | The B.F. GOODRICH Company | Diester and polymeric compositions containing it |
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