GB1298159A - Manufacture of phosphorus pentafluoride - Google Patents
Manufacture of phosphorus pentafluorideInfo
- Publication number
- GB1298159A GB1298159A GB01526/70A GB1152670A GB1298159A GB 1298159 A GB1298159 A GB 1298159A GB 01526/70 A GB01526/70 A GB 01526/70A GB 1152670 A GB1152670 A GB 1152670A GB 1298159 A GB1298159 A GB 1298159A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reaction
- pof
- acid
- heating
- fluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- OBCUTHMOOONNBS-UHFFFAOYSA-N phosphorus pentafluoride Chemical compound FP(F)(F)(F)F OBCUTHMOOONNBS-UHFFFAOYSA-N 0.000 title 1
- 238000010438 heat treatment Methods 0.000 abstract 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 abstract 2
- FFUQCRZBKUBHQT-UHFFFAOYSA-N phosphoryl fluoride Chemical compound FP(F)(F)=O FFUQCRZBKUBHQT-UHFFFAOYSA-N 0.000 abstract 2
- PNGLEYLFMHGIQO-UHFFFAOYSA-M sodium;3-(n-ethyl-3-methoxyanilino)-2-hydroxypropane-1-sulfonate;dihydrate Chemical compound O.O.[Na+].[O-]S(=O)(=O)CC(O)CN(CC)C1=CC=CC(OC)=C1 PNGLEYLFMHGIQO-UHFFFAOYSA-M 0.000 abstract 2
- 238000010792 warming Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000012024 dehydrating agents Substances 0.000 abstract 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000005086 pumping Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/10—Halides or oxyhalides of phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
Abstract
1298159 Phosphorous pentafluoride USS ENGS & CONSULTANTS Inc 10 March 1970 11526/70 Heading C1A Phosphorous pentafluoride is produced by the reaction of phosphoryl fluoride with hydrogen fluoride. The PFs is vaporized and condensed and hexafluorophosphoric acid, formed by the reaction of water, phosphoryl fluoride and hydrogen fluoride is further treated by warming with a dehydrating agent to liberate a further quantity of phosphorous pentafluoride. The initial reaction of HF and POF 3 is preferably carried out by mixing the reagents in the cold, warming to room temperature, and heating in the range 60-80‹ C., or by pumping POF 3 into a reactor containing HF and carrying out the reaction in the range 10-100‹ C. It is preferred to use 2-4 moles of HF per mole of POF 3 . The removal of water from hexafluorophosphoric acid may be achieved by heating under pressure with SO 3 , pyrosulphuric acid or fluorosulphuric acid, preferably by cooling to - 196‹ C. before mixing and heating.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB01526/70A GB1298159A (en) | 1970-03-10 | 1970-03-10 | Manufacture of phosphorus pentafluoride |
| FR7009646A FR2082502A5 (en) | 1970-03-10 | 1970-03-18 | |
| DE19702013858 DE2013858A1 (en) | 1970-03-10 | 1970-03-23 | Manufacture of phosphorus pentafluoride |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB01526/70A GB1298159A (en) | 1970-03-10 | 1970-03-10 | Manufacture of phosphorus pentafluoride |
| FR7009646A FR2082502A5 (en) | 1970-03-10 | 1970-03-18 | |
| DE19702013858 DE2013858A1 (en) | 1970-03-10 | 1970-03-23 | Manufacture of phosphorus pentafluoride |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1298159A true GB1298159A (en) | 1972-11-29 |
Family
ID=27182490
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB01526/70A Expired GB1298159A (en) | 1970-03-10 | 1970-03-10 | Manufacture of phosphorus pentafluoride |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE2013858A1 (en) |
| FR (1) | FR2082502A5 (en) |
| GB (1) | GB1298159A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1394108A1 (en) * | 2002-08-19 | 2004-03-03 | Lithdyne LLC | Preparation of hexafluorophosphoric acid |
| US8470278B2 (en) | 2008-08-08 | 2013-06-25 | Stella Chemifa Corporation | Processes for production of phosphorus pentafluoride and hexafluorophosphates |
| US9034290B2 (en) | 2007-08-16 | 2015-05-19 | Stella Chemifa Corporation | Processes for producing phosphorus pentafluoride and phosphate hexafluoride |
| CN115106022A (en) * | 2022-06-20 | 2022-09-27 | 江苏九九久科技有限公司 | High-safety phosphorus pentafluoride generator for controlling reaction process by utilizing thermal deformation |
| CN115784181A (en) * | 2022-11-22 | 2023-03-14 | 福建省德旭新材料有限公司 | Continuous reaction rectification preparation system of phosphorus pentafluoride and preparation thereof |
| CN120246946A (en) * | 2025-06-03 | 2025-07-04 | 池州天赐高新材料有限公司 | A method for efficiently synthesizing phosphorus pentafluoride using phosphoric acid and hydrogen fluoride |
| CN120246947A (en) * | 2025-06-03 | 2025-07-04 | 池州天赐高新材料有限公司 | Method and system for preparing phosphorus pentafluoride by continuous reaction using tubular reactor |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5254555B2 (en) | 2007-02-08 | 2013-08-07 | ステラケミファ株式会社 | Method for producing phosphorus pentafluoride and hexafluorophosphate |
| CN120057872B (en) * | 2025-04-29 | 2025-07-15 | 池州天赐高新材料有限公司 | A method for synthesizing phosphorus pentafluoride using difluorophosphoric acid as raw material |
-
1970
- 1970-03-10 GB GB01526/70A patent/GB1298159A/en not_active Expired
- 1970-03-18 FR FR7009646A patent/FR2082502A5/fr not_active Expired
- 1970-03-23 DE DE19702013858 patent/DE2013858A1/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1394108A1 (en) * | 2002-08-19 | 2004-03-03 | Lithdyne LLC | Preparation of hexafluorophosphoric acid |
| US9034290B2 (en) | 2007-08-16 | 2015-05-19 | Stella Chemifa Corporation | Processes for producing phosphorus pentafluoride and phosphate hexafluoride |
| US8470278B2 (en) | 2008-08-08 | 2013-06-25 | Stella Chemifa Corporation | Processes for production of phosphorus pentafluoride and hexafluorophosphates |
| CN115106022A (en) * | 2022-06-20 | 2022-09-27 | 江苏九九久科技有限公司 | High-safety phosphorus pentafluoride generator for controlling reaction process by utilizing thermal deformation |
| CN115784181A (en) * | 2022-11-22 | 2023-03-14 | 福建省德旭新材料有限公司 | Continuous reaction rectification preparation system of phosphorus pentafluoride and preparation thereof |
| CN115784181B (en) * | 2022-11-22 | 2023-09-22 | 福建省德旭新材料有限公司 | Continuous reactive distillation preparation system and preparation method of phosphorus pentafluoride |
| CN120246946A (en) * | 2025-06-03 | 2025-07-04 | 池州天赐高新材料有限公司 | A method for efficiently synthesizing phosphorus pentafluoride using phosphoric acid and hydrogen fluoride |
| CN120246947A (en) * | 2025-06-03 | 2025-07-04 | 池州天赐高新材料有限公司 | Method and system for preparing phosphorus pentafluoride by continuous reaction using tubular reactor |
| CN120246947B (en) * | 2025-06-03 | 2025-09-05 | 池州天赐高新材料有限公司 | Method and system for preparing phosphorus pentafluoride by continuous reaction using a tubular reactor |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2082502A5 (en) | 1971-12-10 |
| DE2013858A1 (en) | 1971-10-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |