GB1208253A - Process for the treatment of black liquor - Google Patents
Process for the treatment of black liquorInfo
- Publication number
- GB1208253A GB1208253A GB5064/69A GB506469A GB1208253A GB 1208253 A GB1208253 A GB 1208253A GB 5064/69 A GB5064/69 A GB 5064/69A GB 506469 A GB506469 A GB 506469A GB 1208253 A GB1208253 A GB 1208253A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reactor
- black liquor
- flue gas
- air
- hot
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 4
- 239000007787 solid Substances 0.000 abstract 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 6
- 239000003546 flue gas Substances 0.000 abstract 5
- 239000012071 phase Substances 0.000 abstract 5
- 239000007789 gas Substances 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 239000003245 coal Substances 0.000 abstract 1
- 238000010276 construction Methods 0.000 abstract 1
- 239000006193 liquid solution Substances 0.000 abstract 1
- 239000003345 natural gas Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000004537 pulping Methods 0.000 abstract 1
- 238000005201 scrubbing Methods 0.000 abstract 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 abstract 1
- 239000007790 solid phase Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C11/00—Regeneration of pulp liquors or effluent waste waters
- D21C11/10—Concentrating spent liquor by evaporation
- D21C11/103—Evaporation by direct contact with gases, e.g. hot flue gases
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S159/00—Concentrating evaporators
- Y10S159/03—Fluidized bed
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/03—Papermaking liquor
Landscapes
- Paper (AREA)
Abstract
1,208,253. Salts from black liquor. CHEMICAL CONSTRUCTION CORP. 29 Jan., 1969 [8 Feb., 1968], No. 5064/69. Heading C1A. [Also in Division D2] A process for the treatment of black liquor comprises concentrating the weak black liquor by contact with hot air; reacting the product with excess air at elevated temperature, giving a solids phase containing sulphate, and a hot flue gas; using the flue gas to heat the air passing to the concentration step by indirect heat exchange; reducing the solids phase with a reducing agent at an elevated temperature, to give a reduced solids phase containing sodium sulphide, and a hot residual gas; and dissolving the reduced solids phase in an aqueous liquid to form green liquor for recycle. The weak black liquor, preferably of 10-20% solids content, which may be oxidized or unoxidized, is passed to an evaporator unit which may comprise one or more evaporators where the liquid is contacted with hot air in, e.g. a Venturi contactor, a centrifugal or cascade type evaporator. The moist gas exiting from the contactor unit may be discharged direct to the atmosphere. The concentrated solution is then passed to a reactor, preferably a fluidized bed reactor, while some of this stream may be recycled to the contactor entry. The concentrated solution is reacted at high temperature with process air, giving a solids phase and a hot flue gas. The hot flue gas is used to preheat the air used in the evaporators, and then may be discharged to the atmosphere, after a scrubbing with an aqueous liquid solution to remove solid salt particles. The solid from the reactor is then passed to second reactor, where it is reduced, e.g. by carbon monoxide, natural gas, powdered coal or a limited amount of the concentrated black liquor stream. The reduced solid phase is then dissolved, and recycled to the pulping process. The off-gas from the second reactor may be combined with the hot flue gas before passage through the heat exchange. Water may be passed in heat exchange with the first reactor contents to raise steam.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US70405468A | 1968-02-08 | 1968-02-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1208253A true GB1208253A (en) | 1970-10-14 |
Family
ID=24827869
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5064/69A Expired GB1208253A (en) | 1968-02-08 | 1969-01-29 | Process for the treatment of black liquor |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US3574051A (en) |
| GB (1) | GB1208253A (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2076611A5 (en) * | 1970-01-20 | 1971-10-15 | Babcock Atlantique Sa | IMPROVEMENTS TO DIRECT EVAPORATORS TO AIR SUPPLIED WITH HEAT BY A BOILER |
| US3789902A (en) * | 1971-06-18 | 1974-02-05 | Chemical Construction Corp | Method for concentrating dilute acidic solutions |
| SE378119B (en) * | 1972-04-04 | 1975-08-18 | Angpanneforeningen | |
| CA995521A (en) * | 1972-08-09 | 1976-08-24 | Donald E. Helleur | Method and apparatus for removing volatile fluids |
| US3870585A (en) * | 1973-02-15 | 1975-03-11 | Pureco Systems Inc | Apparatus and method for evaporative concentration of aqueous solutions and slurries |
| US4135968A (en) * | 1976-04-09 | 1979-01-23 | Weyerhaeuser Company | Spent liquor treatment |
| US4303469A (en) * | 1980-04-14 | 1981-12-01 | International Paper Company | Process and apparatus for recovery of spent pulping liquors |
| US4522685A (en) * | 1983-01-17 | 1985-06-11 | International Paper Company | Method of operating a spent pulping liquor combustion apparatus |
| SE452995B (en) * | 1985-03-08 | 1988-01-04 | Asea Ab | REGULATION OF LUTATE RECOVERY Aggregates |
| CA1313577C (en) * | 1988-11-17 | 1993-02-16 | Jian Li | Low temperature recovery of kraft black liquor |
| US4979448A (en) * | 1990-01-08 | 1990-12-25 | International Paper Company | Apparatus and method for recovery of constituents and heat from fluidized bed combustion |
| US5012750A (en) * | 1990-01-08 | 1991-05-07 | International Paper Company | Apparatus for recovery of constituents and heat from fluidized bed combustion |
| US5246542A (en) * | 1991-09-18 | 1993-09-21 | Fosberg Theodore M | Evaporation and recovery process for bleached chemical thermo-mechanical pulp (BCTMP) effluent |
| TW245651B (en) * | 1994-02-24 | 1995-04-21 | Babcock & Wilcox Co | Black liquor gasifier |
| ITMI20111599A1 (en) * | 2011-09-06 | 2013-03-07 | Agroittica Acqua & Sole Spa | PROCEDURE AND PLANT FOR THE TREATMENT OF THE PERCOLATE FROM WASTE STORAGE |
-
1968
- 1968-02-08 US US704054A patent/US3574051A/en not_active Expired - Lifetime
-
1969
- 1969-01-29 GB GB5064/69A patent/GB1208253A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US3574051A (en) | 1971-04-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |